Geochemistry,petrogenesis and tectonic setting of Neoproterozoic mafic–ultramafic rocks from the western Jiangnan orogen,South China

The Jiangnan orogenic belt (JOB) has been interpreted as a suture zone between the Yangtze craton and Cathaysian terranes in South China. The Neoproterozoic mafic–ultramafic rocks are extensively exposed in the western JOB, providing an ideal opportunity to study the Neoproterozoic assembly and tectonic evolution of South China. We present integrated field and geochemical studies including LA-ICP-MS zircon U–Pb dating, and whole-rock major and trace element and Sm–Nd isotope analyses of the Neoproterozoic mafic–ultramafic rocks exposed in the northern Guangxi Province, South China. Geochronological results show that the magmatic events took place in two distinct periods: the early Neoproterozoic (861–834 Ma) and the late Neoproterozoic (770–750 Ma). Early Neoproterozoic ultramafic rocks of the Sibao Group have positive ε_Nd(t) values (+ 2.7 to + 6.6) whereas mafic rocks exhibit negative ε_Nd(t) values (− 5.8 to − 0.9). The basaltic rocks show TiO₂ contents of 0.62–0.69 wt.% and Mg-number of 59–65, and also display an enrichment of light rare earth elements (LREEs) and pronounced negative Nb, Ta and Ti anomalies on chondrite- and primitive mantle-normalized diagrams, consistent with subduction-related geochemical signatures. Late Neoproterozoic rocks of the Danzhou Group show ε_Nd(t) values (− 1.23 to + 3.19) for both ultramafic and mafic rocks. The basaltic rocks have TiO₂ contents of 1.01–1.33 wt.% and Mg-number of 57–60, and have a mixture of MORB- and arc-like geochemical affinities, inferred to have formed in an extensional arc environment. Geochemical signatures suggest that all rock types in this study were derived from subarc mantle wedge sources and underwent various degrees of crustal contamination. Thus, we suggest that subduction may have continued to ca. 750 Ma in the western JOB, implying that the amalgamation event between the Yangtze craton and Cathaysian terranes was later than 750 Ma.     

Age and nature of the Jurassic–Early Cretaceous mafic and ultramafic rocks from the Yilashan area,Bangong–Nujiang suture zone,central Tibet: implications for petrogenesis and tectonic Evolution

The Jurassic–Early Cretaceous Yilashan mafic–ultramafic complex is located in the middle part of the Bangong–Nujiang suture zone, central Tibet. It features a mantle sequence composed of peridotites and a crustal sequence composed of cumulate peridotites and gabbros that are intruded by diabases with some basalts. This article presents new whole-rock geochemical and geochronological data for peridotites, gabbros, diabases and basalts to revisit the petrogenesis and tectonic setting of the Yilashan mafic–ultramafic complex. Zircon laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) U–Pb ages of three diabase samples are 169.6 ± 3.3 Ma, 132.5 ± 2.5 Ma, and 133.6 ± 4.9 Ma, respectively. These ages together with previous studies indicate that the Yilashan mafic–ultramafic complex probably formed during the Jurassic–Early Cretaceous. The peridotites exhibit nearly U-shaped REE patterns and are distinct from abyssal peridotites. The diabase and basalt samples show arc features with selective enrichment in light rare earth elements (LREE) and large ion lithophile elements (LILEs; e.g. Rb, U, and Sr) and depletion in high field strength elements (HFSEs; e.g. Nb, Ta, and Ti). The gabbro samples display cumulate features with selective enrichment in LILEs (e.g. Rb, Ba, and Sr) but depletion in LREEs and HFSEs (e.g. Nb, Zr, and Ti). Combing the positive ε_Nd(t) values (+6.1 to +10.0) and negative zircon ε_Hf(t) values (–16.5 to –11.7 and –13.6 to –0.4) with older Hf model ages for the mafic rocks, these signatures suggest that the Yilashan mafic and ultramafic rocks likely originated from an ancient lithospheric mantle source with the addition of asthenospheric mantle materials and subducted fluids coupled with limited crustal contamination in a continental arc setting as a result of the southward subduction of the Bangong–Nujiang Tethys Ocean beneath the Lhasa terrane during the Jurassic–Early Cretaceous.     

Petrogenesis of the Xuanwoling mafic–ultramafic intrusion in the northeastern Tarim Block(Northwest China)

Beishan Terrane, located in the northeast of the Tarim Block, in northwest China, has developed a 500-km long and 100-km wide belt of Permian mafic–ultramafic intrusions One of these mafic–ultramafic intrusions, the Xuanwoling Intrusion, is composed of dunite, troctolite, olivine gabbros and gabbros, with cumulate texture and rhythmic layering The crystallization sequence is olivine ? spinel ? plagio clase ? pyroxene, indicating that the crystallization pressure is lower than 0.5–0.8 GPa and that the intrusion has undergone variable degrees of crustal contamination, increasing from dunite to gabbros. The olivines found in the Xuanwoling Intrusion have high Fo values(up to 90), suggesting a primary magma with a high composition of mg. It is likely that this high-mg magma was produced at extremely high temperatures(1,330–1,350 °C), and as a result, Nd–Sr isotopic compositions similar to oceanic island basalts are found in the Xuanwoling Intrusion, which we propose arose from the mantle plume.     

Geochemical constraints on the origin of the Permian Baimazhai mafic–ultramafic intrusion,SW China

The ∼260 Ma Baimazhai mafic–ultramafic intrusion is considered to be part of the Emeishan large igneous province and consists of orthopyroxenite surrounded by websterite and gabbro. The intrusion is variably mineralized with a massive sulfide ore body (∼20 vol.%) in the core of the intrusion. Silicate rocks have Ni/Cu ratios ranging from 0.3 to 46 with majority less than 7 and are rich in LREE relative to HREE and show Nb and Ta anomalies in primitive mantle-normalized trace element patterns, with low Nb/Th (1.0–4.5) and Nb/La (0.3–1.0) ratios. Their ɛ Nd(t) values range from −3.3 to −8.4. Uniform Pd/Pt (0.7–3.5) and Cu/Pd (100,000–400,000) ratios throughout the intrusion indicate that all the sulfides in the rocks were formed in a single sulfide-saturation event. Modeling suggests that the Baimazhai rocks were formed when an Mg-rich magma became crustally contaminated in a deep-seated staging chamber. Crustal contamination (up to ∼35%) drove the magma to S-saturation and forced orthopyroxene (Opx) onto the liquidus. The crystal-bearing magma forced out of the staging chamber was migrated by flow differentiation and consequently, the denser sulfide melt and the Opx crystals became centrally disposed in the flowing magma to form the Baimazhai intrusion.Electronic Supplementary Material Supplementary material is available to authorised users in the online version of this article at .     

Petrogenesis and tectonic implications of early Devonian mafic dike–granite association in the northern West Junggar,NW China

Mafic dike–granite associations are common in extensional tectonic settings and important and pivotal in reconstructing crust–mantle geodynamic processes. We report results of zircon U–Pb and hornblende ⁴⁰Ar-³⁹Ar ages and major-element and trace-element data for mafic dike–granite association from the northern West Junggar, in order to constrain their ages, petrogenesis, and geodynamic process. The mafic dike–granite association was emplaced in the early Devonian. The Xiemisitai monzogranites have high SiO₂ contents and low MgO, Cr, and Ni concentrations, suggesting that they were mainly derived from crustal sources and were probably generated by partial melt of the juvenile mid-lower crust. The mafic dikes have low Mg^# and Cr and Ni abundances, suggesting that they have experienced significant fractional crystallization. The Xiemisitai mafic dikes contain hornblende and biotite and display negative Nb–Ta–Ti anomalies, enrichment of LREEs and LILEs, and depletion of HREEs and HFSEs, consistent with an origin from a lithospheric mantle metasomatized by subducted slab-derived fluids. In addition, the Xiemisitai mafic dikes are plotted within melting trends with little to no garnet (Cpx: Grt = 6:1) in their source. The La/Yb versus Tb/Yb plot also indicates the presence of less than 1% residual garnet in the source region for the Xiemisitai mafic dikes. Therefore, it can be inferred that the Xiemisitai mafic dikes were generated at a correspondingly shallow depth, mostly within the spinel stability field. The Xiemisitai mafic dikes were most probably generated by the partial melting of the metasomatized lithospheric mantle at relatively shallow depths (<80 km). The Xiemisitai mafic dike–granite association could have been triggered by asthenospheric upwelling as a result of the rollback of the subducted Irtysh–Zaysan oceanic lithosphere.     

Keketuohai mafic–ultramafic complex in the Chinese Altai,NW China: Petrogenesis and geodynamic significance

Devonian magmatism was very intensive in the tectonic evolutionary history of the Chinese Altai, a key part of the Central Asian Orogenic Belt (CAOB). The Devonian Keketuohai mafic–ultramafic complex in the Chinese Altai is a zoned intrusion consisting of dunite, olivine gabbro, hornblende gabbro and pyroxene diorite. The pyroxene diorite gives a zircon U–Pb age of 409 ± 5 Ma. Variations in mineral assemblage and chemical composition suggest that the petrogenesis of the Keketuohai Complex was chiefly governed by fractional crystallization from a common magma chamber. Low SiO₂, K₂O and Na₂O contents, negative covariations between P₂O₅, TiO₂ and Mg# value suggest insignificant crustal assimilation/contamination. Thus the positive ε_Nd(t) values (0 to + 2.7) and slight enrichments in light rare earth elements (e.g., La/Yb_N = 0.98–3.64) suggest that their parental magma was possibly produced by partial melting of the lithospheric mantle. Model calculation suggests that their parental magma was high-Mg (Mg# = 66) tholeiitic basaltic melt. The Keketuohai intrusion was coeval with diverse magmatism, high temperature metamorphism and hydrothermal mineralization, which support a previously proposed model that ridge subduction most likely played an important role in the tectonic evolution of the Chinese Altai.     

40Ar–39Ar age and geochemistry of subduction-related mafic dikes in northern Tibet,China: petrogenesis and tectonic implications

The early Permian Xiaomiao mafic dike swarm in the East Kunlun orogenic belt (EKOB) provides an excellent opportunity to study the petrogenesis of such swarms developed in supra-subduction zone environments, and to investigate the early plate tectonic history of the Palaeo-Tethyan Ocean. Hornblende ⁴⁰Ar–³⁹Ar dating results indicate that the mafic dikes formed in the early Permian (277.76 ± 2.72 Ma). The Xiaomiao mafic hypabyssals have the following compositional range: SiO₂ = 46.55–55.75%, MgO = 2.80–7.38%, Mg^# = 36–61, and (Na₂O + K₂O) = 2.87–4.95%. Chemically, they display calc-alkali affinities, ranging in composition from gabbro to gabbroic diorite. All analysed dikes are enriched in light rare earth elements and large-ion lithophile elements (e.g. Rb and Ba), but are depleted in heavy rare earth elements and high field strength elements (e.g. Nb, Ta, and Ti). Their I_Sr and ?_Nd(t) values range from 0.707 to 0.715 and –2.60 to +2.91, respectively. They are geochemically similar to subduction-related basaltic rocks (e.g. island arc basalt), but differ from E-MORB and N-MORB. Petrographic and major element data reveal that fractional crystallizations of clinopyroxene, olivine, hornblende, and Fe–Ti oxides may have occurred during magma evolution, but that crustal contamination was minor. Based on geochemical and Sr–Nd isotopic bulk-rock compositions, we suggest that the mafic dikes were likely generated by 10–20% partial melting of a spinel + minor garnet lherzolite mantle source metasomatized by subducted, slab-derived fluids, and minor sediments. Based on our results, we propose that the early evolution of the Palaeo-Tethyan Ocean involved the spreading and initial subduction of the Carboniferous to early Permian ocean basin followed by late Permian subduction, which generated the magmatic arc.     

The Early Permian mafic–ultramafic complexes in the Beishan Terrane,NW China: Alaskan-type intrusives or rift cumulates?

The petrogenesis and geodynamic setting of the Early Permian mafic–ultramafic complexes in the Beishan Terrane, NW China have important bearing on the prospects of Ni–Cu–PGE sulfide and Ti–Fe oxide deposits, as well as in understanding the history of evolution of the southern Central Asian Orogenic Belt (CAOB). Here we present results from a detailed study on a representative suit of a mafic–ultramafic rocks from the Bijiashan complex in the Beishan Terrane. The complex is composed of dunite, troctolite, olivine gabbro and gabbro without clinopyroxenite or hornblendite. In addition to olivine and clinopyroxene, orthopyroxene and plagioclase are also present in all these rock types, in the absence of chromite or primary hornblende. The minerals display marked compositional variations with the Fo content in olivines ranging from 66 to 83 and the clinopyroxenes ranging from diopside to augite. The whole-rock geochemistry shows good correlations among the major elements, and the trace elements are characterized by flat REE patterns with Eu positive anomalies, and HFSE depletion relative to LILE. These features are comparable to other mafic–ultramafic complexes in the Beishan and Eastern Tianshan terranes, but obviously deviate from the typical features of Alaskan-type intrusives. The present study suggests that the Beishan complexes were formed in a post-orogenic extensional environment with potential for Ni–Cu mineralization, rather than in arc-related setting with Alaskan-type PGE mineralization. Our study confirms that the Beishan area does not conform to an arc-related setting, but was located within a rift setting in Permian probably related to Permian mantle plume event, suggesting that the subduction of the Paleo-Asian ocean had culminated by this time, and the southern CAOB witnessed a post-orogenic extensional regime in late Paleozoic.     

Geochronology and geochemistry of the Niujuanzi ophiolitic mélange,Gansu Province,NW China: implications for tectonic evolution of the Beishan Orogenic Collage

International Journal of Earth Sciences - The Niujuanzi ophiolitic mélange (NOM), located in the Beishan Orogenic Collage, marks the termination between the Huaniushan arc and Mingshui-Hanshan...     

Geochronology,petrogenesis and tectonic implications of the Jurassic Namco–Renco ophiolites,Tibet

The nature of the Namco–Renco ophiolites in the northern Lhasa subterrane is widely disputed. To investigate their formation age, petrogenesis, and tectonic setting, the harzburgites, basalts, and metagabbros of the Namco ophiolite and the harzburgites, lherzolites, gabbros, and diabasic dikes of the Renco ophiolite were selected for whole-rock geochemical and zircon U-Pb dating and in situ Lu-Hf isotopic analyses. The geochemical and geochronological data indicate that the Namco metagabbros were generated at 178.0 ± 2.9 Ma, along with the Namco–Renco peridotites formed in the initial stage of a continental margin basin; whereas the Renco gabbros were developed at 149.7 ± 1.6 Ma, along with the Renco diabasic dikes and Namco basalts formed later in a mature back-arc basin. The Namco–Renco ophiolites were derived from a depleted mantle source with involvement of minor older crustal materials. Combined with the regional geological background, the Namco–Renco ophiolites were likely formed mainly associated with the southward subduction of the Bangong–Nujiang oceanic lithosphere beneath the Lhasa terrane. This study provides new constraints on the formation ages of the Namco–Renco ophiolites and the tectonic evolution of the Namco–Renco Ocean.     

Early Permian East-Ujimqin mafic–ultramafic and granitic rocks from the Xing’an–Mongolian Orogenic Belt,North China: Origin,chronology, and tectonic implications

The East-Ujimqin complex, located north of the Erenhot–Hegenshan fault, North China, is composed of mafic–ultramafic and granitic rocks including peridotite, gabbro, alkali granite, and syenite. We investigated the tectonic setting, age, and anorogenic characteristics of the Xing’an–Mongolian Orogenic Belt (XMOB) through field investigation and microscopic and geochemical analyses of samples from the East-Ujimqin complex and LA-MC-ICP-MS zircon U–Pb dating of gabbro and alkali granite. Petrographic and geochemical studies of the complex indicate that this multiphase plutonic suite developed through a combination of fractional crystallization, assimilation processes, and magma mixing. The mafic–ultramafic rocks are alkaline and have within-plate geochemical characteristics, indicating anorogenic magmatism in an extensional setting and derivation from a mantle source. The mafic–ultramafic magmas triggered partial melting of the crust and generated the granitic rocks. The granitic rocks are alkali and metaluminous and have high Fe/(Fe + Mg) characteristics, all of which are common features of within-plate plutons. Zircon U–Pb geochronological dating of two samples of gabbro and alkali granite yielded ages of 280.8 ± 1.5 and 276.4 ± 0.7 Ma, placing them within the Early Permian. The zircon Hf isotopic data give inhomogeneous ε_Hf(t) values of 8.2–14.7 for gabbroic zircons and extraordinary high ε_Hf(t) values (8.9–12.5) for the alkali granite in magmatic zircons. Thus, we consider the East-Ujimqin mafic–ultramafic and granitic rocks to have been formed in an extensional tectonic setting caused by asthenospheric upwelling and lithospheric thinning. The sources of mafic–ultramafic and granitic rocks could be depleted garnet lherzolite mantle and juvenile continental lower crust, respectively. All the above indicate that an anorogenic magma event may have occurred in part of the XMOB during 280–276 Ma.     

Zircon U–Pb geochronology and geochemistry of the post-collisional volcanic rocks in eastern Xinjiang Province,NW China: implications for the tectonic evolution of the Junggar terrane

We report zircon U–Pb geochronologic and geochemical data for the post-collisional volcanic rocks from the Batamayineishan (BS) Formation in the Shuangjingzi area, northwestern China. The zircon U–Pb ages of seven volcanic samples from the BS Formation show that the magmatic activity in the study area occurred during 342–304 Ma in the Carboniferous. The ages also indicate that the Palaeo-Karamaili Ocean had already closed by 342 Ma. Moreover, the volcanic rocks also contained 10 inherited zircons with ages ranging from 565 to 2626 Ma, indicating that Precambrian continental crust or microcontinents with accretionary arcs are two possible interpretations for the basement underlying the East Junggar terrane. The sampled mafic-intermediate rocks belong to the medium-K to high-K calc-alkaline and shoshonitic series, and the formation of these rocks involved fractional crystallization with little crustal contamination. These Carboniferous mafic-intermediate rocks show depletions in Nb and Ta and enrichments in large ion lithophile elements (e.g. Rb, Ba, U, and Th) and light rare earth elements. The low initial ⁸⁷Sr/⁸⁶Sr values (0.7034–0.7042) and positive ε_Nd(t) values (+2.63 to +6.46) of these rocks suggest that they formed from depleted mantle material. The mafic-intermediate rocks were most likely generated by 5–10% partial melting of a mantle source composed primarily of spinel lherzolite with minor garnet lherzolite that had been metasomatized by slab-derived fluids and minor slab melts. In contrast, the felsic rocks in the BS Formation are A-type rhyolites with positive ε_Nd(t) values and young model ages. These rocks are interpreted to be derived from the partial melting of juvenile basaltic lower crustal material. Taken together, the mafic-intermediate rocks formed in a post-collisional extensional setting generated by slap breakoff in the early Carboniferous (342–330 Ma) and the A-type rhyolites formed in a post-collisional extensional setting triggered by the upwelling asthenosphere in the late Carboniferous (330–304 Ma).     

Geochemical and Hf isotopic compositions of Late Triassic–Early Jurassic intrusions of the Erguna Block,Northeast China: petrogenesis and tectonic implications

Late Triassic–Early Jurassic intrusions of the Erguna Block, Northeast China, are located along the southern margin of the Mongol–Okhotsk orogenic belt. They comprise granodiorite, monzogranite, syenogranite, and lesser gabbro–diorite, of adakitic and calc­alkaline affinity. The adakite-like and calc­alkaline granites share similar light rare earth elements (LREE) characteristics; however, their heavy rare earth elements (HREE) trends differ from one another. The relative abundances of HREE in the calc­alkaline granites are relatively consistent and are similar to those of intrusive rocks formed from dehydration melting of garnet-free amphibolitic source rocks at relatively low pressures. In contrast, the adakite-like granites show more prominent HREE fractionation trends, indicating that they crystallized at higher pressures, where garnet in the source rocks was stable. At least two isotopically distinct sources were involved in the petrogenesis of the granites, but the extent to which they contributed varies between plutons. Most intrusions have incorporated an isotopically primitive component, possibly juvenile mafic crust. The other sources include a small proportion of old continental crustal material and isotopically evolved wall rocks. The gabbro–diorites have high MgO contents (>7 wt.%), a high Mg^# (>0.6), and show moderate LREE and HREE fractionation, indicating they formed from the melting of subducted metasomatized lithospheric mantle. All of the intrusions in the study area are characterized by a relative enrichment in large ion lithophile elements (LILE) and depletion in high field strength elements (HFSE), indicating they were emplaced in an Andean-type active continental margin setting related to southward subduction of the Mongol–Okhotsk oceanic plate.     

Petrogenesis of the Wudaogou intermediate–mafic complex,NW China: zircon U–Pb dating,whole-rock and isotope geochemistry,and geological implications

The Wudaogou plutonic complex is located in the eastern Yanbian area of Jilin Province and consists of hornblende gabbros, gabbroic diorites, and quartz diorites that contain abundant dioritic microgranular xenoliths. Zircon U–Pb dating of gabbroic and quartz diorites yielded weighted mean ²⁰⁶Pb/²³⁸Pb ages of 263.5 ± 5.1 Ma (N = 12, mean squared weighted deviation (MSWD) = 0.78, probability = 0.66) and 262.0 ± 5.6 Ma (N = 10, MSWD = 0.50, probability = 0.87), respectively. These units are characterized by high Na₂O/K₂O (0.33–0.77) ratios and Al₂O₃ (15.05–18.91 wt%) concentrations and are large ion lithophile element (LILE) (light rare earth element (LREE), Rb, Ba, K, etc.) enriched and high field strength element (HFSE) (Nb, Ta, P, Ti) depleted. They also have initial ⁸⁷Sr/⁸⁶Sr values of 0.70192–0.70420 and ?_Nd(t) values of +1.9 to +4.7 with two-stage model ages (T_DM2) of 653–878 Ma. These characteristics indicate that these rocks formed from calc–alkaline magmas derived from partial melting of a mixture of juvenile crust formed attending the Neoproterozoic subduction of the Palaeo-Asian oceanic crust and lower crustal material. The dioritic xenoliths have whole-rock compositions that are similar to their host rocks, but with negative ?_Nd(t) values (?1.6 to ?4.3) and older T_DM2 ages (1166–1382 Ma), further indicating that this magmatic event involved older crustal material. Combining these data with existing knowledge of the crustal evolution of this area, we conclude that this complex formed in a post-collisional extensional setting during closure of the Palaeo-Asian Ocean.     

Mineralogical,petrological, and geochemical studies of the Limahe mafic–ultramatic intrusion and associated Ni–Cu sulfide ores,SW China

The Limahe Ni–Cu sulfide deposit is hosted by a small mafic–ultramafic intrusion (800 × 200 × 300 m) that is temporally associated with the voluminous Permian flood basalts in SW China. The objective of this study is to better understand the origin of the deposit in the context of regional magmatism which is important for the ongoing mineral exploration in the region. The Limahe intrusion is a multiphase intrusion with an ultramafic unit at the base and a mafic unit at the top. The two rock units have intrusive contacts and exhibit similar mantle-normalized trace element patterns and Sr–Nd isotopic compositions but significantly different cumulus mineralogy and major element compositions. The similarities suggest that they are related to a common parental liquid, whereas the differences point to magma differentiation by olivine crystallization at depth. Sulfide mineralization is restricted to the ultramafic unit. The abundances of sulfides in the ultramafic unit generally increase towards the basal contacts with sedimentary footwall. The δ ³⁴S values of sulfide minerals from the Limahe deposit are elevated, ranging from +2.4 to +5.4‰. These values suggest the involvement of external S with elevated δ ³⁴S values. The mantle-normalized platinum-group element (PGE) patterns of bulk sulfide ores are similar to those of picrites associated with flood basalts in the region. The abundances of PGE in the sulfide ores, however, are significantly lower than that of sulfide liquid expected to segregate from undepleted picrite magma. Cr-spinel and olivine are present in the Limahe ultramafic rocks as well as in the picrites. Mantle-normalized trace element patterns of the Limahe intrusion generally resemble those of the picrites. However, negative Nb–Ta anomalies, common features of contamination with the lower or middle crust, are present in the intrusion but absent in the picrites. Sr–Nd isotopes suggest that the Limahe intrusion experienced higher degrees of contamination with the upper crust than did the picrites. The results of this study permit us to suggest that the parental magma of the Limahe intrusion was derived from picritic magma by olivine fractionation and contamination in a staging chamber at mid-crustal levels. Depletion of PGE in the sulfide ores in the Limahe intrusion is likely due to previous sulfide segregation of the parental magmas in the staging chamber. Sulfide mineralization in the Limahe intrusion is related to second-stage sulfide segregation after the fractionated magmas acquired external S from pyrite-bearing country rocks during magma ascent to the Limahe chamber. The abrupt change in mineralogical and chemical compositions between the ultramafic unit and the overlying unit suggests that at least two separate pulses of magma were involved in the development of the Limahe intrusion. We propose that the Limahe intrusion was once a wider part of a dynamic conduit that fed magma to the overlying subvolcanic dykes/sills or lavas. The ultramafic unit formed by the first, relatively more primitive magma, and the mafic unit formed by the second, relatively more fractionated magma. Immiscible sulfide droplets that segregated from the first magma settled down with olivine crystals to form the sulfide-bearing, olivine-rich rocks in the base of the intrusion. The overlying residual liquids were then pushed out of the chamber by the second magma. Critical factors for the formation of an economic Ni–Cu sulfide deposit in such a small intrusion include the dynamic petrologic processes involved and the availability of external sulfur. The Limahe deposit reminds us that small, multiphase, mafic–ultramafic intrusions in the region should not be overlooked for the potential of economic Ni–Cu sulfide deposits.     

Study of oxygen fugacity during magma evolution and ore genesis in the Hongge mafic–ultramafic intrusion,the Panxi region,SW China

Economic concentrations of Fe–Ti oxides occurring as massive layers in the middle and upper parts of the Hongge intrusion are different from other layered intrusions (Panzhihua and Baima) in the Emeishan large igneous province, SW China. This paper reports on the new mineral compositions of magnetite and ilmenite for selected cumulate rocks and clinopyroxene and plagioclase for basalts. We use these data to estimate the oxidation state of parental magmas and during ore formation to constrain the factors leading to the abundant accumulation of Fe–Ti oxides involved with the Hongge layered intrusion. The results show that the oxygen fugacities of parental magma are in the range of FMQ?1.56 to FMQ+0.14, and the oxygen fugacities during the ore formation of the Fe–Ti oxides located in the lower olivine clinopyroxenite zone (LOZ) and the middle clinopyroxenite zone (MCZ) of the Hongge intrusion are in the range of FMQ?1.29 to FMQ?0.2 and FMQ?0.49 to FMQ+0.82, respectively. The MELTS model demonstrates that, as the oxygen fugacity increases from the FMQ?1 to FMQ+1, the proportion of crystallization magnetite increases from 11 % to 16 % and the crystallization temperature of the Fe–Ti oxides advances from 1134 to 1164 °C. The moderate oxygen fugacities for the Hongge MCZ indicate that the oxygen fugacity was not the only factor affecting the crystallization of Fe–Ti oxides. We speculated that the initial anhydrous magma that arrived at the Hongge shallow magma chamber became hydrous by attracting the H₂O of the strata. In combination with increasing oxygen fugacities from the LOZ (FMQ?1.29 to FMQ?0.2) to the MCZ (FMQ?0.49 to FMQ+0.82), these two factors probably account for the large-scale Fe–Ti oxide ore layers in the MCZ of the Hongge intrusion.     

Geochronological and geochemical studies of mafic and intermediate dykes from the Khao Khwang Fold–Thrust Belt: Implications for petrogenesis and tectonic evolution

Zircon U–Pb, mica 40Ar/39Ar ages and geochemistry of the Permo-Triassic mafic to intermediate dyke swarms at the south-western margin of the Indochina Terrane, central Thailand, are reported here and used to decipher the timing of the Sukhothai-Indochina & Sibumasu-Indochina collisions during the Permo-Triassic stages of the Indosinian Orogeny. The mafic dyke swarms in the folded layers of the Khao Khwang Fold–Thrust Belt (KKFTB) were emplaced between the Late Permian and the Late Triassic. The volcanic rocks range from slightly tholeiitic to mostly calc-alkalic, but can be subdivided into three different volcanic groups on the basis of trace and incompatible element abundances such as Ni, Cr, P, Co, and Th. However, all the groups present similar chemical footprints and are enriched in large ion lithophile elements (LILEs) (Rb, Ba, Sr, Pb) and light rare earth elements (LREEs), and depleted in HFSE such as Nb, and Ti highlighting the volcanic arc nature of the system. Isotopically, the three groups are characterized by subtle differences in εNd(t) values (from + 3.2 to + 5.2) and initial 87Sr/86Sr ratios (from 0.7056 to 0.7067). The KKFTB mafic dykes share a few geochemical characteristics of the mafic dykes from the Chiang Khong volcanic suite in the Sukhothai terrane, and from the Loei volcanic belt in northern Indochina. These geochemical features suggest that the KKFTB mafic dykes, and the volcanic rocks in central-northern Thailand, were likely emplaced in a similar orogenic setting. The rocks of Group III are interpreted to have intruded from the Early Triassic (255 ± 6 Ma) to the Late Triassic (207 ± 2 Ma), and were probably sourced from a more crustally contaminated magma.     

Geochemical and Sr–Nd–Pb isotopic compositions of Mesozoic mafic dikes from the Gan-Hang tectonic belt,South China: petrogenesis and geodynamic significance

Mesozoic mafic dikes in the Gan-Hang tectonic belt (GHTB) provide an opportunity to explore both the nature of their mantle source(s) and the secular evolution of the underlying Mesozoic lithospheric mantle in the region. The geochronology and primary geochemical and Sr–Nd–Pb isotopic compositions of Group 1 (middle section of GHTB) and Group 2 (the rest of the section) dolerite dikes spanning the GHTB were investigated. K–Ar ages indicate that dikes of both groups were emplaced during the Cretaceous (131–69 Ma). The dikes are doleritic in composition and are enriched in both large ion lithophile elements (LILEs; e.g. Rb, Ba, and Pb) and light rare earth elements (LREEs), with a wide range of Eu anomalies, but are depleted in high field strength elements (HFSEs; e.g. Nb, Ta, and Ti) and heavy rare earth elements (HREEs). Dikes sampled in the middle section of the GHTB (Group 1) show more pronounced REE differentiation and a greater contribution from crustal material than those from the east and west sections (Group 2) and are similar to GHTB volcanic rocks in exhibiting a slight enrichment in LREEs. The dolerites are further characterized by a wide range in ⁸⁷Sr/⁸⁶Sr _i ?=?0.7041–0.7110, ¹⁴³Nd/¹⁴⁴Nd _i ?=?0.511951–0.512758, ?Nd _t ?=?–10.4 to?+5.6, and Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb _i ?=?18.1–18.3, ²⁰⁷Pb/²⁰⁴Pb _i ≈ 15.6, and ²⁰⁸Pb/²⁰⁴Pb _i ?=?38.2–38.7). The dikes have undergone fractional crystallization of olivine, clinopyroxene, plagioclase, and Ti-bearing phases, except for dikes from the Anding area, which possibly experienced fractionation of plagioclase. Geochemically, all the dike samples originated from mantle sources ranging in composition from depleted to enriched that contained a component of foundered lower crust; crustal contamination during the ascent of these magmas was negligible. In the context of the late Mesozoic lithospheric extension across South China, mafic dike magmatism was likely triggered by the reactivation of deep faults, which promoted foundering of the lower crust and subsequent mantle upwelling in the GHTB.