共查询到20条相似文献,搜索用时 265 毫秒
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为了解决工业生产中甲醇-丁酮共沸体系难分离的问题,本研究采用一步法合成了N-乙基吡啶溴盐([EPy][Br])、N-丁基吡啶溴盐([BPy][Br])和N-己基吡啶溴盐([HPy][Br])3种离子液体(IL),测定了101.3 kPa下这3种离子液体对甲醇-丁酮共沸物系的溶剂选择性,并考察了溶剂比对其选择性的影响,同时将离子液体的分离性能与有机溶剂进行了比较。实验结果表明:合成的3种离子液体都可提高甲醇对丁酮的相对挥发度,它们的选择性大小顺序为[EPy][Br]> [BPy][Br]> [HPy][Br],同时,它们的选择性随溶剂比的增加而增大,与常规有机溶剂相比,离子液体作为萃取剂具有显著优势。因此,可以选用[EPy][Br]作为分离甲醇-丁酮共沸物系的萃取剂。 相似文献
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离子液体/盐双水相萃取技术的研究进展 总被引:2,自引:0,他引:2
离子液体/盐双水相萃取技术是一种新型的双水相萃取技术。它具有传统双水相萃取技术所不具备的诸多优点。本文介绍了离子液体/盐双水相体系的类型和特点,综述了离子液体/盐双水相萃取技术在生物分离、天然有机物的提取、有毒物质处理中的应用,指出了该技术目前存在的问题并提出今后发展的展望。 相似文献
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加盐萃取精馏分离邻二甲苯-苯乙烯的研究 总被引:1,自引:0,他引:1
测定了不同萃取剂和盐对邻二甲苯-苯乙烯近沸程物系相对挥发度的影响,研究了盐质量浓度、萃取剂加入速率和回流比对加盐萃取精馏的影响,并建立了反映塔顶馏出液中邻二甲苯质量分数与各因素关系的回归模型。研究结果表明,环丁砜(DMSO)-水(质量分数3%)-硫氰酸钾(KCNS,0.03 g/mL)可作为加盐萃取精馏分离邻二甲苯和苯乙烯体系的最佳加盐萃取剂。 相似文献
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浊点萃取技术及其在分离过程中的应用 总被引:6,自引:0,他引:6
浊点萃取(CPE)技术是一种新型的环境友好的溶质富集和分离方法,其应用领域已经自最初的样品分析扩展到大规模的分离过程如水处理和生物产品提取.与传统的溶剂萃取技术相比,该技术具有快速、高效、简便、无需大量有机溶剂等特点.本文简要介绍了浊点萃取技术机理研究的新进展和近期报道的分离过程中的应用. 相似文献
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浊点萃取技术在环境样品分析中的应用 总被引:3,自引:0,他引:3
浊点萃取技术(CPE)是近年来提出的一种新型的液-液、液-固萃取分离提取技术,是将表面活性剂应用于分析化学领域的一种重要而实用的技术,具有萃取效率高、富集因子大、操作简便、安全、无需大量有机溶剂等优点。适用于环境样品中金属离子及痕量有机污染物的分析。本文主要介绍了CPE技术在环境样品分析中的应用,且探讨了该技术的发展前景。 相似文献
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Ana B. Pereiro Ana Rodríguez 《Chemical engineering journal (Lausanne, Switzerland : 1996)》2009,153(1-3):80-85
Ionic liquids (ILs) are playing an increasingly important role in separation science. In this account, the application of ILs in all areas of separation including extraction, gas chromatography, and supported liquid membrane processes is highlighted. 1,3-Dimethylimidazolium methyl sulfate [MMIM] [MeSO4] is suitable for use as solvent in the petrochemical extraction process for the removal of ethanol from its mixture with hexane. The knowledge of liquid–liquid equilibria (LLE) is essential for the design of the separation technique applied. For this reason, the experimental LLE for the ternary system hexane + ethanol + [MMIM] [MeSO4] has been determined at 298.15 K. The solvent capacity of the [MMIM] [MeSO4] is compared with other ILs. Extraction process with this solvent is simulated using conventional software and the obtained results are shown. Experimental data are obtained in a laboratory-scale packed column extraction system for the separation of this azeotropic mixture using [MMIM] [MeSO4]. IL could be recycled and then the separating process reduces the energy consumption greatly. 相似文献
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《分离科学与技术》2012,47(2):285-290
Abstract Mesityl oxide (4-methyl-3-pentene-2-one) has been used extensively for the solvent extraction separation of several transition elements (l). In the present communication, solvent extraction behavior of indium (III) toward mesityl oxide as a function of HCl or HBr concentrations has been studied and a simple and rapid method for the solvent extraction separation of gallium, indium, and aluminum has been proposed. 相似文献
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J. A. Singleton L. F. Stikeleather 《Journal of the American Oil Chemists' Society》1995,72(4):481-483
This paper discusses the details of a high-performance liquid chromatography method for the simultaneous concentration and
separation of phospholipids or other trace compounds by direct oil injection using two different solvent systems. The system
equilibrates and concentrates phospholipids on a silica column using hexane. At the same time, an analytical column is equilibrating
and separating phospholipids using two binary solvent mixtures. This system eliminates a preconcentration step previously
accomplished by solid-phase extraction, open-column chromatography, and other previously used methodology. Other advantages
include: a 40% reduction in analysis time, elimination of a second transfer of labile compounds, decreased solvent use, and
a simpler array of solvents to separate phospholipids. The method described has broader applications, such as trace organic
compounds in water supplies, and trace metals with appropriate modifications for the particular analysis. 相似文献
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Predispersed solvent extraction (PDSE) is a new method for separating solutes from aqueous solution by solvent extraction and one which has shown promise for extraction from extremely dilute solution very efficient and very quick. The use of colloidal liquid aphrons in predispersed solvent extraction may ameliorate the problems such as emulsion formation, reduction of interracial mass transfer and low interfacial mass transfer areas in solvent extraction process. In present paper, colloidal liquid aphrons are successfully generated using kerosene as a solvent,tributyl phosphate(TBP) as an extractant, sodium dodecyl benzene sulphate(SDBS) as surfactant in aqueous phase and Tween-80 in oil phase. Extraction of phenol from dilute solution was studied by using colloidal liquid aphrons and colloidal gas aphrons in a semi-batch extraction column. It has been found that the PDSE process is more suitable for extraction of dilute solutions. It has also been discovered that the PDSE process has a great advantage over traditional single-stage extraction process. 相似文献
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Gregg J. Lumetta Tatiana G. Levitskaia Andreas Wilden Amanda J. Casella Gabriel B. Hall Leigh Lin 《溶剂提取与离子交换》2017,35(6):377-395
A solvent extraction system was developed for separating trivalent actinides from lanthanides. This “Advanced TALSPEAK” system uses 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP]) to extract the lanthanides into an n-dodecane-based solvent; the actinides are retained in a citrate-buffered aqueous phase by complexation to a polyaminocarboxylate ligand. Several aqueous-phase ligands were investigated, and N-(2-hydroxyethyl)ethylenediamine-N,N’,N’-triacetic acid (HEDTA) was chosen for further study. Batch distribution measurements indicate that the separation of americium (Am) from the light lanthanides increases as the pH increases. However, previous investigations indicated that the extraction rates for the heavier lanthanides decrease with increasing pH. Therefore, a balance between these competing effects is required. An aqueous phase at pH 2.6 was chosen for further process development, because this offered optimal separation. Centrifugal-contactor single-stage efficiencies were measured to characterize the system’s performance under flow conditions, and an Advanced TALSPEAK flowsheet was designed. 相似文献
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Vanessa E Holfeltz Emily L. Campbell Dean R. Peterman Robert F. Standaert Alena Paulenova Gregg J. Lumetta 《溶剂提取与离子交换》2018,36(1):22-40
In solvent extraction processes, organic phase impurities can negatively impact separation factors, hydrolytic performance, and overall system robustness. The resulting inconsistent performance can affect the process-level viability of a separation concept, and thus knowledge of the impurities present, their effects on the process, and how to remove them are vital. Deleterious impurities may be introduced into a system from reagent synthesis, or result from degradation via radiolysis and hydrolysis during use. In this work, the acidic extractant, 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP])—proposed for application in extractive processes aimed at separating trivalent minor actinides from lanthanides and other fission products—is characterized with respect to its common impurities and their impact on Am(III) stripping in the Actinide Lanthanide SEParation (ALSEP) system. To control impurities in HEH[EHP], existing purification technologies commonly applied for the acidic organophosphorus reagent were assessed and a new chromatographic purification method specific to HEH[EHP] is presented. 相似文献