共查询到20条相似文献,搜索用时 31 毫秒
1.
Mohamad Reza Toorani Reza Farhoosh Mohamad-Taghi Golmakani Ali Sharif 《Journal of the American Oil Chemists' Society》2021,98(8):871-880
Oxidation kinetics of the triacylglycerols (TAGs) and fatty acid methyl esters (FAMEs) of sesame, olive, and canola oils were studied in the presence of the different concentrations of sesamol (0.1%–0.16%) at 60, 80, and 100°C. Sesamol increased the temperature coefficient, TC, and Q10 number of the TAGs more significantly compared to the FAMEs. All the sesamol-added TAG and FAME systems, respectively, of the olive, canola, and sesame oils, respectively, exerted increased values of the Arrhenius (activation energy, Ea, and frequency factor, A) and Eyring (enthalpy, ΔH++, and entropy, ΔS++) equation parameters. Sesamol improved the Gibbs free energy (ΔG++) of the activated complex formation in the canola, sesame, and olive systems, respectively, and the effect was greater in the FAMEs. 相似文献
2.
Weiguo Lang Shahab Sokhansanj Frank W. Sosulski 《Journal of the American Oil Chemists' Society》1992,69(10):1054-1055
Viscosities of refined, bleached, deodorized (RBD) and refined, bleached, winterized (RBW) canola oils were measured at temperatures
from 4 to 100°C. The viscosities of these refined canola oils were exponentially related to the oil temperature. Viscosity
of the RBW oil was slightly greater than that of the RBD oil when the temperature was below 15°C. Compared to refined soybean
oil, the canola oils were substantially more viscous. The viscosity of canola oil was modelled asv = exp(C0 + C1T + C2T2). The maximum predicted error was less than 1.6% over the tested temperature range. 相似文献
3.
Detection of Adulteration in Iranian Olive Oils Using Instrumental (GC,NMR, DSC) Methods 总被引:2,自引:0,他引:2
Maryam Jafari Mahdi Kadivar Javad Keramat 《Journal of the American Oil Chemists' Society》2009,86(2):103-110
This paper describes an investigation into the usefulness of some instrumental methods (GC, NMR, and DSC) in the detection
of adulteration of olive oil with soybean, sunflower, and canola oils (that are relatively cheap oils mixed as adulterants
with olive oil). These seed oils were compared with genuine and commercial olive oils, two of which appeared to have been
adulterated. It was observed that from among physical and chemical indices, the iodine value and the refractive index in the
two olive oil samples (named A and B) were significantly higher (P < 0.01) than in the reference (genuine) olive oil, both values being above standard limits established for olive oil. On
the other hand, fatty acid (FA) profiles in these two samples exhibited higher amounts of linolenic and linoleic acids (5.34
and 39.92%, 6.38 and 54.42%, 0.79 and 12.88% for A, B and genuine olive oils respectively) but significantly lower amounts
of oleic acid (30.07, 21.72 and 67.86%, respectively). The number and intensity of signals observed using 1H NMR indicated that the peaks numbered 2 and 7 were useful in the determination of olive oil purity. Because of higher linolenic
and linoleic acid contents in samples A and B, the intensity and integrated areas for these two signals were higher than those
for other olive oil samples in which signal 2 was not observed and signal 7 had a very low intensity. Satisfactory results
were achieved from quantitation of DSC parameters. The results show that due to increased unsaturated FAs in samples A and
B and the consequent changes in triacylglycerol profiles, offset crystallization temperature and onset melting temperature
in these two olive oils differed from those of the reference and clearly shifted to lower values. Crystallization and melting
curves were similar to the corresponding curves observed for soybean and sunflower oils in terms of shape and number of peaks. 相似文献
4.
Reza Farhoosh Seyedeh-Zohreh Hoseini-Yazdi 《Journal of the American Oil Chemists' Society》2014,91(2):281-293
A comparative study was carried out in order to evaluate the kinetics of the formation of a number of primary and secondary oxidation products during oxidation of olive oil in the Rancimat test at 100–130 °C. There were good correlations between the Rancimat index (OSI) and stability indices (IP) measured in the Rancimat test with no significant differences in kinetic parameters calculated from them. Mean values of the temperature coefficient, Q10 number, activation energy (Ea), frequency factor (A), and free energy of activation (ΔG++) for olive oil oxidation were calculated to be ?3.44 × 10?2°C?1, 2.21, 98.91 kJ/mol, 12.17 × 1012 h?1, and 128.25 kJ/mol, respectively. Each unit change in Ea was accompanied by an average 1.43 × 1012 change in A, indicating a higher contribution for factor A than for Ea to the olive oil stability. The Ea and A correlated well with the values of enthalpy and entropy, respectively. The values of OSI or IP could be described well by the ΔG++ values. Kinetic data indicated that olive oil stability is more affected by the indigenous antioxidants than by the fatty acid composition. 相似文献
5.
Patrizia Comandini Vito Verardo Paola Maiocchi Maria Fiorenza Caboni 《European Journal of Lipid Science and Technology》2009,111(9):933-940
Accelerated oxidation tests, such as the determination of the induction period, increase the lipid oxidation rate by exposing a food to elevated temperatures, in the presence of excess quantities of air or oxygen. In addition to the well‐founded oxidative stability index (OSI) method, an innovative and promising technique is the oxidation test (OXITEST) reactor. A new analytical method was developed with OXITEST to oxidize vegetable oils. At a preliminary stage of the investigation, the induction periods of sunflower and extra‐virgin olive oil obtained by the OXITEST reactor were plotted against temperature, on the basis of the Arrhenius law; the activation energy and the frequency factor of lipid oxidation were calculated and resulted in 98.61 kJ/mol and 2.33×1010 s–1, respectively, for sunflower oil and 106.48 kJ/mol and 6.27×1010 s–1, respectively for extra‐virgin olive oil. The new oxidative technique was employed to determine the induction periods of vegetable oils; the results obtained were well correlated with those achieved with OSI technology, with a Pearson correlation coefficient r = 0.9785 (p <0.05) for oilseeds and palm oil and r = 0.9501 (p <0.05) for extra‐virgin olive oils. 相似文献
6.
The purpose of this investigation was to study differences in the chlorophyll, carotenoid, and phenolic fractions of virgin
olive oils from the Arbequina variety cultivated in different olive growing areas of Spain. Virgin olive oil from Lleida was
less heavily pigmented, and these oils showed more negative values for the ordinate a* (of the CIELAB colorimetric system). Pheophytin a was the major chlorophyll pigment, and lutein was the major component of the carotenoid fraction in all oils analyzed. The
chlorophyll a concentration in virgin olive oils from Lleida was 700 μg kg−1, but was 175 μg kg−1 in oils from Jaén, and 200 μg kg−1 in oils from Tarragona. Finally, the chlorophyll a/chlorophyll b ratio was 9 in oils from Lleida and around 0.6 in the other two Arbequina olive oils. In relation to the phenolic fraction,
the hydroxytyrosol and tyrosol contents were significantly higher in olive oils from Jaén (grown at higher altitude and precipitation
rates). The secoiridoid derivatives showed a significantly higher concentration in olive oils from Tarragona, probably due
to the low altitude where they grow, and finally the ratio of (dialdehydic form of elenolic acid linked to tyrosol)/lignans
had a value of 1.4 in olive oils from Lleida, whereas this value was around 0.7 in the other Arbequina olive oils. 相似文献
7.
Ratjika Chanamai D. Julian McClements 《Journal of the American Oil Chemists' Society》1998,75(10):1447-1448
The frequency dependence (1–60 MHz) of the ultrasonic attenuation coefficient of canola oil, corn oil, olive oil, peanut oil,
safflower oil, soybean oil, and sunflower oil was measured at 25°C. The attenuation coefficient of all the oils could be described
by the relation: α ∼ Af
n(with A between 6 and 40 × 10−12, and n between 1.74 and 1.86). 相似文献
8.
Bioactive Compounds of Portuguese Virgin Olive Oils Discriminate Cultivar and Ripening Stage
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Fátima Peres Luisa L. Martins Miguel Mourato Conceição Vitorino Suzana Ferreira-Dias 《Journal of the American Oil Chemists' Society》2016,93(8):1137-1147
The presence of different bioactive compounds in virgin olive oil affects its nutritional, oxidative and sensorial properties. Phenolic compounds are olive endogenous bioactive compounds highly susceptible to degradation. Olive endogenous oxidoreductases, mainly polyphenol oxidases (PPO) and peroxidases (POD), may play an important role on the profile of bioactive compounds in olive oil by promoting oxidation of phenolic compounds. The aim of this study was to evaluate if changes on PPO and POD activities in olive fruits from two Portuguese cultivars (Olea europaea, cv ‘Cobrançosa’ and cv ‘Galega Vulgar’) are related with the composition of their olive oils, especially phenolic compounds. Pattern recognition techniques [principal component analysis (PCA), cluster analysis (CA), and discriminant analysis (DA)] were used for multivariate data analysis. Olive oils characterized by their FA composition were grouped by cultivar. When olive oils were characterized by their phenolic composition, green pigments, and enzymatic activities in fruits, they could be discriminated by olive ripening stage. Along ripening, PPO activity was only detected in the fruit mesocarp of both cultivars and POD activity was mainly detected in the seeds. The POD activity, as well as vanillin and gamma‐tocopherol contents in olive oil increased with the ripening index. Conversely, higher PPO activity in fruits at early ripening stages together with higher levels of total phenols, green pigments, beta‐tocopherol, hydroxytyrosol and p‐coumaric acid in olive oils were observed. The ripening stage of fruits showed to be a key factor on the amount and profile of bioactive compounds of olive oil. 相似文献
9.
Elizabeth M. Prior Vivekenand S. Vadke Frank W. Sosulski 《Journal of the American Oil Chemists' Society》1991,68(6):407-411
Oxidative stability of the canola press oils increased with increasing heat treatment to the seed, and decreased on refining.
The tocopherol content of the press oils was relatively uniform and could not account for the observed variations in oxidative
stability. The variation in stability corresponded to variations in the content of other non-triglyceride components. In general,
the greater the initial quality of the oils,i.e., the lower the content of non-triglyceride material, the lower their oxidative stability. Oxidative stability was found to
be significantly correlated to phosphorus content (R2>0.99). This could be explained by synergism between tocopherols and phospholipids, in the range from 0.025% to 0.22% phospholipid.
Above this level increasing the phosholipid content did not significantly improve the oxidative stability. After oxidation
the oils were“bleached”,i.e., there was a loss of color bodies. This loss was related to both the original content of color bodies in the oil and the
degree of oxidation of the oil. 相似文献
10.
Estela Sena‐Moreno Manuel Cabrera‐Bañegil Juan M. Pérez‐Rodríguez Concepción De Miguel María H. Prieto Daniel Martín‐Vertedor 《Journal of the American Oil Chemists' Society》2018,95(3):349-359
The main objective of this study was to evaluate the effect of different deficit irrigation treatments (control, regulated deficit irrigation [RDI]‐1, RDI‐2, and RDI‐3) on the phenolic profile of the olive paste and oil content. Irrigation treatments with more stress water led to a considerable increase in the phenolic compounds of olive paste, especially in oleuropein (60.24%), hydroxytyrosol (82%), tyrosol (195%), and verbascoside (223%) compared to control. A significant increase in the content of total flavonoids and phenolic acids was also observed for these samples. In virgin olive oils (VOO) elaborated from the most stressed olive trees (RDI‐2 and RDI‐3), a noticeable increase in phenolic substances with antioxidant properties (oleuropein, hydroxytyrosol, tyrosol, secoiridoid derivatives, and o‐vanillin) was observed. Consequently, water stress conditions improved antioxidant activity of VOO. 相似文献
11.
We examined growth performance and the lipid content in juvenile cobia, Rachycentron canadum, fed a taurine supplemented (1.5 %), plant protein based diet with two fish oil replacements. The first fish oil replacement was a thraustochytrid meal (TM + SOY) plus soybean oil (~9 % CL) and the second was a canola oil supplemented with the essential fatty acids (EFA) docosahexaenoic acid (DHA) and arachidonic acid (ARA) (~8 % CL). The diet using the thraustochytrid meal plus soybean oil performed equivalently to the fish oil diet; both resulting in significantly higher growth rates, lower feed conversion ratios, and higher survival than the supplemented canola oil diet, even though all three diets were similar in overall energy and met known protein and lipid requirements for cobia. The poor performance of the canola oil diet was attributed to insufficient addition of EFA in the supplemented canola oil source. Increasing levels of EFA in the supplemented canola oil above 0.5 g EFA kg?1 would likely improve results with cobia. When fish fed either of the fish oil replacement diets were switched to the fish oil control diet, fatty acid profiles of the fillets were observed to transition toward that of the fish oil diet and could be predicted based on a standard dilution model. Based on these findings, a formulated diet for cobia can be produced without fish products providing 100 % survivorship, specific growth rates greater than 2.45 and feed conversion ratios less than 1.5, as long as taurine is added and EFA levels are above 0.5 g EFA kg?1. 相似文献
12.
Effect of natural antioxidants in virgin olive oil on oxidative stability of refined,bleached, and deodorized olive oil 总被引:1,自引:0,他引:1
M. Teresa Satue Shu-Wen Huang Edwin N. Frankel 《Journal of the American Oil Chemists' Society》1995,72(10):1131-1137
The factors influencing the oxidative stability of different commercial olive oils were evaluated. Comparisons were made of
(i) the oxidative stability of commercial olive oils with that of a refined, bleached, and deodorized (RBD) olive oil, and
(ii) the antioxidant activity of a mixture of phenolic compounds extracted from virgin olive oil with that of pure compounds
andα-tocopherol added to RBD olive oil. The progress of oxidation at 60°C was followed by measuring both the formation (peroxide
value, PV) and the decomposition (hexanal and volatiles) of hydroperoxides. The trends in antioxidant activity were different
according to whether PV or hexanal were measured. Although the virgin olive oils contained higher levels of phenolic compounds
than did the refined and RBD oils, their oxidative stability was significantly decreased by their high initial PV. Phenolic
compounds extracted from virgin olive oils increased the oxidative stability of RBD olive oil. On the basis of PV, the phenol
extract had the best antioxidant activity at 50 ppm, as gallic acid equivalents, but on the basis of hexanal formation, better
antioxidant activity was observed at 100 and 200 ppm.α-Tocopherol behaved as a prooxidant at high concentrations (>250 ppm) on the basis of PV, but was more effective than the
other antioxidants in inhibiting hexanal formation in RBD olive oil.o-Diphenols (caffeic acid) and, to a lesser extent, substitutedo-diphenols (ferulic and vanillic acids), showed better antioxidant activity than monophenols (p- ando-coumaric), based on both PV and hexanal formation. This study emphasizes the need to measure at least two oxidation parameters
to better evaluate antioxidants and the oxidative stability of olive oils. The antioxidant effectiveness of phenolic compounds
in virgin olive oils can be significantly diminished in oils if their initial PV are too high. 相似文献
13.
Alfonso Ranalli Stefania Contento Carlo Schiavone Nicola Simone 《European Journal of Lipid Science and Technology》2001,103(4):228-238
Three Italian olive varieties (Caroleo, Leccino and Dritta) were processed by centrifugation in the oil mill. The olive paste was kneaded at 20, 25, 30 and 35 °C. The results achieved revealed that the oil content in green volatiles from lipoxygenase pathway (including C5 and C6 compounds and especially unsaturated C6 aldehydes) decreased progressively as the kneading temperature increased, dropping markedly at 35 °C. The content of phenols, o‐diphenols and secoiridoids showed an opposite trend, but the temperature of 35 °C was critical also for them, as it was for the majority of the other components, analytical parameters and indices related to quality, typicality and genuineness. In general, an increasing kneading temperatures increased the release of oil constituents from the vegetable tissue. This factor also affected the oil extraction yields. The best overall results were achieved by malaxing the olive paste at 30 °C. In fact, this temperature level led to achieving both pleasant green virgin olive oils and satisfactory oil extraction outputs. 相似文献
14.
Characterization and oxidative stability of enzymatically produced fish and canola oil-based structured lipids 总被引:1,自引:7,他引:1
Casimir C. Akoh Charment O. Moussata 《Journal of the American Oil Chemists' Society》2001,78(1):25-30
Two-kilogram quantities of structured lipids (SL) of menhaden fish and canola oils containing caprylic acids (8∶0) were produced
in a laboratory-scale packed-bed bioreactor by acidolysis catalyzed by an immobilized lipase, Lipozyme IM, from Rhizomucor miehei. SL were characterized and their oxidative stabilities investigated. The SL contained 29.5% 8∶0 for fish oil and 40.15 for
canola oil. Polyunsaturated fatty acids (PUFA) of fish oil remained unchanged after the modification while PUFA of canola
oil were reduced from 29.6 to 21.2%. Monoenes, especially 18∶1n−9, were completely replaced by 8∶0 in fish oil and reduced
from 61.9 to 34.7% in canola oil. Downstream processing of enzymatically produced SL led to loss in natural total tocopherol
contents of the fish and canola oils. The effects of antioxidants such as α-tocopherol (TOC), tert-butylhydroxyquinone (TBHQ), and combinations thereof on the oxidative stability of SL were investigated. SL were analyzed
for oxidative stability index, peroxide value, conjugated diene content, free fatty acid content, iodine value, saponification
number, and thiobarbituric acid value. Iodine value of unmodified fish oil (154.71) was reduced to 144.10 and that of canola
oil (114.49) to 97.27 after modification. The SN increased from 183.72 to 242.63 for fish oil and from 172.50 to 227.90 for
canola oil. TBHQ exhibited better antioxidant effects than TOC. A combination of TBHQ/TOC also proved to be an effective antioxidant
for SL. We suggest the addition of antioxidants to enzymatically produced and purified SL. 相似文献
15.
Federica Flamminii Elettra Marone Lilia Neri Luciano Pollastri Angelo Cichelli Carla Daniela Di Mattia 《European Journal of Lipid Science and Technology》2021,123(11):2000382
Despite the fact that Italy holds the most important olives heritage in the world, with about 800 cultivars, most of them are still underestimated, in particular those from Abruzzo, a region located in the center of the peninsula. The aim of this work is to study the changes in quality parameters of olive fruits and related oils of two autochthonous Abruzzo olive cultivars, Tortiglione and Dritta during ripening (from September to November 2017). Both cultivar and ripening time affect the chemical parameters of olive fruits. Results highlight an increasing trend of the oil content with final values, based on fresh matter, of 38.7 ± 0.3% and 38.1 ± 0.9% for Tortiglione and Dritta, respectively. Olive oils chemical composition is also affected by ripening time and cultivar, with Tortiglione oils resulting generally richer than Dritta oils; on the first sampling time (30th of October) values for total phenolic content, antioxidant activity, and chlorophylls are 803.8 ± 68.2 mg gallic acid equivalent kg−1, 2.7 ± 0.5 mmol trolox equivalent kg−1, and 30.8 ± 1.6 mg pheophytin a kg−1, respectively. Tocopherols seem to be more affected by ripening time than by cultivar, in particular for Dritta. Practical Application : The results on Abruzzo minor olive cultivars indicate that olive fruits and olive oil composition are strongly influenced by both cultivar and ripening time, giving rational indications about the optimal cultivar specific harvesting time and opening interesting opportunities for olive oil producers in a perspective of sustainable production to obtain high quality fruits and oils. The research provides detailed information about Tortiglione and Dritta olive cultivar, useful in the global context of revaluation of Italian minor olive varieties. 相似文献
16.
In this study, the effect of deep fat frying on oil degradation, total phenols (TP) and total antioxidant activity (TAA) of
hazelnut, corn, soybean and olive oils were investigated. Oil degradation and oxidation were monitored by measuring the total
polar compounds (TPC) and the peroxide value (PV). The amount of TPC in corn, soybean and olive oils increased significantly
with the time increment (p < 0.05). The PV of the oils did not exceed the maximum acceptable limit of 10 mequiv O2/kg after 125 min frying except for hazelnut oil (10.64 mequiv O2/kg). Deep-fat frying did not cause any significant change in the TP of corn oil, soybean oil and olive oil (p < 0.05). A significant decrease in the antioxidant activity was observed after 50 min frying using hazelnut oil and corn
oil (p < 0.05). However, the antioxidant activity of soybean oil and olive oil significantly decreased after 75 and 25 min frying,
respectively. 相似文献
17.
Eda Köse Baran Sema Bağdat Yaşar 《European Journal of Lipid Science and Technology》2012,114(11):1320-1326
A new method has been developed for the extraction and determination of zinc and nickel in liquid edible oils by using the complexation of these metals with [N,N′‐bis(salicylidene)‐2,2′‐dimethyl‐1,3‐propanediaminato]. Zn(II) and Ni(II) complexes with a tetradentate Schiff base have been investigated spectrophotometrically. Experimental extraction conditions for these metals from liquid oil standards were optimized using central composite design. Optimum conditions for Zn(II) and Ni(II) extractions from oil have been found close to each other. The ratio of the volume of used Schiff base solution to the amount of oil (VLDM/moil; mL/g), the stirring time and the temperature were round about 1.00 mL/g, 55 min, 32°C, respectively, for simultaneous determination of both metals in same sample. The recovery percentages at the optimum experimental conditions were found 98.9 ± 2.8 and 101.8 ± 4.7 for Zn(II) and Ni(II), respectively. The proposed method was applied on the raw and spiked samples such as olive oil, sunflower oil, corn oil, canola oil and obtained recovery values were between 93.7–107.2 and 93.1–101.1% for Zn(II) and Ni(II), respectively. Practical applications: There is interest in the determination of metals in liquid edible oils because of their catalytic effect on the oxidation reaction of oils. A new method for the determination of Zn(II) and Ni(II) in liquid edible oils which does not require any digestion or decomposition was developed. This study offeres a cheap, rapid, accurate, sensitive, risk‐free, and practical metal determination method after the extraction. 相似文献
18.
Derya Alkan Figen Tokatli Banu Ozen 《Journal of the American Oil Chemists' Society》2012,89(2):261-268
The aim of this research was to characterize the extra virgin olive oil samples from different locations in the Aegean coastal
area of Turkey in terms of their phenolic compositions for two consecutive years to show the classification of oil samples
with respect to harvest year and geography. Forty seven commercial olive oil samples were analyzed with HPLC–DAD, and 17 phenolic
compounds were quantified. Hydroxytyrosol, tyrosol, vanillic acid, p-coumaric acid, ferulic acid, cinnamic acid, luteolin and apigenin were the characteristic phenols observed in all oil samples
for two harvest years. Syringic acid, vanillin and m-coumaric acid were the phenolic compounds appeared in the olive oil depending on the harvest year. Partial least square-discriminant
analysis (PLS-DA) of data revealed that oils from the north Aegean and south Aegean areas had different phenolic profiles.
The phenolic compounds, which played significant roles in the discrimination of the olive oils, were tyrosol, oleuropein aglycon,
cinnamic acid, apigenin and hydroxytyrosol to tyrosol ratio. The Aegean coastal region is the largest olive oil producer and
exporter of Turkey. This study shows that the olive oils from different parts of the region have their own defining characteristics
that can be used in the authentication studies and geographical labeling of Turkish olive oils. 相似文献
19.
Georgios Blekas Eleni Psomiadou Maria Tsimidou Dimitrios Boskou 《European Journal of Lipid Science and Technology》2002,104(6):340-346
A large number of virgin olive oil samples obtained from different areas in Greece were analyzed for various quality parameters. The work focuses on the colorimetric determination of total phenols with the Folin‐Ciocalteu reagent and its importance in predicting shelf life of virgin olive oil. The results indicate a good correlation of total polar phenol content with the stability of the oil. Colorimetric determination of ortho‐diphenol content does not seem to be a better means for predicting virgin olive oil stability. RP‐HPLC quantification of hydroxytyrosol and tyrosol in their free form gives poor results in the case of freshly extracted oils. It is concluded that until an easy‐to‐manage HPLC method will be available, which will quantify accurately both free and bound forms of hydroxytyrosol and other phenolics, the colorimetric method for the determination of total polar phenols remains a good practical means to evaluate the stability of virgin olive oil. 相似文献
20.
Application of arrhenius kinetics to evaluate oxidative stability in vegetable oils by isothermal differential scanning calorimetry 总被引:1,自引:0,他引:1
C. P. Tan Y. B. Che Man J. Selamat M. S. A. Yusoff 《Journal of the American Oil Chemists' Society》2001,78(11):1133-1138
In this study, 10 different vegetable oils were oxidized at four different isothermal temperatures (383, 393, 403, and 413
K) in a differential scanning calorimeter (DSC). The protocol involved oxidizing vegetable oils in a DSC cell with oxygen
flow. A rapid increase in evolved heat was observed with an exothermic heat flow appearing during initiation of the oxidation
reaction. From this resulting exotherm, the onset of oxidation time (T
o) was determined graphically by the DSC instrument. In our experimental data, linear relationships were determined by extrapolation
of the log (T
o) against isothermal temperature. The rates of lipid oxidation were highly correlated with temperature. In addition, based
on the Arrhenius equation and activated complex theory, reaction rate constants (k), activation energies (E
a), activation enthalpies (ΔH
‡), and activation entropies (ΔS
‡) for oxidative stability of vegetable oils were calculated. The E
a′, ΔH
‡, and ΔS
‡ for all vegetable oils ranged from 79 to −104 kJ mol−1, from 76 to −101 kJ mol−1, and from −99 to −20 J K−1 mol−1, respectively. Based on the results obtained, differential scanning calorimetry appears to be a useful new instrumental method
for kinetic analysis of lipid oxidation in vegetable oil. 相似文献