四川攀枝花二叠纪双峰式火山岩地球化学特征及其地质意义

攀枝花二叠纪火山岩发育有玄武岩和粗面岩的基性和碱性两个端元,区域上明显缺失中间过渡类型。玄武岩SiO_2含量处于45.65%~49.32%范围内,粗面岩SiO_2含量介于64.39%~69.17%之间,构成经典的"双峰式"火山岩特征组合。两者均具有富Na、贫K、轻稀土富集、轻重稀土明显分馏的特征。特征微量元素Nb/Ta、Th/Ta、Th/U比值变化相对较小,玄武岩分别为15.16、2.70和4.13,粗面岩分别为15.40、2.55和4.12,显示两者具有相似的地球化学属性。微量元素特征显示,除了Ti和Y等少数高场强元素不协调以外,玄武岩与粗面岩绝大多数微量元素变化规律相似,且Rb、Ce、Y、Nb、Hf、Ta等元素与洋岛玄武岩(OIB)特征一致,说明它们具有地幔柱构造系统下的岩浆属性,岩浆源于石榴石二辉橄榄岩岩石圈地幔的部分熔融。结合前人资料,攀枝花二叠纪双峰式火山岩的厘定,不仅暗示了岩浆形成于拉张的裂谷构造环境,也为西南地区二叠纪峨眉山大火成岩地幔柱成因提供支撑。     

四川盐源地区晚二叠纪双峰式火山岩的厘定及其地质意义

四川省盐源县柏林山一带广泛分布着一套基性岩、酸性岩的火山岩组合,两类火山岩在时空上紧密伴生,二者之间缺失中性火山岩,构成典型的双峰式火山岩组合。通过对区内双峰式火山岩的空间分布调查,基性岩主要为致密块状玄武岩、斑状玄武岩,酸性火山岩主要为碱流岩,碱流岩位于玄武岩顶部,为晚二叠纪峨眉山大火成岩省的组成部分。在地质背景、岩石学、地球化学等方面研究的基础上,对区内双峰式火山岩的成因和形成环境进行了探讨,表明玄武岩的原始岩浆来自富集型地幔源区,为地幔橄榄岩小程度部分熔融的产物,形成于洋岛构造环境,碱流岩主要为玄武岩浆极度分离结晶后的酸性残余岩浆形成,形成于陆内拉张构造环境。柏林山地区晚二叠纪双峰式火山岩的发现和厘定为峨眉山玄武岩的演化提供了新的线索和依据,为区域成矿研究以及稀有稀土找矿提供了新的启示。     

广东三水盆地火山岩: 地球化学特征及成因--兼论火山岩性质的时空演化和南海形成的深部过程

位于中国东南部的三水盆地、珠江口盆地、雷琼半岛和北部湾地区广泛分布新生代火山岩。火山岩的形成时间具有从内陆向沿海变新的特点,早第三纪三水和珠江口盆地火山岩具有由玄武岩与粗面岩-流纹岩构成的双峰式特点。其中玄武岩和粗面岩的微量元素和稀土元素的配分形式相似,富集大离子亲石元素并且有相似的εNd(T)同位素组成(2.34～6.4),说明它们来自相同的地幔源区,为同源岩浆演化的产物。玄武岩和粗面岩经历了不同的结晶分异过程,其中玄武岩在较深部岩浆房中经历橄榄石和单斜辉石为主的分离结晶作用,而粗面岩则是在浅部岩浆房中由玄武岩浆分异形成的过渡性岩浆再经过强烈的钾长石和斜长石、以及磷灰石的结晶分异形成的。晚第三纪珠江口盆地和北部湾火山岩、雷琼半岛第四纪火山岩则由碱性和拉斑玄武岩构成。这些火山岩的形成时间和地球化学和同位素特征表明它们经历了连续的软流圈地幔上涌和部分熔融过程,受控于自晚中生代以来的地幔柱构造。南海的形成是地幔柱活动引起的地幔上涌和大陆裂解作用的结果。     

塔里木早二叠世大火成岩省的时空特征和岩浆动力学

塔里木早二叠世大火成岩省是继峨眉山大火成岩省之后在中国境内发现的又一个二叠纪大火成岩省。近十多年来,对塔里木大火成岩省及其与地幔柱和大规模成矿的关系受到极大关注。本文结合近年来国内外的最新研究进展,对塔里木大火成岩省的时空分布、岩石地球化学特征、成因演化和动力学过程以及成矿潜力进行综述。塔里木大火成岩省的残余分布面积达25万km2,岩石类型主要有大陆溢流玄武岩(分布广泛),长英质火山岩类(主要分布在塔里木盆地的北部)和基性-超基性及中酸性侵入岩类等(主要出露于巴楚、巴什索贡和皮羌等地区)。该大火成岩省事件的岩浆活动时间主要集中在292~285 Ma(玄武岩和第一期长英质火山岩类形成阶段)和284~274 Ma(侵入岩类、含钒钛磁铁矿床和第二期长英质火山岩类形成阶段)。系统和深入的岩石地球化学和Sr-Nd-Hf-Pb同位素研究表明,塔里木大火成岩省从早期喷发的玄武岩到晚期的侵入岩类具有明显不同的地球化学特征,指示其岩浆源区发生了从富集岩石圈地幔来源到地幔柱来源的明显转变。结合相关的地质学和岩石学证据及铂族元素(PGEs)等研究,提出了一个上涌的地幔柱不断向位于岩石圈地幔底部的岩浆源区注入亏损地幔物质、持续改变其同位素地球化学特征并最终形成塔里木大火成岩省各主要岩石类型的岩浆演化新模型。最后,巴楚瓦吉里塔格含钒钛磁铁矿的存在也表明在塔里木大火成岩省中具有找寻大型钒钛磁铁矿床的潜力。     

南秦岭元古宙板内火山作用特征及构造意义

南秦岭元古宙火山岩主要由两大类岩石构成，一类为SiO245%-57%的基性火山岩系，另一类为SiO267%-78%的酸性火山岩系，主要岩石类型为细碧岩、玄武岩和石英角班岩、流纹岩。基性火山岩整体上属拉斑玄武岩系列，酸性火山岩属钙碱系列。火山岩强烈富集稀土元素，尤其是轻稀土元素，酸性火山岩和基性火山岩有相似的稀土元素特征，显示了源区特征的不同。基性火山岩富集强不相容元素，相对亏损Nb和Ti, 成于大陆裂谷环境，具有大陆拉斑玄武岩的特征。同位素特征表明基性火山作用与地幔柱活动密切相关。南秦岭的中、晚元古代大陆拉张及由古地幔柱活动所引发的陆裂火山岩浆活动是古秦岭洋打开的先兆。     

同位素地球化学在峨眉山大火成岩省研究中的应用现状与进展

系统总结分析了峨眉山大火成岩省的同位素地球化学研究成果。总结前人研究资料中大量峨眉山大火成岩省（ELIP）中玄武岩和侵入体的同位素年龄数据,并结合生物地层学特征,确认我国西南峨眉山大火成岩省中的各个岩石单元的形成时代为251~263 Ma,其中基性-超基性侵入岩体形成于约259 Ma,而作为峨眉山大火成岩省主体的峨眉山玄武岩系形成于251~253 Ma。Sr-Nd、Re-Os、Lu-Hf及O同位素地球化学数据表明峨眉山大火成岩省的源区为地幔柱或者大陆岩石圈地幔(SCLM),其中峨眉山玄武岩与富含Fe-Ti氧化物基性侵入体的Sr-Nd同位素特征相似,具有与OIB相似的同位素性质;而含Cu-Ni硫化物的基性-超基性岩体的同位素特征接近地壳物质,可能与地壳混染作用有关。     

桂西龙川-世加辉绿岩型金矿的成矿背景研究

<正>位于杨子地台西南缘的桂西分布着大面积的晚古生代基性侵入岩(辉绿岩和玄武岩)。众多研究表明,这些基性侵入岩介于华南、印支和思茅地块三者交界分布,呈层状或似层状小岩体产出,与峨眉山地幔柱有关。桂西基性岩的分布虽然距离峨眉山大陆溢流玄武岩主体比较远,但是它位于峨眉山大火成岩省(ELIP)东南部,表明二叠纪峨眉山大火成岩省岩浆活动已经影响到了桂西地区,故桂西地区基性岩可能是二叠纪峨眉山大火成岩省外带外侧东南端的产物(吴浩若等,1997;王忠诚等,1997;廖帅等,2013)。     

峨眉山大火成岩省Cu-Ni-PGE成矿作用——几个典型矿床岩石地球化学特征的分析

峨眉山大火成岩省岩浆型Cu-Ni-PGE矿化岩体广泛分布,构成峨眉山地幔柱成矿系统中一个非常重要的成矿系列。本文剖析了峨眉山大火成岩省该类矿床的分布及部分典型矿床的地质地球化学特征和矿化特征,揭示了成矿岩体统一的地幔柱成因,阐述了Cu-Ni-PGE成矿作用与峨眉山地幔柱岩浆活动体系的关系,探讨了由于岩浆演化过程及硫化物熔离富集过程的差异所导致的矿化类型变异。指出Cu-Ni-PGE矿床成矿岩体原始岩浆为地幔柱高程度熔融的高镁玄武岩浆,成矿岩体与峨眉山低钛玄武岩同源,矿化岩体主要产于峨眉山地幔柱活动模型的内带低钛玄武岩分布区;金宝山、朱布、力马河、杨柳坪矿床分别代表峨眉山地幔柱Cu-Ni-PGE成矿作用不同成矿机制的端员类型。     

峨眉山地幔柱为云南金刚石矿的形成提供了条件——以大理海东为例

大理海东地区,地处二叠纪峨眉山地幔柱活动形成的川滇黔接壤地区峨眉山大火成岩省之一的扬子陆块西缘盐源-丽江凹陷(火山岩)带南端。1华力西晚期岩浆活动受峨眉山地幔柱影响,引发扬子陆块内大规模超基性-基性岩浆的侵入与喷出。早阶段通常产生剧烈的深成爆发,形成爆发角砾岩筒、火山     

北祁连山元古宙末－寒武纪主动大陆裂谷火山作用

北祁连山元古宙末－寒武纪大陆裂谷火山岩系为双峰式火山岩套，主要由基性与酸性火山岩组成。基性火山岩有磁性玄武岩与拉斑玄武岩两个岩浆系列，且富集ＬＲＥＥ与ＬＩＬ，其岩浆源区为与洋岛玄武岩源相似的富集地幔柱源。软流圈地幔柱上涌导致岩石圈地慢部分熔融，其熔体与地幔柱衍生熔浆混合，形成本区具有中等钕，锶同位素比值特点的基性岩浆。基性岩浆上侵至陆壳，引起下部陆壳深熔，产生长英质岩浆。地幔柱上隆促使大陆扩张，及至形成北祁连山元古宙末－寒武纪大陆裂谷。     

峨眉山大火成岩省东区普安玄武岩系年代学、地球化学及成因研究

广泛分布于中国西南川、滇、黔三省的峨眉山玄武岩是我国最早被国际认可的大火成岩省,受到了国内外学者的广泛关注。前人对大火成岩省西区玄武岩已达成多项共识,而对东区玄武岩的岩石组合、火山活动时限、岩石成因等方面还存在诸多争议。本文以峨眉山大火成岩省东区贵州普安玄武岩系为研究对象,通过解析典型剖面,明确该区玄武岩系岩石类型从底到顶总体为第1旋回的爆发相火山角砾岩、第2旋回的溢流相玄武岩以及第3旋回的火山沉积相凝灰岩。玄武岩系顶部凝灰岩锆石LA-ICP-MS U-Pb测年结果限定了大火成岩省东区火山活动时间持续上限为250 Ma。主微量元素显示该区玄武岩系以高Ti碱性玄武岩为主。玄武岩稀土元素球粒陨石标准化为轻稀土元素富集的右倾曲线模式,Rb和Sr亏损、Ba和Hf富集等特征与贵州地区玄武岩、峨眉山大火成岩省西区高Ti玄武岩以及OIB地球化学特征基本一致。微量元素显示该区玄武岩源区可能为受交代的石榴石地幔橄榄岩,由深部地幔柱上升至石榴石橄榄岩稳定区部分熔融产生熔融体,和富集交代流体的大陆岩石圈地幔混合形成,岩浆上升运移过程中发生了一定程度分离结晶作用和微弱地壳混染作用。研究表明,峨眉山大火成岩省东区普安玄武岩系形成于峨眉山地幔柱边部埋深较大、低程度部分熔融以及高压的环境。     

四川华蓥偏岩子晚二叠世玄武岩地球化学特征及其与峨眉山大火成岩省的成因关系

四川华蓥偏岩子地区位于四川盆地中东部,新发现的晚二叠世玄武岩介于茅口组(下伏)和龙潭组(上覆)之间,可与峨眉山玄武岩进行对比.矿物学和地球化学研究表明,偏岩子玄武岩属于高钛亲碱性系列,具有OIB型的稀土元素和微量元素配分模式.偏岩子玄武岩基本未遭受地壳混染,单斜辉石的结晶温度为1405～1439℃,指示源区存在异常高温...     

峨眉山大火成岩省岩石成因与空间差异性研究——基于全区高Ti玄武岩地球化学数据分析与模拟

高Ti玄武岩成因是峨眉山大火成岩省(ELIP)研究的热点问题。由于高Ti玄武岩地球化学特征在空间上存在差异,其岩石成因尚未达成共识。本文系统收集了峨眉山大火成岩省中高Ti玄武岩地球化学数据以及锆石ID-TIMS U-Pb测年结果,并进行统一处理分析与模拟。研究结果显示,峨眉山大火成岩省形成于约259～258 Ma,高Ti玄武岩在大火成岩省全区均有出露。自西向东,岩石年龄无明显变化规律,厚度逐渐变薄。高Ti玄武岩起源于具有富集地幔特征的地幔柱源区,几乎没有遭受地壳混染,经历了低程度部分熔融作用并可能混入了少量岩石圈地幔物质,发生了以单斜辉石为主的分离结晶作用。峨眉山大火成岩省深部存在一个非对称式的地幔柱,自西向东,高Ti玄武质岩浆起源深度变浅、温度降低,熔融深度和压力随之降低,熔融程度相对增大。模拟表明,源区石榴石相和尖晶石相的熔融程度分别为0.5%～2%和5%,石榴石相熔融比例自西向东由90%减小至40%,而尖晶石相熔融比例由10%增大至60%。     

http://www.sciencedirect.com/science/article/pii/S1674987113001072

The late Permian Emeishan large igneous province(ELIP) covers ~0.3 x 106 km2 of the western margin of the Yangtze Block and Tibetan Plateau with displaced,correlative units in northern Vietnam(Song Da zone).The ELIP is of particular interest because it contains numerous world-class base metal deposits and is contemporaneous with the late Capitanian(~260 Ma) mass extinction.The flood basalts are the signature feature of the ELIP but there are also ultramafic and silicic volcanic rocks and layered maficultramafic and silicic plutonic rocks exposed.The ELIP is divided into three nearly concentric zones(i.e.inner,middle and outer) which correspond to progressively thicker crust from the inner to the outer zone.The eruptive age of the ELIP is constrained by geological,paleomagnetic and geochronological evidence to an interval of 3 Ma.The presence of picritic rocks and thick piles of flood basalts testifies to high temperature thermal regime however there is uncertainty as to whether these magmas were derived from the subcontinental lithospheric mantle or sub-lithospheric mantle(i.e.asthenosphere or mantle plume) sources or both.The range of Sr(I_(Sr) = 0.7040-0.7132),Nd(ε_(Nd)(t) ≈-14 to +8),Pb(~(206)Pb/~(204)Pb_1≈ 17.9-20.6) and Os(γ_(Os) =-5 to +11) isotope values of the ultramafic and mafic rocks does not permit a conclusive answer to ultimate source origin of the primitive rocks but it is clear that some rocks were affected by crustal contamination and the presence of near-depleted isotope compositions suggests that there is a sub-lithospheric mantle component in the system.The silicic rocks are derived by basaltic magmas/rocks through fractional crystallization or partial melting,crustal melting or by interactions between mafic and crustal melts.The formation of the Fe-Ti-V oxide-ore deposits is probably due to a combination of fractional crystallization of Ti-rich basalt and fluxing of C02-rich fluids whereas the Ni-Cu-(PGE) deposits are related to crystallization and crustal contamination of mafic or ultramafic magmas with subsequent segregation of a sulphide-rich portion.The ELIP is considered to be a mantle plume-derived LIP however the primary evidence for such a model is less convincing(e.g.uplift and geochemistry) and is far more complicated than previously suggested but is likely to be derived from a relatively short-lived,plume-like upwelling of mantle-derived magmas.The emplacement of the ELIP may have adversely affected the short-term environmental conditions and contributed to the decline in biota during the late Capitanian.     

Review Section

ABSTRACT

The petrology, geochronology, and geochemistry of the early Permian volcanic rocks from Houtoumiao area, south Xiwuqi County in central Inner Mongolia of China, are studied to elucidate the early Permian tectonic setting of the region. The volcanic rocks, which are interbedded with sandstone, feature both mafic and felsic compositions and show a bimodal nature. Zircon U–Pb dating reveals that the volcanic rocks formed at 274–278 Ma, similar to the ages of bimodal magmatism in neighbouring areas. The mafic rocks are composed of tholeiitic basalt, basaltic andesite, basaltic trachyandesite, and trachyandesite. They are rich in Th, U, and LILEs, depleted in HFSEs Nb, Ta, and Ti, and have positive ε_Nd(t) values (+3.6 to +7.9). Geochemical analyses indicate that the mafic rocks originated from metasomatized lithospheric mantle. The felsic volcanic rocks are mainly rhyolite, with minor trachyte and dacite. They have different evolutionary tendencies of major elements, chondrite-normalized REE patterns, and isotopic compositions from the mafic volcanic rocks, which preclude formation by fractional crystallization of mafic melts. The ε_Nd(t) values of the felsic rocks are similar to those of the Carboniferous Baolidao arc rocks in the region. It is suggested that Permian felsic melts originated from the partial melting of Carboniferous juvenile arc-related rocks. By comparison with typical Cenozoic bimodal volcanism associated with several tectonic settings, including rift, post-collisional setting, back-arc basin, and the Basin and Range, USA, the bimodal volcanic rocks in central Inner Mongolia display similar petrological and geochemical characteristics to the rocks from back-arc basin and the Basin and Range, USA. Based on the analysis of regional geological data, it is inferred that the early Permian bimodal volcanic rocks in the study area formed on an extensional continental margin of the Siberian palaeoplate after late Carboniferous subduction–accretion.     

Petrogenesis of the Dullstroom Formation, Bushveld Magmatic Province, South Africa

The Precambrian Dullstroom Formation of South Africa, which is predominantly composed of basaltic andesites interbedded with subordinate sedimentary and felsic volcanic strata, represents the first phase of an extended period of magmatism that was responsible for the Bushveld Magmatic Province, including the extrusive Rooiberg Group and the intrusive Bushveld Complex. New geochemical and isotopic data for the Dullstroom Formation are presented in an effort to elucidate the petrogenetic processes operative during the initiation of this magmatic episode. The volcanic units of the central portion of the Dullstroom Formation have been subdivided into at least three interbedded compositional groups: low Ti mafic to intermediate units, high-Ti mafic to intermediate units, and high Mg felsic units. High Ti and low Ti volcanic units are similar in some compositional characteristics to basalts of the nearby northern and southern provinces, respectively, of the Mesozoic Karoo continental flood basalts. Isotopic and compositional data for low Ti Dullstroom strata are consistent with bulk assimilation into a melt similar in composition to a southern Karoo basalt of 20% upper continental crust accompanied by 20% fractional crystallization of pyroxene and plagioclase. Isotopic and compositional data for high Ti Dullstroom strata are consistent with magma mixing of 30% northern Karoo K-rich basalt and 70% southern Karoo basalt followed by 20% assimilation of upper continental crust and 20% fractional crystallization of pyroxene and plagioclase. Compositions of high Mg felsic volcanic strata are consistent with 25% assimilation of a mixture of silica-rich sedimentary rock and upper continental crust into a melt similar in composition to low Ti volcanic units with 25% fractional crystallization of pyroxene and plagioclase. However, it has been suggested that compositions of these high Mg felsic strata may also be consistent with interaction of a crustal melt. Assimilation, fractional crystallization, and magma mixing that apparently affected these Dullstroom Formation volcanic strata may have occurred in a series of shallow magma chambers. These data are consistent with the suggestion that Dullstroom Formation volcanic rocks are the result of a mantle plume. Mantle plume origin also is suggested by the large volume of intrusive and extrusive strata associated with this magmatic episode. These data do not support the hypothesis that the Bushveld Complex and the Rooiberg Group formed by impacts of a cluster of comets or asteroids. Received: 14 October 1998 / Accepted: 17 May 1999     

黔西南下三叠统飞仙关组沉积物源分析对峨眉山大火成岩省火山剥蚀序列的重建约束

峨眉山大火成岩省在形成后遭受了强烈的风化剥蚀,与右江盆地构成了独特的源-汇沉积体系,相关的碎屑沉积记录是重建峨眉山大火成岩省晚期火山序列、揭示大火成岩省岩浆演化的关键。本文对黔西南地区右江盆地北缘下三叠统下部飞仙关组开展了详细的沉积物源研究。飞仙关组泥岩由长石、石英和黏矿物等组成,具有低SiO₂、高TiO₂含量和低Al₂O₃/TiO₂值的特征,具Eu的弱负异常,微弱的Nb、Ta负异常。基于Al₂O₃/TiO₂和La/Sm物源图解分析,研究样品的主要物源由峨眉山大火成岩省的高-Ti玄武岩和少量酸性火山岩构成,这与右江盆地晚二叠世的碎屑沉积物源组成一致。碎屑锆石具有～260 Ma的年龄峰值,对应锆石具有较低的Th/Nb和较高的Nb/Hf值,均支持峨眉山大火成岩省作为主要的沉积物源区,而同时存在的>400 Ma的碎屑锆石则对应于峨眉山玄武质岩浆上升时所捕获的华南地壳物质。与上二叠统的碎屑锆石U-Pb年龄组成和锆石...     

新疆新源县城南石炭纪火山岩岩石学和元素地球化学研究

新疆新源县南部那拉提山北坡出露的石炭纪火山岩主要由玄武岩、玄武质粗面安山岩、粗面安山岩、安山岩、流纹岩和火山碎屑岩组成。该火山岩中玄武岩属于钙碱性系列,安山质岩石和流纹岩属于高钾钙碱性系列,其中轻稀土轻微富集而重稀土相对亏损,玄武岩富集大离子亲石元素、U、Th和Pb,亏损高场强元素。研究表明,该火山岩岩浆可能是由俯冲板片脱水产生的流体交代地幔楔后,地幔楔发生部分熔融的结果。微量元素模拟计算表明,该玄武岩岩浆可以由石榴石二辉橄榄岩经3％～6％的部分熔融得到;安山质岩浆可由玄武岩岩浆经15％-28％的分离结晶形成。