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郑园园 《化学工业与工程技术》2015,(3):48-53
采用非随机双流体电解质(E-NRTL)热力学模型,通过拟合N-甲基二乙醇胺(MDEA)的热容数据,MDEA-H2O二元体系的气液平衡、热容和混合热数据,以及MDEA-H2O-CO2三元体系的气液平衡、热容和吸收热数据,建立了MDEA吸收CO2的热力学模型,并将气液平衡、热容、混合热和吸收热数据的模型计算值与试验值进行了比对。MDEA-H2O-CO2体系的核磁共振(NMR)组成数据被用来验证模型的准确性。 相似文献
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研究了313K时40%(质量分数)哌嗪(PZ)、N-氨乙基哌嗪(N-AEPZ)和羟乙基哌嗪(HEPZ)溶液吸收CO2性能以及30%AEE+10%PZ、30%AEE+10%N-AEPZ和30%AEE+10%HEPZ溶液对CO2的吸收性能。考察了吸收速率、吸收量、吸收时间、温度变化和PZ及其衍生物含量之间的相互关系。考察了解吸量与解吸时间的关系,解吸温度为393K。结果表明,分子结构中的多氨基基团有利于提高吸收性能;在复合体系中,N-AEPZ为主吸收作用,PZ与AEE共同作用,HEPZ为助吸收作用,提高主吸收组分的浓度有利于提高溶液的吸收能力,其中30%AEE+10%PZ的混胺溶液具有良好的吸收和解吸性能。 相似文献
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《应用化工》2015,(9):1639-1642
采用自制的功能离子液体1-2-胺乙基丁基咪唑溴盐([NH2ebim]Br)、1-2-胺乙基甲基咪唑溴盐([NH2emim]Br)的水溶液作为吸收剂,进行吸收CO2的研究。考察了不同浓度的功能离子液体水溶液吸收CO2的吸收速率,温度对CO2的吸收速率的影响,不同功能离子液体水溶液对吸收速率的影响,以及吸收剂的再生效率,并探讨了功能离子液体水溶液吸收CO2的机理。结果表明,功能离子液体水溶液实现了对CO2的化学吸收,吸收速率随着功能离子液体浓度和温度的增加而增加,而功能离子液体阳离子碳链长短对水溶液吸收CO2的速率影响不显著。实验中每摩尔功能离子液体吸收的CO2大于0.5 mol,其反应机理被提出。 相似文献
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《应用化工》2022,(9):1639-1642
采用自制的功能离子液体1-2-胺乙基丁基咪唑溴盐([NH2ebim]Br)、1-2-胺乙基甲基咪唑溴盐([NH2emim]Br)的水溶液作为吸收剂,进行吸收CO2的研究。考察了不同浓度的功能离子液体水溶液吸收CO2的吸收速率,温度对CO2的吸收速率的影响,不同功能离子液体水溶液对吸收速率的影响,以及吸收剂的再生效率,并探讨了功能离子液体水溶液吸收CO2的机理。结果表明,功能离子液体水溶液实现了对CO2的化学吸收,吸收速率随着功能离子液体浓度和温度的增加而增加,而功能离子液体阳离子碳链长短对水溶液吸收CO2的速率影响不显著。实验中每摩尔功能离子液体吸收的CO2大于0.5 mol,其反应机理被提出。 相似文献
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单乙醇胺水溶液化学吸收CO_2的研究 总被引:2,自引:1,他引:2
有机胺水溶液化学吸收CO2在工业上广泛应用,对其传质过程的微观机理进行研究十分必要。文中以对流扩散方程为基础,考虑了界面阻力对传质的影响,建立了带有化学反应的气液吸收过程液相侧非稳态传质模型,得到了传质系数表达式。利用激光全息干涉仪对不同液相主体流速下单乙醇胺(MEA)水溶液化学吸收CO2过程进行了实验研究,测定了传质达到稳态时的液相侧近界面浓度、浓度边界层厚度和传质系数。结果表明:随着液相主体流速的增加,近界面浓度和浓度边界层厚度减小,而传质系数增大;MEA在水溶液中的质量分数由0.1%增大到0.2%时,CO2吸收过程达到稳态时的近界面浓度、浓度边界层厚度及传质系数均增大。传质系数模型计算值与实验值吻合良好。 相似文献
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Absorption rate of CO2 into aqueous solution of N-methyldiethanolamine (MDEA) blended with diethanolamine (DEA) and piperazine (PZ) was studied and a kinetic model was established. It is shown that homogeneous activation mechanism could explain this absorption process. The absorption rate coefficients of carbon dioxide into MDEA aqueous solution blended with DEA, PZ or DEA PZ were compared with each other. The results demonstrated that the different activation effect of DEA, PZ and DEA PZ on the carbon dioxide absorption comes from the difference in CO2 combination rate, transport of PZ and DEA to MDEA and the regeneration rate of PZ and DEA. 相似文献
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N-甲基二乙醇胺溶液对H_2S和CO_2的吸收模拟 总被引:1,自引:0,他引:1
采用N-甲基二乙醇胺(MDEA)吸收炼化过程中干气及液态烃中过量的H2S和CO2,以达到生产要求。文中利用PRO/II软件对MDEA溶液吸收H2S和CO2的过程,采用合适的热力学模型(Electrolyte-NRTL),建立吸收塔模型进行模拟。研究了进料气液质量比、进料温度、操作压力、塔板高度、吸收液浓度等条件的改变对吸收效果的影响,并对操作条件进行评估。MDEA溶液对CO2的吸收效果不是很理想,由于伯、仲胺可直接与CO2反应,故向溶液中添加DEA,采用PRO/II的Kent-Eisenberg模型对MDEA/DEA混合胺的吸收状况进行模拟,其吸收效果较理想。文中对现有装置提出了一些技术改造建议。 相似文献
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研究了T形微通道内N-甲基二乙醇胺(MDEA)和单乙醇胺(MEA)混合水溶液吸收CO2的传质过程。考察了弹状流型下气液两相流量、MEA和MDEA浓度对液侧传质系数kL和体积传质系数kLa的影响。液侧传质系数和体积传质系数均会随着MEA浓度的升高而升高。与MEA相比,MDEA浓度的提高对传质影响较小。传质系数会随着液体流量的增大而增大,但气体流量的变化对其影响较小。体积传质系数随液体流量的增大而增大,但随气体流量的增大先增大,之后趋于稳定。考虑到化学反应对传质的强化作用,引入了Hatta数,提出了一个新的体积传质系数预测式,预测效果良好。 相似文献
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The electrolyte version of SRK plus association equation of state(e SRK-CPA Eo S) was employed to correlate CO_2 solubility in MDEA aqueous solutions. The applied model comprises the classic form of CPA Eo S including SRK Eo S plus Wertheim association term in addition to MSA theory and Born terms so that the two last terms are responsible for the long-range interactions. A reaction-containing bubble pressure computation technique comprising two nested loops was utilized to model the systems. The internal loop, calculates the liquid phase concentrations via reaction, mass and charge balance equation solving, whereas, the vapor phase concentrations will be obtained in the external one. 470 experimental data were used to correlate binary subsystems and the H_2O + MDEA + CO_2 ternary system. Since, there not exist any binary VLE data for MDEA + CO_2 subsystem, two fitting scenarios were applied. At the first scenario, the binary interaction parameter was assumed equal to zero, while, in second approach the parameter was obtained through ternary system correlation. Both scenarios show very good accuracy in that the Absolute Average Deviation percentages(AAD) obtained were 19.12% and 18.85%, respectively. Also, to show the efficiency of the used model, a comparison between our results and those of the best-known models was made.Finally, having model parameters for H_2S solubility from our previous work [A. Afsharpour, Petroleum Science and Technology 35(3)(2017) 292-298], simultaneous solubility of CO_2+ H_2S mixtures in MDEA solutions was predicted using the e SRK-CPA Eo S with no new optimizable parameters. As the results show,the applied model has a good performance for correlation and prediction of acid gas solubility in a wide range of pressures, temperatures, acid gas loadings, and MDEA concentrations. 相似文献
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Absorption rates for CO2 into aqueous solutions of TEA, MDEA and blends of MEA with MDEA and TEA were measured in a stirred cell by a method similar to that used by Laddha and Danckwerts (1981). Second order rate constants for CO2-TEA and CO2-MDEA were obtained from the single amine data for temperatures in the range of 25-60°C. A modified pseudo first order model based on the film theory is used to predict the rate of absorption of CO2 into mixed amine solutions. This model accounts for the variation of amine concentration in the film and assumes a shuttle mechanism for rate enhancement. Bulk liquid concentrations of the various species present are obtained from a simplified thermodynamic model. The model predicts absorption rates that are in agreement with experimental measurements. 相似文献