Al基复合材料分形特性及其磨损特性的研究

以亚微米级(130nm)SiCp和(100～200)目(149～75μm)Al粉为原料,采用冷压烧结和热挤压方法制备出不同体积含量的微米SiCp增强Al基复合材料,研究了其分形特性和耐磨性能.结果表明:SiCp/Al基复合材料具有分形特性,SiCp/Al基复合材料耐磨性优于市售挤压态锡青铜QSn6.5-0.4和纯Al,且随SiCp含量增加,复合材料的分形维数增大,耐磨性能提高;磨损表面形成Al基体+孔隙+弥散分布SiCp的理想耐磨组织.     

Microstructure and wear characteristics on Al alloy matrix composite reinforced with Ni perform

Al based composite reinforced with Nickel is used for diesel engine piston, because the thermal properties, strength and corrosion resistant are for better than Al alloy alone. For processing, the intermetallic compounds of Ni and Al improves wear resistance due to its high hardness. Existing process methods for MMC (metal matrix composite) using preform were manufactured under high-pressure. However, this causes deformation of the preform or weaknesses in the completed MMC. Low-pressure infiltration can prevent these problems, and there is an advantage of cost reduction in of production with small-scale of production equipment. In this study, the microstructure and wear characteristics of Al-based composite with Ni preform as reinforcement with low-pressure infiltration was analyzed.     

Dry sliding friction and casing wear behavior of PCD reinforced WC matrix composites

The friction and casing wear properties of PCD reinforced WC matrix composites were investigated using a cylinder-on-ring wear-testing machine against N80 casing steel counterface under dry sliding conditions. The results indicate that the friction and casing wear rate of PCD reinforced WC matrix composites are the lowest among the materials. As the applied load and sliding speed steadily increase, the friction coefficients of PCD reinforced WC matrix composites decrease. In addition, the casing wear rates increase with increasing load, but decline with sliding velocity. The dominant wear mechanism of the PCD composite is the micro-cutting wear, accompanied by adhesive wear.     

Failure behavior / characteristics of fabric reinforced polymer matrix composite and aluminum6061 on dynamic tensile loading

Composite materials are composed of multiple types of materials as reinforcement and matrix. Among them, CFRP (Carbon fiber reinforced polymer) is widely used materials in automotive and defense industry. Carbon fibers are used as a reinforcement, of which Young's modulus is in a prepreg form. In automotive industry, especially, high strain rate test is needed to measure dynamic properties, used in dynamic analysis like high inertia included simulation as a car crash. In this paper, a SHTB (Split Hopkinson tensile bar) machine is employed for estimating stress-strain curve under dynamic load condition on aluminum 6061 and CFRP. The strain rate range is about from 100 /s to 1000 /s and the number of prepreg layers of composite specimen is total eight plies which are stacked symmetrically to structure CFRP. As a result, stress / strain point data are obtained and used for simulation into stacked composites.     

Friction and wear behavior of hybrid glass/PTFE fabric composite reinforced with surface modified nanometer ZnO

Nano-ZnO was successfully grafted with 2,4-toluenediisocyanate (TDI) and β-aminoethyltrimethoxylsilane (OB551) to avoid the agglomeration of nano-ZnO in composite. The hybrid glass/PTFE fabric composites reinforced with the untreated, OB551 and TDI modified nano-ZnO, respectively, were prepared by dip-coating of the hybrid fabric in a phenolic adhesive resin containing the nanoparticles to be incorporated and the successive curing. The friction and wear behaviors of various nano-ZnO reinforced hybrid glass/PTFE fabric composites sliding against AISI-1045 steel in a pin-on-disk configuration were evaluated on a Xuanwu-III high-temperature friction and wear tester, with the unfilled one as a reference. The morphologies of the worn surfaces of the composites and of the counterpart pins were analyzed using scanning electron microscopy. In addition, FTIR spectrum was taken to characterize the untreated and treated nano-ZnO. It is found that the untreated and treated nano-ZnO reinforced hybrid glass/PTFE fabric composites exhibit improved wear resistance and friction-reduction in comparison with the unfilled one. The TDI modified nano-ZnO reinforced composite can obtain the best friction and wear performance under different applied load; followed by the OB551 modified nano-ZnO reinforced one. Sliding conditions, such as environmental temperature and lubricating condition, significantly affect the tribo-performances of the unfilled and filled hybrid glass/PTFE fabric composites.     

A study of the wear behavior of polymer–matrix composites containing discontinuous nanocrystalline alloy reinforcements

The tribological behavior of bakelite resin–matrix composites reinforced with nanocrystalline Al 6061 T6 particles produced by machining (grain size 70–500 nm) has been studied using block-on-ring and pin-on-disk tests. The polymer–matrix composite reinforced with nanostructured Al 6061 particles aged for 10 h [Al 6061 (3) 10 h] shows a wear reduction of around 60% with respect to the conventional microstructured reinforcement. Also it shows the lowest wear rates when compared with the nanostructured reinforcements aged for 5 h or 1 h, respectively. Friction coefficients and wear rates increased with increasing sliding speed and normal load. Under 10 N and 0.10 m s⁻¹, Al 6061 (3) 10 h showed an initial friction and contact temperature increase and a very severe wear with material transfer to the steel ball surface. Increasing the steel–composite contact temperature to 100 °C (1 N; 0.05 m s⁻¹) produced a one order of magnitude decrease both in friction and wear. Wear mechanisms for the polymer matrix and the aluminum reinforcement are discussed on the basis of SEM and EDS observations.     

Abrasive wear behavior of thermally sprayed diamond reinforced composite coating deposited with both oxy-acetylene and HVOF techniques

Diamond and diamond-based coatings have long been studied for their exceptional properties. Although a great deal of research has been carried out in this field, little is known about their tribological wear behavior. In the present work, diamond reinforced composite (DRC) coatings of varying diamond content was deposited on mild steel substrates using both oxy-acetylene (OA) and high velocity oxy fuel (HVOF) thermal spraying techniques. The high stress abrasive wear behavior of these coatings is studied by performing two body abrasion tests for varying experimental parameters. It is observed that the HVOF-sprayed coatings suffered abrasion at a relatively low wear rate. The reasons for variations observed in the wear rate as a function of displacement during abrasion and grit size could be attributed to the deterioration of abrasive particles and the particle size effect respectively. While the disparity in the wear rates with respect to composition of the coatings was primarily controlled by the diamond content in the coating. The abrasive wear mechanism was found to be the same in both the coatings except that the coating deposited by HVOF spray technique, offered better abrasion resistance and therefore abraded at a slower rate. This is possibly due to lower porosity in the coating and higher bond strength between reinforced diamond particulates and the bronze matrix in HVOF-sprayed specimens.     

颗粒增强铝基复合材料干滑动摩擦性能研究进展

综述了近几十年来各国对颗粒增强铝基复合材料(PRA)干滑动摩擦性能的研究成果,对PRA主要参数的测量、影响PRA耐磨性的因素和磨损机制进行了分析和总结,指出了今后的研究方向。     

Dry three-body abrasive wear behavior of WC reinforced iron matrix surface composites produced by V-EPC infiltration casting process

This paper fabricated tungsten carbide (WC) particles reinforced iron matrix surface composites on gray cast iron substrate using vacuum evaporative pattern casting (V-EPC) infiltration process, investigated dry three-body abrasive wear resistance of the composites containing different volume fractions of WC particles, comparing with a high chromium cast iron. The fabricated composites contained WC particles of 5, 10, 19, 27, 36, and 52 vol.%, respectively. The results in abrasive wear tests showed that, with the increase in the volume fraction of WC particles, the wear resistance of the composites first increased until reached the maximum when the volume fraction of WC was 27%, then decreased, and was 1.5–5.2 times higher than that of the high chromium cast iron. The changes of the wear resistance of the composites with the volume fraction of WC particles and the mode of material removal in dry three-body abrasive wear condition were analyzed.     

Al/Fe3Al网状结构复合材料的制备

采用机械合金化及退火工艺制备纳米级Fe3Al金属间化合物粉体;利用有机前驱体烧蚀技术,氩气保护下在真空热处理炉中经过1460℃热处理,制备具有高气孔率、高尺寸稳定性、耐高温的Fe3Al金属间化合物网状结构;采用负压浸渗法制备Al/Fe3Al网状结构复合材料,材料的耐磨性能明显优于基体材料,在100N载荷、400r/min转速的试验条件下,摩擦时间为20min时,Al/Fe3Al复合材料的磨损量较纯Al试样降低66%.     

Fretting wear behavior of nanocrystalline surface layer of copper under dry condition

Unlubricated fretting tests were performed with a nanocrystalline surface layer of a 99.99 wt.% copper fabricated by means of surface mechanical attrition treatment (SMAT), in comparison with a coarse-grained (CG) copper. The measured friction and wear data show that the fretting wear resistance is markedly enhanced with the nanocrystalline surface layer relative to the CG counterpart. The friction coefficient and wear volume of the SMAT Cu are lower than that of the CG Cu. For both samples, the friction coefficients and wear volumes increase with an increasing applied load and fretting frequency. A rapid increase of the friction coefficient and wear volume under an applied load above a critical value (30 N for the SMAT Cu and 20 N for the CG Cu) is noticed, corresponding to the formation of a continuous oxide layer between two contact surfaces. Also two sharp increases of the friction coefficient and wear volume at fretting frequencies of 50 Hz and 175 Hz were observed for the SMAT and the CG Cu. The former is correlated with the formation of a continuous oxide layer, while the latter corresponds to wearing away of the oxide layer.     

Sliding wear behavior of nanocrystalline nickel coatings: Influence of grain size

In the present study the sliding wear behavior of pulse electrodeposited nanocrystalline Ni coatings as a function of grain size including bulk annealed Ni has been systematically studied using pin-on-disc configuration against the WC-Co counter body. The sliding wear has been analyzed with respect to wear rate, coefficient of friction, subsurface deformation and composition of wear debris. The result indicates that the sliding wear rate and coefficient of friction of Ni decreases with decreasing grain size. The subsurface beneath the worn pin surface is composed of a near surface shear region and beneath it a region of bulk plastic deformation. The ratio of the depth of the shear region to the depth of bulk deformed region decreases with decreasing grain size indicating a greater localization of near surface deformation with decreasing grain size.     

Adhesive wear and frictional performance of bamboo fibres reinforced epoxy composite

The aim of the present work is to investigate the adhesive wear and frictional performance of BMBFRE composite. Adhesive wear performance of BMBFRE composite was found to be superior for AP-O. The frictional performance of BMBFRE composite was found to be greater at low sliding velocity for AP-O by 44% relative to the high sliding velocity. The temperature differential of BMBFRE composite for AP-O to the sliding direction gave lower interface temperatures of about 31.4% and 13.2% as compared to R-O and P-O. The predominant wear mechanisms for AP-O was back film transfer associated with the formation of fine grooves on the worn surfaces.     

Sliding wear behavior of planar random zinc-alloy matrix composites

The friction and wear behavior of planar random zinc-alloy matrix composites reinforced by discontinuous carbon fibres under dry sliding and lubricated sliding conditions has been investigated using a block-on-ring apparatus. The effects of fibre volume fractions and loads on the sliding wear resistance of the zinc-alloy matrix composites were studied. Experiments were performed within a load range of 50–300 N at a constant sliding velocity of 0.8 m s⁻¹. The composites with different volume fractions of carbon fibres (0–30%) were used as the block specimens, and a medium-carbon steel used as the ring specimen. Increasing the carbon fibre volume fraction significantly decreased the coefficient of friction and wear rates of both the composites and the medium-carbon steel under dry sliding conditions. Under lubricated sliding conditions, however, increasing the carbon fibre volume fraction substantially increased the coefficient of friction, and slightly increased the wear of the medium-carbon steel, while reducing the wear of the composite.Under dry sliding conditions, an increasing load increased not only the wear rates of both the composite and the unreinforced zinc alloy, but also those of their corresponding steel rings. However, the rate of increase of wear with increasing load for both the composite and its corresponding steel ring was much smaller than for the unreinforced zinc alloy and its corresponding steel ring. The coefficient of friction under dry sliding conditions appeared to be constant as load increased within a load range of 50–150 N for both the composite and the unreinforced zinc alloy, but increased at the higher loads. Under any load the coefficient of friction of the composite was lower than half that of the unreinforced zinc alloy under dry sliding conditions.     

Friction and wear properties of short carbon fiber reinforced aluminum matrix composites

The friction and wear properties of short carbon fibers (SCFs) reinforced aluminum matrix composite were studied. The influences of the fiber volume fraction, load applied, rotating speed, and wear mechanism were discussed. The results indicated that SCFs/Al composite had better tribological properties than Al alloy. The friction coefficient and wear mass loss decreased with the fiber volume fraction increased, but increased as the load and rotating speed increased, respectively. SCF reduced direct contact between the matrix and counterpart and improved the wear resistance of SCFs/Al composite greatly. The wear displayed a linear evolution in all the range of load. Surfaces before and after wear tests were characterized using scanning electron microscopy (SEM) and energy-dispersive analysis of X-ray (EDAX) spectroscopy.     

Fretting wear behavior of nanocrystalline surface layer of pure copper under oil lubrication

Lubricated fretting tests in mineral oil were performed with a nanocrystalline surface layer on a pure bulk Cu prepared by surface mechanical attrition treatment (SMAT) against a WC-Co ball. It was found that the nanocrystalline surface layer exhibited a markedly enhanced fretting wear resistance and higher friction coefficient relative to the coarse-grained (CG) form. The wear volume of the SMAT Cu is one order of magnitude lower than that of the CG Cu. The friction coefficient of the SMAT Cu increases with an increasing load and frequency, while for the CG Cu, the friction coefficient increases with an increasing fretting frequency up to 100 Hz and thereafter decreases. The higher hardness of the SMAT Cu is suggested to be the main factor causing its improved wear resistance and higher friction coefficient. A discontinuous metal transfer layer can be found on the WC-Co ball only after fretting against the SMAT Cu, which may partly account for the higher wear resistance of the SMAT Cu in comparison with the CG Cu.     

Friction and wear behavior of electroless Ni-based CNT composite coatings

Ni-based carbon nanotube (CNT) composite coatings with different volume fraction (from 5 to 12 vol.%) of CNTs were deposited on medium carbon steel substrates by electroless plating. The friction and wear behavior of the composite coatings were investigated using a pin-on-disk wear tester under unlubricated condition. Friction and wear tests were conducted at a sliding speed of 0.0623 m s⁻¹ and at an applied load of 20 N. The experimental results indicated that the friction coefficient of the composite coatings decreased with increasing the volume fraction of CNTs due to self-lubrication and unique topological structure of CNTs. Within the range of volume fraction of CNTs from 0 to 11.2%, the wear rate of the composite coatings showed a steadily decreasing trend with increasing volume fraction of CNTs. Because of the conglomeration of CNTs in the matrix, however, the wear rate of the composite coatings increased with further increasing the volume fraction of CNTs.     

Microstructure and wear properties of in situ TiC/FeCrBSi composite coating prepared by gas tungsten arc welding

Using a gas tungsten arc welding (GTAW) process, in situ synthesis TiC particles reinforced Fe-based alloy composite coating has been produced by preplaced FeCrBSi alloy, graphite and ferrotitanium powders. The microstructure and wear properties of the composite coatings were studied by means of scanning electron microscopy (SEM), X-ray diffractometer (XRD) and wear test. The effects of thickness of the pre-placed powder layer on the microstructure, hardness and wear resistance of the composite coatings were also investigated. The results indicated that TiC particles were produced by direct metallurgical reaction between ferrotitanium and graphite during the GTAW process. TiC particles with sizes in the range of 3–5 μm were dispersed in the matrix. The volume fraction of TiC particles and microhardness gradually increased from the bottom to the top of the composite coatings. The TiC-reinforced composite coatings enhance the hardness and wear resistance. The highest wear resistance of the composite coating with a 1.2 mm layer was obtained.     

Microstructure and wear properties of in situ TiC/FeCrBSi composite coating prepared by gas tungsten arc welding

Using a gas tungsten arc welding (GTAW) process, in situ synthesis TiC particles reinforced Fe-based alloy composite coating has been produced by pre-coated FeCrBSi alloy, graphite and ferrotitanium powders on the substrate. The microstructure and wear properties of the composite coatings were studied by means of scanning electron microscopy (SEM), X-ray diffractometer (XRD) and wear test. The effects of thickness of the pre-coated powder layer on the microstructure, hardness and wear resistance of the composite coatings were also investigated. The results indicated that TiC particles were produced by direct metallurgical reaction between ferrotitanium and graphite during the GTAW process. TiC particles with sizes in the range of 3–5 μm were dispersed in the matrix. The volume fraction of TiC particles and microhardness gradually increased from the bottom to the top of the composite coatings. The TiC-reinforced composite coatings enhance the hardness and wear resistance. The highest wear resistance of the composite coating with a 1.2 mm layer was obtained.