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1.
Food-grade polyvinyl chloride (PVC) film containing 28.3% di-(2-ethylhexylexyl)adipate (DEHA) plasticizer was used to wrap three different types of cheese (Kefalotyri, Edam, and Feta). Samples were split into two groups and stored at 5+/-0.5 degrees C. One group was analyzed for DEHA content at intervals between 1 and 240 h of contact (kinetic study), and a second group was cut into slices (1.2 mm thick) after 240 h of cheese/PVC contact and was analyzed for DEHA content (penetration study). The DEHA was determined by indirect gas chromatography. Statistically significant differences in migration of DEHA were observed between the cheese types. Migration of DEHA depended on contact time, fat, and moisture contents, and consistency of cheese samples. Equilibrium conditions were approached after approximately 100 h of contact for Edam and 150 h for Kefalotyri cheese. Equilibrium conditions were not reached for Feta cheese, even after 240 h of contact. After 240 h of contact under refrigeration, the migration of DEHA was approximately 345.4 mg/kg (18.9 mg/dm2) for Kefalotyri, 222.5 mg/kg (12.2 mg/dm2) for Edam, and 133.9 mg/kg (7.3 mg/dm2) for Feta. The loss of DEHA from the PVC film into the three cheese types was 37.8, 24.3, and 14.6%, respectively. These values, with the exception of Feta, were higher than the upper limit for global migration from plastic packaging materials into food and food stimulants set by the European Union (EU) (10 mg/dm2 or 60 mg/kg). After 240 h of cheese/film contact, DEHA was detected in the first three slices beneath the cheese surface (3.6 mm total depth) of Edam cheese and in the first two slices (2.4 mm total depth) of Kefalotryi and Feta cheeses. DEHA was not detected in subsequent layers. The effect of cheese rind on migration of DEHA was studied in Edam and Kefalotyri cheeses. The DEHA migration after 240 h into the first 1 mm beneath the surface of Kefalotyri cheese was 22.4 mg/kg, while DEHA was not detected in Edam cheese.  相似文献   

2.
Liquid-crystalline co-polyesters (e.g. a random copolyester based on p -hydroxybenzoic acid (HBA) and 2-hydroxy-6-naphthoic acid (HNA) known as Vectra A950) offer good barrier properties, but for food-contact use they require overall and specific migration testing. For Vectra A950 films, the highest overall migration level obtained was 2.3 mg dm -2 (13.8 mg kg -1 ) in olive oil (10 days at 40°C), well below the EC limit of 10 mg dm -2 (60 mg kg -1 ). The highest specific migration of HBA was 15.2 μg dm -2 (91.2 μg kg -1 ) in olive oil (2 h at 175°C). In this case, the migration level was well below the EC limit of 10 mg dm -2 (60 mg kg -1 ). For HNA, the highest value obtained was 4.3 μg dm -2 (26 μg kg -1 ) in 10% ethanol (4 h at 100°C), well below the specific migration limit (SML = 50 μg kg -1 ). The results obtained shows that even at these severe conditions, the migration values comply with the new European Union Directive 2002/72/EC, which regulates plastic materials and articles for food contact use. In addition, the polymer Vectra A950 complies with Food Contact Notification (FCN) No. 103 of the United States Food and Drug Administration (FDA). Vectra A950 is therefore permitted for food-contact use both in the European Union and the USA.  相似文献   

3.
探讨了利用电感耦合等离子体发射光谱法(ICP-AES)同时测定食品中钙铁锌含量的测定方法。应用ICP-AES对奶粉成分标准物质(GBW 10017)中的钙铁锌含量进行测定,结果表明:方法具有灵敏度高、检测限低、高效、稳定的优点,方法的检出限分别为钙0.1mg/kg,铁0.02mg/kg,锌0.01mg/kg,相对标准偏差低于6%。  相似文献   

4.
The effect of biofortified cassava root starch (YfCRS) (90–98 %) and whole egg powder (WEP) (2–10 %) on the pasting, chemical and sensory properties of cassava starch-based custard powder (CbCP) were studied using response surface methodology. The result revealed that there are variations in the pasting properties of the CbCP notwithstanding the levels of WEP inclusion, and all the custard powder could form paste below the boiling point of water at the peak time of <5 min. Additionally, the CbCP with high quantity of WEP had the highest protein (6.39 %), iron (29.39 mg/kg) and zinc (4.25 mg/kg) contents, but with low amylose (18.68 %) and trans-β-carotene (0.0756 μg/g) contents. The YfCRS increased the amylose and trans-β-carotene contents of the custard powder. The models for the responses were highly adequate (R2 > 80 %), except for peak viscosity, pasting temperature, hydrogen cyanide and overall acceptability. Although all the sensory attributes of the formulated CbCP gruel fall within the likeness range, 93.13 % YfCRS and 7.56 % WEP is the optimum combinations for good quality CbCP. Therefore, to replace maize starch with cassava starch in the production of a quality CbCP, 93.13 % YfCRS and 7.56 % WEP could be used.  相似文献   

5.
Lead, cadmium, iron, copper and zinc contents of Ka?ar cheese sold in the markets of Ankara, Turkey, were determined over 12 months. A total of 240 samples comprising 10 different brands were analysed. Graphite-furnace atomic absorption was employed for the determination of lead and cadmium, and flame atomic absorption for iron, copper and zinc. The mean (range) of the lead, cadmium, iron, copper and zinc content of the samples were 86 (10-421) microg kg(-1), 1.8 (0.3-8.3) microg kg(-1), 4.2 (1.0-14.1) mg kg(-1), 0.7 (0.3-1.6) mg kg(-1) and 37.7 (26.5-63.0) mg kg(-1), respectively. The samples in November, December and January contained higher amounts of lead than those in other months (p < 0.01). Moreover, important differences existed in lead content of the samples between different cheese producers (p < 0.01). The differences in cadmium and iron content of the samples for different months were important (p < 0.01). The iron content of the samples among manufacturers also varied significantly (p < 0.01). However, there were no significant differences in copper and zinc contents of the samples over 12 months (p > 0.05). These findings suggested that some contamination occurred during milk production and/or manufacturing of cheese depending on the equipment used. For a consumption of 100 g Ka?ar cheese, one would ingest approximately 8.6 microg (4% of the provisional tolerable daily intake, PTDI) of lead, 0.2 microg (0.3%) of cadmium, 0.4 mg (0.9%) of iron, 0.07 mg (2%) of copper and 3.8 mg (6%) of zinc. Therefore, it was concluded that Ka?ar cheese is not a significant contributor to the intake of investigated heavy metals.  相似文献   

6.
目的对食品加工设备中与食品接触的铝及铝合金制品中锌、铅、镉、砷、铬、镍、锰7种元素的迁移规律进行研究。方法在流通领域进行抽样,设定不同浸泡条件,参照GB/T 5009.72—2003《铝制食具容器卫生标准的分析方法》进行分析。结果发现迁移条件对迁移量的影响与元素的类别有关,在相同条件下,元素不同其迁移量的变化也不同;锌、铬、镍、锰4种元素在高温的条件下较易发生迁移(尤其是锌),并且均表现出在高温环境中时间越长迁移量越高的趋势。结论不同元素受迁移条件的影响不同,在高温条件下较易发生迁移,建议不要将铝及铝合金制品长时间放置于高温环境中使用,以降低各元素发生迁移的风险。  相似文献   

7.
《Food chemistry》2005,89(4):599-603
Seven wild edible mushrooms commonly consumed in the Khasi hills of Meghalaya were analyzed for their contents of dry matter, crude protein, fat, fibre and ash along with minerals (Ca, P, Fe, Mn, Cu, Zn, Na, K, Mg and Se), ascorbic acid and the profile of essential amino acids. The macronutrient profile in general revealed that the wild mushrooms were rich sources of protein and had low amounts of fat. In general, most of the mushrooms studied had good amounts of minerals, including trace minerals. On average, phenylalanine was the limiting amino acid (0.9 μg%) while the highest amount of EAA present in the mushrooms studied was leucine (704 μg%). One serving of the studied mushrooms (250 g fresh weight) contained an average of 6.12 g of protein, 287 mg of calcium, 9.3 mg of iron and 3.72 mg of zinc. More importantly it had low levels of fat (0.712 g) and sodium (0.077 mg).  相似文献   

8.
目的建立电感耦合等离子体发射光谱法同时测定珍珠粉中6种元素的方法,进一步完善珍珠粉的测定方法,为珍珠粉的质量控制提供依据。方法采用微波消解法处理样品,电感耦合等离子体发射光谱法测定珍珠粉中钙、钠、镁、铁、锶、锌6种元素。对6种元素采取低、中、高3个浓度水平进行加标回收实验,对混合标准溶液连续测定6次进行精密度实验。另称取6份同一样品,采用微波消解法消解处理,对样品测定进行重复性实验。结果 6种元素中钙、钠、镁、铁在0~10 mg/L范围内线性关系良好,锶、锌在0~1 mg/L范围内线性关系良好。加标回收率为91%~105%,精密度为0.5%~1.0%,重复性为0.8%~1.3%。结论本方法简便快速准确,可用于珍珠粉中6中元素的测定。  相似文献   

9.
目的 分析39个聚乳酸(polylactic acid, PLA)基、淀粉基、纤维基材质的一次性生物基餐具中的22种元素迁移,并评估其安全风险。方法 样品经迁移实验得到迁移液,使用电感耦合等离子体质谱法对迁移液中的22种元素进行分析。结果 锑、铊未检出, 20种元素(铍、硼、镁、铝、钛、钒、铬、锰、铁、钴、镍、铜、锌、镓、砷、锶、镉、锡、钡、铅)均有检出,其中铝、锰、锌、镓、锶、钡迁移的检出率为100%。各元素迁移量范围为1.0×10-4~6.9×101 mg/kg,镁的平均迁移量最高为3.5 mg/kg。22种元素在PLA基与淀粉基制品中的迁移水平整体低于纤维基制品且不存在元素迁移的安全风险。纤维基样品中铝、铬、锰、锌、铅超出特定迁移限量,锌、镉、铅的日暴露量可能存在潜在的安全风险,而且还出现了多个金属元素迁移同时超标的现象。结论 部分纤维基样品中金属迁移存在超标现象及潜在安全风险,需要重点对纤维基样品的金属迁移加强关注和监管。本研究为不同材质一次性生物基餐具中金属迁移的安全性研究及监管提供了科学依据。  相似文献   

10.
The zinc content of 300 food and 79 beverage samples was determined using flame atomic absorption spectrometry. Sample recoveries, repeatability, and analyses of NIST and CBR-CEC reference materials demonstrated the reliability and accuracy of this technique. Mean zinc concentrations varied from 0.02 microg/ml in fresh water to 71.0 microg/g (fresh weight) in pork liver. The daily dietary intake of zinc for inhabitants of southeastern Spain was estimated to be 10.1 mg (5.5, 4.0, 0.5, and 0.1 mg Zn/day per person from foods of animal and vegetable origin, drinks, and other foods, respectively). Zinc levels found in high protein foods (meat, fish, milk products, eggs, dry fruits, cereals and legumes) were significantly higher than those found in food with a low protein content (vegetables, fruits and drinks) (p < 0.001). A significant linear correlation between zinc levels and the corresponding protein content of cereals, legumes and dry fruits was found (r = 0.754, p < 0.005). Zinc concentrations in milk samples were significantly modified by the thermal treatment (p < 0.001), and the skimming (p < 0.05) and calcium enrichment processes (p < 0.001). Shellfish zinc levels were also significantly higher than those measured in fish (p < 0.05). Mean zinc concentrations found in cheese were statistically higher than those determined in the remaining milk products (p < 0.001). Zinc levels measured in distilled beverages were also statistically lower than those found in fermented ones (p < 0.001).  相似文献   

11.
A study was undertaken by European industry to estimate the consumption of canned beverages and foodstuffs. European can production data were used with adjustments for imports into and out of the EU. It was further assumed that can production, with adjustments, equalled consumption. Owing to the lack of actual consumption country-by-country or household-by-household data throughout Europe, only per capita estimates of consumption were possible. Data were compiled country-by-country for seven major can-producing EU Member States and for eight different types of canned food and two types of canned beverage (beer and soft drinks). The per capita consumption of canned foods was 1.1 cans/person/week, and consumption of canned fish was estimated as 2.2 kg/person/year. The estimate of per capita consumption of canned food was 62 g/person/day or 22.6 kg/person/year. Canned beverages account for about 60% of the consumption of canned foodstuffs. The usefulness of per capita consumption of beverages is questionable because consumption habits may vary more widely than those for canned foods. However, as the migration into beverages is insignificant, these data were added for completeness. Per capita consumption of canned beverages is 67 cans/person/year or 61 g/person/day. From the average can sizes, the surface area of the cans consumed was estimated. The per capita surface area exposure was 0.55 dm(2)/person/day for canned foods and 0.55 dm(2)/person/day for canned beverages, giving 1.1 dm(2)/person/day. Migration of a substance at 0.02 mg dm(2) gives an exposure of 0.01 mg/person/day assuming a per capita consumption, using a surface area model. Migration at 0.12 mg kg(-1) in food gives an exposure of 0.007 mg/person/day using a weight model. Both models assumed migration into all food types at the same level, which is highly unrealistic. Exposure to BADGE from canned foods has been used as a case study. The best estimate for a worst case per capita exposure to BADGE and relevant derivatives was between 6 and 10 micro g/person/day, depending upon the approach and assumptions used.  相似文献   

12.
Levels of copper, zinc, calcium and magnesium were measured in alcoholic beverages (whiskies, gins, rums, liquors, brandies, wines and beers) and by-products (non-alcoholic liquors and vinegars) using flame atomic absorption spectrometry (FAAS). Mineral concentrations were found to be significantly different between the nine alcoholic and non-alcoholic by-products studied (p < 0.001). In distilled alcoholic beverages, concentrations measured in rums and brandies were statistically lower than those determined in gins and alcoholic liquors (p = 0.001). For Cu, measured concentrations were statistically different for each of the five groups of distilled alcoholic beverages studied (p < 0.001). In fermented beverages, Zn, Ca and Mg levels were significantly higher than those concentrations determined in distilled drinks (p < 0.005). Contrarily, Cu concentrations were statistically lower (p < 0.001). Wines designated as sherry had significantly higher Ca and Mg levels (p < 0.005). White wines had significantly higher Ca and Zn levels (p < 0.05) compared with red wines and, contrarily, Cu concentrations were significantly lower (p < 0.005). In wine samples and corresponding by-products (brandy and vinegar), statistical differences were established for all minerals analysed (p < 0.01). Remarkably, for Cu, the concentrations determined in brandies were statistically higher. On the basis of element levels and the official data on consumption of alcoholic beverages and by-products in Spain, their contribution to the daily dietary intake (DDI) was calculated to be 124.6 microg Cu day(-1) and 193.3 microg Zn day(-1), 40.3 mg Ca day(-1) and 19.9 mg Mg day(-1). From all studied elements, Cu was the one for which alcoholic beverages constitute a significant source (more than 10% of recommended daily intake). These findings are of potential use to food composition tables.  相似文献   

13.
Borojo果是一种天然的高钾低钠水果,是补充钾、钙和镁优良的食品来源。本文用火焰原子吸收光谱法测定Borojo果及其制品中铜、铁、镁、锌、锰、钾、钠、钙8种微量元素的含量,为Borojo果功效开发及深加工提供科学依据。样品经硝酸消解过夜,重复测定6次,计算精密度。方法前处理简单快速,重复性好,试剂用量小,加标回收率在94%-104%之间,相对标准偏差≤3.15%。Borojo冷冻干燥粉中8种微量元素分别是果肉的3倍左右。酶解浓缩粉中微量元素高于冷冻干燥粉,铜、锌分别高5和7倍;锰、镁、钾、钙、铁分别高1.08,1.16,1.22,1.12和1.23倍,钠高了55倍。Borojo果肉、冷冻干燥粉和酶解浓缩粉中的钾:钠比分别为2435:1,2870:1和63:1。8种微量元素比例同金丝枣、榴莲和干枣中相似,且比后者含有更多的镁。  相似文献   

14.
The main component of scallop-shell powder is calcium carbonate (CaCO3). Through heat treatment, CaCO3 in the shell is converted to CaO, which exhibits antibacterial activity. The disinfecting effect of heated scallop-shell powder on shredded cabbage was investigated for various powder concentrations (0.1 to 1.0 g dm(-3)) and treatment temperatures (10 to 40 degrees C). Scallop-shell powder treatment was found to reduce the aerobic bacteria count in cabbage, with increasing effectiveness at higher powder concentrations and treatment temperatures. Coliforms were completely eliminated within 5 min with as little as 0.1 g dm(-3) powder treatment. During storage at 4 degrees C, aerobic bacterial counts did not increase after powder treatment, whereas counts increased with water-washing or sodium hypochlorite treatment at 200 microg dm(-3). The inactivation pattern of bacterial cells in shredded cabbage involved an accelerated decline followed by an extended tail at powder concentrations of 0.1 and 0.5 g dm(-3). We postulate that a fraction of bacterial cells in the initial population becomes tolerant to the shell powder. A proposed model accurately predicts the reducing bacterial counts on shredded cabbage by scallop-shell powder treatment. The decrease in the L-ascorbic acid content of shredded cabbage was approximately 20 to 30% for scallop-shell powder treatment at 0.1 and 0.5 g dm(-3) (20 degrees C), which is almost identical to that by sodium hypochlorite treatment at 200 micorg dm(-3).  相似文献   

15.
We completed a series of studies to assess the acceptability of zinc-fortified, cereal-based complementary foods and zinc-fortified wheat breads. Young children and their caregivers completed acceptability tests with complementary foods fortified with iron only (60 mg iron as ferrous fumarate per kilogram cereal flour), or the same level of iron and zinc (240 mg zinc as zinc oxide per kilogram cereal flour), and the caregivers completed triangle taste tests to compare the same products. A separate group of adult participants completed acceptability tests with wheat breads fortified with iron and folic acid (15 mg iron as ferrous fumarate per kilogram flour and 1.5 mg folic acid per kilogram flour) or the same levels of iron-folic acid and 2 levels of zinc (63 mg zinc or 126 mg zinc as zinc oxide per kilogram flour). Finally, a threshold test was administered to another group of adult participants to compare nonfortified wheat bread to breads fortified with zinc in 80 mg increments ranging from 80 to 400 mg zinc as zinc oxide per kilogram flour. All products were acceptable when compared to non-zinc-fortified equivalents, and were well liked by the respective participants. For the triangle tests, caregivers were not able to detect significant differences between products. For threshold tests, adult participants detected differences in breads prepared from fortified wheat flour at 80 mg, 160 mg, and 320 mg zinc per kilogram flour, but not at 240 mg and 400 mg zinc per kilogram flour, respectively, when compared to nonfortified bread equivalents. Zinc fortification of cereal flours in the ranges of fortification that were tested does not adversely affect the acceptability of complementary foods and breads prepared from these flours. Practical Application: Fortification of staple food products is a low-cost approach to deliver additional micronutrients (including zinc) to large segments of a population. Determining the acceptability of products fortified with zinc is an important step in the development of zinc fortification programs.  相似文献   

16.
目的 建立电感耦合等离子体发射光谱法(inductively coupled plasma atomic emission spectroscopy, ICP-AES)同时检测食品接触用搪瓷制品中11种重金属(铝、砷、钡、镉、钴、铬、锰、镍、铅、锑、锌)迁移量的分析方法。方法 采用4%(V:V)乙酸溶液, 在特定迁移试验条件下, 避光浸泡试样, 优化仪器参数和实验条件, 用电感耦合等离子体发射光谱法同时测定浸泡液中11元素迁移量。结果 方法检出限为0.001~0.010 mg/L, 样品加标回收率为92.2%~105.5%, 相对标准偏差为0.91%~3.65%。结论 方法操作简便, 准确度好, 灵敏度高、检出限低, 为食品接触用搪瓷制品中多种痕量有害元素迁移量进行合理产品风险评估提供一种高效、可行的手段。针对国标GB 4806.3-2016《食品安全国家标准搪瓷制品》中理化指标与迁移试验提出合理建议。  相似文献   

17.
The occurrence of aflatoxin in commodities imported into Qatar was investigated from 1999 to 2000. During the 4 years, 351 samples of susceptible commodities were analysed. Aflatoxin was detected in 71 (20%) samples in the range 0.1-20 microg kg(-1) and in 50 (14%) samples above the permitted level of 20 microg kg(-1). The highest incidence and levels of aflatoxin contamination were recorded in pistachio without shell followed by pistachio with shell. Aflatoxin levels >20 microg kg(-1) in the pistachio samples varied from 8.7 to 33%. The highest level of total aflatoxin found in pistachio without shell was 289 microg kg(-1). A few samples of corn and corn products (three of 54 analysed), peanut and peanut products (nine of 42 analysed) and other nuts like almond, walnut and cashew (one of 40 analysed) were found contaminated with low levels (0.1-20 microg kg(-1)) of aflatoxins. Only one sample of custard powder and one sample of roasted peanut were found with aflatoxin >20 microg kg(-1)  相似文献   

18.
The barrier effect of a silicon oxide (SiOx) coating on the inner surface of PET bottles, in terms of the ability to reduce the migration of post-consumer compounds from the PET bottle wall into food simulants (3% acetic acid and 10% ethanol), was investigated. The barrier effect was examined by artificially introducing model substances (surrogates) into the PET bottle wall to represent a worst-case scenario. Test bottles with three different spiking levels up to approximately 1000 mg kg(-1) per surrogate were blown and coated on the inner surface. The SiOx-coated bottles and the non-coated reference bottles were filled with food simulants. From the specific migration of the surrogates with different bottles wall concentrations, the maximum surrogate concentrations in the bottle wall corresponding to migration of 10 microg l(-1) were determined. It was shown that the SiOx coating layer is an efficient barrier to post-consumer compounds. The maximum bottle wall concentrations of the surrogates corresponding to migration of 10 microg l(-1) were in the range of 200 mg kg(-1) for toluene and approximately 900 mg kg(-1) for benzophenone. Consequently, the SiOx coating allows use of conventionally recycled post-consumer PET flakes (without a super-clean recycling process) for packaging aqueous and low alcoholic foodstuffs (under cold-fill conditions) and protects food from migration of unwanted contaminants from post-consumer PET.  相似文献   

19.
本文首先采用微波消解法对我国不同区域代表性的野生可食用蘑菇进行前处理,再通过电感耦合等离子体光谱和质谱法测定消解液中代表性元素含量并对部分元素进行形态分析。实验结果表明,通过电子耦合等离子体光谱检测常见元素(钾、钙、钠、镁、锌、锰、磷、铁和铜),检测的线性范围均为0~500 μg/mL, 得到的线性方程相关系数均大于0.999,各元素检出限在0.1~7 mg/kg之间;通过电感耦合等离子体光谱和质谱检测重金属元素(硼、铝、钛、钒、铬、钴、镍、砷、硒、锶、钼、镉、锡、锑、钡、汞、铊和铅),检测的线性范围为0~500 μg/mL,得到的线性方程相关系数均大于0.999,各元素检出限在0.0001~2 mg/kg之间;同时,确定了对砷和硒的形态分析前处理和检测方法,并分析无机砷和无机硒的占比,该方法能够满足日常分析检测,并为科学评价野生蘑菇中常见元素含量提供数据参考。  相似文献   

20.
以鸡蛋和香菇粉为主要原料,通过单因素结合响应面试验考察了水的添加量、蔗糖的添加量、香菇粉添加量对香菇鸡蛋羹感官品质的影响,利用质构仪、DSC(差式热量扫描仪)、RVA(快速粘度分析仪)研究未添加蔗糖和香菇粉、只添加香菇粉、只添加蔗糖、同时添加蔗糖和香菇粉的四种蛋羹的凝胶特性的变化。实验结果表明,当水添加量为173.28%、蔗糖添加量为4.04%、香菇粉添加量为1.57%(均以蛋液质量为基准),香菇鸡蛋羹感官品质预测最佳得分为88.94分,验证实验感观评分为90分。同时添加蔗糖和香菇粉显著增强香菇鸡蛋羹的硬度和咀嚼性,热焓值最大,凝胶强度也最大,研究结果表明蔗糖和香菇粉同时添加对香菇鸡蛋羹的凝胶强度具有增效作用。这为香菇鸡蛋羹的工业化生产奠定了一定的理论基础。  相似文献   

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