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纳米氢氧化镍制备的最新进展 总被引:1,自引:0,他引:1
纳米材料由于其颗粒较小,因此其性能和常规材料相比有较大的改变.随着纳米材料科学技术的迅猛发展,纳米材料的研究逐渐扩展到化学电源领域.氢氧化镍作为Ni-MH二次电池的主要正极活性材料,对电池的容量和寿命起着关键性的作用.但是目前传统方法制备的氢氧化镍容量较低,远没有达到其理论值.随着将纳米材料制备技术引入到氢氧化镍的合成,使其比容量有了质的提升,合成纳米氢氧化镍也成为研究的热点.介绍了纳米材料的一般性知识,同时阐述了纳米氢氧化镍作为Ni-MH电池的正极活性材料所具有的特性和制备方法上的最新进展,以及在制备和应用方面出现的一些问题. 相似文献
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氢氧化镍纳米片的制备 总被引:1,自引:0,他引:1
以硝酸镍为镍源,采用水热法制备N i(OH)2纳米片,通过改变反应物浓度、反应时间、反应温度,研究不同实验条件对N i(OH)2纳米片的影响;通过X-射线衍射、扫描电子显微镜等手段对样品进行了表征。 相似文献
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采用微乳液法合成了Co、Zn复合掺杂的纳米Ni(OH)_2粉体,通过改变温度、pH值对产品堆积密度、比容量的影响, 发现T=50℃、pH=11时,样品电极的性能较好,以50 mA·g~(-1)恒电流充放电,终止电压为1.0V的充放电制度下,其比容量达 282mAh·g~(-1),样品经过50次循环后容衰减率仅为2.5%. 相似文献
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利用溶胶-凝胶方法制备出纳米二氧化锡,并对所制备的纳米材料进行扫描电镜SEM、透射电镜TEM、粉末X射线衍射(XRD)、循环伏安(CV)以及循环性能测试.电化学性能测试表明所制备出的纳米电极材料具有较高的放电比容量,在电流密度为0.3mA/cm2、电位区间为0.05~1.2V vs.Li /Li时首次可逆放电比容量可达789mAh.g-1. 相似文献
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以高能球磨后的MnO2为前躯体,用水热法成功合成了平均粒径为60nm的LiMn2O4纳米微粒。实验结果表明,所合成的纳LiMn2O4在0.2℃倍率放电条件下,首次放电比容量为122mAh/g,样品在经过20次循环后容量下降约为5%左右,表现出较好的电化学性能。 相似文献
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以Na2SnO3.4H2O为原料,CO(NH2)2为表面活性剂,采用水热法制备了SnO2纳米球。利用X射线衍射(XRD)、扫描电子显微镜(SEM)、比表面积测试仪(BET)及电化学测试仪等研究材料的结构、形貌、比表面积及电化学性能。结果表明,制备的SnO2材料具有较好的球体形貌,颗粒分散均匀,形状规准,半径约为400 nm,结构呈典型的金红石相。在电压范围为0.01~3 V, 200 mA/g的电流密度下进行充放电测试,首次放电比容量为2206.6 mAh/g,50次循环后,放电比容量保持在440 mAh/g,具有较好的循环性能。 相似文献
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高密度氢氧化镍的制备研究 总被引:1,自引:0,他引:1
用氨催化液相沉淀法合成了氢氧化镍颗粒。研究了pH、反应时间、反应原料等工艺条件对堆积密度和颗粒形态的影响规律。在50±2℃,pH10.8±0.1下,并流加入Ni(NO_3)_2、KOH和氨水,反应14小时制得堆积密度1.82g/cm~3的球形均匀Ni(OH)_2颗粒。 相似文献
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The regular and yttrium-doped spherical β-phase nickel hydroxides were synthesized by means of chemically co-precipitation. The yttrium-doping with long needle-like nanocrystallites observed by TEM promoted the formation of the spherical nickel hydroxide with the larger diameter of about 5 μm. The discharge capacity of the yttrium-doped spherical nickel hydroxide was measured to be slightly lower than that of the regular spherical nickel hydroxide at room temperature. At temperatures of above 50 °C, however, the discharge capacity of the yttrium-doped nickel hydroxide is much higher than that of the regular spherical nickel hydroxide. The improvement of discharge capacity at elevated temperatures was contributed to the increase of the charge acceptance of yttrium-doped nickel hydroxide. The formation of an yttrium-rich surface layer on nickel hydroxide particles raised the oxygen evolution over-potential, leading to performance improvements of the nickel hydroxide electrode. The improvement of high temperature charge acceptance of yttrium-doped nickel hydroxide remarkably contributed to the high temperature charge-discharge efficiency of the nickel-metal hydride (Ni-MH) batteries with a commercial AAA size. 相似文献
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B. Liu X.Y. Wang H.T. Yuan Y.S. Zhang D.Y. Song Z.X. Zhou 《Journal of Applied Electrochemistry》1999,29(7):853-858
Substitution of 20 aluminium for nickel in the lattice of nickel hydroxide, prepared by coprecipitation, leads to a hydrotalcite-like compound of formula Ni0.8Al0.2(OH)2(CO3)0.1.0.66H2O. It has been found that the compound has prolonged stability in 6m KOH solution and can be used as the positive electrode material in rechargeable alkaline batteries. The structure, morphology and composition of the compound have been investigated by X-ray diffraction, scanning electron microscopy and infrared spectroscopy. The electrode comprising the aluminium-substituted nickel hydroxide has greater discharge capacity and higher utilization of active material than the -Ni(OH)2 electrode. Cyclic voltammetry suggest that the aluminium-substituted nickel hydroxide has better reversibility of the Ni(OH)2/NiOOH redox couple and higher oxygen evolution overpotential than -Ni(OH)2. The mechanism of the electrode reaction has also been discussed and the proton diffusion coefficient in the compound has been determined. 相似文献
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Nanostructured nickel hydroxide powder has been synthesized by a chemical precipitation method with the aid of ultrasound radiation, and the physical properties of the synthesized material were characterized by scanning electron microscopy, specific surface area, X-ray diffraction and differential scanning calorimetry. It was found that nanostructured nickel hydroxide was crystalline -Ni(OH)2 with a nanocrystalline and nanoporous surface structure. The crystallite sizes of nanostructured -Ni(OH)2 along the c- and a-axis were 2.5 and 2.3 nm, respectively, as calculated from (001) and (100) X-ray diffraction peaks. In comparison with spherical -Ni(OH)2 which has now been widely used as the active material for pasted nickel electrodes, nanostructured -Ni(OH)2 possessed a smaller crystallite size, more structural defects, a larger lattice parameter of c0, a higher specific surface area and lower thermal decomposition temperature. These physical characteristics were advantageous to the improvement of electrochemical activity of the nanostructured nickel hydroxide powder. Studies indicated that the filling property and flowability of nanostructured -Ni(OH)2, which were characterized by the measurements of tapping density and angle of repose, were inferior to those of spherical -Ni(OH)2. Pasted nickel electrodes with a porous nickel-foam substrate were prepared using a mixture of the nanostructured and spherical Ni(OH)2 powders as the active material. Charge/discharge tests showed that the addition of an appropriate amount of nanostructured Ni(OH)2 powder to spherical Ni(OH)2 powder could enhance the specific discharge capacity and high-rate capability of the pasted nickel electrodes. This enhancement could be attributed to a lowered electrochemical reaction impedance for the nickel electrode with the addition of nanostructured Ni(OH)2 relative to the electrode without nanostructured Ni(OH)2. 相似文献
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卤水-石灰乳法制备纳米氢氧化镁新工艺研究 总被引:1,自引:0,他引:1
以天然盐湖卤块为原料,采用石灰乳为沉淀剂,控制温度在40~90 ℃,采用特殊的除钙技术,使产品中氢氧化镁质量分数大于98%,氧化钙质量分数小于0.2%,分解温度396.93℃,热质量损失30.96%.利用扫描电子显微镜对产品形貌进行表征,结果显示制得的氢氧化镁产品粒径在80 nm左右,粒子呈片状晶体结构.制得的氢氧化镁产品比表面积为39.2 m2/g.此生产工艺简单,生产成本低,是一种比较清洁的合成工艺路线.新工艺生产的产品质量不仅达到国家行业标准,而且达到国外企业标准,可望进行工业性生产. 相似文献
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Effects of ball milling on the physical and electrochemical characteristics of nickel hydroxide powder 总被引:1,自引:0,他引:1
Nickel hydroxide powder was modified by the method of ball milling, and the physical properties of both the ball-milled and
un-milled nickel hydroxide were characterized by scanning electron microscopy, specific surface area, particle size distribution
and X-ray diffraction. It was found that the ball milling processing could obviously increase the surface area, decrease the
particle and crystallite size, and reduce the crystallinity of β-Ni(OH)2, which was advantageous to the improvement of the electrochemical activity of nickel hydroxide powder. Electrochemical performances
of pasted nickel electrodes using the ball-milled nickel hydroxide as an active material were investigated, and were compared
with those of the electrodes prepared with the un-milled nickel hydroxide. Charge/discharge tests showed that the ball-milled
nickel hydroxide electrodes exhibited better performances in the charging efficiency, specific discharge capacity, active
material utilization and discharge voltage. The improvement of the performances of β-Ni(OH)2 through ball milling could be attributed to the better reaction reversibility, higher coulombic efficiency, higher oxygen
evolution potential and lower electrochemical impedance, as indicated by the cyclic voltammetry and electrochemical impedance
spectroscopy studies. Thus, ball milling was an effective method to modify the physical properties and enhance the electrochemical
performances of nickel hydroxide powder for the active material of rechargeable alkaline nickel batteries. 相似文献
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介绍了目前国内外纳米粉体二氧化铈的主要制备方法,其中包括水热晶化法、溶胶-凝胶法、微乳液和均匀沉淀耦合法、均匀沉淀和炭吸附耦合法、模板剂共沉淀法、室温(湿)固相化学反应法、一步熔融盐分解法等。通过对各方法的实验条件、制备工艺、产品性状等探讨研究,分析评述了各方法的应用及其工业化前景,旨在为高附加值稀土材料的研制开发提供方向。 相似文献