Effects of grain-boundary configuration on the high-temperature creep strength of cobalt-base L-605 alloys

The effects of grain-boundary configuration on the high-temperature creep strength are investigated using commercial cobalt-base L-605 alloys with low carbon content in the temperature range 816 to 1038° C (1500 to 1900° F). Serrated grain boundaries are formed principally by the precipitation of tungsten-rich b c c phase (the same as ₂ phase found in Ni-20Cr-20W alloys) on grain boundaries by a relatively simple heat treatment in these alloys. The creep rupture properties are improved by strengthening of grain boundaries by the precipitation of tungsten-rich bcc (₂) phase. The specimens with serrated grain boundaries have longer rupture lives and higher ductility than those with normal straight grain boundaries under low stress and high-temperature creep conditions, while the rupture lives and the creep ductility of both specimens are almost the same under high stresses below 927° C. The matrix of the alloys is strengthened by the precipitation of carbides at temperatures below 927° C and by the precipitation of tungsten-rich ₂ phase at 1038° C during creep. It is found that there is an orientation relationship between tungsten-rich a2 phase particles and-Co matrix, such that (0 1 1)₂ ¶ (1 1 1) _-Co and [1 1]₂ ¶ [1 0] _-Co. The fracture surface of specimens with serrated grain boundaries is a ductile grain-boundary fracture surface, while typical grain-boundary facets prevailed in specimens with straight grain boundaries.     

Grain refinement by utilizing grain-boundary reaction in heat-resistant alloys

The possibility of grain refinement by thermal cycling is examined on commercial heatresistant alloys, namely, an austenitic 21Cr-4Ni-9Mn steel and a cobalt-base HS-21 alloy, in which the grain-boundary reaction occurs. A thermal cycle is composed of a high-temperature ageing which causes the grain-boundary reaction, and a subsequent short-term heating at the resolution temperature, which ensures complete dissolution of the grain-boundary reaction precipitates into the matrix. The grain diameter is finally reduced to about one-half or one-third of the original grain size after four thermal cycles, while a larger grain-size reduction is observed in the specimens with initially larger grain size. The effects of the amount of the grain-boundary reaction and the heat-treatment conditions on grain refinement are also experimentally discussed.     

On the initiation of wedge-type cracks at grain-boundary triple junctions during high-temperature creep

The typical grain boundary cracks are often formed at the grain-boundary triple junction as a result of blocking of grain-boundary sliding. However, a theoretical discussion has not fully been made on the nucleation of grain corner cracks at high temperatures where diffusional recovery occurs. In this study, a continuum mechanics model which incorporated the recovery effect by diffusion of atoms has been developed to explain the initiation of wedge-type cracking during high-temperature creep. A good agreement was found between the result of calculation based on this model and experimental results in austenite steels. It was considered that there is a critical creep rate for wedge-type cracking. The model was also applied to the prediction of the rupture life in creep.     

Creep and creep fracture of commercial aluminium alloys

Using standard power law equations, creep rate and creep life measurements at 373–463 K are analysed for a series of aluminium alloys, namely, 2419, 2124, 8090 and 7010. The seemingly complex behaviour patterns are easily rationalized through a modified power law expression, which incorporates the activation energy for lattice diffusion in the alloy matrices (145 kJ mol⁻¹) and the value of the ultimate tensile stress at the creep temperature. By considering the changes in microstructure and creep curve shape as the test duration and temperature increase, all results are then interpreted straightforwardly in terms of the processes shown to govern strain accumulation and damage evolution. Moreover, the data rationalization procedures are also included in new relationships which superimpose the property sets onto sigmoidal ‘master curves’, allowing accurate prediction of the 100,000 h creep-rupture strengths of 2124 by extrapolation of creep lives determined from tests having a maximum duration of only around 1000 h.     

The effect of cyclic creep on grain-boundary cavitation in ceramics

Small-angle neutron scattering has been used to characterize the cavity distribution in crept samples of a hot-pressed silicon carbide, which contained a thin continuous amorphous phase, and a sintered alumina, which contained no amorphous phase. The compression creep experiments were performed under cyclic loading at 1600° C and a frequency of 0.33 Hz. Comparison of the cavitation rates under cyclic loading with previously measured rates under static loading indicates that cavitation in the silicon carbide was unaffected by the cyclic loading, while the cavity volume fraction and the cavity size in the alumina were slightly increased by the cyclic loading. The results suggest that 0.33 Hz is too slow a frequency to affect the stress distribution and thus cavitation in the glassy phase containing silicon carbide, but it is rapid enough to accelerate cavitation in the absence of a glassy phase. This hypothesis is supported both by experimental results from other ceramic and metal systems and by calculations of characteristic stress relaxation times.     

On the fractal dimension of fracture surfaces of concrete elements

The problem of the relation between the fractal dimension of a fractured surface and the fracture toughness expressed by the stress intensity factor is investigated. The theoretical conditions for such assumptions are discussed. Collected experimental results and new tests performed onconcrete specimens subjected to Mode II fracture seem to confirm that relation within the scope of materials tested and with certain necessary restrictions.     

Analysis of the fractal dimension of grain boundaries of AA7050 aluminum alloys and its relationship to fracture toughness

Quantitative analysis of the grain boundaries in partially recrystallized microstructures of heat-treated 7050 aluminum alloys has been performed. Fractal dimensions of the extracted grain boundaries were calculated by box-counting method. Five different types of tear-tested materials rolled in different processes each at two orientations of 0° and 90° were studied. Efforts were made to connect the fractal dimensions of grain boundaries in the crack propagation direction to the fracture toughness (unit propagation energy, UPE, in tear test). The results show that there is a linear correlation between UPE and the fractal dimensions of the grain boundaries along the crack propagation direction for both 0° and 90° samples. The dependence corresponds well with the observation of transition from intergranular fracture to transgranular fracture with the increase of UPE. Quantitative analysis has also been performed on the micrographs to estimate the degree of recrystallization and the grain size in crack growth direction. No correlation between the fraction of recrystallized grains and the UPE could be detected.