The cavity profile of a diaphragm compressor for a hydrogen refueling station

A low flow rate and short diaphragm life are the two disadvantages of diaphragm compressors when applied in hydrogen refueling stations. A new generatrix of the cavity profile of a diaphragm compressor was developed in this study to increase the cavity volume and decrease the diaphragm radial stress. A reduction in the diaphragm radial stress that resulted from the new design was validated by experiment and numerical simulation. The volumes of the cavities with different generatrices and the radial stress distribution of the diaphragm were investigated under various design conditions. The results indicated that the volume of the cavity with the new generatrix was approximately 10% larger than that with a traditional generatrix at the same allowable stress and cavity radius. At a similar cavity volume and radius, the radial stress values of the diaphragm in the cavity with the new generatrix were low. The decrease rate of the maximal radial stress of the diaphragm in the cavity with the new generatrix reached 13.8%. In the diaphragm centric region, where additional stress was induced by discharge holes, the maximal radial stress decrease rate reached 19.6%.     

Thermal-structural coupled analysis and improvement of the diaphragm compressor cylinder head for a hydrogen refueling station

When applied in the hydrogen refueling station, the diaphragm compressor with super-high pressure ratio will experience a high discharge temperature of over 200 °C, especially for that with large capacity and horsepower. Considering the thermal stress, the structural strength and deformation of the cylinder head are crucial to the reliability and efficiency of the diaphragm compressor. In this paper, a thermal-structural coupled analysis was proposed, based on which the deformation and stress of the diaphragm compressor cylinder head under high-temperature and high-pressure conditions were obtained. And the fatigue life of the studs on the cylinder head was also estimated based on the stress results obtained in the thermal-structural coupled analysis. The experimental method was conducted for verifying the numerical results. The results indicated that during the operation of the compressor, the temperature in the discharge holes was the highest, resulting in not only plastic deformation but also large stress concentration, and the high thermal stress could reach up to the strength limit of the material. A structural improvement was therefore proposed to decrease the stress in the region of the discharge holes by cutting a larger hole and attaching a new separate one for valve installation. Further stress analysis showed that the stress in the same region of the improved structure was significantly reduced, which guaranteed the safety of the compressor.     

Effect of hydraulic oil compressibility on the volumetric efficiency of a diaphragm compressor for hydrogen refueling stations

The low volumetric efficiency of the diaphragm compressor under hydrogen refueling process, which hereby results in poor energy efficiency and high cost of hydrogen applications, should be paid attention to. This paper presents theoretical analysis and experimental investigation of the factors affecting the volumetric efficiency of the diaphragm compressor for hydrogen refueling process, focusing on the influence of hydraulic oil compressibility. A mathematical model was established to estimate the volumetric efficiency of diaphragm compressors, in which the effects of clearance volume, superheating of suction gas and pressure loss were taken into account and the emphasis was focused on the compressibility of hydraulic oil. A test rig was built to validate the theoretical model and further experimental investigations were carried out to identify the factors influencing the oil compressibility and hereby the volumetric efficiency. The volumetric efficiency was measured and compared under varied oil compressibility conditions by varying elastic modulus, oil overflow pressure and oil volume. The results indicated that the measured volumetric efficiency agrees well with the calculated value. The compression and expansion of hydraulic oil have a dominant influence on the volumetric efficiency, resulting in a loss of 37% of volumetric efficiency as compared to 2.4%, 18% and 1%, respectively for losses associated with clearance volume, superheating of suction gas and pressure loss, for a diagram compressor under refueling conditions with suction pressure of 30 MPa and discharge pressure of 90 MPa. The volumetric efficiency reduced rapidly with the increased oil overflow pressure, at a rate of 5% decrease with every 10 MPa rise in oil overflow pressure. As the oil volume increased by 100% of the stroke volume, the volumetric efficiency droped by 5.5%.     

A study of hydrogen leak and explosion in different regions of a hydrogen refueling station

The consequences of hydrogen leaks and explosions are predicted for the sake of the safety in hydrogen refueling stations. In this paper, the effect of wind speed on hydrogen leak and diffusion is analyzed in different regions of a hydrogen refueling station, and the influence of delayed ignition time on hydrogen explosion after an accidental hydrogen leak is further studied by numerical simulation. Results show that the effect of wind speed on the probability of hydrogen fires is distinctive in different regions of hydrogen refueling station. The size of combustible clouds in the trailer front region and the outer region increases in the low wind speed case, and the front of combustible clouds is formed in a spherical shape in the outer region, which can greatly increase the probability of hydrogen explosion. However, the high wind speed may cause an increase of the risk of accidents in the near ground region. Moreover, a non-linear correlation is shown between the rate of combustible cloud dissipation and wind speed after the hydrogen stops leaking. In addition, it is found that an increase in delayed ignition time may lead to an increase in explosion intensity, which is related with the larger high temperature area and stronger explosion overpressure. Two flame fronts and the reverse propagation of the explosion overpressure can be observed, when the delayed ignition time is larger.     

Two-tier pressure consolidation operation method for hydrogen refueling station cost reduction

An operation strategy known as two-tier “pressure consolidation” of delivered tube-trailers (or equivalent supply storage) has been developed to maximize the throughput at gaseous hydrogen refueling stations (HRSs) for fuel cell electric vehicles (FCEVs). The high capital costs of HRSs and the consequent high investment risk are deterring growth of the infrastructure needed to promote the deployment of FCEVs. Stations supplied by gaseous hydrogen will be necessary for FCEV deployment in both the near and long term. The two-tier pressure consolidation method enhances gaseous HRSs in the following ways: (1) reduces the capital cost compared with conventional stations, as well as those operating according to the original pressure consolidation approach described by Elgowainy et al. (2014) [1], (2) minimizes pressure cycling of HRS supply storage relative to the original pressure consolidation approach; and (3) increases use of the station's supply storage (or delivered tube-trailers) while maintaining higher state-of-charge vehicle fills.     

A numerical study of hydrogen leakage and diffusion in a hydrogen refueling station

Studies focused on the behavior of the hydrogen leakage and diffusion are of great importance for facilitating the large scale application of the hydrogen energy. In this paper, the hydrogen leakage and diffusion in six scenarios which including comparison of different leakage position and different wind effect are analyzed numerically. The studied geometry is derived from the hydrogen refueling station in China. Due to the high pressure in hydrogen storage take, the hydrogen leakage is momentum dominated. The hydrogen volume concentration with the variation of the leakage time in different scenarios is plotted. More importantly, profiles of the flammable gas cloud at the end of the leakage are quantitatively studied. Results indicate that a more narrow space between the leakage hole and the obstacle and a smaller contact area with the obstacle make the profile of the flammable gas cloud more irregular and unpredictable. In addition, results highlight the wind effect on the hydrogen leakage and diffusion. Comparing with scenario which the wind direction consistent with the leakage direction, the opposite wind direction may result in a larger profile of the flammable gas cloud. With wind velocity increasing, the profile of the flammable gas cloud is confined in a smaller range. However, the presence of the wind facilitates the form of the recirculation zone near the obstacle. With an increase of the wind velocity, the recirculation zone moves downward along the obstacle. Thus, the hydrogen accumulation is more prominent near the obstacle.     

Research on sealing performance and self-acting valve reliability in high-pressure oil-free hydrogen compressors for hydrogen refueling stations

Piston ring sealing and valve design play an important role in high-pressure oil-free reciprocating compressors for hydrogen refueling stations. The severe non-uniformity of the pressure distribution was suggested to be the root cause of the premature failure of the sealing rings, and therefore a mathematical model was established to simulate the unsteady flow within the gaps of piston rings, based on which the pressure distribution was obtained and the mechanism of the non-uniform abrasion of the rings was disclosed. The method to equalize the pressure difference through each ring was proposed by re-distributing the cut size of each ring, and it was validated experimentally. Aiming at the problem that the self-acting valves in hydrogen compressors could be easily destroyed by severe impact, this paper investigated the motion and impact of valves theoretically and experimentally, based on which the methodology was explored to design the parameters of valves for hydrogen compressors.     

Experimental correlations and integration of gas boosters in a hydrogen refueling station

Air driven gas boosters are often deployed in small scale compression systems. Manufacturers specifications, reporting outlet flow for a fixed inlet pressure, do not reflect the batch operation from a limited source storage. Thus, the dynamic variation of critical process parameters such as efficiency, temperature and flow are not documented.Using a hydrogen refueling station demonstrator, the data from more than 20′000 compression cycles is compiled and analyzed. Experimentally derived correlations are determined for an air driven gas booster feeding a cascade storage. A specific analysis of the clearance volume and the working air pressure is introduced.An engineering tool was developed in MATLAB for performance forecasting. It allows the user to simulate the process trends with an accuracy of ±5%. In the context of a hydrogen refueling station, duration, temperature, compression cycles and air consumption data can be used for process management and maintenance planning.     

Numerical simulation of hydrogen leakage diffusion in seaport hydrogen refueling station

Ningbo's seaport hydrogen refueling station was used as the research object. The effects of different leakage angles, wind direction, roof shape, leakage hole diameters, temperature, and humidity on the diffusion of hydrogen leakage were studied by numerical simulation. The influence of leakage angle on hydrogen leakage is mainly reflected in the presence or absence of obstacles. The volume of the flammable hydrogen cloud was reduced by 31.16%, and the volume of the hazardous hydrogen cloud was reduced by 63.22% when there was no obstacle. The wind direction can significantly impact hydrogen leakage, with downwind and sidewind accelerating hydrogen discharge and reducing the risk. At the same time, headwind significantly increases the volume of the flammable hydrogen cloud. Compared with no wind, the volume of the flammable hydrogen cloud increased by 71.73% when headwind, but the volume of the hazardous hydrogen cloud decreased by 24.00%. If hydrogen shows signs of accumulation under the roof, the sloping roof can effectively reduce the hydrogen concentration under the roof and accelerate the hydrogen discharge. When the leakage angle θ = 90°, the sloping roof reduced the volume of the flammable hydrogen cloud by 11.74%. The leakage process was similar for different leak hole diameters in the no wind condition. The inverse of the molar fraction of hydrogen on the jet centerline was linearly related to the dimensionless axial distance of the jet in different cases. Using a least squares fit, the decay rate was obtained as 0.0039. In contrast, temperature and humidity have almost no effect on hydrogen diffusion. Hydrogen tends to accumulate on the lower surface of the roof, near the roof pillars and the hydrogen dispenser. In this paper, a set of hydrogen detector layout schemes was developed, and the alarm success rate was verified to be 83.33%.     

Multi-hub hydrogen refueling station with on-site and centralized production

In recent decades, the consequences of climate changes due to greenhouse gas (GHG) emissions have become ever more impactful, forcing international authorities to find green solutions for sustainable economic development. In this regard, one of the global targets is the reduction of fossil fuels utilization in the transport sector to encourage the diffusion of more environmentally friendly alternatives. Among them, hydrogen is emerging as a viable candidate since it is a potentially emission-free fuel when produced by exploiting renewable energy sources (RES). Nevertheless, to allow widespread use of this gas in the transport sector, several technoeconomic barriers, including production cost, and lack of distribution and storage infrastructure, have to be overcome. Distributed hydrogen production via renewable energy-powered electrolysis could be an effective solution to reduce cost and lead to economies of scale. In this study a multi-hub configuration with on-site production from PV-powered electrolysis and centralized production from steam methane reforming (SMR) is proposed. In particular, an infrastructure network for a bus refueling station located in Lazio is considered as a case study. First, each hub, composed of PV panels, an electrolyzer, a compression system, high-pressure and low-pressure storages, and hydrogen dispensers with chiller, is modeled in a Matlab/Simulink environment. Then, a design perturbation analysis is carried out to determine the impact of the configuration on the refueling station performance in terms of carbon emissions levels and the Levelized Cost of hydrogen (LCOH). The results show a significant influence of the station size on the economic performance highlighting significant benefits (reduction up to 40% in the LCOH) for a 80 bus HUB with a saturating trend towards larger sizes. CO₂ emissions per unit mass of hydrogen are kept limited for all the stations thanks to the synergistic effects of SMR and Electrolyzer. Interconnecting more than one station each other further benefits can be achieved from the environmental perspective (savings up to 5 tons of CO₂ are demonstrated for a typical summer case study).     

Quantitative risk assessment using a Japanese hydrogen refueling station model

Although hydrogen refueling stations (HRSs) are becoming widespread across Japan and are essential for the operation of fuel cell vehicles, they present potential hazards. A large number of accidents such as explosions or fires have been reported, rendering it necessary to conduct a number of qualitative and quantitative risk assessments for HRSs. Current safety codes and technical standards related to Japanese HRSs have been established based on the results of a qualitative risk assessment and quantitative effectiveness validation of safety measures over ten years ago. In the last decade, there has been much development in the technologies of the components or facilities used in domestic HRSs and much operational experience as well as knowledge to use hydrogen in HRSs safely have been gained through years of commercial operation. The purpose of the present study is to conduct a quantitative risk assessment (QRA) of the latest HRS model representing Japanese HRSs with the most current information and to identify the most significant scenarios that pose the greatest risks to the physical surroundings in the HRS model. The results of the QRA show that the risk contours of 10^?3 and 10^?4 per year were confined within the HRS boundaries, whereas the risk contours of 10^?5 and 10^?6 per year are still present outside the HRS. Comparing the breakdown of the individual risks (IRs) at the risk ranking points, we conclude that the risk of jet fire demonstrates the highest contribution to the risks at all of the risk ranking points and outside the station. To reduce these risks and confine the risk contour of 10^?6 per year within the HRS boundaries, it is necessary to consider risk mitigation measures for jet fires.     

Effect of wind condition on unintended hydrogen release in a hydrogen refueling station

Ambient condition, especially the wind condition, is an important factor to determine the behavior of hydrogen diffusion during hydrogen release. However, only few studies aim at the quantitative study of the hydrogen diffusion in a wind-exist condition. And very little researches aiming at the variable wind condition have been done. In this paper, the hydrogen diffusion in different wind condition which including the constant wind velocity and the variable wind velocity is investigated numerically. When considering the variable wind velocity, the UDF (user defined function) is compiled. Characteristics of the FGC (flammable gas cloud) and the HMF (hydrogen mass fraction) are analyzed in different wind condition and comparisons are made with the no-wind condition. Results indicate that the constant wind velocity and the variable wind velocity have totally different effect for the determination of hydrogen diffusion. Comparisons between the constant wind velocity and the variable wind velocity indicate that the variable wind velocity may cause a more dangerous situation since there has a larger FGC volume. More importantly, the wind condition has a non-negligible effect when considering the HMF along the radial direction. As the wind velocity increases, the distribution of the HMF along the radial direction is not Gaussian anymore when the distance between the release hole and the observation line exceeds to a critical value. This work can be a supplement of the research on the hydrogen release and diffusion and a valuable reference for the researchers.     

Performance of a hydrogen refueling station in the early years of commercial fuel cell vehicle deployment

Since 2003, the National Fuel Cell Research Center at the University of California, Irvine (UCI) has operated the first U.S. publicly accessible hydrogen refueling station (HRS). During this period, the UCI HRS supported all manufacturers in the early, pre-commercialization years of the fuel cell electric vehicle (FCEV). This paper describes and analyzes the performance of the UCI HRS during the first five years of FCEV commercialization, over which time the station has dispensed the most hydrogen daily in the California network. The station performance is compared to aggregate data published by NREL for all U.S. HRSs. Using the Hydrogen Delivery Scenario Analysis Model, typical daily refueling profiles are analyzed to determine the effect on HRS design. The results show different daily refueling profiles could substantially affect HRS design and ultimately the cost of hydrogen. While technical issues have been reduced, the compressor, dispenser, and fueling rate are areas for improvement.     

Multi-objective and multi-period hydrogen refueling station location problem

Creating a distribution network and establishing refueling stations arises as an important problem in order to meet the refueling needs of hydrogen fuel cell vehicles. In this study, a multi-objective and multi-period hydrogen refueling station location problem that can take into account long-term planning decisions is proposed. Firstly, single objective mathematical models are proposed for the problem by addressing the cost, risk and population convergence objectives. Afterwards, a goal programming model is proposed and the results that will arise when three objectives are taken into consideration at the same time are examined. A risk analysis approach applied for each location alternative is considered in order to handle risk concerns about the hydrogen refueling station settlement. A case study is conducted in Adana, one of the crowded cities in Turkey, to determine the long-term location network plan. Covered population, operational risk and earthquake risks are used as input of the risk analysis method. The case study results show that the goal programming model covers the area with 77 hydrogen refueling stations by different types and capacities during the years from 2020 to 2030. In addition, a computational study is carried out with different alternative scenarios (different number of consumption nodes and all parameters in the model). The computational study results show that the highest deviations from the optimal solution on the model are observed in the distances between consumption nodes and targeted service area parameters which affect about 50% of absolute deviations on average. According to results, the proposed approach selects the station location suitable for the expected changes over the years.     

Impact of pipelines on cooling demand in the gaseous hydrogen refueling station

Hydrogen precooling is an effective method to realize safe, adequate, and fast filling for fuel cell vehicles. Estimating cooling demand is essential for the precooling unit configuration and energy analysis. Complex pipelines exist between the station's storage tanks and the vehicle cylinder. However, their impact on the cooling demand is often underestimated. In this paper, a thermodynamic model of the whole hydrogen refueling process was established to investigate the impact of pipelines in different positions. Accordingly, the influence of pipelines on the thermodynamic parameters was analyzed. Then the effects on the precooling performance were concluded. The results show that flow resistance before the breakaway increases total cooling demand by 9.9%. Meanwhile, heat dissipation through the pipe, located between the control valve and the heat exchanger, smoothens the cooling demand curve and reduces the total cooling demand by 5.7%. After the break-away, the flow resistance of pipelines significantly changes the mass flow rate curve and cooling demand. Heat absorption from the pipe wall slightly influences the cooling demand but jeopardizes refueling safety.     

Numerical investigation of the leakage and explosion scenarios in China's first liquid hydrogen refueling station

Promoting fuel cells has been one of China's ambitious hydrogen policies in the past few years. Currently, several hydrogen fueling stations (HRSs) are under construction in China to fuel hydrogen-driven vehicles. In this regard, it is necessary to assess the risks of hydrogen leakage in HRSs. Aiming at conducting a comprehensive consequence assessment of liquid hydrogen (LH2) leakage on China's first liquid hydrogen refueling station (LHRS) in Pinghu, a pseudo-source model is established in the present study to simulate the LH2 leakage using a commercial CFD tool, FLACS. The effects of the layout of the LHRS, leakage parameters, and local meteorological conditions on the LH2 leakage consequence has been assessed from the perspectives of low-temperature hazards and explosion hazards. The obtained results reveal that considering the prevailing southeast wind in Pinghu city, the farthest low-temperature hazard distance and lower flammable limit (LFL) -distance occurs in the leakage scenario along the north direction. It is found that the trailer parking location in the current layout of the LHRS will worsen the explosion consequences of the LH2 leakage. Moreover, the explosion will completely destroy the control room and endanger people on the adjacent road when the leakage equivalent diameter is 25.4 mm. The performed analyses reveal that as the wind speed increases, the explosion hazard decreases.     

Dynamic simulation for optimal hydrogen refueling method to Fuel Cell Vehicle tanks

A dynamic simulation approach to investigate an optimal hydrogen refueling method is proposed. The proposed approach simulates a transient temperature, pressure and mass flow rate of hydrogen flowing inside filling equipment in an actual station during the refueling process to an Fuel Cell Vehicle (FCV) tank. The simulation model is the same as in an actual hydrogen refueling station (HRS), and consists of a Break-Away, a hose, a nozzle, pipes and an FCV tank. Therefore, we can set actual configurations and thermal properties to the simulation model, and then simulate the temperature, pressure and mass flow rate of hydrogen passing through each position based on the supply conditions (temperature and pressure) at the Break-Away. In this study, the simulated temperature, pressure and mass flow rate are compared with the corresponding experimental data. Therefore, we show that the dynamic simulation approach can accurately obtain those values at each position during the refueling process and is an effective step in proposing the optimal refueling method.     

Optimal operation of a photovoltaic generation-powered hydrogen production system at a hydrogen refueling station

As the popularity of fuel cell vehicles continues to rise in the global market, production and supply of low-carbon hydrogen are important to mitigate CO₂ emissions. We propose a design for a hydrogen refueling station with a proton exchange membrane electrolyzer (PEM-EL)-based electrolysis system (EL-System) and photovoltaic generation (PV) to supply low-carbon hydrogen. Hydrogen is produced by the EL-System using electricity from PV and the power grid. The system was formulated as a mixed integer linear programming (MILP) model to allow analysis of optimal operational strategies. Case studies with different objective functions, CO₂ emission targets, and capacity utilization of the EL-System were evaluated. Efficiency characteristics of the EL-System were obtained through measurements. The optimized operational strategies were evaluated with reference to three evaluation indices: CO₂ emissions, capacity utilization, and operational cost of the system. The results were as follows: 1) Regardless of the objective function, the EL-System generally operated in highest efficiency state, and optimal operation depended on the efficiency characteristics of the EL-System; 2) mitigation of CO₂ emissions and increase in capacity utilization of the EL-System required trade-offs; and 3) increased capacity utilization of the EL-System showed two opposing effects on hydrogen retail price.     

Review on equipment configuration and operation process optimization of hydrogen refueling station

The construction of hydrogenation infrastructure is important to promote the large-scale development of hydrogen energy industry. The technical performance of hydrogen refueling station (HRS) largely determines the refueling efficiency and cost of hydrogen fuel cell vehicles. This paper systematically lists the hydrogen refueling process and the key equipment applicable in the HRS. It comprehensively reviews the key equipment configuration from the hydrogen supply, compression, storage and refueling of the HRS. On the basis of the parameter selection and quantity configuration method, the process optimization technology related to the equipment utilization efficiency and construction cost was quantitatively evaluated. Besides, the existing problems and prospects are put forward, which lays the foundation for further research on the technical economy of HRSs.     

Development of strategic hydrogen refueling station deployment plan for Korea

The Republic of Korea government has set yearly targets of hydrogen cars and buses and plans to install hydrogen refueling stations nationwide. This paper proposes a methodology for developing a strategic deployment plan with three mathematical models. For a given target, future refueling demand locations and amount from general road and expressway are systematically estimated. First, the required number of refueling stations to satisfy the target covering ratio of the total demand set by the government is determined by the Station number determination model. Next, the locations of the capacitated stations and the allocation of demand to the stations are determined by the second Max cover and the third p-median models. Since the max covering is more important than minimizing the travel time, the two models are used sequentially. The nationwide hydrogen station deployment plan for the years 2022–2040 obtained by the proposed methodology is reported.