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1.
People are an important source of pollution indoors, through activities such as cleaning, and also from “natural” emissions from breath and skin. This paper investigates natural emissions in high‐occupancy environments. Model simulations are performed for a school classroom during a typical summer in a polluted urban area. The results show that classroom occupants have a significant impact on indoor ozone, which increases from ~9 to ~20 ppb when the pupils leave for lunch and decreases to ~14 ppb when they return. The concentrations of 4‐OPA, formic acid, and acetic acid formed as oxidation products following skin emissions attained maximum concentrations of 0.8, 0.5, and 0.1 ppb, respectively, when pupils were present, increasing from near‐zero concentrations in their absence. For acetone, methanol, and ethanol from breath emissions, maximum concentrations were ~22.3, 6.6, and 21.5 ppb, respectively, compared to 7.4, 2.1, and 16.9 ppb in their absence. A rate of production analysis showed that occupancy reduced oxidant concentrations, while enhancing formation of nitrated organic compounds, owing to the chemistry that follows from increased aldehyde production. Occupancy also changes the peroxy radical composition, with those formed through isoprene oxidation becoming relatively more important, which also has consequences for subsequent oxidant concentrations. 相似文献
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Xiaopu Lyu Yunxi Huo Jin Yang Dawen Yao Kaimin Li Haoxian Lu Yangzong Zeren Hai Guo 《Indoor air》2021,31(5):1340-1352
Due to the high health risks associated with indoor air pollutants and long-term exposure, indoor air quality has received increasing attention. In this study, we put emphasis on the molecular composition, source emissions, and chemical aging of air pollutants in a residence with designed activities mimicking ordinary Hong Kong homes. More than 150 air pollutants were detected at molecular level, 87 of which were quantified at a time resolution of not less than 1 hour. The indoor-to-outdoor ratios were higher than 1 for most of the primary air pollutants, due to emissions of indoor activities and indoor backgrounds (especially for aldehydes). In contrast, many secondary air pollutants exhibited higher concentrations in outdoor air. Painting ranked first in aldehyde emissions, which also caused great enhancement of aromatics. Incense burning had the highest emissions of particle-phase organics, with vanillic acid and syringic acid as markers. The other noteworthy fingerprints enabled by online measurements included linoleic acid, cholesterol, and oleic acid for cooking, 2,5-dimethylfuran, stigmasterol, iso-/anteiso-alkanes, and fructose isomers for smoking, C28-C34 even n-alkanes for candle burning, and monoterpenes for the use of air freshener, cleaning agents, and camphor oil. We showed clear evidence of chemical aging of cooking emissions, giving a hint of indoor heterogeneous chemistry. This study highlights the value of organic molecules measured at high time resolutions in enhancing our knowledge on indoor air quality. 相似文献
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Zachary Finewax Demetrios Pagonis Megan S. Claflin Anne V. Handschy Wyatt L. Brown Olivia Jenks Benjamin A. Nault Douglas A. Day Brian M. Lerner Jose L. Jimenez Paul J. Ziemann Joost A. de Gouw 《Indoor air》2021,31(5):1323-1339
Humans spend approximately 90% of their time indoors, impacting their own air quality through occupancy and activities. Human VOC emissions indoors from exercise are still relatively uncertain, and questions remain about emissions from chlorine-based cleaners. To investigate these and other issues, the ATHLETic center study of Indoor Chemistry (ATHLETIC) campaign was conducted in the weight room of the Dal Ward Athletic Center at the University of Colorado Boulder. Using a Vocus Proton-Transfer-Reaction Time-of-Flight Mass Spectrometer (Vocus PTR-TOF), an Aerodyne Gas Chromatograph (GC), an Iodide-Chemical Ionization Time-of-Flight Mass Spectrometer (I-CIMS), and Picarro cavity ringdown spectrometers, we alternated measurements between the weight room and supply air, allowing for determination of VOC, NH3, H2O, and CO2 emission rates per person (emission factors). Human-derived emission factors were higher than previous studies of measuring indoor air quality in rooms with individuals at rest and correlated with increased CO2 emission factors. Emission factors from personal care products (PCPs) were consistent with previous studies and typically decreased throughout the day. In addition, N-chloraldimines were observed in the gas phase after the exercise equipment was cleaned with a dichlor solution. The chloraldimines likely originated from reactions of free amino acids with HOCl on gym surfaces. 相似文献
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室内空气中潜在的化学反应与空气品质 总被引:2,自引:0,他引:2
探讨了室内污染物发生潜在反应的环境条件 ,分析了臭氧与室内无机物和有机物可能发生的化学反应和光化学反应 ,讨论了这些潜在的反应对室内空气品质的影响 ,提出了改善室内空气品质的途径 相似文献
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Indoor surfaces are known to support organic films, but their thickness, composition, and variability between environments remain poorly characterized. Alkenes are expected to be a significant component of these films, with the reaction with O3 being a major sink for O3 and source of airborne chemicals. Here, we present a sensitive, microscale, nanospectrophotometric method for quantifying the alkene (C=C bond) content of surface films and demonstrate its applicability in five studies relevant to indoor air chemistry. Collection efficiencies determined for a filter wipe method were ~64%, and the overall detection limit for monoalkenes was ~10 nmol m−2. On average, painted walls and glass windows sampled across the University of Colorado Boulder campus were coated by ~4 nm thick films containing ~20% alkenes, and a simple calculation indicates that the lifetime for these alkenes due to reaction with O3 is ~1 hour, indicating that the films are highly dynamic. Measurements of alkenes in films of skin oil, pan-fried cooking oils, a terpene-containing cleaner, and on various surfaces in a closed classroom overnight (where carboxyl groups were also measured) provided insight into the effects of chemical and physical processes on film and air composition. 相似文献
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Christian Mark Salvador Gabriel Bek Charles J. Weschler Glenn Morrison Michael Le Breton Mattias Hallquist Lars Ekberg Sarka Langer 《Indoor air》2019,29(6):913-925
This study aimed to better understand and quantify the influence of ventilation strategies on occupant‐related indoor air chemistry. The oxidation of human skin oil constituents was studied in a continuously ventilated climate chamber at two air exchange rates (1 h?1 and 3 h?1) and two initial ozone mixing ratios (30 and 60 ppb). Additional measurements were performed to investigate the effect of intermittent ventilation (“off” followed by “on”). Soiled t‐shirts were used to simulate the presence of occupants. A time‐of‐flight‐chemical ionization mass spectrometer (ToF‐CIMS) in positive mode using protonated water clusters was used to measure the oxygenated reaction products geranyl acetone, 6‐methyl‐5‐hepten‐2‐one (6‐MHO) and 4‐oxopentanal (4‐OPA). The measurement data were used in a series of mass balance models accounting for formation and removal processes. Reactions of ozone with squalene occurring on the surface of the t‐shirts are mass transport limited; ventilation rate has only a small effect on this surface chemistry. Ozone‐squalene reactions on the t‐shirts produced gas‐phase geranyl acetone, which was subsequently removed almost equally by ventilation and further reaction with ozone. About 70% of gas‐phase 6‐MHO was produced in surface reactions on the t‐shirts, the remainder in secondary gas‐phase reactions of ozone with geranyl acetone. 6‐MHO was primarily removed by ventilation, while further reaction with ozone was responsible for about a third of its removal. 4‐OPA was formed primarily on the surfaces of the shirts (~60%); gas‐phase reactions of ozone with geranyl acetone and 6‐MHO accounted for ~30% and ~10%, respectively. 4‐OPA was removed entirely by ventilation. The results from the intermittent ventilation scenarios showed delayed formation of the reaction products and lower product concentrations compared to continuous ventilation. 相似文献
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针对常用电器对室内空气品质的危害,分析了常用电器对室内空气品质的影响,提出了改善常用电器对室内空气品质影响的措施,有助于增加人们对常用电器与室内空气品质关系的认识,以帮助人们更好地保护室内空气品质。 相似文献
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Andrea Spinazzè Davide Campagnolo Andrea Cattaneo Patrizia Urso Ioannis A. Sakellaris Dikaia E. Saraga Corinne Mandin Nuno Canha Rosanna Mabilia Erica Perreca Victor G. Mihucz Tamás Szigeti Gabriela Ventura Eduardo de Oliveira Fernandes Yvonne de Kluizenaar Eric Cornelissen Otto Hänninen Paolo Carrer Peder Wolkoff Domenico M. Cavallo John G. Bartzis 《Indoor air》2020,30(1):76-87
The aim of this study was to identify determinants of aldehyde and volatile organic compound (VOC) indoor air concentrations in a sample of more than 140 office rooms, in the framework of the European OFFICAIR research project. A large field campaign was performed, which included (a) the air sampling of aldehydes and VOCs in 37 newly built or recently retrofitted office buildings across 8 European countries in summer and winter and (b) the collection of information on building and offices’ characteristics using checklists. Linear mixed models for repeated measurements were applied to identify the main factors affecting the measured concentrations of selected indoor air pollutants (IAPs). Several associations between aldehydes and VOCs concentrations and buildings’ structural characteristic or occupants’ activity patterns were identified. The aldehyde and VOC determinants in office buildings include building and furnishing materials, indoor climate characteristics (room temperature and relative humidity), the use of consumer products (eg, cleaning and personal care products, office equipment), as well as the presence of outdoor sources in the proximity of the buildings (ie, vehicular traffic). Results also showed that determinants of indoor air concentrations varied considerably among different type of pollutants. 相似文献
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建材VOC吸附特性的研究进展 总被引:3,自引:0,他引:3
阐述了研究室内空气质量(IAQ)的重要性及建材吸附挥发性有机化合物(VOC)对IAQ的影响,介绍了建材VOC吸附特性的研究现状,指出了目前存在的研究局限,提出了努力的方向及研究目标. 相似文献
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挥发性有机化合物对室内空气品质影响研究进展 总被引:25,自引:4,他引:25
系统回顾了近年来一些国家对室内空气环境中挥发性有机化合物(VOC)研究的各个方面,包括VOC研究在室内空气品质研究中的地位,建筑物内VOC对人体健康的影响,VOC研究的实验方法、理论方法及主要研究结论,各国政府、学术团体采取的行动等。得出结论:与建筑科学、环境科学及人体健康相关的工作人员,如居住者、建筑业主、建筑科学家、环境科学家、心理学家和生理学家、建筑师与暖通空调设计人员、建筑和装饰材料生产商、供应商,都应重视VOC问题。 相似文献
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Indoor air quality (IAQ) was assessed in homes in an experimental community of single-family dwellings that had been built with materials chosen for low pollutant emission and other modified design features to provide enhanced residential indoor air quality. The IAQ was measured in six of these experimental homes and also in three conventionally built homes of similar size and price range. The IAQ was assessed shortly after construction before the houses were occupied and again after each of the houses had been occupied for five months. Before occupancy, there were higher levels of airborne panicles and of some volatile organic compounds in the conventional homes than in the experimental homes. During occupancy, benzene, ethylbenzene, m-and p-xylene, and o-xylene were all higher in the conventional homes, but dichloromethane, Freon 11, and trichlorethylene were higher in the experimental homes. In the conventional homes, mean levels of benzene and chloroform increased, whereas methylchlomform and toluene levels decreased from preoccupancy to occupancy. In the experimental homes, dichloromethane increased, and m-and p-xylene and o-xylene decreased from preoccupancy to occupancy. The results suggest that attached garages, geographical siting, and occupants' activities substantially influenced the IAQ in these homes. The enhanced indoor air quality homes tested in this study were judged to be at least partially effective, with the most obvious sustained IAQ benefits being related to the lack of an attached garage. 相似文献
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D. B. Day J. Xiang J. Mo M. A. Clyde C. J. Weschler F. Li J. Gong M. Chung Y. Zhang J. Zhang 《Indoor air》2018,28(3):360-372
High‐efficiency particulate air (HEPA) filtration in combination with an electrostatic precipitator (ESP) can be a cost‐effective approach to reducing indoor particulate exposure, but ESPs produce ozone. The health effect of combined ESP‐HEPA filtration has not been examined. We conducted an intervention study in 89 volunteers. At baseline, the air‐handling units of offices and residences for all subjects were comprised of coarse, ESP, and HEPA filtration. During the 5‐week long intervention, the subjects were split into 2 groups, 1 with just the ESP removed and the other with both the ESP and HEPA removed. Each subject was measured for cardiopulmonary risk indicators once at baseline, twice during the intervention, and once 2 weeks after baseline conditions were restored. Measured indoor and outdoor PM2.5 and ozone concentrations, coupled with time‐activity data, were used to calculate exposures. Removal of HEPA filters increased 24‐hour mean PM2.5 exposure by 38 (95% CI: 31, 45) μg/m3. Removal of ESPs decreased 24‐hour mean ozone exposure by 2.2 (2.0, 2.5) ppb. No biomarkers were significantly associated with HEPA filter removal. In contrast, ESP removal was associated with a ?16.1% (?21.5%, ?10.4%) change in plasma‐soluble P‐selectin and a ?3.0% (?5.1%, ?0.8%) change in systolic blood pressure, suggesting reduced cardiovascular risks. 相似文献
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Antoine Depoorter Carmen Kalalian Corinne Emmelin Chantal Lorentz Christian George 《Indoor air》2021,31(3):682-692
People spend approximately 80% of their time indoor, making the understanding of the indoor chemistry an important task for safety. The high surface-area-to-volume ratio characteristic of indoor environments leads the semi-volatile organic compounds (sVOCs) to deposit on the surfaces. Using a long path absorption photometer (LOPAP), this work investigates the formation of nitrous acid (HONO) through the photochemistry of adsorbed nitrate anions and its enhancement by the presence of furfural. Using a high-resolution proton-transfer-reaction time-of-flight mass spectrometer (PTR-TOF-MS), this work also investigates the surface emissions of VOCs from irradiated films of furfural and a mix of furfural and nitrate anions. Among the emitted VOCs, 2(5H)-furanone/2-Butenedial was observed at high concentrations, leading to maleic anhydride formation after UV irradiation. Moreover, the addition of potassium nitrate to the film formed NOx and HONO concentrations up to 10 ppb, which scales to ca. 4 ppb for realistic indoor conditions. This work helps to understand the high levels of HONO and NOx measured indoors. 相似文献
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Tania Martellini Chiara Berlangieri Luigi Dei Emiliano Carretti Saul Santini Angelica Barone Alessandra Cincinelli 《Indoor air》2020,30(5):900-913
Indoor Air Quality monitoring in cultural institutions is of particular concern to protect these places and the cultural heritage content. An indoor monitoring campaign was performed in three museums in Florence (Italy) to determine the occurrence and levels of volatile organic compounds (VOCs). VOCs of interest included BTEX (benzene, toluene, ethylbenzene, xylenes), terpenes, aldehydes, organic acids, and cyclic volatile methyl siloxanes (cVMS). The most abundant VOCs in all samples analyzed were BTEX, which were strictly related to the traffic source, followed by siloxanes and terpenes. Among BTEX, toluene was always the most abundant followed by xylenes, ethylbenzene, and benzene. cVMS in exhibition rooms with the presence of visitors showed higher values compared to samples collected when the museums were closed. Terpenes showed not only the influence of vegetation-biogenic sources surrounding a museum but could also be related to the wood used for the construction of showcases and furniture and the use of cleaning products. Data obtained also showed the presence of organic acids and aldehydes whose source can be traced back to exhibits themselves and wood-based furniture. Assessing the levels of organic acids in museums is important because, over time, it can cause deterioration of the artifacts. 相似文献
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为研究我国与国外相关室内空气标准中所控制VOCs指标的合理性,本文选取了5类常见的湿建材(内墙涂料、木器漆、防水涂料、胶粘剂、环氧地坪)共15种样品作为测试对象,在小型环境测试舱内测量样品的甲醛和TVOC散发率,并进行定性、定量分析。实验结果表明,湿建材的甲醛散发率比较低,内墙涂料、木器漆、万能胶、环氧地坪的TVOC散发率较高。进一步的分析显示,内墙涂料所散发的VOCs中不包含受控的挥发性有机污染物,而在其它湿建材测试中,甲苯、二甲苯、乙苯等高风险物质均被不同程度地检出,这表明TVOC散发率与湿建材的健康风险没有直接联系,我国相关室内空气质量标准中使用的TVOC限值有一定的局限性。 相似文献
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We present a model for the growth of organic films on impermeable indoor surfaces. The model couples transport through a gas‐side boundary layer adjacent to the surface with equilibrium partitioning of semivolatile organic compounds (SVOCs) between the gas phase and the surface film. Model predictions indicate that film growth would primarily be influenced by the gas‐phase concentration of SVOCs with octanol‐air partitioning (Koa) values in the approximate range 10≤log Koa≤13. Within the relevant range, SVOCs with lower values will equilibrate with the surface film more rapidly. Over time, the film becomes relatively enriched in species with higher log Koa values, while the proportion of gas‐phase SVOCs not in equilibrium with the film decreases. Given stable airborne SVOC concentrations, films grow at faster rates initially and then subsequently diminish to an almost steady growth rate. Once an SVOC is equilibrated with the film, its mass per unit film volume remains constant, while its mass per unit area increases in proportion to overall film thickness. The predictions of the conceptual model and its mathematical embodiment are generally consistent with results reported in the peer‐reviewed literature. 相似文献