Ti-Nb作缓冲层的TiC金属陶瓷/不锈钢脉冲加压扩散连接

采用Ti-Nb中间层对TiC金属陶瓷和不锈钢06Cr19Ni10进行了脉冲加压扩散连接,以实现缩短焊接时间并缓解界面产物对接头的有害作用的目的。连接温度890℃,脉冲压力2~10MPa工艺条件下,在4~12min时间内即实现了陶瓷与不锈钢的有效连接,与传统扩散焊相比连接时间大幅缩短。对接头进行显微组织表征发现在反应界面处存在溶解了少量Nb的σ相以及溶解了Ni的α β-Ti固溶体。在连接时间为10min时得到了最大的剪切强度110MPa。在剪切载荷下,接头沿着剩余的Ti/α β-Ti界面扩展至陶瓷内部断裂。结果表明,脉冲加压扩散连接能在一定程度上缩短焊接时间,中间层Ti/Nb的合理选择能很好的抑制了有害的金属间化合物的生成。     

Cu作缓冲层的TiC金属陶瓷/304不锈钢扩散连接（英文）

对TiC金属陶瓷和304不锈钢进行真空扩散连接实验,并采用Ti/Nb/Cu中间层以实现活性连接并缓解接头残余应力的目的。对焊后接头进行详细的组织分析和力学性能测试来评估焊接工艺。分析发现在TiC金属陶瓷和304不锈钢之间形成明显的转变过渡区,界面反应产物为(Ti,Nb)、剩余Nb、剩余Cu以及Cu(s.s)。连接温度925℃,保温时间20 min,压力8 MPa下得到的接头剪切强度达84.6 MPa,此时脆性断裂发生在靠近界面处的陶瓷内部。结果表明,中间层Ti/Nb/Cu的合理选择能很好的降低金属间化合物对接头性能的有害作用,而且Nb对接头残余应力的改善起到关键作用,有效的提高了接头强度。     

304L不锈钢夹层扩散连接研究

采用Nb做中间层对304L不锈钢进行了真空扩散连接研究,焊后利用扫描电镜和EDS对焊接接头的微观组织及元素扩散行为进行了研究.在焊接温度750℃,扩散时间20 min,焊接压力10 MPa的工艺下,接头最高抗拉强度为185 MPa.     

Ti-Nb作缓冲层的TiC金属陶瓷/不锈钢脉冲加压扩散连接（英文）

采用Ti-Nb中间层对TiC金属陶瓷和不锈钢06Cr19Ni10进行了脉冲加压扩散连接,以实现缩短焊接时间并缓解界面产物对接头的有害作用的目的。连接温度890℃,脉冲压力2~10 MPa工艺条件下,在4~12 min时间内即实现了陶瓷与不锈钢的有效连接,与传统扩散焊相比连接时间大幅缩短。对接头进行显微组织表征发现在反应界面处存在溶解了少量Nb的σ相以及溶解了Ni的α+β-Ti固溶体。在连接时间为10 min时得到了最大的剪切强度110 MPa。在剪切载荷下,接头沿着剩余的Ti/α+β-Ti界面扩展至陶瓷内部断裂。结果表明,脉冲加压扩散连接能在一定程度上缩短焊接时间,中间层Ti/Nb的合理选择能很好的抑制有害的金属间化合物的生成。     

扩散时间对Al/Cu真空扩散连接的影响

采用真空扩散焊工艺对Al/Cu异种材料进行连接,研究了保温时间对接头微观组织及力学性能的影响.利用扫描电镜和EDS对焊接接头的微观组织及元素扩散行为进行了研究.结果表明:随着扩散时间的延长,接头的抗拉强度随之升高,焊接接头最高抗拉强度为185 MPa.     

扩散连接温度对304不锈钢接头性能与组织的影响

以304不锈钢为研究对象,探究了扩散连接温度(925～1000℃)对接头厚度变形量及力学性能的影响,并分析了其对界面组织的影响作用.扩散连接接头剪切强度随扩散温度升高呈现抛物线式变化.在950℃,30 MPa和60 min条件下扩散连接,接头抗剪切强度为580 MPa,达到母材剪切强度的98.47％,厚度变形量为1.2...     

镍作中间层脉冲加压扩散连接钛合金与不锈钢

采用纳米Ni粉、纳米Ni镀层、Ni箔作中间过渡层,对TA17近。型钛合金与0Cr18Ni9Ti不锈钢进行了脉冲加压扩散连接,接头抗拉强度分别达到了175,212,334MPa。在金相显微镜下,对拉伸断口形貌进行了观察和分析;利用扫描电镜（SEM）、能谱仪（EDS）、X射线衍射分析（XRD）测定了连接接头各区域内的微区成分和物相。结果表明,纳米Ni粉致密度不够高,纳米Ni镀层质量不够高,在很大程度上限制了接头强度的提高;Ni箔中间层的存在成功地阻止了Fe与Ti之间的互扩散,避免了形成脆而硬的Fe—Ti系金属间化合物。     

316L不锈钢/T2紫铜热等静压扩散连接接头的微观组织与力学性能

采用热等静压(hot isostatic pressing,HIP)工艺对棒材316L不锈钢/T2紫铜进行连接,分析连接界面微观组织和力学性能.结果表明,在塑性变形和扩散反应的连接机制下,异种金属连接接头结合良好,两侧基体元素发生了明显的互扩散,最终形成了3.9μm厚的扩散层,扩散层分为两侧的扩散影响区(diffusion affected zone,DAZ)和中间反应层(reaction layer,RL),扩散层及其附近的T2紫铜侧有树枝状的γ-Fe相、条状α(Cu, Ni)相和不规则块状富Cr相析出.硬度试验结果表明,连接接头硬度要高于较弱T2紫铜母材,接头平均硬度为94 HV0.1,未出现硬度突变的现象,表明接头没有脆性金属间化合物生成,拉伸试验最终在T2紫铜母材断裂,断裂机制为韧性断裂,最大抗拉强度为165 MPa,接头及其附近析出相的弥散分布形成了第二相强化机制,阻碍位错的运动,最终使得连接接头具有较高的硬度和较好的结合强度.     

用非晶态合金作中间层扩散连接Si3N4与40Cr钢的研究

本文采用非晶态Ｃｕ５０Ｔｉ５０Ｂ薄膜和纯Ｎｉ缓释层作复合中间层，较好地实现了Ｓｉ３Ｎ４与４０Ｃｒ钢的扩散连接，连接时间和连接温度及缓释层厚度对接头的强度影响很大，最佳连接工艺为：９００℃．４０ｍｉｎ．３０ＭＰａ，Ｎｉ缓释层的合适工为１ｍｍ，接头的微观分析表明，缓释层与非晶态Ｃｕ５０Ｔｉ５０Ｂ之间存在着较强的物理冶金交互作用，导致非晶态中间层的Ｔｉ的活度降低，并产生脆性金属间化合物，使接头强度下降，     

TiC金属陶瓷/钢钎焊接头的界面结构和连接强度

采用BAg45CuZn钎料对自蔓延高温合成的TiC金属陶瓷与中碳钢进行了真空钎焊连接,利用扫描电镜、电子探针、X射线衍射等分析手段对接头的界面结构和室温抗剪强度进行了研究.结果表明,利用BAg45CuZn钎料可实现TiC金属陶瓷与中碳钢的连接;接头的界面结构为TiC金属陶瓷/(Cu,Ni)固溶体/Ag基固溶体 Cu基固溶体/(Cu,Ni)固溶体/(Cu,Ni) (Fe,Ni)/中碳钢;在连接温度为850℃保温10min的钎焊条件下,接头的抗剪强度可达121MPa.     

TiC硬质合金/碳钢爆炸焊接复合板界面微观组织

用透射电镜、扫描电镜和X射线能谱仪对TiC硬质合金/碳钢爆炸焊接复合板界面微观组织和相组成进行分析.结果表明,界面上有一断续的熔合层,层厚约10μm,层内为尺寸位于几十个～几百个纳米之间的纳米或亚微米超细晶粒,组成相为铁素体、奥氏体和少量TiC.在界面附近碳钢侧可以看到明显的流线状组织特征,铁索体具有板条状马氏体的结构特征,珠光体层片间距减小,呈流线分布.焊接过程中Ti向钢中扩散15μm左右.     

TiC金属陶瓷/铸铁钎焊接头热应力的有限元模拟

研究了采用Ag-Cu-Zn钎料在1173K温度下钎焊TiC金属陶瓷与铸铁时，接头在冷却过程中的热应力最大值和应力集中区。模拟结果表明，在冷却过程中，铸铁／TiC金属陶瓷接头的剪应力主要集中在界面端点处，且剪应力的最大值出现在Ag-Cu-Zn／TiC金属陶瓷界面处。TiC金属陶瓷下表面的拉应力最大值出现在TiC金属陶瓷的端点处，且随着连接温度的降低拉应力的最大值逐渐降低。TiC金属陶瓷下表面的压应力最大值出现在TiC金属陶瓷中部，且随着连接温度的降低压应力值逐渐增加。     

Investigation on microstructure and mechanical properties of diffusion bonded Al/Mg2Si metal matrix composite using copper interlayer

Diffusion bonding of Al/Mg₂Si metal matrix composite (MMC) using Cu interlayer at optimal bonding temperature of 540 °C for various bonding durations was investigated. This metal matrix composite (MMC) containing 15% Mg₂Si particles was produced by in situ technique. Specific diffusion bonding process was introduced as a low vacuum technique. The composition and microstructure of the joined areas were examined by X-ray diffraction (XRD) and scanning electron microscopy equipped with energy dispersive X-ray spectroscopy (EDS). Microhardness and shear tests were conducted to the samples to evaluate the effect of bonding duration on weldability. Several different diffusion layers exist at the bond region depending on the bonding duration. The shear strength of joints increased with bonding duration due to elimination of CuAl₂ brittle diffusion layer.     

Oxidation behavior of TiC particle-reinforced 304 stainless steel

TiC particle-reinforced 304 stainless steels were prepared using a new developed in situ technology and exhibited the uniform distribution of TiC particles in the matrix. The oxidation behavior of 304SS-2TiC and 304SS-6TiC (all in weight percentage) was compared with that of 304SS at 850 °C in air for 96 h using thermogravimetry analysis. For 304SS, the rate of weight gain was very slow initially, but accelerated suddenly to a very high level, forming breakaway oxidation. The addition of TiC particles to 304SS resulted in no breakaway oxidation and maintained a low oxidation rate in the whole reaction time investigated. Examination of oxide scale morphology and cross-section analysis by scanning electron microscopy and optical microscopy showed a significant scale spallation and a deep oxide penetration in the case of 304SS, but a rather continuous, dense and adherent oxide layer formed on the surface of TiC particle-reinforced alloys. XRD analysis revealed the presence of Cr₂O₃ together with spinel-type oxides in the oxide scale. For TiC-containing alloys, fine TiO₂ was also found on the surface and the amount of this oxide increased with TiC addition. The TiC addition developed finer matrix structure before oxidation, which accelerates chromium diffusion. As a result, scale adherence was improved and oxidation resistance was increased.     

Transient liquid phase bonding of 304 stainless steel using a Co-based interlayer

Transient liquid phase bonding of AISI 304 austenitic stainless steel was carried out using a Co-based interlayer with 40?μm thickness. The effect of bonding time and solid-state homogenisation time on the microstructure and mechanical properties of samples was investigated. The results showed that isothermal solidification was completed within 30?min at a constant temperature of 1180°C. With increasing homogenisation time, at 1000°C, a more uniform distribution of alloying elements and hardness profile across the joint region was achieved. The average shear strength of homogenised samples was about 72% that of the base metal at the same heat treatment cycle.     

Microstructure and mechanical properties of diffusion bonded titanium/304 stainless steel joint with pure Ag interlayer

Abstract

In the present study, diffusion bonding of commercially pure titanium to 304 stainless steel (SS) using a pure Ag interlayer was carried out. It is found that the pure Ag interlayer can effectively block the interdiffusion and interaction between Ti and SS. The resultant joints were composed of Ti substrate, Ti–Ag solid solution, TiAg intermetallic phase, the remnant Ag interlayer and SS. Upon tensile loading, fracture took place through the remnant Ag interlayer, indicating that the TiAg intermetallic phase exhibits no detrimental effect on the strength of the joints. A maximum tensile strength of 421 MPa was achieved, which is notably improved compared with previous results. Furthermore, extensive dimples were observed on the fracture surfaces, clearly indicating that the joints were ductile in nature.     

Interface structure and mechanical properties of Ti(C,N)-based cermet and 17-4PH stainless steel joint brazed with nickel-base filler metal BNi-2

The effects of brazing temperature on microstructure and bonding strength of vacuum brazed joints of Ti(C,N)-based cermet and 17-4 PH stainless steel, using filler metal BNi-2, were investigated. At a lower brazing temperature of 1050 °C, the distribution of melting point depressants (MPD) concentrated on the diffusion affected zone (DAZ) and the brazing seam near the Ti(C,N)-based cermet, the generation of brittle phases in the brazing seam was unavoidable. The uniform distribution of the MPD and full solid solution of γ-nickel occurred in the brazing seam at a higher brazing temperature of 1150 °C. A maximum shear strength of 690 MPa was achieved at a brazing temperature of 1150 °C.     

原位合成TiC弥散强化304不锈钢的高温氧化行为

研究了TiC颗粒增强304不锈钢在950℃的高温氧化性能。结果表明:TiC的加入降低了304不锈钢氧化速率,且随着TiC的加入量越多,氧化速率降低的越明显。进入稳定氧化期后,304钢的氧化遵守线性规律,含2%TiC的304不锈钢氧化遵守线性-抛物线规律,而含6%TiC的304不锈钢的氧化遵守抛物线规律。TiC的加入显著的改善了304不锈钢氧化膜的抗剥落性。     

304不锈钢扩散焊界面的超声非线性成像

运用信号处理技术对扩散焊界面的超声非线性行为进行了研究.首先通过控制焊前表面处理和焊接工艺制备了具有典型缺陷的扩散焊接头,并对其进行超声检测,获得了反映界面状态的超声信号数据.在固相连接接头超声非线性的理论分析、界面超声非线性图像、界面显微特征和接头抗剪强度的基础上,研究了不锈钢扩散焊接头不同界面状态的超声非线性效应.结果表明,非线性超声检测对弱结合缺陷比较敏感,可在一定程度上将超声C扫描成像和超声非线性成像结合起来实现扩散焊接头的无损检测.