Characteristics of Coal Ashes in Yanzhou Mining District and Distribution of Trace Elements in Them

In the process of combustion of coal organic and inorganic materials in it will undergo a complex variation.Part of thew will become volatiles and,together with coal smoke,enter into atmosphere,some will remain in micro-particulates such as ash and dust and find their way into atmosphere in the form of solid particles,and the rest will be retained in ash and slag.Coal ashes are the residues of organic and inorganic substances in coal left after coal combustion and the compostition of coal ashes in dependent on that of minerals and organic matter in coal.This paper deals with the chemical composition of coal ashes,the distribution of trace elements in them and their petrological characteristics,and also studies the relationship between the yield of coal ashes and the distribution of trace elements.In addition,a preliminary study in also undertaken on the factors that affect the chemical composition of coal ashes.As viewed from the analyses of coal ash samples collected from the Yanzhou mining district,it can be seen clearly that coal ashes from the region studied are composed chiefly of crystalline materials,glassy materials and uncombusted organic matter and the major chemical compositions are SiO2,Al2O3,Fe2O3,and CaO,as well as minor amounts of SO3,PWO5,Na2O,K2O and TiO2.During the combustion of coal,its trace elements will be redistributed and most of them are enriched in coal ashes.At the same time,the concentrations of the trace elements in flying ash are much higher than those of bottom ash,i.e.,with decreasing particle-size of coal ashes their concentrations will become higher and higher.So the contents of trace elements are negatively proportional to the particle-size of coal ashes.There has been found a positive correlation between the trace elements Th.V.Zn,Cu and Pb and the yield of coal ashes while a negative correlation between Cl and the yield of coal ashes.     

Sulfur in Coal and Its Environmental Impact from Yanzhou Mining District,China

Sulfur is one of the havardous elements in coal The concentrations of sulfur are relatively high in coal.The major forms of sulfur in coal are pyritic,organic and sulfate.Pyritic and organic sulfur generally account for the bulk of sulfur in coal.Elemental sulfur also occurs in coal,but only in trace to minor amounts.When coals are burned,leached and washed,sulfur will be released in the form of sulfide and H2S,which then reach with O2,water and other substances to change into vitriol,and in some places it may form acid rain.And they will impact water environment,acidify the soil and do great harm to plants and human health.In this paper,on the basis of the data from the Yanzhou mining district,the distribution and concentrations of sulfur are analyzed and the existing forms of sulfur are studied.The variation of sulfur and its impact on the environments also are described when coal is used.     

Sulfur Isotopic Characteristics of Coal in China and Sulfur Isotopic Fractionation during Coal—burning Process

The determined results of the sulfur contents and isotopic composition of coal samples from major coal mines in 15 provinces and regions of China show that the coal mined in the north of China is characterized by higher ^34S and lower sulfur content, but that in the south of China has lower ^34S and higher sulfur content.During the coal-burning process in both indrstrial and daily use of coal as fuel the released sulfur dioxide is always enriched in lighter sulfur isotope relative to the corresponding coal;the particles are always enriched in heavier sulfur isotope.The discussion on the environmental geochemical significance of the above-mentioned results also has been made.     

The Distribution of Trace Elements in Granitoids in the Nanling Region of China

Granitoids are widely spread in the Nanling Region of China.Four rockbodies in the region the been studied for their REE,Rb,Sr,Ba and Sc distributions.The four rockbodies occurred in different locations and are characterized as being different in age and type.The rock types are presented as follows:Qinghu monzonite,Guangxi;Fuxi granodiorite,Guangdong;Jiufeng monzonitic granite,Hunan;Zudong K-feldspar granite,Jiangxi.From the major and trace element distributions in these granitoids it is clearly shown that Rb/Sr ratios in the rocks tend to increase with increasing SiO2 content and differentiation index(DI),but LREE/HREE,La/Yb and K/Rb ratios tend to decrease,suggesting a correlation between trace element distribution and major element composition for the granitoids.The distribution characteristics of trace elements in each of the rockbodies are described in detail.From the comparative analysis of the Qinghu monzonite and Fuxi granodiorite it is evidenced that the REE distribution is closely related to the sequence of crystallization for the minerals,and also to the petrochemical types of these granitoids in addition to their crystal chemistry.     

Distribution Characteristics of Gold and Other Trace Elements in the Proterozoic Lengjiaxi Group,Northeastern Hunan Province

Systematic geochemical studies of the Proterozoic Lengjiaxi Group in northeastern Hunan Province suggest that the Lengjiaxi Group is a Au-As-Sb-W association-type Au-bearing turbidite formation.The contents of Au,As,Sb,W,Cr,Mn,Pb and Zn in the turbidite formation are more than two times as high as the average contents of trace elements in the upper continental crust.The low abundance of Ag and the close correlation between Au and As are two important characteristic features.In the Au-bearing turbidite formation the enrichment of gold is due to the extensive occurrence of Au-bearing pyrites.Higher contents of Au,W,Sb and Ag in the greywacke indicate that they also exist in the form of heavy minerals.Au,Ag,As,Sb,W and REE in the Au-bearing turbidite formation have a close genetic relation with the chemistry of the gold deposits.     

Contents and Distribution of Carbon,Sulfur and Phosphorus in the Lithospheric Layers of China‘s Continent

Based on the most recently avalilable petrochemical data from China‘s Continent and the thickness of the crust,the authors have calculated the contents of carbon,sulfur and phosphorus in the lithosphere of China‘s Continent (including the Sedimentary-metamorphic structural layer,the granite layer and the basalt layer)and their distribution in the major types of rocks.In addition,a discussion is made on the significance of the results in the study of global circulation of carbon,sulfur and phosphorus.     

Distribution and Collection of China’s Dinosaurs

<正>It is estimated that the world has discovered more than1000 species and 800 genera of dinosaurs.Chinese scientists have named more than 170 species of dinosaurs,with 17 genera and 44 species of dinosaur egg fossils,35genera and 39 species of dinosaur footprints,since their first discovery in China in 1902.China has dinosaur occurrences from the Upper Triassic to the Upper     

Geochemistry of Sulfur and Hazardous Elements in Late Paleozoic Coals and Partings from Taozao Coalfield, Shandong Province, China

Intermsoftheharmfulmattersincoalandcoalminingwastes,thefirstisabouthazardouselements ,theotherin cludessulfurandhazardousorganicmatter.Muchresearchontracetoxicelementsandtheirimpactsonenvironmenthasbeeninvestigatedinmanycountries (Goodarzi,1995 ;Finkelman ,1994 ;Chouetal.,1982 ) .Althoughthere searchconcerningthisaspectwasstartedmuchlaterinChi na ,manystudieshavebeenstrengthenedsince 1980 ,andmuchprogresshasbeenmade ,alargenumberofdatahavebeencollected ,andthecomparisonshavebeenmadeforthedata…     

Basic Characteristics of the Earth''s Temperature Distribution in Southern China

Sourthern China referred to in this paper embraces all the provinces to the south of latitude 32° N within the territory of China, exclusive of Tibet and Taiwan.The paper is based on the data obtained from temperature measurements of 680 boreholes drilled for petroleum, coal and hydrogeology. The depth of these boreholes ranges between 1,000 and 2,000m in most cases, being generally not less than 400m and reaching 7,000m in maximum.Through the elaboration and analysis of the temperature data, isotherm maps showing the temperatures at depths of 1,000m, 2,000m and 3,000m respectively and a geothermal gradient map of southern China have been compiled. These maps indicate that the earth's temperature distribution in southern China is characterized by a elatively low value in areas of its central part and those to the west of the Anning River valley of the western part(30℃, 40℃ and 70℃ at depths of 1,000m, 2,000m and 3,000m respectively), and a comparatively high value in the southeastern coastal areas and western Yunnan(60℃, 80℃ and over 120℃ respectively), and that the geothermal gradient also increases from less than 1.5℃/100 m in the central part towards both the east and the west to 2.0-3.0℃/100m or even over 4.0℃/100m.The earth's temperature distribution is strictly controlled by the deep structure of the earth's crust and is very closely related to the character of the regional geological structure, The stable central areas remarkably differ in the earth's temperature distribution from the tectonicalty active areas such as the southeastern coastal areas and the Jinggu-Tengchong area in western Yunnan, the former being lower than the latter. Meanwhile, due to the well-developed karst features in southern China, the strong groundwater flow may exert certain cooling effect on the temperature down to a depth of about 1,500m.According to the regularity of the earth's temperature distribution, regional deep structure of the earth's crust, regional geological structure and hydrogeological conditions, the following four models are proposed to explain the mechanism of formation and distribution of the earth's temperature fields in southern China: 1) onduction type; 2) convection type; 3) deep heat-source conduction-convection type; and 4) precipitation infiltration cooling type.     

The General Characteristics and Distribution of the Glaucophane-Schist Belts of China

On the basis of the temperature variation, the glaucophane-schist facies Gan be classified into two faciesgroups, the glaucophane-lawsonite facies group and the glaucophane-greenschist facies group, and forms vari-ous facies series with other metamorphic facies. Glaucophane-schist belts of China are of different types withregard to their average T-P gradients and tectonic environments. They are: (1) Proterozoic intracratonicglaucophane-schist belts, (2) Caledonian intracratonic glaucophane-schist belts, (3) Palaeozoic pericratonicglaucophane-schist belts along the northern margin of the Chinese Platform, and (4) Meso-Cenozoicglaucophane-schist belts related to subduction. The initiation and evolution of glaucophane-schist metamorphism are related to their tectonic environ-ments. Most glaucophane-schist belts of China were formed in sialic environments. First the crust began tobreak up and eventually oceanic crust was formed. It seems that a non-uniformitarian mechanism may be in-volved as this evolution is related to the change of the configuration of the heat flow within the crust.     

Breakthrough in the China’s Separation Technology for Extraction of Rare Earth Elements

Separation technology of rare earth elements （REEs）, as the critical step in the separation process, had long been fraught with technical difficulty. A research project conducted by Baotou Shibo Rare Earth Extraction ＆ Equipment Co. Ltd., Baotou REE Research Institute, and Baotou Steel ＆ REE Group Hi-Tech Co. Ltd （Inner Mongolia）, has successfully solved the problem using a centrifugal extractor and advanced techniques to achieve a key breakthrough.     

Types, Metallogenic Environments and Characteristics of Temporal and Spatial Distribution of Copper Deposits in China

Based upon a comprehensive study of 123 copper deposits in China. this paper reaches the following conclusions: 1. The crust in China was solidified pretty late; with the accretion of the plate, the copper mineralization moved towards its margin in space and became successively younger in age. 2. The major copper ore types ever found in the world have mostly been discovered in China, in which the porphyry type seems to be the most important and the massive sulfide type in the transitional bed between marine clastic and carbonate rocks is clearly defined. 3. Carbonate strata are widespread in China and their deposition lasted for a long geological period, so the proportion of copper deposits occurring in them is large as compared with other parts of the world. 4. Seven metallogenic epochs can be recognized, in which the Mesozoic one plays the leading role and the middle(late) Palaeozoic and Cenozoic ones are next in importance. Mineralization was comparatively simple in the early geological period. and became diversified later on. In the early epochs copper deposits related to basaltic magmatism and metamorphosed marine sediments predominated, whereas in the later epochs those related to granitic magmatism and continental sedimentation were dominant. 5. There exist in China thirteen metallogenic provinces, of which the Lower Yangtze downwarping belt, Sanjiang fold system, Jiangnan axis and Xikang-Yunnan axis are of greater significance. 6. The crustal mobility in China was rather pronounced, the polycyclic evolution of the crust has resulted in such obvious phenomena as the inheritance of mineralization, the coexistence of various types and the superposition of different genetic types.     

Metamorphic Rock Characteristics of the Main Elements and Discrimination of Tectonic Setting from Au Mining District in Wengake Ximeng, Yunnan

Please?refer?to?the?attachment(s)?for?more?details.     

Mercury in coal from the People＇s Republic of China

The Peoples＇ Republic of China produces and consumes the largest quantity of coal in the world; about 2.19 billion tons of coal were produced in 2005. It is estimated that coal consumption will reach 7 billion tons by 2020. Although the nationwide percentage of electrical production from coal is falling due to increased coal-fired power generation efficiency and alternative sources, China will bum more coal than any other country for the foreseeable future. China also is estimated to be the largest producer of Hg emissions （Dastoor and Larocque, 2004, Atmos. Envirn. 38：147-161）. A recent comprehensive study of anthropogenic Hg emissions in China （Streets et al., 2005, Atmos. Envirn. 39：7789-7806） produced a figure of 536 tons of Hg for the year 1999 with coal combustion （all types） accounting for 38% of the total. Atmospheric Hg emission is an international problem as the upper atmosphere provides effective global transport of mercury. Although the estimates vary, China produces about three times more Hg/t of coal burnt than the USA because of the lack of modem technology for pollution control and limited use of cleaned coal. Knowledge of the mercury content, mode of occurrence, and regional distribution in Chinese coal is vital in order to assess the global atmospheric contribution from Chinese coal combustion.     

Types and Distribution of Geological Hazards in the South China Sea

Various types of geological hazards exist in the South China Sea. In dynamics sense, they can be categorized into 5 principal genetic types related to effects of hydraulic dynamics, gaseous activity, soil mechanics, gravity and tectonism, respectively. Integrated analyses indicate that the geological hazards associated with volcanoes, earthquakes and fractures are mainly distributed in tectonically active regions, whereas those resulting from mudflows, landslides and diapirs are usually concentrated in the region of slope, that shallow gas, high pressure gas pockets and soft intercalations are major potential geological hazards in the inner shelf, and that strong hydraulic dynamics, especially storm tide, is one of the major causes of geological hazards in the littoral areas. The geological hazards that occurred in the South China Sea are also characterized by periodicity, succession and, to a certain extent, unpredictability in addition to regionalization.     

Compositional Characteristics and Sulfur Isotope of Pyrites in the Zhibo Iron Deposit, Western Tianshan Mountain, NW China

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Distribution Characteristics of Alkylcyclohexanes in Lower Paleozoic Strata on the Northern Margin of the Tarim Basin,China

Organic matter from the Lower Paleozoic strata on the northern margin of the Tarim Basin of China contains abundant alkylcyclohexanes.The n-alkylcyclohexanes show the even(C16-C20) and odd (C17-C21) carbon number predominance and smooth distribution,and the methyl-n-alkylcycolhexanes the odd carbon number predominance(C17-C21) and smooth distribution,which may be related to their depositional environments and organic precursors.There are some differences in carbon number distribution between the two series of monocyclic alkanes and the n-alkanes marked by smooth distribution.The genetic relationship between the three series of compounds needs to be further studied.     

Main stages and geodynamic regimes of the Earth’s crust formation in East Antarctica in the Proterozoic and Early Paleozoic

Geological, geochemical, and isotopic data (U-Pb for zircon and Sm-Nd for whole-rock samples) are summarized for Proterozoic and Early Paleozoic geological complexes known from various regions of East Antarctica. The main events of tectonothermal and magmatic activity are outlined and correlated in space and time. The Paleoproterozoic is characterized as a period of rifting in Archean blocks, their partial mobilization, and formation of a new crustal material over a vast area occupied by present-day East Antarctica. In most areas, this material was repeatedly reworked at the subsequent stages of evolution (1800–1700, 1100–1000, 550–500 Ma). Complexes of Mesoproterozoic juvenile rocks (1500, 1400–1200, 1150–1100 Ma) arising in convergent suprasubduction geodynamic settings are established in some areas (basalt-andesite and tonalite-granodiorite associations with characteristic geochemical signatures). The evolution of the Proterozoic regions in East Antarctica may be interpreted as a Wilson cycle with the destruction of the Archean megacontinent 2250 Ma ago and the ultimate closure of the secondary oceanic basins by 1000 Ma ago. The Mesoproterozoic regions make up a marginal volcanic-plutonic belt that combines three provinces of different ages corresponding to consecutive accretion of terranes 1500–1150, 1400–950, and 1150–1050 Ma ago. The Neoproterozoic and Early Paleozoic tectonomagmatic activity developed nonuniformly. In some regions, it is expressed in ductile deformation, granulite-facies metamorphism, and postcollision magmatism; in other regions, a weak thermal effect and anorogenic magmatism are noted. The evolution of metamorphic complexes in the regime of isothermal decompression and the intraplate character of granitoids testify to the collision nature of the Early Paleozoic tectonomagmatic activity.     

Geochemical Behaviors of REE and Other Trace Elements during the Formation of Strata-bound Skarns and Related Deposits: A Case Study of the Dongguashan Cu (Au) Deposit, Anhui Province, China

REE and other trace elements in the altered marbles, massive skarns and ores, as well as garnet and quartz were determined in order to examine the behaviors of trace elements during hydrothermal alteration. It is demonstrated that the high-field-strength (HFS) elements Zr, Hf, Th and Nb were immobile while other trace elements were mobile during the formation of skarns and related deposits. REE and ore-forming elements such as Cu and Ag in hydrothermally-altered marbles and skarns were provided primarily by hydrothermal fluids. In the direction transverse of the strata, the more deeply the marbles were altered, the higher the total REE abundance and the larger the negative Eu anomalies would be. The chondrite-normalized REE patterns of skarns are similar to those of the marbles, but the former are distinguished by much higher REE contents and more remarkable negative Eu anomalies. Those patterns were apparently not inherited from the marble protolith, but were controlled by garnets, which were determine