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核/壳型有机硅改性苯丙乳液印花粘合剂的合成及应用 总被引:1,自引:0,他引:1
以过硫酸钠(NaPS)为引发剂,苯乙烯(St)和丙烯酸丁酯(BA)为核单体,甲基丙烯酸甲酯(MMA)、丙烯酸异辛酯(EHA)、苯乙烯(St)、丙烯酸(AA)为壳单体,采用种子乳液聚合法,制备了硬壳软核型苯丙乳液,对其进行有机硅改性,得到核壳型有机硅改性苯丙乳液(简称硅丙乳液),将其用作涂料印花粘合剂。研究了核壳单体质量比、丙烯酸用量、乙烯基硅油用量对乳液性能及印花性能的影响;并用热失重分析仪和透射电镜进行了表征。较佳配方为:核/壳单体质量比为6∶4,AA质量分数为2.5%,乙烯基硅油质量分数为10%~15%。该乳液的理化性能较好,耐热性优于核/壳苯丙乳液,将其用于涂料印花,改善了堵网性,印花织物的干、湿摩擦牢度,皂洗牢度,手感以及表观得色量可以达到工业用华润粘合剂的水平。 相似文献
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以丙烯酸甲酯(MA)、丙烯酸乙酯(EA)、丙烯酸丁酯(BA)、环氧树脂和乳化剂分别制备核、壳预乳化剂,然后通过种子乳液聚合法制备了具有核壳结构的聚合乳液。以环氧树脂E-44和有机硅氧烷KH-570对聚合乳液进行改性,制备了印花涂料用乳液。研究了乳化剂和核壳单体的配比以及不同改性剂用量对乳液稳定性和成膜性能的影响。结果表明,制备乳液的较佳条件为:复合乳化剂[m(十二烷基硫酸钠)∶m(非离子型乳化剂OS-15)=1∶3]的质量分数为4%,核单体组成为m(MA)∶m(EA)∶m(BA)=1∶1∶3、质量分数为30%~40%,壳单体组成为m(MA)∶m(EA)∶m(BA)=2∶1∶1,改性剂环氧树脂E-44和有机硅氧烷KH-570的用量分别为2%和6%。当烘焙工艺条件为140℃/3min时,制得的印花涂料涂膜在弹性、手感、牢度等性能指标方面均达到了设计要求。 相似文献
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苯丙乳液的合成及水性防锈涂料的制备研究 总被引:10,自引:4,他引:10
以丙烯酸丁酯、苯乙烯为主单体,甲基丙烯酸缩水甘油酯、甲基丙烯酸为交联单体,磷酸酯PAM-200为功能单体合成了一种具有核壳结构的交联苯丙乳液。研究了乳化剂的用量和配比、交联单体用量以及磷酸酯功能单体的用量对乳液及涂膜性能的影响。当乳化剂用量为单体总量的1.5%,核层为DSB(0.5%)/SE-10N(0.5%),壳层为SE-10N(0.5%);交联单体用量为所在层单体总量的3%,磷酸酯功能单体用量为壳层单体总量的4%时,乳液及其涂膜具有较好的综合性能。该乳液配制的水性防锈涂料与普通苯丙乳液相比具有更优异的防锈性能,在3%的盐水中浸泡400h漆膜无起泡生锈现象。 相似文献
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以丙烯酸丁酯、甲基丙烯酸甲酯、苯乙烯和丙烯腈作为共聚单体制备了TF-320自交联型涂料印花粘合剂,适宜的合成工艺参数为:交联单体A为单体总质量的3%。4%:分别g/,单体质量3%-4%的十二烷基磺酸钠和AE09(质量比为1:3)为复合乳化剂、0.5%~0.8%的过硫酸铵为引发剂,分别以总体系质量O.1%的磷酸二氢钠为缓冲剂、0.05%的正十二硫醇为调节剂,反应温度在80℃,采用连续滴加单体和引发剂的方法,滴加时间控制在2.0~3.0h。在此条件下所得产品可以给予织物优异的牢度、较高的得色量和柔软的手感,印花织物的干、湿摩擦牢度均达到或超过某市场主流产品。 相似文献
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研究了在制备中空聚合物乳胶粒过程中,甲基丙烯酸用量、乳化剂用量对最终中空乳胶粒粒径、空径的影响。实验结果表明,甲基丙烯酸用量为单体量的30%,乳化剂在核层以及壳层制备过程中用量分别为单体量的0.15%和0.2%时,能得到粒径均一、空径最大的中空乳胶粒。 相似文献
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指接材双组分胶粘剂的研制 总被引:1,自引:0,他引:1
研制了指接材双组分胶粘剂。研究了丙烯酸用量、引发剂用量和多亚甲基多苯基多异氰酸酯用量对乳液剪切强度的影响,同时还研究了引发剂用量和保温时间与乳液转化率的关系。结果表明:当丙烯酸用量为3%、过硫酸铵为0.5%、保温时间为40min、多亚甲基多苯基多异氰酸酯为14%时,乳液的干/湿态剪切强度分别为11.2MPa和6.3MPa。 相似文献
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The perovskite-type oxides La0.8Ce0.2Cu0.4Mn0.6O3 and La0.8Ce0.2Ag0.4Mn0.6O3 prepared by reverse microemulsion and sol–gel methods (denoted as R and S, respectively), have been investigated on their catalytic performance for the (NO + CO) reaction, and characterized by means of temperature-programmed desorption (TPD), X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). XRD measurements proved the presence of the perovskite phase with a considerable amount of CeO2 phase and the formation of CeO2 phase was restrained with the reverse microemulsion method. TEM investigations revealed that the La0.8Ce0.2Cu0.4Mn0.6O3-R nanoparticles were uniform spheres in shape with diameters ranging from 40 to 50 nm, whereas an aggregation of particles was found for the La0.8Ce0.2Cu0.4Mn0.6O3-S catalyst. The activity of NO reduction with CO decreased in the order of La0.8Ce0.2Cu0.4Mn0.6O3-R > La0.8Ce0.2Cu0.4Mn0.6O3-S > La0.8Ce0.2Ag0.4Mn0.6O3-R > La0.8Ce0.2Ag0.4Mn0.6O3-S. In NO-TPD experiments, the principal desorbed species detected in the effluent was NO with a trace amount of O2 and N2O, suggesting that the non-dissociated adsorption of NO on the surface of the perovskite-type oxides was dominant. The XPS results revealed that Ce4+ and Cu+ was the predominant oxidation state for Ce and Cu components in La0.8Ce0.2Cu0.4Mn0.6O3 and La0.8Ce0.2Ag0.4Mn0.6O3 catalysts. The existence of Cu+ ions and its redox reaction (Cu+ ↔ Cu2+) would benefit the NO adsorption and reduction by CO. 相似文献
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为解决天然染料核桃青皮染色色调单一的问题,以颜色特征值和染色牢度为指标,通过单因素和正交实验优化了影响染色效果的温度、时间、pH值及核桃青皮色素染液的质量浓度等因素,比较了单金属盐的不同媒染方法和双金属盐复配对纯棉织物染色性能的影响。结果表明,核桃青皮色素染色的优化条件为:温度90oC、质量浓度71.40 g/L、染浴pH=4.0、时间140 min。核桃青皮提取液染色棉织物色谱的范围广,耐摩擦牢度好;耐皂洗牢度上单金属盐媒染是后媒>前媒>同浴>直接染色,双金属盐复配及Fe3+、Fe2+、Cu2+、Al3+、Cr6+等单金属盐媒染的耐皂洗色牢度均能达到3级以上。X-射线衍射分析表明棉织物内部结构未受影响,Fe3+、Fe2+、Cr6+、Sr2+、Na+和K+等单金属盐和Fe2+/Cu2+、Fe2+/Ti4+、Cu2+/Ti4+、Cu2+/Sn2+、Al3+/Cr6+、Cr6+/Ti4+和Cr6+/Sn2+等双金属盐媒染后的棉织物紫外线防护能力增强。 相似文献
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实验制备的氧化蜡具有与天然巴西棕榈蜡相近的性能。考察了反应温度、反应时间、空气流速、蜡的选择和用量、催化剂用量等因素对氧化蜡质量的影响。结果表明,最佳工艺条件为:反应温度150~160℃,激发温度180~185℃,反应时间6~8 h,空气流速0.4 m3/h,石蜡用量65.0%,聚乙烯蜡用量20.0%,硬脂酸用量10.0%,氢氧化钙用量2.5%~3.0%,催化剂用量0.02%~0.05%,DTBP用量0.6%~1.0%。得到的产品具有较高的酸值、皂化值和较佳的针入度值。 相似文献
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采用多壁纳米碳管(MWNTs)与La0.6Sr0.4CoO2.8复合催化剂制备复合催化剂氧电极,研究了它的电化学特性。发现MWNTs对氧还原具有明显的催化作用,电极中单独采用MWNTs为催化剂时,氧电极工作电流密度可达200 mA/cm2(-0.6 V Hg/HgO参比电极)。结果表明,采用正交实验法获得了复合催化剂的最佳配比为:0.1 gMWNTs+0.02 g La0.6Sr0.4CoO2.8+0.5 mL PTFE+0.1 g ZnO,在最佳配比条件下,氧电极工作电流密度可达317mA/cm2(-0.6 V Hg/HgO参比电极),其交换电流密度为144.1 mA/cm2;MWNTs与La0.6Sr0.4CoO2.8催化剂具有催化性能的叠加特性,明显优于单一催化剂氧电极;MWNTs与不同类型的钙钛石组成复合催化剂时,La0.6Sr0.4CoO2.8与La0.6Ca0.4CoO2.8性能接近,但明显优于La0.8Sr0.2MnO2.9。 相似文献
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F. J. Sánchez-Muniz C. Cuesta C. Garrido-Polonio 《Journal of the American Oil Chemists' Society》1993,70(3):235-240
The alterations of a sunflower oil were evaluated by column, gas and high-performance size-exclusion chromatography after
being used for deep-fat frying fifteen repeated and discontinuous times. Polar compounds increased significantly (6.2 ± 0.3%
to 18.7 ± 0.8% in oil). Linoleic acid decreased (53.8 ± 0.2 to 48.1 ± 0.8 mg/100 mg oil) while oleic acid remained unaltered
after 15 fryings. Saturated fatty acids such as palmitic and stearic, also remained unaltered. Triglyceride polymers (0.1
± 0.0 to 2.4 ± 0.2 mg/100 mg oil), triglyceride dimers (1.0 ± 0.2 to 6.7 ± 0.3 mg/100 mg oil) and oxidized triglycerides (3.4
± 0.2 to 7.6 ± 0.3 mg/100 mg oil) increased significantly in the oil used 15 times to fry potatoes. These thermoxidative compounds
correlated well with the number of fryings (r=0.9864, r=0.9535 and r=0.9758, respectively). Diglyceride compounds remained
unaltered, while free fatty acids increased from 0.4 ± 0.0 to 0.6 ± 0.0 mg/100 mg oil. Both of these, which are characteristic
of hydrolytic alteration, did not correlate significantly (r=0.5985 and r=0.4261, respectively) with the number of fryings.
These data suggest that a thermoxidative process, rather than a hydrolytic one, took place in this study. 相似文献
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Duncan Phillips Richard Percival John Scotney Geoff Bevan John Lloyd 《Coloration Technology》2003,119(3):177-181
The effect of liquor ratio on the amount of cross‐staining and shade change in the ISO 105‐C08 wash fastness test has been studied in order to improve the correlation between the results from the laboratory test and to those obtained in a domestic washing machine. It has been shown that the correlation obtained for cross‐staining but not shade change is improved when the liquor ratio is reduced below the 50;1 currently in use. A revised setting of 20;1 is recommended for an international ring test to confirm repeatability and reproducibility. 相似文献
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高炉渣的主要成分与玻璃相似,采用熔融法以高炉渣为主要原料制备微晶玻璃(高炉渣配比为70%),以少量纯化学试剂调整基础玻璃成分,通过实验研究了晶核剂Cr2O3、Fe2O3对玻璃熔化性能的影响规律.结果表明:基础玻璃中加入0.5%~2.5%的Cr2O3作晶核剂时,随着Cr2O3加入量的增多,熔化温度呈现逐渐升高趋势,当向基础玻璃中加入1.0%~3.0%Fe2O3作晶核剂时,随着Fe2O3加入量的增多,熔化温度逐渐降低.将0.5%~2.5%Cr2O3、1.0%~3.0%Fe2O3按一定比例配合作为复合晶核剂,总量控制在3.5%,Cr2O3与Fe2O3对玻璃熔化性能的影响可以互相抵消.晶核剂Cr2O3、Fe2O3的引入,可明显降低玻璃的熔化性温度,为了保证玻璃液的顺利浇注成型,至少应将温度控制在1360 ℃以上. 相似文献
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M Javaid Mughal M Naeem Ausaf Aleem Rehana Saeed Kamran Ahmed 《Coloration Technology》2008,124(1):62-65
Cationisation of cotton is emerging as an effective tool that may help to solve the environmental problems associated with the dyeing of cotton with reactive dyes. The efficiency of the cationising agent CA200 has been investigated and was found to be more effective when compared with the usual method for reactive dyeing of cotton. Pretreatment of the cotton fabric with the cationising agent increases the rate of dyeing compared with the existing method of reactive dyeing. The colour yields, in terms of the Kubelka–Munk values as a function of the amount of dye fixed, showed that cationisation enhances the colour strength. It also improves the washing fastness, rubbing fastness and depth of shade. The positive environmental impact of this cationisation process is significant and the cationised cotton shows a similar fabric quality as with the normal dyeing process. 相似文献