超重元素合成反应机制研究

回顾了超重元素研究的现状和超重元素合成反应机制研究的发展,指出目前超重元素合成研究中存在的困难和对超重余核鉴别的一些设想.对近对称反应系统的熔合反应机制进行了较深入的讨论,建议对这类反应生成复合核的截面进行理论和实验上的研究.The status and development of the studies on reaction mechanism for synthesis of superheavy elements has been reviewed. In this paper it is pointed out the difficulties existing in the studies and synthesis of superheavy elements and some conceives for measurement and identification of very heavy residues. The fusion of near symmetric reaction systems is discussed and proposed to do more investigations on the fusion cross sections of these reactions on both theory and experiment.     

预平衡反应多步复合理论和复合核反应理论的统一表示

将Feshbach-Kerman-Koonin(FKK)量子多步复合(MSC)理论推广至核子自旋为1/2,靶核自旋任意,在j-j表象严格处理角动量耦合,得到自旋为1/2的FKK-MSC公式.进一步用光学模型吸收代替门态强度函数,以及用复合核衰变宽度代替平衡态的逃逸宽度,给出了FKK-MSC理论与复合核反应Hauser-Feshbach模型(HFM)的一个统一表达式.这一公式将MSC和HFM与光学模型相联系,对核反应给出自洽和一致的描述.利用上述工作对一些典型的核反应实验进行了初步地分析,计算结果合理,与实验数据符合尚好.     

A Detail Investigation on the Synthesis of Superheavy Element Z = 119

Physics of Particles and Nuclei Letters - We have studied the α-decay properties of superheavy nuclei Z = 119 in the range 265 ≤ A ≤ 316. By studying the α-decay properties,...     

Effects of the HMT on Nucleon Collective Flows within BUU Transport Model

Within the framework of a semiclassical Boltzmann-Uehling-Uhlenbeck(BUU) transport model,the high momentum tail(HMT) effects of nucleon momentum distribution in the nucleus on the nucleon collective Bows are studied in semicentral Au+Au collisions.The HMT due to the isospin-dependent short-range correlations causes a smaller value of the collective Bows.We Bnd that the HMT effects on the nucleon collective Bows are remarkable at beam energy of 300 MeV/nucleon and become weak as the incident beam energy increases.The results indicate that for the collective Bow studies at intermediate energies,the HMT of nucleon momentum distribution in nucleus should be taken into account in transport models.     

Ground State Properties of Superheavy Nuclei in Macroscopic-Microscopic Model

The ground state properties of superheavy nuclei are systematically calculated by the macroscopic-microscopic (MM) model with the Nilsson potential. The calculations well produced the ground state binding energies, α-decay energies, and half lives of superheavy nuclei. The calculated results are systematically compared with available experimental data. The calculated results are also compared with theoretical results from other MM models and from relativistic mean-field model. The calculations and comparisons show that the MM model is reliable in superheavy region and that the MM model results are not very sensitive to the choice of microscopic single-particle potential.     

利用BUU模型研究11Li的核反应总截面和双中子剥去截面

发展了BUU模型,能够同时研究双中子晕结构核¹¹Li引起反应的核反应总截面和双中子剥去截面,计算中使用软的核物质状态方程和0.8倍的核子–核子碰撞截面,同时还用相对论平均场模型计算的中子和质子密度代替通常使用的方密度分布,计算结果可以很好地拟合不同反应系统的实验数据,假定对于晕核及其核芯核,彼此的核反应总截面与相互作用截面之间的差别相同,那么¹¹Li的双中子剥去截面可以表示成”Li及其核芯核⁹Li引起反应的核反应总截面之差,研究结果表明这一假定可以适用于高能,对于中能核反应需要更多的实验数据来检验.     

Dynamical Study on Fusion Barrier in the Synthesis of Superheavy Elements

Based on the improved isospin-dependent quantum molecular dynamics model, the fusion barrier in the synthesis of superheavy elements is studied dynamically. Deformation effect and nucleon transfer in neck region are also investigated systematically, which can lower the dynamical barrier since the neck formation. It is shown that the neck radius is dependent on the incident energy and collision orientation. For the static barrier, the model almost gives the same results with the proximity potential.     

Ground State Properties of Superheavy Nuclei in Macroscopic-Microscopic Model

The ground state properties of superheavy nuclei are systematically calculated by the macroscopic- microscopic （MM） model with the Nilsson potential. The calculations well produced the ground state binding energies, α-decay energies, and half lives of superheavy nuclei. The calculated results are systematically compared with available experimental data. The calculated results are also compared with theoretical results from other MM models and from relativistic mean-field model. The calculations and comparisons show that the MM model is reliable in superheavy region and that the MM model results are not very sensitive to the choice of microscopic single-particle potential.     

钴原子插层增强磷烯纳米片析氢反应活性

本文基于第一性原理计算,证明了钴插层磷烯的析氢催化活性可以显著增强.钴插层磷烯具有金属特性,电荷从钴原子向磷烯转移,增强了磷烯的催化活性.钴插层磷烯表面的氢吸附吉布斯自由能与铂(111)表面相当,与氢覆盖度无关.研究结果表明钴原子插层提供了一种有效的方法来增强磷烯的析氢反应催化活性.     

Origin of Unexpected Isotopic Trends in Synthesis of Superheavy Nuclei

We investigate the dependence of the yield of superheavy nuclei with Z = 110, 112, 114 on the neutron excess of the projectile nucleus with a two-parameter Smoluchowski equation. It is confirmed that in some cases, the cold fusion reactions with less neutron excess are more favourable than those with more neutron excess. In order to probe the origin of these unexpected isotopic trends, we also investigate the probabilities of capture, fusion and survival in the cold fusion reactions in detail It is found that the maximal ER cross sections of the superheavy nuclei exponentially increase as a function of Bf - Sn with Bf being the fission barrier and Sn being the neutron separation energy. Although the probabilities of capture and fusion have some influences, the unexpected isotopic trends mainly due to the dependence of the ER cross sections on the Bf - Sn value. Therefore, the reactions with larger Bf - Sn values should be more favourable for synthesis of superheavy nuclei.     

High Energy Nucleus–Nucleus Collisions in View of the Multi-Peripheral Model

The hypothesis of the ulti-peripheral odel is extended to the hadron –nucleus interactions and then generalized to the nucleus –nucleus case. The processing of the odel depends on input parameters that are extracted fro the features of the experiments in this .eld.The number of encountered nucleons from both target and projectile are estimated according to the eikonal scattering approach.The screening effect due to the interaction of the projectile nucleons in successive manner with the target nucleus is considered.The rapidity distributions of fast particles are reproduced for the successive collisions in p –S and 32 S –32 S interactions at 200 A GeV.A global fair agreement is found in comparison with data of the experi ent CERN-NA-035.     

Neutron and Proton Diffusion in Fusion Reactions for the Synthesis of Superheavy Nuclei

The restriction of the one dimensional （1D） master equation （ME） with the mass number of the projectile-like fragment as a variable is studied, and a two-dimensional （2D） master equation with the neutron and proton numbers as independent variables is set up, and solved numerically. Our study showed that the 2D ME can describe the fusion process well in all projectile target combinations. Therefore the possible channels to synthesize super-heavy nuclei can be studied correctly in wider possibilities. The available condition for employing 1D ME is pointed out.     

NiSb纳米颗粒的热液路线制备及电催化析氢性能研究

本文发展了一种简单经济的过渡金属锑化物热液合成路线,在160 oC的温和条件下,由商业易得的乙酰丙酮基镍和三苯基铋在油胺介质中还原制备出NiSb纳米颗粒. 反应中,还原剂甲硼烷-叔丁基胺络合物的使用能够有效促进金属源的快速还原,用以促进NiSb纳米颗粒的生成. 结构表征显示,所制备的NiSb产物为六方相(空间群P6₃/mmc)颗粒状纳米晶,其粒径约为10 nm. 该合成方法可拓展用于CoSb和Ag₃Sb等纳米颗粒的温和制备. 电催化析氢性能研究显示,NiSb纳米颗粒具有良好的电化学析氢反应性能. 结果显示,当阴极电流密度达到50 mA/cm²和10 mA/cm²时所需要的过电位分别为531和437 mV. 同时,NiSb纳米颗粒还具有较小的电荷转移阻抗和优良的循环稳定性能.     

RMF理论对N=60同中子核素形状演化的研究

利用形变约束的相对论平均场理论系统研究了N=60同中子核素的形状演化, 给出了这些核的基态结合能、 形变、 单粒子能级以及形变激发的位能曲线。 通过比较和分析发现, 随着质子数的增加, N=60同中子核的基态形变向轴对称形变方向演化, 114Xe和116Ba位于球形U（5）和轴对称SU（3）的过渡区, 存在形状相变的临界点结构, 这些结果与实验观测一致。 The shape phase transition between spherical U（5）and axially SU（3）deformed nuclei is investigated systemically for N=60 isotonic chain by the constrained relativistic mean|field theory with the interactions NL3 and PK1. The values of bind energy and quadruple deformation β2 are calculated and a good agreement is obtained as compared with the experiments. By examining the potential energy curve and single particle spectra obtained with this microscopic approach, the possible critical point nuclei with the structure of shape phase transition are suggested to be 114Xe and 116Ba, which is favored by the experiments.     

Laser Acceleration of Nuclei for Synthesis of Superheavy Elements in the Stability Island of the Periodic Table

Within a three-dimensionalmodel of interaction of a powerful electromagnetic fieldwith plasma of solid-state density, the effect of acceleration of calcium nuclei ( ₂₀ ⁴⁸ Ca) to high energies that are likely to be sufficient for the synthesis of superheavy elements within the “stability island” of the periodic table of elements is obtained by numerically solving the Vlasov–Maxwell equations.     

Study of 2n-Removal and Total Reaction Cross Section Induced by 11Li in BUU Framework

The σ_R and σ_－2n have been calculated via the BUU model by using soft EOS and 0.8σ_Cug. The density distribution which come from RMF model has been introduced to replace the normal used square-type distributions in BUU calculation. The calculated results can reproduce the experimental data well for various reaction systems. Here σ_－2n is calculated as the difference between σ_R of halo nucleus and core nucleus, by assuming σ_corr=0. It indicates that this assumption works very well in the BUU calculation.     

原子核壳模型单体密度矩阵的数值计算

提出平均场壳模型下原子核单体密度矩阵的一种计算方法,验证该方法的可靠性.计算双幻核⁴⁰Ca,⁹⁰Zr的单体密度矩阵,利用单体密度矩阵计算核子密度分布和动量分布,并分别与Hartree-Fock-Bogolubov理论结果、定域费米气体模型结果以及实验数据进行比较.     

推广的液滴模型对超重核288115及其α衰变链性质的研究

运用推广的液滴模型来确定新核素²⁸⁸115及其α衰变链上核的衰变位垒, 采用量子力学中处理α衰变的WKB方法, 对该链上各原子核的α衰变半寿命进行了研究．计算结果表明推广的液滴模型结合WKB方法可以很好地在超重区符合α衰变半寿命的实验值. 同时把推广的液滴模型的计算结果和采用密度相关的M3Y微观核力的结果做了详细的比较, 宏观模型(推广的液滴模型)和微观模型(密度相关的M3Y微观核力)计算的α衰变半寿命以及实验值三者之间的符合是对新核素²⁸⁸115及其α衰变链上核半寿命很好的检验.     

醇体系中合成CuGaS2纳米晶及其形貌演变

以CuCl2·2H2O,自制的GaCl3和(NH2)2CS为原料,在乙二醇体系中合成了花状结构的CuGaS2纳米晶．产物分别用X射线粉末衍射仪、透射电子显微镜、场发射扫描电子显微镜、高分辩透射电子显微镜和X射线光电子能谱仪进行了表征．实验结果表明,220℃反应24 h得到均匀的花状纳米结构CuGaS2,它是由厚度80-100 nm的片晶组成．同时,通过反应时间的控制,可以清楚的看到由纳米颗粒到纳米球以及花状纳米结构的演变过程．另外,研究了反应温度、反应时间、溶剂等对产物和形貌的影响．此外,对花状结构纳米晶的生长机理进行了初步的探讨．室温荧光光谱表明,随粒径的降低,发光位发生了部分蓝移．