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甲基异丁基醇气相催化脱氢制备甲基异丁基酮的工艺研究 总被引:1,自引:0,他引:1
在固定床反应器上研究了自制 CuO/ZnO/Al_2O_3为催化剂,常压下由甲基异丁基醇脱氢制备甲基异丁基酮的反应,得到了较佳的工艺条件:温度240~250℃,甲基异丁基甲醇质量空速1.0~1.5 h~(-1),催化剂还原温度低于240℃。在该条件下,甲基异丁基甲醇的单程转化率最高可达82.2%,甲基异丁基酮选择性达到99.0%。实验结果表明,在实验条件下该催化剂具有较好的稳定性。 相似文献
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针对顺丁烯二酸二异辛酯酯化合成催化剂进行了综述,着重介绍了硫酸、对甲苯磺酸、超强固体酸、金属等催化剂在酯化反应中制备顺丁烯二酸二异辛酯的研究进展,为开发新型高效、清洁环保、价廉经济的催化剂提供借鉴. 相似文献
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Sang-Eon Kim Soon-Do Yoon Ki-Pung Yoo Hun-Soo Byun 《Korean Journal of Chemical Engineering》2009,26(1):199-205
Experimental cloud-point data of binary and ternary mixtures for poly(isodecyl methacrylate) [P(IDMA)] in supercritical carbon
dioxide, dimethyl ether (DME), propane, propylene, butane and 1-butene have been studied experimentally using a high pressure
variable volume view cell. These systems show the phase behavior at temperature of 308 K to 473 K and pressure up to 255 MPa.
The cloud-point curves for the P(IDMA)+CO2+isodecyl methacrylate (IDMA) are measured in changes of the pressure-temperature (P-T) slope, and with cosolvent concentrations
of 0-60.1 wt%. Also, experimental data of phase behaviors for IDMA in supercritical carbon dioxide is obtained at temperature
range of 313.2–393.2 K and pressure range of 5.8–22.03 MPa. The experimental results were modeled with the Peng-Robinson equation
of state. The location of the P(IDMA)+CO2 cloud-point curve shifts to lower temperatures and pressures when DME is added to P(IDMA)+CO2 solution. The P(IDMA)+C4 hydrocarbons cloud-point curves are ca. 16.0 MPa lower pressures than the P(IDMA)+C3 hydrocarbons curves at constant temperature.
This article is dedicated to Professor Chul Soo Lee in commemoration of his retirement from Department of Chemical and Biological
Engineering of Korea University. 相似文献
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Crosslinked 1‐octene‐isodecyl acrylate copolymers were synthesized and evaluated for oil‐absorbency applications. The copolymer was crosslinked at different concentrations of ethylene glycol diacrylate (EGDA) and EG dimethacrylate (EGDMA) crosslinkers via catalytic initiation or by electron‐beam irradiation at a dose rate 80 kGy. The concentration of both crosslinkers was varied from 0.5 to 2%. The effects of the crosslinking conditions such as crosslinker concentration, method of polymerization and monomer concentrations on the conversion and gel fraction were examined through oil‐ absorption tests using petroleum crude oil. It was found that the oil absorbency was influenced mainly by the degree of crosslinking and the hydrophobicity of the copolymer units. The final equilibrium oil content, volume fraction of the polymer, and swelling capacity were determined at 298 K. The effective crosslinking density, average molecular weight between the crosslinks, and polymer–toluene interaction parameter were determined from stress–strain measurements. The crosslinking efficiencies of EGDA and EGDMA toward copolymers were determined. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 80–91, 2005 相似文献
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Hydrophobically modified water‐soluble polymers have been prepared by copolymerization of 2‐acrylamido‐2‐methylpropane sulfonic acid (AMPS) and isodecyl methacrylate (iDMA) in N,N‐dimethylformamide under nitrogen atmosphere, varying the composition feed. Fluorescence spectroscopy was used to further confirm the copolymers self‐aggregate in water. Critical concentration of the self‐aggregate formation (CAC) decreased by increasing the molar fraction of iDMA in the AMPSco copolymers and varied between 1.20 and 0.04 g/L depending on the degree of hydrophobic modification. Hence, copolymer composition and charge density allowed tuning the pseudomicellar characteristics of these new amphiphilic copolymers. The addition of a salt or a low‐molecular‐weight surfactant was studied. Binding of CTAB to the AMPSco copolymers leads to a high decrease of CAC, i.e., 0.006 g/L. Effect of the composition in the viscosimetric behavior of the hydrophobically modified copolymers AMPSco was investigated. The removal of single metal ions, Cu2+, and m‐cresol from aqueous solutions by ultrafiltration with the help of the copolymers was investigated. Equilibrium dialysis experiments demonstrate that the formation of hydrophobic microdomains can be used to control the sequestration of foulants, and thus these novel copolymers have potential application as polymeric surfactants in micellar‐enhanced ultrafiltration processes for water purification. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
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Yanhui Yuan 《The Journal of Supercritical Fluids》2010,55(1):358-362
We have recently proposed a compressible lattice model for CO2 + polymer systems in which CO2 forms complexes with one or more functional groups in the polymer. Furthermore, we have shown that this model is able to simultaneously correlate phase equilibria, sorption behavior, and glass transition temperatures in such systems. In the present work, we extend the model to ternary CO2 + cosolvent + polymer systems and demonstrate that cloud point behavior in CO2 + dimethyl ether + poly (?-caprolactone), CO2 + dimethyl ether + poly (isopropyl acrylate), and CO2 + dimethyl ether + poly (isodecyl acrylate) systems can be predicted using parameters obtained from binary data. Our results also suggest that dimethyl ether may form weak complexes with poly (?-caprolactone), poly (isopropyl acrylate), and poly (isodecyl acrylate). 相似文献
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The results of the evaluation of zinc maleate and zinc anthranilate as thermal stabilizers for poly(vinyl chloride) (PVC) are reported in this article. Calcium stearate, diphenyl isodecyl phosphite, and epoxidized soya oil were used as costabilizers. Both zinc compounds showed good stabilizing performance in static and dynamic tests, particularly at low concentrations. The best results were obtained with zinc anthranilate. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 2603–2605, 2000 相似文献
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Effects of three different plasticizers and their blends with dioctyl phthalate (DOP) on thermal stability, flammability, mechanical, electrical, and permanence properties of poly(vinyl chloride) (PVC) compound were studied. Various plasticizers used were DOP, butyl benzyl phthalate (BBP), isodecyl diphenyl phosphate (IDDP), and polybutylene adipate (PBA) at concentrations of up to 40 phr level. Studies showed that processability and softness were improved by addition of BBP. An increase in the content of IDDP increased the electrical and flammability properties, whereas compositions with PBA exhibited the best permanence properties. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3278–3284, 2003 相似文献
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Mahua Upadhyay Gobinda Karmakar Gurpreet Singh Kapur Pranab Ghosh 《Polymer Engineering and Science》2018,58(5):810-815
In an anticipation to produce biodegradable additives with multifunctional performance for a cost‐effective lubricant composition, copolymers are synthesized by incorporating rice bran oil, peanut oil, β‐pinene in the backbone of isodecyl acrylate through microwave irradiation method using AIBN (azobisisobutyronitrile) as radical initiator. The prepared polymers are characterized by spectral techniques (IR, NMR) and SEC‐GPC analysis, thermal stability was determined by thermogravimetric analysis. Performance of the polymers as antiwear (AW), pour point depressant (PPD), viscosity modifier/viscosity index improver (VII) in different mineral base oils (SN1 and SN2) were done by standard ASTM methods. Biodegradability test of the polymers was carried out by disk diffusion (DD) and soil burial test methods. The copolymers of rice bran oil showed better viscosity index values and AW property, whereas the copolymers of peanut oil found to be most effective as PPD. Copolymers with higher concentration of green units showed better performance as viscosity modifier, pour point depressant and AW performance along with excellent biodegradability. POLYM. ENG. SCI., 2017. © 2017 Society of Plastics Engineers 相似文献
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随着工业化进程的不断加快,东太湖水质日趋恶化,给常规处理增加了很大的处理难度。针对水源污染问题和给水深度处理的需要,开展了超滤-纳滤双膜组合工艺处理东太湖原水的中试研究,考察双膜工艺对出水水质的提升效果。结果表明,超滤-纳滤双膜工艺对水质常规指标具有较好的去除效果,CODMn和TOC的去除率分别为91.7%和90%;对荧光类物质的去除主要表现在对芳香族蛋白质、类富里酸物质、溶解性微生物代谢产物的去除;此外,双膜组合工艺对小分子二甲基异莰醇(2-MIB)和土臭素(GSM)的去除率分别为70%和77%,表明该工艺对水中主要致嗅物质具有良好的去除能力。 相似文献
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对异构十醇聚氧乙烯醚(IC_(10)EO_n)、十二烷基苯磺酸钠(LAS)和脂肪醇聚氧乙烯(2)醚硫酸钠(C_(12~14)E_2S)的水溶性进行分析,研究了LAS和C_(12~14)E_2S对异构十醇聚氧乙烯(8)醚(IC_(10)EO_8)浊点的影响,同时考察了IC_(10)EO_8与LAS和C_(12~14)E_2S复配体系的润湿力、泡沫性能、去污力等。结果表明,在25℃下,当IC_(10)EO_n的EO加合数为3,8和9时可与水以任意比例互溶,不会形成凝胶;在IC_(10)EO_8与LAS和C_(12~14)E_2S的复配体系中,当LAS和C_(12~14)E_2S的质量分数大于0.6%时,浊点迅速上升;IC_(10)EO_8与LAS和C_(12~14)E_2S的质量比在3∶1~1∶3范围内,复配体系的润湿性能优于单一表面活性剂,当IC_(10)EO_8与LAS和C_(12~14)E_2S的质量比为1∶1时,润湿性能最佳;IC_(10)EO_8的泡沫性能较差,随着阴离子表面活性剂的含量增加,复配体系起泡力逐渐增强,泡沫稳定性呈不规则变化;加入一定量的阴离子表面活性剂可提高IC_(10)EO_8的去污力。 相似文献
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Rohini Agarwal Sahil Chandrakant Kalambe Pampi Chakraborty Subhendu Ray Chowdhury Harish Jagat Pant 《应用聚合物科学杂志》2024,141(5):e54871
Ethylene propylene diene elastomer (EPDM) harbors diverse microbiota that form biofilms. Such biofilms may contaminate water and can increase drag force impacting the hydrodynamic performance of a ship, once it is used as fenders. Here, the EPDM surface is modified by radiation-assisted grafting to prevent biofilm formation. Three different monomers, namely, methacrylic acid (MAA), isodecyl methacrylate (IDM), and lauryl methacrylate (LMA), are grafted on EPDM. The modified surfaces are characterized by Fourier transform infrared (FTIR) spectroscopy, surface wettability, mechanical and dynamic mechanical properties (DMA), and scanning electron microscopy (SEM). The modified surfaces are subjected to biofouling by prominent biofilm adherents, that is, Pseudomonas aeruginosa and Klebsiella pneumoniae. The standard plate count and resazurin fluorescence assays are performed to observe the microbial load on these surfaces. The MAA-grafted EPDM, which is hydrophilic in nature, shows a considerable decrease in bacterial adhesion compared to pure EPDM, but for IDM and LMA-grafted EPDM, it is the opposite. The deterioration of the surface with bacteria by environmental scanning electron microscopy (ESEM) supports the findings. The tensile property of the modified EPDM is observed to be within satisfactory limits. After such modification, the EPDM is expected to expand its application. 相似文献