Spatial patterns of soil nitrate in Japanese forested watersheds: importance of the near-stream zone as a source of nitrate in stream water

Spatial patterns of N dynamics in soil were evaluated within two small forested watersheds in Japan. These two watersheds were characterized by steep slopes (>30°) and high stream NO⁻₃ drainage rates (8·4 to 25·1 kg N ha⁻¹ yr⁻¹) that were greater than bulk precipitation N input rates (7·5 to 13·5 kg N ha⁻¹ yr⁻¹). Higher rates of nitrification potential at near-stream zones were reflected in greater NO⁻₃ contents for soil at the near-stream zones compared with ridge zones. Both stream discharge rates and NO⁻₃ concentrations in deep unsaturated soil at the near-stream zones were positively correlated to NO⁻₃ concentrations in stream water. These relationships, together with high soil NO⁻₃ contents at the near-stream zones, suggest that the near-stream zone was an important source of NO⁻₃ to stream water. Nitrate flux from these near-stream zones was also related to the drainage of cations (K⁺, Ca²⁺ and Mg²⁺). The steep slope of the watersheds resulted in small saturated areas that contributed to the high NO⁻₃ production (high nitrification rates) in the near-stream zone. © 1998 John Wiley & Sons, Ltd.     

Characterizing the flush of stream chemical runoff from forested watersheds

A flush can be defined as stream chemical exhibiting higher concentrations during the prophase of a storm event at an event scale, or exhibiting progressively lower concentrations during several successive storms at a seasonal scale. Investigating the flush characteristics of chemical runoff from forested watersheds is important and helpful to understand the chemical dynamics as well as to design a sampling schedule strategy during storm events. Here, three parameters describing the flush characteristic are quantified and the flush characteristics of chemicals from four Japanese forested watersheds (Mie, Kochi, Nagano and Tokyo) were investigated at both event and seasonal levels. We found that the characteristics of the flush were complicated, and depended on the constituents of the hydrochemistry, climate and runoff quality. Generally, the flush occurs more readily for particulate components than for those in solution; the flush on nitrate‐nitrogen is weaker in regions of nitrogen saturation, such as Nagano and Tokyo, than in Mie and Kochi. Rainfall feature was the main factor controlling the flush of particulate components. However, the source available in a watershed plays a main role on the flushes of dissolve chemicals. Copyright © 2010 John Wiley & Sons, Ltd.     

Significance of processes in the near‐stream zone on stream water acidity in a small acidified forested catchment

The near‐stream zone has received increasing attention owing to its influence on stream water chemistry in general and acidity in particular. Possible processes in this zone include cation exchange, leaching of organic matter and redox reactions of sulphur compounds. In this study the influences of processes in the near‐stream zone on the acidity in runoff from a small, acidified catchment in central southern Sweden were investigated. The study included sampling of groundwater, soil water and stream water along with hydrological measurements. An input–output budget for the catchment was established based on data from the International Co‐operative Programme on Integrated Monitoring at this site. The catchment was heavily acidified by deposition of anthropogenic sulphur, with pH in stream water between 4·4 and 4·6. There was also no relationship between stream flow and pH, which is indicative of chronic acidification. Indications of microbial reduction of sulphate were found in some places near the stream, but the near‐stream zone did not have a general impact on the sulphate concentration in discharging groundwater. The near‐stream zone was a source of dissolved organic carbon (DOC) in the stream, which had a median DOC of 6·8 mg L¹. The influence on stream acidity from organic anions was overshadowed by the effect of sulphate, however, except during a spring flow episode, when additional organic matter was flushed out and the sulphate‐rich ground water was mixed with more diluted event water. Ion exchange was not an important process in the near‐stream zone of the Kindla catchment. Different functions of the near‐stream zone relating to discharge acidity are reported in the literature. In this study there was even a variation within the site. There is therefore a need for more case studies to provide a more detailed understanding of the net effects that the near‐stream zone can have on stream chemistry under different circumstances. Copyright © 2001 John Wiley & Sons, Ltd.     

Baseflow and peakflow chemical responses to experimental applications of ammonium sulphate to forested watersheds in north‐central West Virginia,USA

Stream water was analysed to determine how induced watershed acidification changed the chemistry of peakflow and baseflow and to compare the relative timing of these changes. Two watersheds in north‐central West Virginia, WS3 and WS9, were subjected to three applications of ammonium sulphate fertilizer per year to induce acidification. A third watershed, WS4, was the control. Samples were collected for 8 years from WS9 and for 9 years from WS3. Prior to analyses, concentration data were flow adjusted, and the influence of natural background changes was removed by accounting for the chemical responses measured from WS4. This yielded residual values that were evaluated using robust locally weighted regression and Mann–Kendall tests. On WS3, analyte responses during baseflow and peakflow were similar, although peakflow responses occurred soon after the first treatment whereas baseflow responses lagged 1–2 years. This lag in baseflow responses corresponded well with the mean transit time of baseflow on WS3. Anion adsorption on WS3 apparently delayed increases in SO₄ leaching, but resulted in enhanced early leaching losses of Cl and NO₃. Leaching of Ca and Mg was strongly tied, both by timing and stoichiometrically, to NO₃ and SO₄ leaching. F‐factors for WS3 baseflow and peakflow indicated that the catchment was insensitive to acid neutralizing capacity reductions both before and during treatment, although NO₃ played a large role in reducing the treatment period F‐factor. By contrast, the addition of fertilizer to WS9 created an acid sensitive system in both baseflow and peakflow. On WS9, baseflow and peakflow responses also were similar to each other, but there was no time lag after treatment for baseflow. Changes in concentrations generally were not as great on WS9 as on WS3, and several ions showed no significant changes, particularly for peakflow. The lesser response to treatment on WS9 is attributed to the past abusive farming and site preparation before larch planting that resulted in poor soil fertility, erosion, and consequently, physical and chemical similarities between upper and lower soil layers. Even with fertilizer‐induced NO₃ and SO₄ leaching increases, base cations were in low supplies and, therefore, unavailable to leach via charge pairing. The absence of a time lag in treatment responses for WS9 baseflow indicates that it has substantially different flow paths than WS3. The different hydrologies on these nearby watersheds illustrates the importance of understanding watershed hydrology when establishing a monitoring programme to detect ecosystem change. Published in 2002 by John Wiley & Sons, Ltd.     

Acidification recovery in a changing climate: Observations from thirty-five years of stream chemistry monitoring in forested headwater catchments at the Turkey Lakes watershed,Ontario

Long-term ecosystem studies are valuable for understanding integrated ecosystem response to global changes in atmospheric deposition and climate. We examined trends for a 35-year period (1982/83–2017/18) in concentrations of a range of solutes in precipitation and stream water from nine headwater catchments spanning elevation and surficial geology gradients at the Turkey Lakes watershed (TLW) in northeastern Ontario, Canada. Average annual water year (WY, October to September) concentrations in precipitation significantly declined over the period for sulphate (SO₄²⁻), nitrate (NO₃⁻) and chloride (Cl⁻), while calcium (Ca²⁺) and potassium (K⁺) concentrations increased, resulting in a significant pH increase from 4.2 to 5.7. Trends in stream chemistry through time are generally consistent with expectations associated with acidification recovery. Concentration of many stream water solutes (SO₄²⁻, Cl⁻, calcium [Ca²⁺], magnesium [Mg²⁺] and NH₄⁺ generally decreased, while others (silica [SiO₂] and dissolved organic carbon [DOC]) generally increased. Increases were also observed for alkalinity (six of nine catchments), acid neutralizing capacity ([ANC]; six of nine catchments) and pH (eight of nine catchments), while conductivity declined (six of nine catchments). Variability in trends among catchments are associated with differences in surficial geology and wetland cover. While absolute solute concentrations were generally lower at bedrock dominated high-elevation catchments compared to till dominated lower elevation catchments, the rate of change of concentration was often greater for high elevation catchments. This study confirms continued, but non-linear stream chemistry recovery from acidification, particularly at the less buffered high and moderate elevation sites. The heterogeneity of responses among catchments highlights our incomplete understanding of the relative importance of different mechanisms influencing stream chemistry and the consequences for downstream ecosystems.     

The role of antecedent groundwater heads in controlling transient aquifer storage and flood peak attenuation in karst watersheds

Transient storage of floodwaters in aquifers is known to attenuate peak flows in rivers and drive subsurface dissolution. Transient aquifer storage could be enhanced in watersheds overlying karst aquifers where caves facilitate surface and groundwater exchange. Few studies, however, have examined controls on, or magnitudes of, transient aquifer storage or flood peak attenuation in karstic watersheds. Here we evaluate flood peak attenuation with multiple linear regression analyses of 10 years of river and groundwater data from the Suwannee River, which flows over the karstic upper Floridan aquifer in north-central Florida and experiences frequent flooding. Regressions show antecedent river stage exerts the dominant control on magnitudes of transient aquifer storage, with recharge and time to peak having secondary controls. Specifically, low antecedent stages result in larger magnitudes of transient aquifer storage and thus greater flood attenuation than conditions of elevated antecedent stage. These findings suggest subsurface weathering, including cave formation and enlargement, caused by transient aquifer storage could occur on a more frequent basis in aquifers where groundwater table elevation is lowered due to anthropogenic or climatic influences. Our work also shows that measures of groundwater table elevation prior to an event could be used to improve predictive flood models. © 2018 John Wiley & Sons, Ltd.     

The role of wetland coverage within the near‐stream zone in predicting of seasonal stream export chemistry from forested headwater catchments

Stream chemistry is often used to infer catchment‐scale biogeochemical processes. However, biogeochemical cycling in the near‐stream zone or hydrologically connected areas may exert a stronger influence on stream chemistry compared with cycling processes occurring in more distal parts of the catchment, particularly in dry seasons and in dry years. In this study, we tested the hypotheses that near‐stream wetland proportion is a better predictor of seasonal (winter, spring, summer, and fall) stream chemistry compared with whole‐catchment averages and that these relationships are stronger in dryer periods with lower hydrologic connectivity. We evaluated relationships between catchment wetland proportion and 16‐year average seasonal flow‐weighted concentrations of both biogeochemically active nutrients, dissolved organic carbon (DOC), nitrate (NO₃‐N), total phosphorus (TP), as well as weathering products, calcium (Ca), magnesium (Mg), at ten headwater (<200 ha) forested catchments in south‐central Ontario, Canada. Wetland proportion across the entire catchment was the best predictor of DOC and TP in all seasons and years, whereas predictions of NO₃‐N concentrations improved when only the proportion of wetland within the near‐stream zone was considered. This was particularly the case during dry years and dry seasons such as summer. In contrast, Ca and Mg showed no relationship with catchment wetland proportion at any scale or in any season. In forested headwater catchments, variable hydrologic connectivity of source areas to streams alters the role of the near‐stream zone environment, particularly during dry periods. The results also suggest that extent of riparian zone control may vary under changing patterns of hydrological connectivity. Predictions of biogeochemically active nutrients, particularly NO₃‐N, can be improved by including near‐stream zone catchment morphology in landscape models.     

Influence of sea salt on stream water chemistry in an upland afforested catchment

The chemistry of bulk precipitation and stream water was monitored in an acidic afforested catchment at Llyn Brianne in upland Wales between 1985 and 1990. Throughfall, stemflow and soil water chemistry were also monitored between 1988 and 1989. Marine-derived solutes dominated the ionic composition of precipitation and stream water, which had mean Cl concentrations of 113 μequiv. 1^?1 and 245 μequiv. 1^?1, respectively. The higher concentrations in stream water reflect occult and dry deposition on the forest canopy and the effect of interception and transpiration losses. Chloride variations in stream water (112-454μequiv. 1^?1) were damped compared with bulk precipitation (28-762μequiv. 1^?1) due to the mixing of event (‘new’) water with pre-event (‘old’) water in the catchment soils. A storm episode monitored in the catchment in April 1989 was associated with high sea salt inputs and Cl concentrations in throughfall (1466μequiv. 1^?1) and storm runoff were exceptionally high (392μequiv. 1^?1). The Cl signal in stream water during the episode was consistent with an event (‘new’) water contribution to the storm response. However, a short-term hydrochemical budget estimated that although Cl outputs from the catchment during the event (1.17 kg ha^?1) were equivalent to 8% of inputs in throughfall and stemflow, the storm runoff was equivalent to 32% of effective precipitation. This indicates that pre-event (‘old’) water was the dominant source (> 75%) of storm runoff. Although sea salt inputs during the event had a marked impact on stream water chemistry, the anomalously high levels of acidity sometimes associated with sea salt events were not observed in this particular study.     

Characterizing the climatic water balance dynamics and different runoff components in a poorly gauged tropical forested catchment,Nicaragua

ABSTRACT

The water balance dynamics and runoff components of a tropical forested catchment (46?km²) on the southwestern Pacific coast of Nicaragua were studied combining hydrometry, geological characterization and hydrochemical and isotopic tracers (three-component hydrograph separation). The climatic water balance was estimated for 2010/11, 2011/12 and 2012/13 with net values of 811?mm year^-1, 782?mm year^-1 and –447?mm year^-1, respectively. Runoff components were studied at different spatial and temporal scales, demonstrating that different sources and temporal contributions are controlled by dominant landscape elements and antecedent rainfall. In forested sub-catchments, permeable soils, stratigraphy and steep slopes favour subsurface stormflow generation contributing 50% and 53% to total discharge. At catchment scale, landscape elements such as smooth slopes, wide valleys, deeper soils and water table allow groundwater recharge during rainfall events. Groundwater dominates the hydrograph (50% of total discharge) under dry prior conditions. However, low soil infiltration capacity generates a larger surface runoff component (42%) under wet prior conditions which dominates total discharge. Our results show that forested areas are important to reduce surface runoff and thus soil degradation, which is relevant for the design of water management plans.

Editor D. Koutsoyiannis Associate editor D. Gerten     

Relationship of topography to surface water chemistry with particular focus on nitrogen and organic carbon solutes within a forested watershed in Hokkaido,Japan

We studied the relationships between streamwater chemistry and the topography of subcatchments in the Dorokawa watershed in Hokkaido Island, northern Japan, to examine the use of topography as a predictor of streamwater chemistry in a watershed with relatively moderate terrain compared with other regions of Japan. Topographic characteristics of the Dorokawa watershed and its subcatchments were expressed as topographic index (TI) values, which ranged from 4·5 to 20·4 for individual grid cells (50 × 50 m²), but averaged from 6·4 to 7·4 for the 20 subcatchments. Streamwater samples for chemical analyses were collected four times between June and October 2002 from 20 locations in the watershed. The pH of water that passed through the watershed increased from ～5·0 to 7·0, with major increases in Na⁺ and Ca²⁺ and marked decreases in NO₃^? and SO . Distinctive spatial patterns were observed for dissolved organic carbon (DOC), dissolved organic nitrogen (DON), and NO₃^? concentrations of streamwater across the watershed. Statistical analyses indicated significant linear relationships between the average TI values of subcatchments and DOC, DON, and NO₃^? concentrations. Furthermore, the proportion of DOC in streamwaters in the wet season increased with TI values relative to other nitrogen species, whereas NO₃^? concentrations decreased with TI. The gradients of soil wetness and the presence of wetlands explained many of the observed spatial and temporal patterns of DOC, DON, and NO₃^? concentrations in the surface waters of the Dorokawa watershed. Our results suggest that the TI is especially useful for predicting the spatial distribution of DOC, DON and NO₃^? in the surface waters of Hokkaido, where topographical relief is moderate and wetlands more common than in other regions of Japan. Copyright © 2006 John Wiley & Sons, Ltd.     

Long-term precipitation and stream discharge records at seven forested experimental watersheds along a latitudinal transect in Japan: Jozankei,Kamabuchi, Takaragawa,Tsukuba, Tatsunokuchi-yama,Kahoku and Sarukawa

This data note introduces a database of long-term daily total precipitation and stream discharge data for seven forested watersheds in Japan that have been continuously monitored by the Forestry and Forest Products Research Institute. Three of the watersheds started data collection in the 1930s. Forest cover across the sites ranges from cool to warm temperate regions with the latitude spanning from 31 to 44° N and annual precipitation ranging from 1200 to 3000 mm yr⁻¹. The effects of vegetation change via clearcutting, thinning and forest fire (among other stressors) on stream discharge can be analysed from the long-term observation sites. Moreover, this multi-site dataset allows for inter- and intra-site comparisons of annual water loss (difference of annual precipitation and stream discharge). These long-term datasets can provide comprehensive insights into the effects of climate change and other stressors on forested ecosystems, not only in Japan but across a spectrum of forest types, if combined with other long-term records from other forested watersheds across the world.     

A spatially distributed model for the assessment of land use impacts on stream temperature in small urban watersheds

Stream temperatures in urban watersheds are influenced to a high degree by changes in landscape and climate, which can occur at small temporal and spatial scales. Here, we describe a modelling system that integrates the distributed hydrologic soil vegetation model with the semi‐Lagrangian stream temperature model RBM. It has the capability to simulate spatially distributed hydrology and water temperature over the entire network at high time and space resolutions, as well as to represent riparian shading effects on stream temperatures. We demonstrate the modelling system through application to the Mercer Creek watershed, a small urban catchment near Bellevue, Washington. The results suggest that the model was able to produce realistic streamflow and water temperature predictions that are consistent with observations. We use the modelling construct to characterize impacts of land use change and near‐stream vegetation change on stream temperatures and explore the sensitivity of stream temperature to changes in land use and riparian vegetation. The results suggest that, notwithstanding general warming as a result of climate change over the last century, there have been concurrent increases in low flows as a result of urbanization and deforestation, which more or less offset the effects of a warmer climate on stream temperatures. On the other hand, loss of riparian vegetation plays a more important role in modulating water temperatures, in particular, on annual maximum temperature (around 4 °C), which could be mostly reversed by restoring riparian vegetation in a fairly narrow corridor – a finding that has important implications for management of the riparian corridor. Copyright © 2014 John Wiley & Sons, Ltd.     

Observing lingering hyporheic storage using electrical resistivity: variations around stream restoration structures,Crabby Creek,PA

Time‐lapse geophysical surveys can map lingering hyporheic storage by detecting changes in response to saline tracer. Tracer tests were conducted in Crabby Creek, an urban stream outside Philadelphia, to examine the influence of stream restoration structures and variable sediment thickness. We compared electrical resistivity surveys with extensive well sampling (57 wells) in two 13.5‐m‐long reaches, each with a step drop created by a J‐hook. The two step drops varied in tracer behaviour, based on both the well data and the geophysical data. The well data showed more variation in arrival time where the streambed sediment was thick and was more uniform where sediment was thin. The resistivity in the reach with thin sediment showed lingering tracer in the hyporheic zone both upstream and downstream from the J‐hook. In the second reach where the sediment was thicker, the lingering tracer in the hyporheic zone was more extensive downstream from the J‐hook. The contrasting results between the two reaches from both methods suggested that sediments influenced hyporheic exchange more than the step at this location. Resistivity inversion differed from well data in both reaches in that it showed evidence for tracer after well samples had returned to background, mapping lingering tracer either upstream or downstream of a step. We conclude that resistivity surveys may become an important tool for hyporheic zone characterization because they provide information on the extent of slow moving fluids in the hyporheic zone, which have the potential to enhance chemical reactions. Copyright © 2012 John Wiley & Sons, Ltd.     

Historical land use as a driver of alternative states for stream form and function in forested mountain watersheds of the Southern Rocky Mountains

We demonstrate how land use can drive mountain streams in the Southern Rockies across a threshold to induce an alternative state of significantly reduced physical complexity of form and reduced ecological function. We evaluate field data from 28 stream reaches in relatively laterally unconfined valleys and unmanaged forest that is either old‐growth forest or naturally disturbed younger forest, and 19 stream reaches in managed forest with past land use. We evaluate potential differences in stream form, as reflected in channel planform, cross‐sectional geometry, and in‐stream wood loads, and stream function, as reflected in pool volume and storage of organic carbon. Field data indicate a threshold of differences in stream form and function between unmanaged and managed stream reaches, regardless of forest stand age, supporting our hypothesis that the legacy effects of past land use result in an alternative state of streams. Because physical complexity that increases stream retentiveness and habitat can maintain aquatic‐riparian ecosystem functions, the alternative physical state of streams in managed watersheds creates a physical template for an alternative ecological state with reduced pool volume, organic carbon storage, and ecosystem productivity. We recommend maintaining riparian forests that can supply large wood to streams as a stream restoration technique in historically forested stream segments. Copyright © 2017 John Wiley & Sons, Ltd.     

Comparison of stormflow responses of surface‐mined and forested watersheds in the Appalachian Mountains,USA

The results of a hydrological analysis that was conducted as part of a larger, multifaceted, collaborative effort to quantify ecosystem functions in watersheds subjected to land‐use and land‐cover change are presented. The primary goal of the study was to determine whether a small watershed in the Appalachian region (USA) that was recently subjected to surface mining and reclamation practices produces stormflow responses to rain events that are different from those produced by a nearby reference watershed covered by young, second‐growth forest. Water balances indicated that runoff yields did not vary significantly between the two watersheds on an annual basis. Statistically significant differences (p?0·05) in runoff responses were observed on an event basis, however, with the mined/reclaimed watershed producing, on average (a) higher storm runoff coefficients (2·5×), (b) greater total storm runoff (3×), and (c) higher peak hourly runoff rates (2×) when compared with the reference watershed. Results of a unit hydrograph analysis also showed, unexpectedly, that the modelled unit responses of the two watersheds to effective rainfall pulses were similar, despite the noted differences in land cover. Differences in stormflow responses were thus largely explained by dramatic reductions in cumulative rates of rainfall abstraction (measured using infiltrometers) attributable to soil compaction during land reclamation. Additional field hydrological measurements on other mined watersheds will be needed to generalize our results, as well as to understand and predict the cumulative hydrological impacts of widespread surface mining in larger watersheds and river basins. Copyright © 2006 John Wiley & Sons, Ltd.     

Hydrological flow paths at the allt A' mharcaidh catchment: An analysis of plot and catchment scale observations

An integrated programme of hydrological monitoring at the 10 km² Allt a' Mharcaidh catchment in north-east Scotland has been based on observations at plot, hillslope and catchment scale. The resonse of the principal soil types has been characterized from a combination of throughflow and three-dimensional tensiometer data at plot scale, and plot sequences have been used to investigate hillslope scale effects. Seep emergence is associated with downslope drainage and local topographic convergence; in parallel preferential pathways generate a highly dynamic throughflow response. Catchment and subcatchment hydrographs mirror the twin dynamic observed at hillslope scale, and a unified hypothesis of response is presented which is consistent with all scales of observations.     

Relating hydrogeomorphic properties to stream buffering chemistry in the Neversink River watershed,New York State,USA

Monitoring the effects of acidic deposition on aquatic ecosystems in the Northeastern US has generally required regular measurements of stream buffering chemistry (i.e. acid‐neutralizing capacity (ANC) and calcium Ca²⁺), which can be expensive and time consuming. The goal of this paper was to develop a simple method for predicting baseflow buffering chemistry based on the hydrogeomorphic properties of ten nested watersheds in the Neversink River basin (2·0–176·0 km²), an acid‐sensitive basin in the Catskill Mountains, New York State. The tributaries and main reach watersheds have strongly contrasting mean baseflow ANC values and Ca²⁺ concentrations, despite rather homogeneous vegetation, bedrock geology, and soils. A stepwise regression was applied to relate 13 hydrogeomorphic properties to the mean baseflow ANC values and Ca²⁺ concentrations. The regression analysis showed that watersheds with lower ANC values had a higher mean ratio of ‘quickflow’ runoff to precipitation during 20 non‐snowmelt runoff events (referred to as mean runoff ratio). The mean runoff ratio could explain at least 80% of the variability in mean baseflow ANC values and Ca²⁺ concentrations among the ten watersheds. Greater mean runoff ratios also correlated with steeper slopes and greater drainage densities, thus allowing the prediction of baseflow ANC values (r² = 0·75) and Ca²⁺ concentrations (r² = 0·77) with widely available spatial data alone. These results indicate that hydrogeomorphic properties can predict a watershed's sensitivity to acid deposition in regions where the spatial sources of stream buffering chemistry from the bedrock mineralogy and soils are fairly uniform. Copyright © 2010 John Wiley & Sons, Ltd.     

Transformations of runoff chemistry in the Arctic tundra,Northwest Territories,Canada

The transformation of snowmelt water chemical composition during melt, elution and runoff in an Arctic tundra basin is investigated. The chemistry of the water flowing along pathways from the surface of melting snow to the 95·5 ha basin outlet is related to relevant hydrological processes. In so doing, this paper offers physically based explanations for the transformation of major ion concentrations and loads of runoff water associated with snowmelt and rainfall along hydrological pathways to the stream outlet. Late‐lying snowdrifts were found to influence the ion chemistry in adjacent reaches of the stream channel greatly. As the initial pulse of ion‐rich melt water drained from the snowdrift and was conveyed through hillslope flowpaths, the concentrations of most ions increased, and the duration of the peak ionic pulse lengthened. Over the first 3 m of overland flow, the concentrations of all ions except for NO increased by one to two orders of magnitude, with the largest increase for K⁺, Ca²⁺ and Mg²⁺. This was roughly equivalent to the concentration increase that resulted from percolation of relatively dilute water through 0·25 m of unsaturated soil. The Na⁺ and Cl^? were the dominant ions in snowmelt water, whereas Ca²⁺ and Mg²⁺ dominated the hillslope runoff. On slopes below a large melting snowdrift, ion concentrations of melt water flowing in the saturated layer of the soil were very similar to the relatively dilute concentrations found in surface runoff. However, once the snowdrift ablated, ion concentrations of subsurface flow increased above parent melt‐water concentrations. Three seasonally characteristic hydrochemical regimes were identified in a stream reach adjacent to late‐lying snowdrifts. In the first two stages, the water chemistry in the stream channel strongly resembled the hillslope drainage water. In the third stage, in‐stream geochemical processes, including the weathering/ion exchange of Ca²⁺ and Mg²⁺, were the main control of streamwater chemistry. Copyright © 2006 John Wiley & Sons, Ltd.     

Improved understanding of spring and stream water responses in headwaters of the Indian Lesser Himalaya using stable isotopes,conductivity and temperature as tracers

Stable isotope data are presented for precipitation, spring and stream water in a headwater catchments in the Indian Lesser Himalaya. Isotopic contents of phreatic groundwater followed the local meteoric water line and showed minimal alteration by evaporation, suggesting fast recharge. Mean isotopic values for springs and the stream were close to the weighted annual mean for precipitation, indicating recharge was in synchrony with seasonal rainfall distribution. Precipitation exhibited isotopic declines of ?0.6‰ and ?0.2‰ δ¹⁸O per 100 m rise in elevation in July and August (monsoon), respectively. The time lag of one month between rainfall and spring discharge, combined with the isotopic lapse rate indicated a recharge elevation of 70–165 m above the spring outflow point, implying the water originated within the catchment. Time series of electrical conductivity and temperature of spring, seepage and stream waters confirmed the rapid recharge and limited storage capacity of the shallow aquifers.