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采用泡沫分离法分离纯化无患子皂苷溶液,收集溢出分离柱的泡沫液,采用紫外分光光度计分别测定原液和泡沫液的皂苷含量,通过富集比、回收率以及纯度表征分离效果。结果表明:在进料浓度为 2.0 g/L、进料量为 150 mL、气速为 32 L/h、温度为 30 ℃、pH值为4.3条件下,富集比可达到2.153,收率与纯度分别达到 79.19 % 和 74.68 %。 相似文献
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用732FeT^+++型树脂为吸附剂,进行了木糖山梨糖混合溶液的分离试验。通过环 状色谱床层中的物料衡算,取得了连续性方程的解,再以表征双组分混合液分离效果的参数定义为基础,假定了相平衡关系、返混规律和相间传质机制不变的情况下,用木糖或山梨糖色谱分离收集液的产率和分离度为目标函数,以进料浓度、进料液流量、冲洗液流量、床层高度和床层旋转速度等操作条件为变量进行估算,取得了一系列曲线和一些规律,可为连续 相似文献
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运用自制的泡沫分离塔,以十二烷基硫酸钠为表面活性剂对泡沫吸附分离含铜及含锌溶液的操作参数进行了研究。考察了料液浓度、pH值、气体流量、表面活性剂浓度等因素对含铜和含锌溶液泡沫分离效果的影响。结果表明:最佳操作参数为pH值5.0,料液浓度0.125mmol/L,进料流速50mL/min,气体流量100mL/min,表面活性剂浓度0.25mmol/L。同时从理论上推算出泡沫吸附分离铜离子的最佳pH值范围为5.0左右。实验还通过改变孔板的孔径大小以改变气泡的尺寸,特别研究了泡沫尺寸对泡沫吸附分离的影响。 相似文献
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液膜分离过程的新发展—内耦合萃反交替分离过程 总被引:9,自引:0,他引:9
内耦合萃反交替分离过程是液膜分离过程与混合澄清槽式溶剂萃取过程相互交叉,渗透的产物。它利用相混合原理与流体力学原理的有机结合实现了以混合澄清槽为传质单元设备的非平衡传质过程,是液膜分离过程的新发展。 相似文献
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为了加强泡沫相排液,提高目的产物的富集比,设计了一种新型泡沫分离塔即泡沫相部分水平泡沫分离塔.以传统泡沫相垂直泡沫分离塔为对照塔,以牛血清蛋白(BSA)为体系,考察了表观气速、装液量、物料初始浓度和初始pH对牛血清蛋白(BSA)富集比和回收率的影响.结果表明泡沫相部分水平泡沫分离塔有效减小了泡沫相排液的阻力,提高了BS... 相似文献
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Foam fractionation is considered as a unit operation. A theory based upon dimensional analysis is used for calculating continuous fractionation columns. Internal reflux ratio resulting from foam instability was taken into consideration and a numerical value is given. The concepts of specific productivity of the column P* and specific energy consumption E* are introduced. A formula is given for the correlation between P* and the parameters characterizing the column geometry (column diameter, foam height) and operating conditions (gas rate, external reflux ratio, feed concentration, feed rate, feed level). 相似文献
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《分离科学与技术》2012,47(16):2489-2496
A novel method to intensify the foam fractionation process by operating the column under reduced pressure was reported in this paper. It was found that a poorer foam stability, a bigger mean bubble size and a wider bubble size distribution in the foam layer, a less upward liquid flux and volumetric liquid fraction at the top of the foam layer, and a higher enrichment ratio but a lower mass recovery of the foam fractionation process were obtained under reduced pressures compared to the ones under atmospheric pressure. The most important effect of the reduced pressure on the foam layer during the foam fractionation process is the encouraged bubble coalescence process which was exhibited by those unusual foam properties discussed above. The limitations of this new method were also discussed. 相似文献
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泡沫分离法除去水溶液中微量铜离子的工艺 总被引:4,自引:3,他引:1
以十二烷基苯磺酸为表面活性物质,自制的单金属离子水溶液为研究体系,对泡沫分离法除去水溶液中金属离子的工艺进行了研究,重点考察了溶液的pH、鼓泡气体流量、表面活性剂浓度及泡沫塔装液量的影响. 结果表明,十二烷基苯磺酸具有良好的起泡性能,对水溶液中铜离子的去除效果也比较理想,最佳操作条件下富集比为18.2,去除率为96.1%,与常规的表面活性剂十二烷基硫酸钠相比,十二烷基苯磺酸在泡沫分离过程结束后不会在体系中残留金属离子,这为探索脱盐新方法提供了依据. 相似文献
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为了同时分离甘草中有表面活性的甘草酸和黄芩中无表面活性的黄芩苷,开发了甘草配伍黄芩泡沫分离工艺。通过荧光光谱、紫外吸收光谱和红外吸收光谱分析表明,甘草酸与黄芩苷存在相互作用,并且甘草黄芩配伍强化了甘草酸和黄芩苷的提取。以甘草酸和黄芩苷的富集比和回收率为评价指标,当温度为40℃、气体体积流量为100 ml·min-1、甘草酸初始浓度为0.2 g·L-1、甘草黄芩质量比为3:1时,获得甘草酸的富集比和回收率分别为11.0和73.5%,黄芩苷的富集比和回收率分别为5.8和38.5%。通过甘草与黄芩配伍,利用泡沫分离获得黄芩中的黄芩苷。同时,与单独泡沫分离甘草中甘草酸相比,甘草酸的富集比提高了194.9%,回收率提高了23.3%。因此,甘草配伍黄芩能有效泡沫分离甘草酸和黄芩苷。 相似文献
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Cationic metallic ions such as sodium, cadmium and chromium were flotated from aqueous solution by using foam separation or foam fractionation technique in a continuous flow system. Experimental results showed a considerable difference between mono- or divalent and trivalent metallic ions in their affinity to neutralize the negatively charged surface layer formed at the gas-liquid interface. This was verified by use of the Gouy-Chapman diffuse double-layer theory, except for the case of high concentration of the co-existing collector which formed miscellaneous metal-collector complexes. 相似文献
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《分离科学与技术》2012,47(9):1233-1258
Abstract The purpose of this study was to investigate the use of foam fractionation to recover surfactant from water. A simple continuous mode foam fractionation was used and three surfactants were studied (two anionic and one cationic). The effects of air flow rate, foam height, liquid height, liquid feed surfactant concentration, and sparger porosity were studied. This technique was shown to be effective in either surfactant recovery or the reduction of surfactant concentration in water to acceptable levels. As an example of the effectiveness of this technique, the cetylpyridinium chloride concentration in water can be reduced by 90% in one stage with a liquid residence time of 375 minutes. The surfactant concentration in the collapsed foam is 21.5 times the feed concentration. This cationic surfactant was easier to remove from water by foam fractionation than the anionic surfactants studied. 相似文献
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ABSTRACTFoam fractionation for recovering leaf protein from alfalfa (Medicago sativa L.) has been investigated. The extraction yield of alfalfa leaf protein (ALP) from the dried alfalfa leaves reached 71.90% under the extraction conditions of pH 8.0, temperature 70°C, and extracting time 40 min. For strengthening foam drainage at room temperature, a novel foam fractionation column with a cross-internal component covered superhydrophobic coating was developed. By using the extraction liquor as the feeding solution, a two-stage foam fractionation had been performed. Under the suitable operation conditions, the enrichment ratio and the recovery percentage of ALP were 4.33 and 89.0%, respectively. 相似文献
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