中国东北新生代富锦岩体岩石成因及其构造意义

富锦岩体位于佳木斯地块东缘,紧邻环太平洋增生型完达山造山带,是中国东部最年轻的花岗岩体之一。野外出露点在黑龙江省富锦市东11 km、乌尔虎力山西北坡,GPS位置47°14'9.8"N 132°14'5.8"E。岩体由中粒花岗闪长岩组成,围岩是二叠纪砂岩地层,地层南北走向、近直立,砂岩发生接触热变质。花岗闪长岩具半自形粒状结构,含~50%斜长石、~25%石英、~15%黑云母及~10%碱性长石。锆石长轴~250 um,长宽比~3:1,阴极发光下见明显的振荡环带,为典型花岗岩锆石。15粒锆石SHRIMP U-Pb分析结果得出谐和年龄为(54±1)Ma。围岩砂岩的碎屑锆石颗粒直径50~100 um,SHRIMP锆石U-Pb年龄峰值260、500 Ma,少量属前寒武纪。花岗闪长岩Si O2(质量分数)为68.8%~70.3%,Na2O为3.8%~4.2%,K2O为1.9%~2.3%,富集轻稀土元素及大离子亲石元素,亏损高场强元素,强烈分异的稀土配分模式[(La/Yb)N22]、高Sr/Y比(Sr/Y60)、高Ba((699~764)×10-6)和Sr((707~735)×10-6)质量分数等特征表明其为埃达克质高钡锶花岗岩。其初始87Sr/86Sr比值为0.706 099~0.707 265,εNd(t)值为-0.15~-2.07,(208Pb/204Pb)t=38.244~38.279,(207Pb/204Pb)t=15.562~15.576,(206Pb/204Pb)t=18.353~18.376,锆石εHf(t)值为+3~+7,Sr-Nd-Pb-Hf同位素特征与佳木斯地块东缘及完达山造山带西缘的二叠纪岛弧岩浆岩[1]十分接近,反映了EM2同位素特征,而与中国东北新生代以双辽[2]、伊通—大屯[3]玄武岩为代表的DMM软流圈亏损地幔来源物质和以五大连池[4]、牡丹江黄花—海浪玄武岩[5]、永胜正长岩体[6]为代表的高钾质EM1岩石圈富集地幔来源物质有显著差异,亦未见岩浆混合的证据。因此,富锦花岗闪长岩更可能是来自由二叠纪岛弧岩石组成的玄武质下地壳的部分熔融,而不是来自新生代幔源岩浆的结晶分异或岩浆混合。结合研究区周缘广泛发育古近纪断陷盆地的区域地质背景,认为富锦岩体的形成与古近纪太平洋板块俯冲脱水、玄武质岩浆底侵以及陆壳伸展有关。本研究提供了一个新的埃达克质岩石形成于板内伸展环境下的案例[7]。     

北山独龙包地区晚石炭世陆缘弧岩浆作用——花岗闪长岩锆石U Pb年龄及地球化学证据

本文报道了北山地区独龙包南花岗闪长岩的LA-ICP-MS锆石U-Pb年龄与全岩地球化学,以确定其形成时代、岩石成因及构造环境。花岗闪长岩中的锆石呈短柱状或近等轴粒状,具典型的振荡环带,Th/U值介于0.42~0.75之间,指示岩浆成因。对岩浆锆石的定年结果显示,独龙包南花岗闪长岩形成于303.4±2.1 Ma。该期花岗闪长岩的Si O2含量为63.73%~69.12%,Na_2O=3.69%~4.03%,K_2O=2.23%~2.73%,全碱(Na_2O+K_2O)为6.08%~6.44%,Al2O3含量较高(14.83%~15.89%),K2O/Na2O为0.58~0.74,A/NCK=0.91~0.99;该区花岗闪长岩富集轻稀土(LREEs)和大离子亲石元素(LILE)Rb、Th、U、Pb,亏损重稀土元素(HREEs)和高场强元素(HFSE)Nb、Ta、P、Ti,且轻重稀土元素分馏较强,(La/Yb)N变化于4.77~6.35,具有弱的负铕异常,δEu为0.79~0.94。上述特征表明,该期花岗闪长岩属于准铝质钙碱性I型花岗岩,岩浆源区为下地壳,受到地幔物质的混染,形成构造背景为陆缘弧。结合邻区特征,得出红石山—百合山—蓬勃山蛇绿岩带代表的洋盆于晚石炭世可能发生了南北双向俯冲。     

皖南泾县茂林岩体锆石U-Pb年龄和Hf同位素特征

安徽茂林岩体为中国东部中生代皖南构造-岩浆带中的一个浅层侵入岩体,是檀树岭钼矿和湛岭钼矿的成矿母岩。该岩体的主要岩性为花岗闪长岩、花岗斑岩、斑状花岗闪长岩、二长花岗岩等。对茂林花岗闪长岩体进行LA-ICP-MS锆石UPb测年,结果显示锆石Th/U值为0.38~0.66,为典型的岩浆成因锆石。花岗闪长岩~(206)Pb/~(238)U年龄加权平均值为140.8±0.8Ma(n=19,MSWD=2.3),结合锆石自形、岩浆环带发育等特点,该年龄为茂林花岗闪长岩的成岩年龄,显示岩体形成于早白垩世。锆石Hf同位素分析结果显示,茂林花岗闪长岩锆石振荡岩浆环带具负εHf(t)值(-9.7~-6.2),揭示花岗闪长岩主要形成于下地壳的熔融。     

辽宁兴城新立屯地区岩浆杂岩岩石学特征、侵位顺序及地质意义

辽宁兴城新立屯地区岩浆杂岩主要由4种不同的岩石单元组成,分别为似斑状黑云母二长花岗岩,中细粒石英闪长岩,花岗细晶岩和花岗伟晶岩,前两者分布广泛且为研究区的主要岩石单元,后两者则呈脉状侵入到前两者中。应用LA-ICP-MS锆石U-Pb定年方法,测得似斑状黑云母二长花岗岩,中细粒石英闪长岩及花岗细晶岩的年龄分别为2 496±18 Ma,2 490±19 Ma,2 479±29 Ma,形成于古元古代早期。结合野外地质特征,侵位顺序由早到晚依次为:似斑状黑云母二长花岗岩,中细粒石英闪长岩,花岗细晶岩,花岗伟晶岩。岩石地球化学特征显示,新立屯地区岩浆杂岩主量元素方面具高硅(SiO2=61.38%~74.99%),富碱(Na2O+K2O=6.86%~9.41%),富Mg#(56~70)特征;A/CNK=0.91~1.18,属准铝质-过铝质岩石;微量元素方面,相对富集轻稀土元素,亏损重稀土元素,具有Eu异常(δEu=0.50~0.96);富集大离子亲石元素,亏损高场强元素;锆石Lu-Hf同位素特征εHf(t)值为-1.12~+6.13;TDM2(Hf)介于2 594~2 937 Ma,显示该套岩浆杂岩可能为地幔物质加入新生地壳再造的产物。     

滇西梁河勐养花岗闪长岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其构造意义

勐养花岗闪长岩体位于滇西腾冲地块梁河县南勐养镇一带。用LA-ICP-MS技术测得花岗闪长岩锆石U-Pb年龄为115.2±1.0Ma,该年龄被解释为花岗闪长岩的形成年龄,表明该区花岗闪长岩体的形成时代为早白垩世。岩石地球化学特征表明,花岗闪长岩中SiO_2含量为62.39%~67.97%,Na_2O+K_2O为6.26%~7.80%,K_2O为1.98%~4.11%,具有贫钾(K_2O/Na_2O值为0.45~1.11)、低P2O5(0.09%~0.38%)的特征;MgO为1.78%~1.98%,Mg~#为34.90~48.40,属于准铝质-弱过铝质钙碱性系列。微量元素具有相对富集大离子亲石元素(U、Th、Rb、Ba)、亏损高场强元素(Tb、Nb、Zr、Hf)的特点。该花岗闪长岩具有I型花岗岩的特征,同时兼有S型花岗岩之特点,具有明显的岩浆混合作用特征。岩石具有岛弧或活动陆缘岩系的微量元素分布特征。地球化学特征和微量元素构造判别图解揭示,勐养早白垩世花岗闪长岩形成于碰撞后岩浆弧环境。花岗闪长岩为幔源岩浆与高黎贡山群古老地壳部分熔融的岩浆混合的产物。该区早白垩世花岗闪长岩是腾冲地块早白垩世侵入岩与班公湖-怒江-泸水-瑞丽洋盆的闭合、洋壳向南西俯冲及板块间的碰撞造山作用的产物。     

柴北缘大柴旦滩间山花岗斑岩体锆石U-Pb年代学、地球化学及Hf同位素

为了研究柴北缘大柴旦地区在华力西期构造演化特征,对大柴旦地区滩间山花岗斑岩进行了锆石U-Pb年代学、岩石地球化学以及Hf同位素的研究.花岗斑岩中锆石LA-ICP-MS U-Pb定年结果表明,该岩体形成于晚泥盆世(356.0±2.8 Ma,MSWD=0.53).地球化学分析显示花岗斑岩属于中钾钙碱性-钙碱性系列,A/CNK值为0.97~1.10,属弱过铝质,为I型花岗岩,富集大离子亲石元素(如K、Ba、Rb)和轻稀土元素(LREE)以及Th、U,相对亏损高场强元素(如Ta、Nb、Ti、P).岩石的ε_Hf(t)值和二阶段模式年龄(T_DM2)分别介于±5.43~±8.38和1 017~1 284 Ma之间.上述特征表明,滩间山花岗斑岩的原始岩浆源于中元古代新增生陆壳的部分熔融.综合区域地质演化背景,认为滩间山花岗斑岩形成于柴达木地块与南祁连地块碰撞后伸展构造环境.      

黑龙江跃进山矽卡岩型铜金矿床花岗闪长岩的年代学和地球化学特征

对跃进山铜金矿床与矽卡岩型矿化有关的花岗闪长岩开展了LA-ICP-MS锆石U-Pb定年、锆石Lu-Hf同位素及岩石地球化学研究。结果表明,花岗闪长岩中26个锆石测点的~(206)Pb/~(238)U加权平均年龄为(118.96±0.77) Ma (MSWD=0.29);岩体中锆石的ε_(Hf)(t)值均为正值(+1.4～+3.2),且具有较年轻的Hf二阶段模式年龄(t_(DM2)=1.09～0.98 Ga);花岗闪长岩表现为富Al、高K和Na以及低Ti、P、Ca的钙碱性I型花岗岩地球化学特征,显示出轻稀土富集、重稀土元素亏损的稀土元素组成特征;样品锆石的ε_(Hf)(t)的值为偏低的正值,表明岩浆物质来源应为壳幔混源。结合岩石地球化学投图以及区域构造背景演化认为,花岗闪长岩和花岗斑岩均属于后碰撞-火山弧花岗岩,研究区的成矿成岩作用与太平洋板块强烈俯冲背景下的下岩石圈地幔拆沉有直接关系。     

粤北扶溪岩体成因及时代:来自矿物化学、岩石地球化学及LA-ICP-MS锆石U-Pb年龄证据

分析了粤北扶溪地区花岗闪长岩角闪石、黑云母矿物化学组成,全岩岩石地球化学及LA-ICP-MS锆石U-Pb年龄。结果显示,花岗闪长岩中角闪石属镁角闪石,黑云母属镁质黑云母。岩石硅含量较高,w(SiO_2)为63.86%~66.19%;富碱,w(K_2O)为4.07%~4.71%,w(Na_2O)在2.42%~2.76%;铝质量分数中等,w(Al_2O_3)为14.27%~15.02%。稀土元素总量w(ΣREE)为183.22×10~(-6)~283.31×10~(-6),稀土元素配分模式右倾,中等强度负Eu异常(0.62~0.80),富集Rb、K、Th、Sr、Pb、Nd等大离子亲石元素,亏损Th、U、Zr、Hf、Nb、Ta、Ti等高场强元素。LA-ICP-MS锆石U-Pb年龄为(440.7±3.3)Ma(MSWD=2.4,n=18)。上述分析结果表明花岗闪长岩为I型花岗岩,是早志留世岩浆活动产物,岩浆主要来源于地壳物质的部分熔融,在温度777~802℃、压力316~442 MPa和氧逸度约lgf(O_2)=-14条件下侵位结晶。     

黑龙江东部海音山花岗闪长岩年龄、岩石成因及构造背景

对黑龙江东部海音山林场地区花岗闪长岩开展锆石U-Pb年代学和岩石地球化学研究,以确定其形成时代,源区性质和构造背景。花岗闪长岩锆石年代学研究表明其形成于早白垩世(128±1 Ma和126±1 Ma)。岩石地球化学研究显示,花岗闪长岩富SiO_2(67.31%~70.19%)、Al_2O_3(13.72%~15.52%)、K_2O(3.01%~4.06%)、Na_2O(2.92%~3.81%),贫CaO(2.03%~3.04%)、FeO和MgO,属于高钾钙碱性岩系列。富集大离子亲石元素(如Rb、Ba、K)、轻稀土元素(LREE),相对亏损高场强元素(如Nb、Ta、Ti、P)。岩浆源区为镁铁质下地壳的部分熔融所形成。结合区域同时代岩浆岩的研究成果,认为海音山花岗闪长岩形成于古太平洋板块向欧亚大陆俯冲下的火山弧环境。     

内蒙古大苏计斑岩钼矿床花岗质杂岩年代学、地球化学、Hf同位素组成及其地质意义

内蒙古卓资县大苏计斑岩钼矿化与区内花岗质杂岩(石英斑岩、正长花岗斑岩和花岗斑岩)有密切的成因联系。LA-ICP-MS锆石U-Pb定年获得石英斑岩、正长花岗斑岩和花岗斑岩的结晶年龄分别为(234±3)Ma、(225±4)Ma和(220±4)Ma。杂岩体富硅(w(SiO_2)=70.37%~78.84%)、富碱(w(Na_2O+K_2O)=4.52%~8.77%),均属高钾钙碱性系列,普遍具有低的w(Na_2O)(0.15%~2.69%)和高的铝指数(ASI介于1.13~3.35)。稀土元素总量介于48.2×10~(-6)~527.0×10~(-6),石英斑岩稀土元素含量(48.2×10~(-6)~83.1×10~(-6))最低,正长花岗斑岩稀土元素含量(272.1×10~(-6)~527.0×10~(-6))最高,花岗斑岩稀土元素含量为162.5×10~(-6)~236.8×10~(-6);杂岩体δEu介于0.15~0.93之间,(La/Yb)N介于3.0~65.5,自正长花岗斑岩、花岗斑岩到石英斑岩,其Eu负异常逐渐増大,而(La/Yb)N逐渐减小。岩体普遍富集Rb、Th、U、K、Nd、Zr、Hf等,强烈亏损Sr、P、Ti等。正长花岗斑岩具有中等Ba、Ta、Nb亏损。石英斑岩和花岗斑岩均属于高分异花岗岩,而正长花岗斑岩属于I型花岗岩。主量、稀土和微量元素特征表明,杂岩体具有后碰撞或后造山花岗岩特征,形成于后碰撞或后造山环境。杂岩体锆石的Hf同位素显示,3种岩石的εHf(t)值介于-21.1~-8.1,二阶段模式年龄tDM2介于1775~2587 Ma。石英斑岩来自于古元古代地壳物质的部分熔融;正长花岗斑岩来自于古元古代晚期地壳物质的部分熔融;花岗斑岩也主要来自于古元古代地壳物质的部分熔融,但有少量新太古代地壳物质参与。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Metals,arsenic, and sulfur in the Aue and Eibenstock granites,Erzgebirge

Average concentrations of Pb, Zn, Cu, and other metals, as well as S and As, were calculated for the Aue granitic cupola, the contact aureole of which hosts the large vein-type uranium deposit of Schlema-Alberoda and the Schneeberg uranium-base metal deposit (Erzgebirge, Germany). The cupola was exposed by mine workings and boreholes, which provided an opportunity to evaluate variations in the abundances of metals in the granites over a vertical interval of more than 2.5 km and estimate their losses in the upper oxidized part of the investigated volume of the cupola (coefficient of iron oxidation, KO _Fe, increases in the granites from bottom to top from 7 to 70%) compared with the lower unaltered and unoxidized part (with a KO _Fe plateau at about 5%). The average concentrations of metals in the upper part of the cupola are lower than those in the lower part by a factor of 2.5 for Pb, 1.56 for Zn, 1.45 for Cu, 1.3 for Co, etc. A similar decrease in the abundances of ore elements along the vertical section associating with the relative epigenetic alteration and oxidation of the granite was previously described by us for U and Th and for the components of high-temperature ores, W, Sn, and Mo. The removal of ore elements from the granite was accompanied by a decrease in the bulk contents of sulfur and arsenic by a factor of 1.35 and 1.65, respectively. The leaching of trace metals from the granites of the upper part of the Aue cupola was followed by their partial redeposition above the cupola in the ore veins of the Schlema and Schneeberg deposits. Original Russian Text ? Vikt. L. Barsukov, N.T. Sokolova, O.M. Ivanitskii, 2006, published in Geokhimiya, 2006, No. 9, pp. 967–982.     

Text, talk, things, and the subpolitics of performing place

This article tells the story of how a group of Dutch and Belgian citizens organized themselves to promote an area that they valued, to put it on the map, to raise awareness about its qualities, and to protect it from urban and industrial development. Our theoretical perspective focuses on the performative and political aspects of this place-making process and the discursive and material practices involved. We connect this to Beck’s concept of subpolitics.Our findings show how the group performed this place not only through text and talk - giving the area a name, using their knowledge and expertise to raise awareness about its values, lobbying and cooperating with decision-makers -, but also through things - installing art objects and information signs that articulate certain characteristics and values of the area. Our findings demonstrate the struggles involved in these performances. The group involved multiple perspectives on what the important values and characteristics of the area are and on what strategies would work best in trying to influence decision-making and protect the area. However, the use of expertise as the main strategy to gain influence excluded the more critical and activist strategies and privileging archaeological and historical values and characteristics came at the expense of attention on agricultural and natural values.Our findings make clear that performing place cannot be taken to be homogeneous and that it inevitably involves multiple perspectives and demands. The struggles, power relations and dynamics of inclusion and exclusion that this multiplicity implicates reveal a form of sub-politics that involves both politicization and depoliticization. Also, it is a form of subpolitics that is more diverse and ambiguous than Beck’s conceptualization presupposes by its emphasis on the role of outsiders as a homogeneous group.     

Total mercury and monomethylmercury in water, sediments, and hydrophytes from the rivers, estuary, and bay along the Bohai Sea coast, northeastern China

Mercury contamination in aquatic environments is of worldwide concern because of its high biomagnification factor in food chains and long-range transport. The rivers, estuary and the bay along the northwestern Bohai Sea coast, northeastern China have been heavily contaminated by Hg due to long-term Zn smelting and chlor-alkali production. This work investigated the distributions of total Hg (THg) and monomethylmercury (MMHg) in the water, sediment and hydrophytes from this area. Concentrations of THg in sediment (0.5–64 mg kg⁻¹) and water (39–2700 ng L⁻¹) were elevated by 1–3 orders of magnitude compared to background concentrations, which induced high concentrations of MMHg in these media. The highest concentration of MMHg in sediment reached 35 μg kg⁻¹, which was comparable to that in the Hg mining area, Wanshan, China, and the highest MMHg concentration of 3.0 ng L⁻¹ in the water sample exceeded the MMHg Chinese drinking water guideline of 1.0 ng L⁻¹. Concentrations of THg in a sediment profile from Jinzhou Bay were found to be consistent with annual Hg emission flux from a local Zn smelter (r = 0.74, p < 0.01), indicating that Hg contamination was mainly caused by Zn smelting locally. For some freshwater hydrophytes, concentrations of THg and MMHg ranged from 5.2 to 100 μg kg⁻¹ and 0.15 to 12 μg kg⁻¹, respectively. Compared to sediment, concentrations of THg in hydrophytes were 2–3 orders of magnitude lower but MMHg was comparable or higher, indicating that the bioaccumulation in plants was distinct for the two Hg species studied. The data suggest that a significant load of Hg has been released into the northwestern coastal region of the Bohai Sea.     

Distribution of REE,LILE, and HFSE between biotite,feldspar, and the melt in the granulite facies migmatite,nimnyr block,Aldan shield

The behavior of trace elements under conditions of partial melting of granitoid rocks has been studied. The element’s partition coefficients between minerals and the melt D_i^min/melt depends, in the first place, on the composition of the primary melt. In biotite the HREE D_i are a little below 1, while those of LREE, especially D_i for Ce, are 1–3 orders of magnitude less. This leads to an efficient differentiation of REEs in anatexic melts especially when biotite is the main mineral phase of restite. On the contrary, there are feldspars, the D_i of which cannot provide such a magnitude of differentiation. Unlike garnets and pyroxenes, whose stability in restite permits enrichment of anatexic melts produced in migmatization zones with Nb, Ti, and Cr, the presence of biotite in restite causes depletion of melts with those elements as well as with Rb. Feldspars, under conditions of their fractional crystallization or during differentiation of an anatexic melt, deplete the latter with Sr, Ba, and Rb, but enrich it with Nb, Ti, Cr, Y, Zr, and V.     

Dielectric constants of apatite,epidote, vesuvianite,and zoisite,and the oxide additivity rule

The dielectric constants and dielectric loss values of 4 Ca-containing minerals were determined at 1 MHz using a two-terminal method and empirically determined edge corrections. The results are: vesuvianitel κ′ _a=9.93 tan δ=0.006 κ′ _c=9.79 tan δ=0.005 vesuvianitel κ′ _a=10.02 tan δ=0.002 κ′ _c=9.85 tan δ=0.003 zoisite1 κ′ _a =10.49 tan δ=0.0006 κ′ _b =15.31 tan δ=0.0008 κ′ _c=9.51 tan δ=0.0008 zoisite2 κ′ _a =10.55 tan δ=0.0011 κ′ _b =15.45 tan δ=0.0013 κ′ _c=9.39 tan δ=0.0008 epidote κ′ ₁₁= 9.52 tan δ=0.0008 κ′ ₂₂=17.1 tan δ=0.0009 κ′ ₃₃= 9.37 tan δ=0.0006 fluorapatite1 κ′ _a =10.48 tan δ=0.0008 κ′ _c = 8.72 tan δ=0.0114 fluorapatite2 κ′ _a =10.40 tan δ=0.0010 κ′ _c=8.26 tan δ=0.0178 The deviation (δ) between measured dielectric polarizabilities as determined from the Clausius-Mosotti equation and those calculated from the sum of oxide polarizabilities according to α _D (mineral)=∑ α _D (oxides) for vesuvianite is ～ 0.5%. The large deviations of epidote and zoisite from the additivity rule with Δ=+ 10.1 and + 11.7%, respectively, are attributed to “rattling” Ca ions. The combined effects of both a large F thermal parameter and possible F-ion conductivity in fluorapatite are believed to be responsible for Δ=+2–3%. Although variation of oxygen polarizability with oxygen molar volume (V_o) is believed to affect the total polarizabilities, the variation of V_o in these Ca minerals is too small to observe the effect.     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.