基于气固流态化原理的油页岩干燥动力学

为了考察气固流化床干燥器能否使油页岩含水质量分数达到要求,以柳树河油页岩颗粒为原料,研究进口气体温度和颗粒直径对油页岩干燥性能的影响,采用薄层干燥模型,对油页岩干燥实验数据进行模拟,确定油页岩干燥方程和干燥速率方程,建立油页岩干燥速率特征常数和有效扩散系数之间的关联式。研究结果表明:薄层干燥模型中修正Page模型Ⅰ适合描述油页岩的干燥过程;油页岩在流化床内干燥过程主要发生在降速干燥阶段,进口气体温度越高,油页岩颗粒直径越小,所需干燥时间越短,进口气体温度为350℃时,使2.4 mm油页岩含水质量分数低于5%,所需干燥时间为2.5 min。     

过热蒸汽间歇干燥酒精糟研究

以高湿物料酒精糟为研究对象,进行了过热蒸汽间歇干燥实验研究。利用自行设计的间歇干燥实验台,酒精糟的初始含水质量分数为66.7%,研究了不同实验条件对干燥速率的影响。结果表明:随着干燥介质温度的升高,干燥速率明显加快;被烘物料质量越少,烘干时间越短;随着物料颗粒直径的减小,恒速段的干燥速率基本不变,而降速段的干燥速率明显增加;过热蒸汽质量流量越大,干燥速率越高。因此随着蒸汽过热度的升高、质量流量的增大,过热蒸汽干燥速率加快,干燥效率越高;随着进料质量的增加、颗粒直径的增大,过热蒸汽干燥速率却有所降低。     

油页岩干燥特性实验研究

以柳树河油页岩颗粒为原料,在恒温介质干燥器内进行油页岩干燥动力学研究,考察干燥介质温度和颗粒直径对油页岩干燥性能的影响,采用薄层干燥模型中的Lewis模型,对油页岩干燥实验数据进行模拟,确定油页岩干燥方程和干燥速率方程,建立油页岩干燥常数表达式。研究结果表明:薄层干燥模型中Lewis模型能较好的描述油页岩在恒温介质干燥器内的干燥过程;其干燥过程主要发生在降速干燥阶段;200℃时油页岩无性质变化,干燥达到平衡时,油页岩含水量可降到0.5%左右,油页岩表观活化能为17～19kJ/mol。     

含油污泥为黏结剂制型煤干燥过程研究

为提高干燥效率、优化干燥效果,采用以含油污泥为黏结剂,与粉煤掺混干燥制备型煤的方式对含油污泥进行资源化处理。研究了掺煤量、干燥风速、干燥温度和型煤粒径对干燥过程的影响,并得到含水率和干燥速率随时间变化曲线。结果表明,以含油污泥为黏结剂制型煤的干燥过程可分为三个阶段:升速阶段、等速阶段和降速阶段。掺煤量主要影响降速阶段,风速主要影响升速阶段,温度主要影响升速阶段和等速阶段,粒径主要影响降速阶段。掺煤量越大、风速越大、温度越高、粒径越小,则干燥速率就越大。试验筛选出最佳干燥条件:掺煤量为65%、风速为2.75m/s、温度为105℃、粒径为10mm。对最佳干燥条件下的干燥过程进行干燥动力学模型拟合,求解干燥方程,得出Page(Ⅱ)模型相关系数平方为0.991时,拟合效果较好,能够反应其干燥特性。     

过热蒸汽流化床流化特性的实验研究

在底部直径为120 mm的锥型流化床中,以玻璃珠为流化颗粒,过热蒸汽为流化介质,研究了固体颗粒在过热蒸汽流化床中的流化特性,考察了操作温度和压力对临界流化速度(umf)的影响.结果表明,过热蒸汽流化床的流化行为与热空气相似,临界流化速度(umf)随床层温度的升高而减小,随床内压力的增大而减小;在相同温度条件下,过热蒸汽流化床的临界流化速度比热空气大.     

单颗粒褐煤高温烟气干燥过程实验研究

针对10mm~25mm粒径的大唐五间房褐煤,通过单颗粒高温烟气干燥实验,得到了600℃~900℃烟气温度下的干燥特性曲线,研究了干燥介质温度和粒径对褐煤高温脱水效果的影响,发现干燥过程主要处于降速干燥阶段;高温条件下,温度对干燥速率的影响并不显著;针对褐煤水分在干燥过程中的迁移特点以及大唐五间房褐煤的孔隙特征,基于努森扩散定律,建立了水分蒸发为蒸汽再扩散出煤粒的缩核干燥动力学模型;得到了不同温度下的有效水分扩散系数,并利用Arrhenius公式求出了10mm~25mm粒径下的干燥活化能.     

甘肃窑街油页岩等温干燥机理分析

采用甘肃窑街油页岩颗粒作为原料,利用电热鼓风箱和电子天平及红外温度测定仪,测定油页岩样品在外界温度恒定条件下的含水率和干燥速率曲线,并讨论各段的干燥机理方程,分析温度、粒径大小对甘肃油页岩干燥效果的影响。结果表明:干燥速率曲线上明显存在拐点,由此可知干燥过程存在不同的干燥机理,当含水率大于拐点含水率时,主要是大孔隙中的自由水和束缚水脱除过程且伴随着体积的缩小,由Keliven公式,这一过程受到毛细管作用影响,蒸发速率逐渐降低;含水率小于拐点含水率阶段对应着油页岩内部更细小孔内水分的受热过程,当水分子动能达到一定值后突然汽化逸出引起含水率下降并引起油页岩干燥后期的热破碎现象。     

热风及过热蒸汽煤调湿工艺比较

针对现有热风和烟道气煤调湿工艺存在易爆风险的问题,提出了一种过热蒸汽为干燥介质的煤调湿新工艺.利用自制穿流干燥装置,以热风和过热蒸汽为干燥介质对炼焦煤进行干燥调湿.研究了不同干燥介质温度、料层厚度和干燥介质流量条件下的炼焦煤干燥特性,计算了热风和过热蒸汽煤调湿工艺处理单位质量物料所需外部输入能耗,绘制了炼焦煤水分变化曲线和能耗分布等值图.结果表明:提高干燥介质温度、减少料层厚度、增大干燥介质流量均有利于炼焦煤干燥,缩短煤调湿过程时间;相比于热风干燥介质,利用过热蒸汽对炼焦煤进行调湿,调湿速率可提高40%以上,能耗可降低35%以上.     

湿污泥颗粒的流化床干燥实验及模型

在鼓泡流化床内以河砂为干燥介质,对单颗粒湿污泥的流态化干燥特性进行实验研究,得到了流化床温度、污泥初始水分、污泥粒径及流化速度对干燥速率的影响规律：流化床温度及污泥粒径对干燥速率的影响都呈指数规律;污泥的水分越大,干燥速率越大;在鼓泡流化床流化速度达到2倍临界流化速度以上时,充分流化,流化速度再增大(2~5倍临界流化速度)对干燥速率没有明显影响. 在基本的扩散传质理论的基础上,利用实验数据回归得到湿污泥在鼓泡流化床内干燥的半经验模型,为流化床污泥干燥器的设计提供了基础数据和依据.     

硫酸铵微波干燥特性及动力学模型分析

采用微波干燥技术进行了硫酸铵干燥的研究.通过系统实验分析了硫酸铵微波干燥特性,并采用薄层干燥模型进行数值分析.结果表明:修正Page模型(Ⅱ)较之其他模型更适于薄层硫酸铵微波干燥的模拟.应用Fick第二定律得到微波功率230-700 W,物料质量150-300 g条件下薄层硫酸铵微波干燥的有效扩散系数的变化范围分别为:...     

Inversion Temperature and Pinch Analysis,Ways to Thermally Optimize Drying Processes

This work studies the compatibility and suitability of a combined inversion temperature and pinch analysis with the process selection for air and superheated steam spray drying of milk solids. The inversion temperature is a good starting point for an energy analysis because it is a simplified rate-based approach to comparing the steam and air drying systems. pinch analysis enables process integration, at least on a heat recovery and heat exchanger network level.

The resulting inversion temperature for the studied system was estimated as 182°C for the dryer inlet temperature. However, mass and energy balances showed that a minimum inlet temperature for spray drying of 184°C was required for the superheated steam dryer in order to ensure that the outlet solids temperature above the dew point temperature.

The inversion temperature is still very relevant in the early stages of a design process because it allows a quick assessment of which drying medium should result in a smaller dryer. It was evident that the steam system is better from an energy perspective because of the recoverable latent heat of the water vapor carried out of the dryer with the recycled steam. The steam system has between 82 and 92% of thermal energy recovery potential as condensable steam, compared with 13–30% energy recovery of the air system. However, other important design and operational factors are not discussed here in detail.

Combining the inversion temperature and pinch analysis suggests that superheated steam drying both gives better energy recovery and is likely to give smaller dryers for all operational conditions.     

DRYING RATE AND TEMPERATURE PROFILE FOR SUPERHEATED STEAM VACUUM DRYING AND MOIST AIR DRYING OF SOFTWOOD LUMBER

Two charges of green radiata pine sapwood lumber were dried, either using superheated steam under vacuum (90°C, 0.2 bar abs.) or conventionally using hot moist air (90/60°C). Due to low density of the drying medium under vacuum, the circulation velocity used was 10 m/s for superheated steam drying and 5.0 m/s for moist air drying, and in both cases, the flow was unidirectional. In drying, stack drying rate and wood temperatures were measured to examine the differences between the superheated steam drying and drying using hot moist air.

The experimental results have shown that the stack edge board in superheated steam drying dried faster than in the hot moist air drying. Once again due to the low density of the steam under vacuum, a prolonged maximum temperature drop across load (TDAL) was observed in the superheated steam drying, however, the whole stack dried slower and the final moisture content distribution was more variable than for conventional hot moist air drying. Wood temperatures in superheated steam drying were lower.     

DRYING RATE AND TEMPERATURE PROFILE FOR SUPERHEATED STEAM VACUUM DRYING AND MOIST AIR DRYING OF SOFTWOOD LUMBER

Abstract

Two charges of green radiata pine sapwood lumber were dried, either using superheated steam under vacuum (90°C, 0.2 bar abs.) or conventionally using hot moist air (90/60°C). Due to low density of the drying medium under vacuum, the circulation velocity used was 10 m/s for superheated steam drying and 5.0 m/s for moist air drying, and in both cases, the flow was unidirectional. In drying, stack drying rate and wood temperatures were measured to examine the differences between the superheated steam drying and drying using hot moist air.

The experimental results have shown that the stack edge board in superheated steam drying dried faster than in the hot moist air drying. Once again due to the low density of the steam under vacuum, a prolonged maximum temperature drop across load (TDAL) was observed in the superheated steam drying, however, the whole stack dried slower and the final moisture content distribution was more variable than for conventional hot moist air drying. Wood temperatures in superheated steam drying were lower.     

Drying Kinetics of a Porous Spherical Particle and the Inversion Temperature

A model is presented for drying of a single porous particle with superheated steam and humid air. Experimental data for spherical porous ceramic particle reported in the literature were used for the validation of the model. An inversion temperature at which the evaporation rates within superheated steam and humid air are equal was predicted. The effect of thermophysical properties of the particle (permeability 10^-14 - 10^-17 m², diameter 3 × 10^-3 - 10 × 10^-3 m) and operating variables (gas mass flux 0.26 - 0.78 kg m^-2 s^-1, drying agent temperature 120-200°C) is tested. The inversion temperature is shown to be affected by the thermophysical properties of the porous particle and of the drying agent.     

Effect of Fluidizing Particle on Drying Characteristics of Porous Materials in Superheated Steam Fluidized Bed under Reduced Pressure

The hygroscopic porous particle was used as the fluidizing particle for the superheated steam fluidized bed drying under reduced pressure. A relatively large material was immersed in the fluidized bed as the drying sample. The drying characteristics of the sample were examined experimentally and the results were compared with those in the case of inert particle fluidized bed.

The water transfer from the sample to the fluidizing particle bed in the case of hygroscopic porous particle facilitated the drying regardless of pressure and temperature in the drying chamber. The increment degree of the sample temperature at the earlier period of drying was smaller in the case of hygroscopic porous particle than in the case of inert particle, and the phenomenon was more remarkable in the case of superheated steam than in the case of hot air.     

Effect of Fluidizing Particle on Drying Characteristics of Porous Materials in Superheated Steam Fluidized Bed under Reduced Pressure

The hygroscopic porous particle was used as the fluidizing particle for the superheated steam fluidized bed drying under reduced pressure. A relatively large material was immersed in the fluidized bed as the drying sample. The drying characteristics of the sample were examined experimentally and the results were compared with those in the case of inert particle fluidized bed.

The water transfer from the sample to the fluidizing particle bed in the case of hygroscopic porous particle facilitated the drying regardless of pressure and temperature in the drying chamber. The increment degree of the sample temperature at the earlier period of drying was smaller in the case of hygroscopic porous particle than in the case of inert particle, and the phenomenon was more remarkable in the case of superheated steam than in the case of hot air.     

Multiscale Modeling of Superheated Steam Drying of Particulate Materials

A multiscale model for predicting the superheated steam drying behavior of a packed bed filled with particulate porous material is presented. By using a reaction engineering approach (REA) a semi-empirical model is developed that can describe the heat and mass transfer between a single particle and the surrounding drying agent. By analogy between superheated steam drying and hot air drying, the relative activation energy of the REA model is formulated. Next, the single-particle drying model is fed into a continuum-scale model of a packed bed. The temperature and moisture content of the solid and the vapor temperature are successfully predicted by the bed-scale model. To endow the bed-scale model with predictive capabilities, simulation results are compared with experimental literature data.     

Drying of soy sauce residue in superheated steam at atmospheric pressure

Soy sauce residue needs drying to avoid fermentation and oxidation during storage and transportation, and its reutilization as a useful resource is expected. Superheated steam drying was applied to investigate the effects of drying conditions on the drying characteristics and the content changes of salt and protein. The results showed that the inversion temperature was about 130°C, beyond which superheated steam drying was faster than hot air-drying. The drying time approaching equilibrium moisture content was reduced with elevated drying temperature as well as higher steam mass flow rate in the present experimental conditions. The effect of bed thickness on drying time was not obvious when drying temperature increased. Interestingly, the salt content of soy sauce residue could be decreased by 34.8% due to condensate water in the initial drying period (wetting), while protein content had no significant loss (p?相似文献