Nd:YAG陶瓷的烧结性能研究

采用注浆成型和真空烧结制备了Nd:YAG激光透明陶瓷,研究了烧结温度和时间对致密化过程的影响。研究结果表明:在1050~1300℃之间坯体发生明显的收缩生成YAM和YAP相;在1300~1420℃,生成YAG相。随着烧结温度的增加,陶瓷中气孔含量减少,晶粒尺寸长大。在1700~1800℃烧结20h能够获得完全致密的Nd:YAG陶瓷样品。     

Nd:YAG激光透明陶瓷超细粉体的合成及其性能表征

以Al(NO3)3·9H2O和Y2O3为原料,按YAG化学计量比配成相应的硝酸盐混合液,并用一定量的Nd取代Y,加入尿素沉淀剂,利用无机体系均相沉淀法制备了YAG前驱体。对前驱体进行适当处理,并采用高温热解法在1200℃时制备出Nd∶YAG透明陶瓷超细粉体。通过对粉体样品进行XRD,TG DTA,SEM和红外光谱分析表明,所合成的YAG超细粉为立方晶系石榴石结构,晶格常数a=12.01nm。粉体样品颗粒度小、粒径均匀、流动性好,粒径在150～200nm之间。     

Optimization of Diode-Pumped Continuous-Wave Tape-Casting YAG/Nd:YAG/YAG-Ceramic Lasers

We demonstrate a diode-laser-pumped solid-state 1.06 μm laser using a novel YAG/Nd:YAG/YAG composite ceramics with a sandwich structure. We optimize the laser performance using different output couplers, pumping beam waists, and cavity lengths. A maximum CW output power of 11 W for the YAG/Nd:YAG/YAG-ceramic laser is obtained at an absorbed pump power of 25 W resulting in a slope efficiency of 49.4%. The excellent output performance shows that the novel YAG/Nd:YAG/YAGceramic material has a great potential in applications with diode-laser pumping.     

High-peak power,passively Q-switched,composite, all-poly-crystalline ceramics Nd:YAG/Cr<Superscript>4+</Superscript>:YAG laser and generation of 532-nm green light

Output performances of passively Q-switched, composite Nd:YAG/Cr⁴⁺:YAG lasers that consisted of bonded, all-poly-crystalline ceramics Nd:YAG and Cr⁴⁺:YAG are reported. Laser pulses at 1.06 μm with 2.5-mJ energy and 1.9-MW peak power are obtained from a 1.1-at % Nd:YAG/Cr⁴⁺:YAG ceramics that was quasi-continuous-wave (quasi-CW) pumped with a diode laser. Single-pass frequency doubling with LiB₃O₅ (LBO) nonlinear crystal at room temperature yielded green laser pulses at 532 nm of 0.36-mJ energy and 0.3-MW peak power, with a conversion efficiency of 0.27.     

Preparation and characterization of transparent Nd:YAG ceramics

Transparent Nd:YAG ceramics were produced by solid.state reaction of high.purity (4N) nanometric oxides powders, i.e., Al₂O₃, Y₂O₃ and Nd₂O₃. After sintering, mean grain sizes of 2% Nd:YAG samples were about 20 μm and their transparency were a bit worse than that of 0.9% Nd:YAG single crystal. Two types of active elements: rods and slabs were fabricated and characterized in several diode pumping schemes. In end pumping configuration as a pump source 20.W fiber coupled laser diode operating in low duty cycle regime (1 ms pump duration/20 Hz) was deployed. In the best case, 3.7 W of output power for 18 W of absorbed pump power, M² < 1.4 were demonstrated for uncoated ceramics Nd:YAG rod of ϕ 4×3mm size in preliminary experiments. For the ceramics of two times lower Nd dopant level above 30% slope efficiency was achieved. In case of Nd:YAG ceramic slab side pumped by 600.W laser diode stack above 12 W was demonstrated with slope efficiency of 3.5%.     

Thermal-birefringence-induced depolarization in Nd:YAG ceramics

The thermal-birefringence effect in Nd(3+) -doped YAG ceramics has been investigated. The amount of depolarization induced by thermal birefringence in Nd:YAG ceramics is nearly the same as that in (111)-cut single crystals at the same Nd(3+) concentration. However, depolarization becomes larger as the Nd(3+) concentration increases, even at the same absorbed pump power.     

Optical properties and highly efficient laser oscillation of Nd:YAG ceramics

Optical absorption, emission spectra have been measured for polycrystalline Nd-doped Y₃Al₅O₁₂ ceramics. Fluorescence lifetimes of 257.6 μs, 237.6 μs, 184.2 μs and 95.6 μs have been obtained for 0.6%, 1%, 2% and 4% neodymium-doped YAG ceramics, respectively. For the first time, highly efficient laser oscillation at 1064 nm has been obtained with this kind of ceramics. Slope efficiency of 53% has been achieved on a uncoated 4.8-mm thick 1% Nd:YAG ceramics sample. Optical to optical conversion efficiency is 47.6%. Laser oscillation has also been obtained with a 2% Nd:YAG ceramics. The optical properties and laser output results have been compared with that of Nd:YAG single crystal grown by the Czochralski method. Almost identical results have been achieved including laser experiments results. But fabrication of Nd:YAG ceramics is much easier compared to the single-crystal growth method. And also large size (now of about 400 mm diameter×5 mm is available) and high-concentration (>1%) Nd:YAG ceramics can be fabricated. The results show that this kind of Nd:YAG ceramics is a very good alternative to Nd:YAG single crystal. Received: 20 April 2000 / Published online: 16 August 2000     

Temperature characteristics of small signal gain for Nd/Cr:YAG ceramic lasers

Thermal dependence on the small signal gain of Nd/Cr:YAG (yttrium aluminum garnet) ceramics was observed experimentally. Usually, Nd:YAG crystal and ceramics have remarkable gain reduction when optical pumping is performed and the temperature of the laser media is upped to 373 K. A CW laser light generated in a 1064 nm Nd:YAG laser oscillator was amplified by Nd/Cr:YAG ceramic amplifier, and the output power was measured at non-saturation level. Laser small signal gain of the ceramic disk was kept to 470 K. This property was remarkably different from one of Nd:YAG crystals or ceramics. The peak shift of the fluorescence was observed experimentally when the temperature is high.     

Thermoexoelectronic and thermoluminescent properties of transparent YAG:Nd and YAG:Yb nanoceramics

Preliminary investigations of thermoluminescent and thermoexoelectronic properties of transparent microstructured YAG:Nd and YAG:Yb ceramics are performed. Five peaks of thermostimulated luminescence are found for YAG:Nd in the VUV and UV ranges. Four and six peaks of thermostimulated exoemission are found for YAG:Yb and YAG:Nd, respectively. The parameters of carrier traps are calculated.     

High power and highly efficient Nd:YAG laser emitting at 1123 nm

A diode-end-pumped continuous-wave (CW) Nd:YAG laser emitting at 1123 nm is realized efficiently in a 25-mm-long cavity. A composite Nd:YAG (cNd:YAG) crystal is selected as the gain medium. With an incident diode power of 26.1 W, an output power of up to 9.3 W is obtained, corresponding to an optical-to-optical conversion efficiency of 35.6%. The laser performances at 1123 nm are compared between composite Nd:YAG and common Nd:YAG crystals. The results show that composite Nd:YAG is a better choice for 1123-nm laser generations.     

120 watt continuous wave solar-pumped laser with a liquid light-guide lens and an Nd:YAG rod

We propose a simple and efficient pumping approach for a high-power solar-pumped laser by using a liquid light-guide lens (LLGL) and a hybrid pumping cavity. A 2×2 m Fresnel lens is used as a primary concentrator to collect natural sunlight; 120 W cw laser power and a 4.3% total slope efficiency are achieved with a 6-mm diameter Nd:YAG rod within a 14-mm diameter LLGL. The corresponded collection efficiency is 30.0 W/m(2), which is 1.5 times larger than the previous record. This result is unexpectedly better than that of Cr:Nd:YAG ceramics. It is because the scattering coefficient of Cr:Nd:YAG ceramics is 0.004cm(1), which is 2 times larger than that of the Nd:YAG crystal, although both have similar saturation gains.     

Compact corner-pumped Nd:YAG/YAG composite slab laser

Corner-pumping is a new pumping scheme in diode-pumped all-solid-state lasers, having such advantages as high pump efficiency, favorable pump uniformity and low cost. Compact corner-pumped Nd:YAG/YAG composite slab lasers at 1064 nm with low or medium output powers and high efficiency are demonstrated in this paper. Combined with intracavity frequency doubling by a LBO crystal, a corner-pumped Nd:YAG/YAG composite slab 532 nm green laser with a stable output is realized successfully. The experimental results show that corner-pumping can reduce laser costs greatly, release the thermal effects of slab crystals and improve the output beam quality, and that the new pumping scheme is feasible in the design of diode-pumped all-solid-state lasers with low or medium output powers.     

Comparative investigation of spectroscopic and laser emission characteristics under direct 885-nm pump of concentrated Nd:YAG ceramics and crystals

A high-resolution spectroscopic and emission-decay investigation of highly concentrated Nd:YAG single crystals and ceramics shows that the state of the Nd³⁺ ions and their interaction in these materials are similar and can be used for construction of efficient solid-state lasers directly pumped in the emitting level. This possibility is demonstrated by continuous-wave emission of concentrated Nd:YAG crystals with up to 3.5 at. % Nd and ceramics with up to 6.8 at. % Nd under resonant 885-nm end pump. Received: 28 May 2001 / Final version: 17 August 2001 / Published online: 10 October 2001     

Optimization of Yb:YAG/Cr<Superscript>4+</Superscript>:YAG composite ceramics passively Q-switched microchip lasers

The laser characteristics of laser-diode end-pumped Yb:YAG/Cr⁴⁺:YAG composite ceramics microchip passively Q-switched lasers were studied by solving the coupled rate equations numerically taking into account the reabsorption of Yb:YAG ceramics at laser wavelength. Effects of the reflectivity of the output coupler, the concentrations and thickness of the saturable absorbers, and pump beam area on the laser performance were investigated analytically. The simulation results of the Yb:YAG/Cr⁴⁺:YAG composite ceramics passively Q-switched microchip lasers were in good agreement with the experimental data. Better laser performance (high peak power, short pulse width and good optical-to-optical efficiency) of the composite Yb:YAG/Cr⁴⁺:YAG ceramics passively Q-switched laser can be obtained by using a thin Cr⁴⁺:YAG ceramic with high concentration, suitable reflectivity of the output coupler and proper pump beam diameter under high pump power intensity according to our simulations.     

Continuous-wave, 15.2 W diode-end-pumped Nd:YAG laser operating at 946 nm

A high-power continuous-wave (cw) Nd:YAG laser operating at 946 nm by utilizing a quasi-three-level transition is reported. The laser consists of a composite Nd:YAG rod end pumped by a fiber-coupled diode laser and a simple plane-concave cavity. At an incident pump power of 40.2 W, a maximum cw output of 15.2 W at 946 nm is obtained, achieving a slope efficiency of 45%. To the best of our knowledge, this is the highest output at 946 nm ever generated by diode-pumped Nd:YAG lasers. In addition, at an incident pump power of 15.2 W, a 1.25 W blue output at 473 nm is achieved with a simple compact three-element cavity and a type-I lithium triborate (LiB(3)O(5)) crystal as a frequency doubler.     

Fabrication and laser performance of highly transparent Nd:YAG ceramics from well-dispersed Nd:Y<Subscript>2</Subscript>O<Subscript>3</Subscript> nanopowders by freeze-drying

Well-dispersed Nd:Y₂O₃ powders with uniform particle size of about 60 nm were synthesized from freeze-dried precursors. Highly transparent 2 at.% Nd:YAG ceramics were fabricated from the as-synthesized Nd:Y₂O₃ powders and commercial Al₂O₃ powders by vacuum sintering at 1,750 °C for 5 h. Phase evolution, microstructures, and spectroscopic properties of the Nd:YAG transparent ceramics were investigated. Freeze-drying played an important role in the synthesis of high-quality Nd:Y₂O₃ nanosized powders, which were essential for the fabrication of highly transparent Nd:YAG ceramics. Optical transmittance of a 3-mm thick sample reached 82% in the wavelength range of 200–900 nm. 5.23 W output power was obtained with 14.3 W diode laser pumping, giving a slope efficiency of 36.5%.     

Laser pulses amplified by Nd/Cr:YAG ceramic amplifier using lamp and solar light sources

Laser pulses generated in a laser oscillator were amplified by Nd/Cr:YAG ceramic amplifiers. The saturation of output-laser energy was experimentally observed. We found that the stimulated emission cross-section of Nd/Cr:YAG ceramics was effectively increased and the saturation fluence was effectively reduced to 0.1 J/cm² due to the energy transfer between excited Cr and Nd ions. The output-laser energy we calculated was compared with the experimental ones and the extractable stored energy in the Nd/Cr:YAG ceramics was evaluated. This laser material is suitable for high-repetition-rate operations because of the high laser gain with low pumping intensity and low effective saturation fluence.     

Laser-diode pumped self-Q-switched microchip lasers

Optical properties of Cr,Yb:YAG, Cr,Nd:YAG crystals, and composite Yb:YAG/Cr:YAG ceramics self-Q-switched solid-state laser materials are presented. The merits of these self-Q-switched laser materials are given and the potentials of such lasers can be chosen by the applications. Cr,Yb:YAG and composite Yb:YAG/Cr:YAG ceramics self-Q-switched laser are conducted. Although several tens of kW peak power can be obtained with a monolithic microchip Cr,Yb:YAG laser, the experimental results show that the performance of this laser is limited by the absorption of Cr⁴⁺ ions at a pump wavelength of 940 nm and strong fluorescence quenching at high Cr concentration. Composite Yb:YAG/Cr:YAG ceramics are more suitable to realize high pulse energy and peak power (up to MW level) with optimized lasing and Q-switching parts. In addition, the instabilities induced by the multi-longitudinal mode competition in Cr,Nd:YAG and Cr,Yb:YAG microchip lasers are addressed. The different gain bandwidths of Yb:YAG and Nd:YAG play an important role in the instability of the output laser pulse trains. Stable laser pulses from the Cr,Yb:YAG microchip laser were obtained due to the antiphase dynamics. For the Cr,Nd:YAG microchip laser, the instability caused by the multi-longitudinal mode competition is an intrinsic property. Different transverse patterns were observed in Cr,Nd:YAG microchip lasers when a pump beam with larger diameter was used. Saturated inversion population distribution inside the gain medium plays an important role in the transverse pattern formation. Different transverse patterns were reconstructed by combining different sets of the Hermite-Gaussian modes.     

High-power and high optical conversion efficiency diode-end-pumped laser with multi-segmented Nd:YAG/Nd:YVO_4

A novel flat-flat resonator consisting of two crystals(Nd:YAG + Nd:YVO_4) is established for power scaling in a diode-end-pumped solid-state laser. We systematically compare laser characteristics between multi-segmented(Nd:YAG + Nd:YVO_4) and conventional composite(Nd:YAG + Nd:YAG) crystals to demonstrate the feasibility of spectral line matching for output power scale-up in end-pumped lasers. A maximum continuous-wave output power of 79.2 W is reported at 1064 nm, with M_x~2= 4.82, M_y~2= 5.48, and a pumping power of 136 W in the multi-segmented crystals(Nd:YAG + Nd:YVO_4). Compared to conventional composite crystals(Nd:YAG + Nd:YAG), the optical-optical conversion efficiency of multi-segmented crystals(Nd:YAG + Nd:YVO4) from 808 nm to 1064 nm is enhanced from 30% to 58.8%,while the laser output sensitivity as affected by the diode-laser temperature is reduced from 55% to 9%.     

A diode side-pumped YAG/Nd:YAG/YAG composite crystal laser

A diode-bar side-pumped YAG/Nd:YAG/YAG composite crystal laser is presented. A maximum output power of 18.4 W at 1.064 μm with a slop efficiency of 57% and an optical-optical conversion efficiency of 46% was obtained for a pump power of 40 W. Compared with a side-pumped conventional crystal laser in the same experimental conditions, the side-pumped composite crystal laser improved the optical-to-optical conversion efficiency by 12%. Experimental results indicate that a composite crystal can depress the thermal effects effectively and improve the optical-to-optical conversion efficiency easily in the diode side-pumped lasers. The composite crystal has great potential in high-power diode side-pumped lasers.