Dynamic modeling of a photovoltaic hydrogen fuel cell hybrid system

The objective of this paper is to mathematically model a stand-alone renewable power system, referred to as “Photovoltaic–Fuel Cell (PVFC) hybrid system”, which maximizes the use of a renewable energy source. It comprises a photovoltaic generator (PV), a water electrolyzer, a hydrogen tank, and a proton exchange membrane (PEM) fuel cell generator. A multi-domain simulation platform Simplorer is employed to model the PVFC hybrid systems. Electrical power from the PV generator meets the user loads when there is sufficient solar radiation. The excess power from the PV generator is then used for water electrolysis to produce hydrogen. The fuel cell generator works as a backup generator to supplement the load demands when the PV energy is deficient during a period of low solar radiation, which keeps the system's reliability at the same level as for the conventional system. Case studies using the present model have shown that the present hybrid system has successfully tracked the daily power consumption in a typical family. It also verifies the effectiveness of the proposed management approach for operation of a stand-alone hybrid system, which is essential for determining a control strategy to ensure efficient and reliable operation of each part of the hybrid system. The present model scheme can be helpful in the design and performance analysis of a complex hybrid-power system prior to practical realization.     

Experimental investigation on the dynamic performance of a hybrid PEM fuel cell/battery system for lightweight electric vehicle application

A hybrid system combining a 2 kW air-blowing proton exchange membrane fuel cell (PEMFC) stack and a lead–acid battery pack is developed for a lightweight cruising vehicle. The dynamic performances of this PEMFC system with and without the assistance of the batteries are systematically investigated in a series of laboratory and road tests. The stack current and voltage have timely dynamic responses to the load variations. Particularly, the current overshoot and voltage undershoot both happen during the step-up load tests. These phenomena are closely related to the charge double-layer effect and the mass transfer mechanisms such as the water and gas transport and distribution in the fuel cell. When the external load is beyond the range of the fuel cell system, the battery immediately participates in power output with a higher transient discharging current especially in the accelerating and climbing processes. The DC–DC converter exhibits a satisfying performance in adaptive modulation. It helps rectify the voltage output in a rigid manner and prevent the fuel cell system from being overloaded. The dynamic responses of other operating parameters such as the anodic operating pressure and the inlet and outlet temperatures are also investigated. The results show that such a hybrid system is able to dynamically satisfy the vehicular power demand.     

Fuel cell-battery hybrid powered light electric vehicle (golf cart): Influence of fuel cell on the driving performance

A light electric vehicle (golf cart, 5 kW nominal motor power) was integrated with a commercial 1.2 kW PEM fuel cell system, and fuelled by compressed hydrogen (two composite cylinders, 6.8 L/300 bar each). Comparative driving tests in the battery and hybrid (battery + fuel cell) powering modes were performed. The introduction of the fuel cell was shown to result in extending the driving range by 63–110%, when the amount of the stored H₂ fuel varied within 55–100% of the maximum capacity. The operation in the hybrid mode resulted in more stable driving performances, as well as in the increase of the total energy both withdrawn by the vehicle and returned to the vehicle battery during the driving. Statistical analysis of the power patterns taken during the driving in the battery and hybrid-powering modes showed that the latter provided stable operation in a wider power range, including higher frequency and higher average values of the peak power.     

The study on the power management system in a fuel cell hybrid vehicle

This paper presents a model of a hybrid electric vehicle, based on a primary proton exchange membrane fuel cell (PEMFC) and an auxiliary Li-ion battery, and its dynamics and overall performance. The power voltage from the fuel cell is regulated by a DC/DC converter before integrating with the Li-ion battery, which provides energy to the drive motor. The driving force for propelling the wheels comes from a permanent magnet synchronous motor (PMSM); where the power passes through the transmission, shaft, and the differential.     

Design and testing of a 9.5 kWe proton exchange membrane fuel cell–supercapacitor passive hybrid system

The design and test of a 9.5 kWe proton exchange membrane fuel cell passively coupled with a 33 × 1500 F supercapacitor pack is presented. Experimental results showed that the system reduced dynamic loads on the fuel cell without the need for additional DC/DC converters. Fuel efficiency gains of approximately 5% were achieved by passive hybridisation in addition to addressing two main operational degradation mechanisms: no-load idling and rapid load cycling.     

Design and set up of a hybrid power system (PV-WT-URFC) for a stand-alone application in Mexico

The Mexican territory has a large potential for renewable energy development, such as geothermal, hydro, biofuels, wind and solar. Thus, a 2.5 kW hybrid power system (solar, wind and hydrogen) was designed and installed to meet the power demand for a stand-alone application at the University of Zacatecas. The hybrid unit integrates three power energy sources –a photovoltaic system (PV), a micro-wind turbine (WT), a prototype of a unitized regenerative fuel cell (URFC) and energy storage devices (batteries)– in addition to their interaction methodology. The main contribution of this work is the URFC integration to a hybrid power system for the production of H₂ (water electrolyzer mode) and energy (fuel cell mode). These three energy technologies were connected in parallel, synchronized to the energy storage system and finally coupled to a power conversion module. To achieve the best performance and energy management, an energy management and control strategy was developed to the properly operation of the power plant. A meteorological station that has wireless sensors for the temperature, the humidity, the solar radiation and the wind speed provides the necessary information (in real time) to the monitor and control software, which computes and executes the short and mid–term decisions about the energy management and the data storage for future analysis.     

Numerical modeling of a non-flooding hybrid polymer electrolyte fuel cell

Experimental results were recently reported regarding a novel “non-flooding” hybrid fuel cell consisting of proton exchange membrane (PEM) and anion exchange membrane (AEM) half-cells on opposite sides of a water-filled, porous intermediate layer. Product water formed in the porous layer, where it could permeate to the exterior of the cell, rather than at the electrodes. Although electrode flooding was mitigated, the reported power output was low. To investigate the potential for increased power output, a physicochemical charge transport model of the porous electrolyte layer is reported here. Traditional electrochemical modeling was generalized in a novel way to consider both ion transport and reaction in the aqueous phase and electronic conduction in the graphitic scaffold using a unified Poisson–Nernst–Planck framework. Though the model used no arbitrary or fitting parameters, the ionic resistance calculated for the porous layer agreed well with the highly non-Ohmic experimental values previously reported for the entire fuel cell. Interestingly, electronic charge carriers in the scaffold were found to obviate the need for counterion presence in this unique electrolyte structure. Still, the thickness- and temperature-dependent model results offer limited prospects for improving the power output.     

A hybrid PEMFC/supercapacitor device with high energy and power densities based on reduced graphene oxide/Nafion/Pt electrode

Proton exchange membrane fuel cells (PEMFCs) possess high energy and low power densities, while supercapacitors are characterized by high power and low energy densities. A hybrid PEMFC/supercapacitor device (HPSD) with high energy and power densities was proposed and fabricated for the first time using a reduced graphene oxide/Nafion/Pt electrode in this study. The reduced graphene oxide (rGO) was a capacitive material, and Pt was used as the electrocatalyst. Nafion ionomers adsorbed onto the rGO sheets surface and connected the rGO sheets and the electrolyte (Nafion membrane), thus increasing the utilization rate and specific capacitance of rGO. During the half-cell tests, the rGO/Nafion/Pt electrode exhibited better pulse discharge and galvanostatic discharge performance than the conventional Nafion/Pt electrode. Due to the unique synergy of electrochemical reaction current and capacitance current during the discharge process, the HPSD exhibited a higher power density (26.2 kW kg⁻¹) than the PEMFC (23.9 kW kg⁻¹). The energy density (12.7 kWh kg⁻¹) exhibited by HPSD was close to that of the PEMFC (13.5 kWh kg⁻¹). Therefore, the concept of HPSD is to create a new method for developing next-generation electrochemical devices with high energy and power densities.     

Catalytic combustion and system performance assessment of MCFC-MGT hybrid system

The catalytic combustor is applied as an off-gas and startup combustor for a molten carbonate fuel cell-micro-gas turbine (MCFC-MGT) hybrid system (HS) so as to utilize the waste energy of fuel cell off-gas. Three types of catalysts are prepared over a cordieritic honeycomb support. One is Pt catalyst which is not cost effective and less high temperature stability. CeZrO₂ and LaMnO₃ have been selected as an additive for another two Pt catalysts to improve the performance. Tests have been completed in realistic conditions and reaction feed close to the MCFC-MGT hybrid system. Simulations are carried out with a fluid mechanical code that incorporates detailed transport and heat loss mechanisms. The simulation results are compared with the Pt catalyst test results. The agreement confirms the accuracy of simulation. The model can be used to develop an MCFC-MGT hybrid system with an off-the-shelf gas turbine and assess the performances during part-load operation. From the experimental results, the reaction starts at 620 K for 1 vol.% CH₄ using Pt catalyst, while the temperature is above 800 K for the addition of additive. For the 50% CH₄ conversion, the preheated temperature of the three catalysts is 713 K, 870 K and 950 K respectively. While all of the catalysts exhibit good performance when using the MCFC off-gas as fuel. The results of performance analysis for part-load conditions show that the cell operation temperature and turbine inlet temperature (TIT) should be maintained as close as possible to the design value to prevent the performance degradation.     

Parametric analysis of a hybrid power system using organic Rankine cycle to recover waste heat from proton exchange membrane fuel cell

Using fuel cell systems for distributed generation (DG) applications represents a meaningful candidate to conventional plants due to their high power density and the heat recovery potential during the electrochemical reaction. A hybrid power system consisting of a proton exchange membrane (PEM) fuel cell stack and an organic Rankine cycle (ORC) is proposed to utilize the waste heat generated from PEM fuel cell. The system performance is evaluated by the steady-state mathematical models and thermodynamic laws. Meanwhile, a parametric analysis is also carried out to investigate the effects of some key parameters on the system performance, including the fuel flow rate, PEM fuel cell operating pressure, turbine inlet pressure and turbine backpressure. Results show that the electrical efficiency of the hybrid system combined by PEM fuel cell stack and ORC can be improved by about 5% compared to that of the single PEM fuel cell stack without ORC, and it is also indicated that the high fuel flow rate can reduce the PEM fuel cell electrical efficiency and overall electrical efficiency. Moreover, with an increased fuel cell operating pressure, both PEM fuel cell electrical efficiency and overall electrical efficiency firstly increase, and then decrease. Turbine inlet pressure and backpressure also have effects on the performance of the hybrid power system.     

Transient power characteristic measurement of a proton exchange membrane fuel cell generator

An experimental study on the transient power characteristics of a fuel cell generator has been conducted. The generator is hybridized by a proton exchange membrane (PEM) as the main power source and a lithium-ion battery as the secondary power source. power-conditioning module consisting of a main bidirectional converter and an auxiliary converter has been designed to manage the hybrid power of the generator that copes with fast dynamics of variable loads. Sensors embedded in the generator have measured the electrical properties dynamically. It was found that the present power-conditioning scheme has well controlled the power flow between the fuel cell stack and the battery by regulating the power flow from or to the battery. In addition, the thermal management system using pulse width modulation (PWM) schemes could limit the operation temperature of the fuel cell generator in a designed range. Furthermore, the dynamics of electrical efficiency of the generator are found to be parallel with those of the net system power. Finally, the stability and reliability of the fuel cell generator is proven by the rational dynamic behaviors of thermal and electrical properties for over 30-h demonstration.     

An energy management strategy based on dynamic power factor for fuel cell/battery hybrid locomotive

In order to efficiently absorb more regenerative braking energy which sustains much longer compared with the conventional vehicle, and guarantee the safety of the hybrid system under the actual driving cycle of locomotive, an energy management control based on dynamic factor strategy is proposed for a scale-down locomotive system which consists of proton exchange membrane fuel cell (PEMFC) and battery pack. The proposed strategy which has self-adaption function for different driving cycles aims to achieve the less consumption of hydrogen and higher efficiency of the hybrid system. The experimental results demonstrate that the proposed strategy is able to maintain the charge state of battery (SOC) better than Equivalent Consumption Minimization Strategy (ECMS), and the proposed strategy could keep the change trend of SOC, which the final SOC is closed to the target value regardless of the initial SOC of battery. Moreover, the hydrogen consumption has been reduced by 0.86g and the efficiency of overall system has been raised of 2% at least than ECMS under the actual driving cycle through the proposed strategy. Therefore, the proposed strategy could improve the efficiency of system by diminishing the conversion process of energy outputted by fuel cell.     

Experimental study of dynamic performance of defective cell within a PEMFC stack

Defective cell in a PEMFC stack may reduce durability and reliability of the stack and even damage the stack. However, the dynamic performance of defective cell within a PEMFC stack is not clear. In this paper, the dynamic characteristics of the defective cell under different load conditions are analyzed. The results reveal that the defective cell has slower dynamic response rate than other single fuel cells, and the defective cell causes a poor voltage uniformity of the stack. The increased frequency of load change makes the voltage change rate of defective cell higher. The increased amplitude of load change has a more negative impact than the increased frequency of load change, and makes the defective cell more prone to flooding. Furthermore, impedance spectrum shows that these load conditions have greater negative effect for the defective cell than other cells. Finally, according to the experimental results and practical application, recommends related to control strategy of PEMFC stack are proposed to extend lifetime.     

Dynamic modelling of PEM fuel cell system for simulation and sizing of marine power systems

This article presents a model of a proton exchange membrane fuel cell (PEMFC) system for marine power systems. PEMFC in marine hybrid power sources can have various power ranges and capacities in contrast with vehicle applications. Investigating PEMFCs behaviour and performance for various conditions and configurations is demanded for proper sizing and feasibility studies. Hence, modelling and simulation facilitate understanding the performance of the PEMFC behaviour with various sizes and configurations in power systems. The developed model in this work has a system level fidelity with real time capabilities, which can be utilized for simulator approaches besides quasi-static studies with a power-efficiency curve. Moreover, the model can be used for scaling the PEMFC power range by considering transient responses and corresponding efficiencies. The Bond graph approach as a multi-disciplinary energy based modelling strategy is employed for the PEMFC as a multi domains system. In the end, various PEMFC cell numbers and compressor sizes have been compared with power-efficiency curves and transient responses in a benchmark.     

Assessment the hydrogen-electric coupled energy storage system based on hydrogen-fueled CAES and power-to-gas-to-power device considering multiple time-scale effect and actual operation constraints

Energy storage technology provides efficient energy management in renewable driven power system. The long duration time-scale fluctuation in unbalance power becomes more obvious and prominent with the elevated renewable penetration level. However, this issue is not widely considered in current energy storage system. In this paper, a green hydrogen-electric coupled energy storage system based on hydrogen-fueled compressed air energy storage (CAES) and power-to-gas-to-power (PtGtP) device is proposed. The hydrogen-based PtGtP device, including proton exchange membrane fuel cell (PEMFC) and PEM electrolzyer, is employed to smooth out the long duration time-scale fluctuation. Whereas, the hydrogen-fueled CAES is used to settle the remaining time-scale fluctuations. Moreover, the coupled feature is reflected by the hydrogen medium. The hydrogen only generates in PtGtP device, but consumes in both PtGtP device and hydrogen-fueled CAES. The performance assessment by considering the actual operation constraints is conducted based on historical data from real world. The simulated results show that the proposed system can provide an effective and flexible power management in the high share renewable power system. The loss of power supply probability (LPSP) is 5.40%, which is higher than that of any single energy storage system. However, the wind curtailment ratio (WCR) is 8.81%, illustrating an insufficient energy storage capacity. Furthermore, the energy shifting occurs in both several days scale and seasonal scale. This is obvious evidence for function of long duration energy storage (LDES) for the proposed coupled energy storage.     

Modeling,control and power management of hybrid photovoltaic fuel cells with battery bank supplying electric vehicle

In this paper, modeling, control and power management (PM) of hybrid Photovoltaic Fuel cell/Battery bank system supplying electric vehicle is presented. The HPS is used to produce energy without interruption. It consists of a photovoltaic generator (PV), a proton exchange membrane fuel cell (PEMFC), and a battery bank supplying an electric vehicle of 3 kW. In our work, PV and PEMFC systems work in parallel via DC/DC converter and the battery bank is used to store the excess of energy. The mathematical model topology and it power management of HPS with battery bank system supplying electric vehicle (EV) are the significant contribution of this paper. Obtained results under Matlab/Simulink and some experimental ones are presented and discussed.     

Experimental performance assessment of an online energy management strategy for varying renewable power production suppression

Lately, interest in renewable sources, especially wind and solar energy, has shown a significant increase in all over the world that mostly depends on climate-threatening conventional fossil fuels. Besides, hybrid use of these power sources with suitable back-up units provides many advantages compared to sole use of these sources. In this regard, a hybrid system consisting of a wind turbine for utilizing the wind energy, photovoltaic panels for solar energy, fuel cell for providing back-up power and a battery unit for storing the possible excess energy production and supplying the transient load is considered in this study. Experimental assessment of this system in different case studies including the real time measured dynamic power demand of an office block is realized. The collaborative actions of the proposed hybrid system with a fuzzy logic based energy management strategy during fluctuations of renewable-based power production are investigated. Thus, results of this study may be valuable for evaluating the feasibility of stand-alone hybrid renewable energy units for future power systems.     

An available method exploiting the waste heat in a proton exchange membrane fuel cell system

Based on the models of a proton exchange membrane (PEM) fuel cell working at steady state and a semiconductor thermoelectric generator, a hybrid system consisting of a PEM fuel cell, a semiconductor thermoelectric generator, and a regenerator is originally put forward. Expressions for the efficiencies and power outputs of the fuel cell, thermoelectric generator, and hybrid system are derived. The relation between the operating electric currents in the fuel cell and thermoelectric generator is obtained. The maximum power output of the hybrid system is numerically given. The optimally operating electric currents in the fuel cell and thermoelectric generator are calculated, and consequently, the optimal region of the hybrid system is determined. The results obtained here will provide some guidance for further understanding the performance and operation of practical PEM fuel cell-thermoelectric generator hybrid systems.     

A model of PEMFC-battery system to evaluate inner operating status and energy consumption under different energy management strategies

A hybrid system with jointed battery and PEMFC is popular and of great potential in New Energy Vehicle (NEV) application. However, reliability and efficiency remain to be improved for commercial products. To reflect the complicated physics inside the proton exchange membrane fuel cell (PEMFC), the PEMFC model consisting of inner muti-physics process and other accessories was built, then a complete hybrid system was established when a matched battery, DC/DC, regenerative braking were taken into consideration. Based on the above model, the stack state and system performance under standard cycle for heavy duty vehicle-CWTVC were obtained. According to the simulation results, fuel cell states such as pressure, water content and voltage suffers severe oscillation with external load, especially in the highway cycle. Membrane electrode assembly (MEA) suffers from pressure impact with average value of more than 24 kPa in highway cycle. In the aspect of relative humidity, the PEMFC stack is most threatened in road cycle. As for the hybrid system, its efficiency and state of charge (SOC) fluctuation perform worst in urban cycle and road cycle respectively, while its highest efficiency occurs in road test. Operating mode of fuel cell has influence on hybrid system. When 3-level mode of fuel cell output was applied, the efficiency increased to its peak value at medium level of 28 kW and then declined gradually. H₂ consumption had an opposite trend compared to efficiency. In the aspect of battery SOC, it declines in operating process and its fluctuations decreases when medium level got bigger. The 3-level mode and 4-level mode were compared using this model. It can be concluded that although 3-level mode performs slightly better in hybrid system efficiency, H₂ consumption, pressure impact, it does not have absolute advantage over 4-level mode in other indicators.     

Development of a proton exchange membrane fuel cell cogeneration system

A proton exchange membrane fuel cell (PEMFC) cogeneration system that provides high-quality electricity and hot water has been developed. A specially designed thermal management system together with a microcontroller embedded with appropriate control algorithm is integrated into a PEM fuel cell system. The thermal management system does not only control the fuel cell operation temperature but also recover the heat dissipated by FC stack. The dynamic behaviors of thermal and electrical characteristics are presented to verify the stability of the fuel cell cogeneration system. In addition, the reliability of the fuel cell cogeneration system is proved by one-day demonstration that deals with the daily power demand in a typical family. Finally, the effects of external loads on the efficiencies of the fuel cell cogeneration system are examined. Results reveal that the maximum system efficiency was as high as 81% when combining heat and power.