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建立了15种邻苯二甲酸酯类化合物的气相色谱-质谱(GC-MS)分析方法,并将其应用于饮料样品的测定。在对检测条件进行优化的基础上,通过提取特征离子进行检测,得到15种目标物的线性范围为5~10000μg/L,方法的检出限(S/N=3)为3~500μg/L;考察了各类饮料的提取方法,并在100μg/L、10000μg/L两个加标水平下对方法的可靠性进行评价,平均回收率为90%~110%(n=6),相对标准偏差(RSD,n=6)为0.58%~4.90%。该方法灵敏度高、精密度好、前处理过程简单、溶剂用量小、净化效果好,可用于饮料中邻苯二甲酸酯的快速准确分析。 相似文献
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以丙酮为内标物,建立了一种气相色谱-质谱法测定己烷中痕量苯的方法.实验结果表明,在质量浓度为0.0006%~0.1808%之间,标准曲线的相关系数为0.9995,线性良好,相对标准偏差为1.02%(n=8),回收率在101.56%~103.22%之间,方法操作简单,检出限低,精密度好,准确度高. 相似文献
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利用气质联用技术(GC-MS)结合交互移动窗口因子分析法(AMWFA)比较分析了厚朴汤(药对厚朴-白术)及其单味药的共有成分,对药对与单味药的挥发油进行了定性和定量分析。鉴定出药对的挥发性组分62种,占总含量的91.60%;厚朴的挥发性组分54种,占总含量的90.43%;白术的挥发性成分53种,占总含量的91.83%。结果表明,厚朴与药对挥发油有35种共有组分,白术与药对挥发油有20种共有组分。药对挥发油成分并不等于两个单味药挥发油成分之和。 相似文献
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Natural rubber was vulcanized with a new binary accelerator system based on 1‐phenyl‐2,4‐dithiobiuret (DTB) and dicyclohexyl benzothiazyl sulfenamide. A significant reduction in cure time was observed with the addition of DTB. The cure kinetics was investigated and the activation energy was determined. The mechanical properties were improved by adding DTB, and the maximum values are shown at an optimum concentration. Estimates of the concentration of crosslinks and of the relative proportions of different types of crosslinks were made by the chemical characterization of the vulcanizates. The crosslink densities obtained from swelling measurements and stress–strain measurements were compared with those obtained from modulus measurements. All of them follow a similar trend and support the observed mechanical properties. A dynamic mechanical analysis of the mixes was carried out and the activation energy was determined from Arrhenius plots. The glass‐transition temperature was found to increase with the increase in crosslink density and frequency of measurements. The stress–strain curves were found to not deviate from the strain crystallizing nature of natural rubber. The mechanical properties, network characterization, and processing characteristics were used to optimize the DTB concentration. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 87: 2193–2203, 2003 相似文献
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The photodegradation of raw natural rubber and natural rubber compound film were studied using an artificial solar energy simulator. The properties of degraded rubber sheets containing benzophenone (BP) were determined by solution viscosity, 1H‐NMR, and FTIR analyses. In the case of rubber compounds containing BP, the changes of tensile strength and crosslinking density were determined. It was found that BP could amply accelerate the photodegradation of rubber. To control the release rate of BP, it was necessary to encapsulate BP with urea–formaldehyde as a matrix. The encapsulated BP or capsule was formed by an interfacial polycondensation reaction between formaldehyde and urea. The kinetic of release rate of BP from urea–formaldehyde capsule was markedly observed within 15 days of release time; after that the rate of BP released from urea–formaldehyde microcapsule was very slow. At the same concentration of BP, the degradation rate of rubber compound by adding BP directly was faster than that of the rubber containing encapsulated BP. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 297–305, 2003 相似文献
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用附着型促进剂PBS在机械混炼插层法的基础上制备了天然橡胶/蒙脱土纳米复合材料。由于硫化后大部分促进剂基团都连在橡胶分子链上,因此用分子一端能和蒙脱土片层有相互作用的附着型硫化促进剂,可以大大增强蒙脱土和橡胶基体的相互作用,得到性能优良纳米复合材料。用PBS制备纳米复合材料其硫化体系活性能低,硫化胶交联密度增大,有机蒙脱土片层在橡胶基体中达到纳米级的分散,具有优良的力学性能,加入8%有机蒙脱土100%模量从1.2 MPa增至2.2 MPa,500%模量从8.12 MPa增至18.23 MPa,邵氏GA硬度从45增至55,而加入2%有机蒙脱土500%模量从8.12 MPa增至17.06 MPa,撕裂强度从36.31 kN/m增至43.65kN/m,加入2~10份有机蒙脱土时其效果相当于加入40份半补强炭黑。 相似文献
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Roberta M. Mariano Helson M. da Costa Marcelo R. L. Oliveira Mayura M. M. Rubinger Leila L. Y. Visconte 《应用聚合物科学杂志》2008,110(4):1938-1944
A conventional vulcanization system containing tetrabutylammonium bis(4‐methylphenyldithiocarbimato)zincate(II) (ZNIBU) was used for curing of natural rubber (NR) compounds. Rheometric (ts1, t90, and CRI) and mechanical properties, such as tensile and tear strengths and modulus at 300%, were measured to evaluate the acceleration potential of ZNIBU. Commercial accelerators (TMTD, MBTS, and CBS) and a binary system CBS/ZNIBU were also tested for comparison purposes. It was observed that ZNIBU alone does not give either safe scorch time or cure rates appropriate for industrial applications. Nevertheless, mechanical properties are comparable to those given by the other accelerators used. As for the binary system, positive synergistic effects can be found in tear strength and modulus of NR vulcanizates. Besides, ZNIBU does not contribute for the formation of nitrosamines in the vulcanization process. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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通过配位反应制备得到双金属硫化促进剂二乙基二硫代氨基甲酸锌镧配合物(ZnLaDC),在不添加传统活化体系氧化锌(ZnO)/硬脂酸(SA)的情况下,考察了ZnLaDC用量对丁苯橡胶(SBR)/天然橡胶(NR)胎面胶复合材料硫化特性及物理机械性能的影响,并与传统硫化体系二乙基二硫代氨基甲酸锌(ZnDC)/ZnO/SA制备的硫化胶性能进行了对比。结果表明,随着ZnLaDC用量的增加,SBR/NR胎面胶复合材料的硫化特性、压缩疲劳生热性能及耐磨性得到有效提高,当ZnLaDC用量为5份时,复合材料的综合性能最佳。与传统硫化体系ZnDC/ZnO/SA制备的硫化胶相比,采用ZnLaDC制备的硫化胶具有更优异的静态力学性能及耐切割性。 相似文献
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低模量硫化硅橡胶粘接研究 总被引:2,自引:0,他引:2
采用sol—gel工艺自制的SiO2补强增韧环氧树脂作为胶粘剂,对低模量硫化硅橡胶与金属或复合材料进行粘接试验,分析胶粘剂中SiO2理论含量及粘接工艺对粘接性能的影响,并把硫化硅橡胶放在改性环氧树脂中进行溶张试验,探索胶粘剂对硅橡胶的粘接机理、结果表明,随着SiO2先驱体-有机硅烷含量的增加,硅橡胶的溶胀程度提高改性环氧树脂胶粘刺能浸入硅橡胶的表层,对硅橡胶具有良好的亲和力。用该胶粘剂对硅橡胶与金属或复合材料进行粘接时,取得了良好的粘接效果。 相似文献
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吹脱-酸析-臭氧氧化预处理橡胶促进剂生产废水 总被引:2,自引:0,他引:2
采用吹脱-酸析-臭氧氧化工艺预处理橡胶促进剂废水,通过改变Na OH投加量、气液比、吹脱时间、p H值、曝气时间、臭氧投加量等,确定最佳反应条件,结果表明:对原水CODCr的质量浓度为12 000 mg/L的橡胶促进剂废水处理后,废水CODCr的总去除率为82%,作为蒸发除盐预处理,可以保障除盐装置的运行。 相似文献
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橡胶促进剂NOBS废水处理工程实践 总被引:3,自引:0,他引:3
采用蒸发-催化氧化预处理橡胶促进剂NOBS废水,在进水COD≤20000mg/L情况下,预处理后COD约为1000mg/L.达到了预期处理效果。 相似文献