A /O泳动床反应器脱氮性能研究

基于A/O工艺与泳动床工艺技术的联合,开发出A/O泳动床生物膜反应器.A/O泳动床系统表现出高效去除COD_(Cr)、NH_3-N和TN以及较好的抗负荷冲击能力.在HRT=12.5 h,回流比为300%,进水COD_(Cr)、NH_3-N平均浓度分别为343.4 mg/L、94.1 mg/L时,COD_(Cr)和NH3-N平均去除率分别为84.6%, 86.8%;COD_(Cr)的容积负荷与去除负荷现良好的线性关系,R~2=0.970 4;系统在较低的C/N下,TN平均去除率为70.8%.     

A/O-MBR处理高浓度氨氮农药废水的试验研究

试验采用了缺氧-好氧一体式膜生物反应器(A/O-MBR)工艺处理高浓度氨氮农药废水。经过120d左右的运行,试验结果表明:在一定DO、pH和温度条件下,进水COD为230~523mg/L,氨氮进水容积负荷在1.5kgNH3-N/(m3·d)以下时,系统逐渐取得良好的出水效果,COD、氨氮、总氮去除率平均分别为86%、91.58%、48%。而且MBR出水浊度0.2NTU、SS3mg/L,间歇抽吸、曝气冲刷以及填料的加入减缓了膜污染,保证系统可持续运行。     

不同填料强化生态浮床对淡水养殖水体的净化效果

人工填料强化生态浮床是近年来发展起来的一种新兴生态工程修复技术。选取3种不同类型的人工填料与挺水植物组合,分析其对高磷浓度养殖水体和上海市养殖池塘水体的净化效果。结果表明,在高磷浓度(2.36~3.42 mg/L)养殖水体中,人工填料强化生态浮床对TN、TP、COD的平均去除率分别为34.9%,12.2%,26.1%,且3组系统之间差异不明显。在上海市养殖水体平均浓度条件下,3组系统对TN和TP的去除能力为:立体弹性填料强化生态浮床＞组合填料强化生态浮床＞生物绳填料强化生态浮床,立体弹性填料强化生态浮床对TN和TP的去除率分别为83.9%和69.3%;3组系统对COD和NH₄⁺-N的去除率均在70%以上。因此,立体弹性填料强化生态浮床可以考虑应用于上海市淡水养殖池塘水体的生态修复工程。     

改进型合并净化槽处理生活污水的影响因素

通过设置改性复合填料和微电解铁屑床对合并净化槽进行工艺改进,采用厌氧(缺氧)好氧(A2/O)工艺处理生活污水。为优化该装置处理生活污水的效果,分别选取水力停留时间、有机负荷、污泥回流比作为运行条件进行试验室中试研究。结合试验结果和经济效益,得出最佳运行条件:水体停留时间为8 h,此时系统对COD、TN和TP的去除率分别为95%、63%8、7%;COD有机负荷为2.7 g/(L.d),该条件下出水COD、TN和TP平均去除率分别可达到90%、74%、88%;污泥回流比为75%,此时净化槽出水COD、TN和TP平均去除率分别达到95%、70%、94%。     

不同生物膜载体净化微污染水挂膜及处理效果研究

采用生物接触氧化工艺,选择生物绳填料、组合填料及弹性填料进行对比试验,在HRT分别为24h、16h和12h的条件下运行生物反应器。对挂膜阶段及稳定运行阶段COD、NH_3-N、TN和TP的去除情况进行测定及分析。结果表明:30天内3种生物膜载体均可挂膜成功且对微污染水体有显著净化作用,改变HRT对COD、NH_3-N、TN和TP的去除效果影响不大。生物绳填料在曝气/停曝时间比为6h∶6h,曝气量为250L/h,HRT为24h的条件下,对COD、NH_3-N、TN和TP的平均去除率分别为75.87%、76.05%、37.1%和25.41%。     

污水二级处理出水深度处理的试验研究

本文对曝气生物滤池用于城市污水和工业废水的深度处理进行了试验研究。分析了曝气生物滤池、纤维球过滤作为主体工艺对城市污水二级处理厂出水进行深度处理的工艺可行性 ;研究了曝气生物滤池的运行特性 ;考察了采用曝气生物滤池、纤维过滤、活性炭吸附、微滤以及反渗透工艺对工业废水二级出水进行深度处理后回用于循环冷却水系统补水的可行性和可靠性。试验结果表明 :①曝气生物滤池对二级处理后的城市污水 (试验Ⅰ )和工业废水 (试验Ⅱ )中COD的去除率分别为2 5 1%和 5 5 6 % ,出水COD浓度为 33mg/L和 33 6mg/L ,对BOD均有 70 %以上的去除率 ,并且对SS及浊度、氨氮均有很高的去除率 ;②曝气生物滤池对SS与浊度的去除率随进水滤速升高呈直线下降趋势 ,而对COD的去除率在某一个滤速范围内达到最高 ,此时滤池内有机负荷为 1～ 1 5kg COD/ (m3 ·d) ,有效水力停留时间为 1～ 1 5h ;③曝气生物滤池中的溶解氧浓度随填料层增高呈线性增加的趋势 ,COD的去除率沿填料层高度变化为非线性的 ,在试验Ⅰ中 1 5～2m之间的填料层内对COD的去除率最高 ;④根据COD和SS去除率的变化判断反冲洗的周期 ,采用气水联合的方式对曝气生物滤池进行反冲洗 ,反冲洗后曝气生物滤池需要一定的时间才能恢复对污染物的去除能力 ,试     

固定化生物流化床处理尿素厂废水的中试研究

采用O/A/O/A(好氧/缺氧/好氧/缺氧)工艺的固定化生物流化床处理技术,对尿素厂的氨氮废水(NH3-N50~500mg/L)进行了现场中试试验研究。试验结果表明该技术处理尿素厂废水效率高,效果好,费用低;当水力停留时间平均为21h时,出水TN平均浓度为26.63mg/L,去除率为90%,出水NH3-N平均浓度为6.51mg/L,去除率可达96%。     

分置式膜-生物反应器处理染料废水的试验研究

对分置式膜—生物反应器处理染料废水进行了研究,进水COD为 350～400mg/L,出水为30～70mg/L,COD去除率约85％,膜的截留去除COD约占10％。TOC去除率为85％～90％,色度去除率约为70%,膜生物反应器中的活性污泥的粒径范围为1～100μm,平均粒径40μm,酶的含量为7.95mgTTC/gVSS。     

水解-混凝-复合生物池工艺处理印染废水的工程应用

采用水解 混凝 复合生物池组合工艺处理印染废水的运行结果表明 ,在进水平均COD15 6 4mg/L ,BOD 4 75mg/L ,色度 5 0 0倍的条件下 ,上述各项指标去除率分别为 90 5 % ,96 6 % ,90 % ,出水满足污水综合排放标准     

曝气生物滤池处理医院污水试验研究

利用曝气生物滤池对某医院污水进行了处理试验研究。试验结果表明 ,该工艺用于医院污水处理具有运行稳定可靠、出水水质好的特点。在进水COD <2 30mg/L ,NH3-N <2 5mg/L ,有机负荷小于 8kg/ (m3·d)的条件下 ,出水COD <76mg/L,NH3-N <10mg/L;在有机负荷小于4kg/ (m3·d)时 ,出水COD <5 0mg/L ,NH3-N <5mg/L。     

Enhanced removal of chemical oxygen demand, nitrogen and phosphorus using the ameliorative anoxic/anaerobic/oxic process and micro-electrolysis

Synthetic wastewater was treated using a novel system integrating the reversed anoxic/anaerobic/oxic (RAAO) process, a micro-electrolysis (ME) bed and complex biological media. The system showed superior chemical oxygen demand (COD), total nitrogen (TN) and total phosphorus (TP) removal rates. Performance of the system was optimised by considering the influences of three major controlling factors, namely, hydraulic retention time (HRT), organic loading rate (OLR) and mixed liquor recirculation (MLR). TP removal efficiencies were 69, 87, 87 and 83% under the HRTs of 4, 8, 12 and 16 h. In contrast, HRT had negligible effects on the COD and TN removal efficiencies. COD, TN and TP removal efficiencies from synthetic wastewater were 95, 63 and 87%, respectively, at an OLR of 1.9 g/(L·d). The concentrations of COD, TN and TP in the effluent were less than 50, 15 and 1 mg/L, respectively, at the controlled MLR range of 75-100%. In this system, organics, TN and TP were primarily removed from anoxic tank regardless of the operational conditions.     

改进型移动床生物膜反应器处理有机废水的试验

改进型移动床生物膜反应器(CMCBR)是在普通移动床生物膜反应器中引入导流板,使填料在全池循环移动,消除了普通移动床生物膜反应器的死角。在CMCBR处理模拟生活污水的试验中,研究了有机物的去除效果,考察了容积负荷、水力停留时间、冲击负荷等参数对处理效果的影响。试验发现,在填料填充比例为50%(体积比),进水COD质量浓度为320~550mg/L,水力停留时间为3 h的条件下,出水COD质量浓度小于100 mg/L,达到国家污水综合排放标准的一级标准。反应器具有较强的抗冲击负荷能力,出水水质稳定。     

Treatment of landfill leachate by a pilot-scale modified Ludzack-Ettinger and sulfur-utilizing denitrification process.

Nitrogen removal efficiency of a pilot-scale system consisted of Modified Ludzack-Ettinger (MLE) followed by sulfur-utilizing denitrification (SUDNR) process was evaluated with a landfill leachate. For SUDNR, a down-flow mode sulfur packed bed reactor (SPBR) filled with sulfur and limestone particles was used. Although total nitrogen removal efficiency of the MLE process was about 80% at the recycle ratio of 4, effluent contained 350-450 mg/L NO(3-)-N. Up to a loading rate of 1.2 kg NO(3-)-N/m3-day, the SPBR could achieve complete removal of nitrate, and nitrate removal rate was kept to that level even at higher loading rate. When a COD/N ratio of MLE process was maintained at 2 instead of 4, more organics with molecular weight less than 500 were utilized for heterotrophic denitrification although denitrification was not complete with the lack of electron donors. Clogging in the SPBR, mainly by the accumulation of nitrogen gas in the pores, could easily be removed by introducing the effluent in an upward direction for 1 min at 1 hr intervals. The proposed treatment system could achieve nitrate free effluent with a slight increase in chemical cost. Furthermore, depending on further COD removal requirement after biological treatment, the proposed treatment system can be an economical solution.     

土壤过滤系统处理农村生活污水的 试验研究

采用一种土壤过滤系统处理农村生活污水,考察了该工艺对CODCr、BOD5、NH3-N、全氮（TN）和全磷（TP）的去除效果。实验结果表明,当水力负荷约为0.05 m3/（m2·d）, 水力停留时间为3 d时。该土壤过滤系统对CODCr、BOD5、NH3-N、全氮（TN）和全磷（TP）的去除效果较好,平均去除率分别达到84.6%、83.3%、64.3%、59.8%和70%。出水CODCr约为18.3~42.1 mg/L,BOD5约为8.9~17.3 mg/L,NH3-N约为11.2~17.7 mg/L,TN约为21.2~31.3 mg/L,TP小于2.0 mg/L,出水水质优于农田灌溉水质标准（GB 5084—2005）。气温变化和进水污染物浓度对处理效果影响明显。总体上来讲,温度大于22 ℃时,进水污染物浓度越低处理效果越好。     

深度处理维生素制药废水的中试研究

维生素制药废水经过初步生化处理后,出水水质无法满足要求,具有难降解、COD和氨氮浓度高的特点,针对这些特点,本文采用"强化复合曝气水解酸化→高效厌氧复合反应→流离生物接触氧化"连续工艺深度处理维生素制药废水,研究其可行性。处理规模为7.2 m3/d的中型试验结果表明:强化复合曝气水解酸化能使进水B/C值由0.33提高到0.48,提高下一步生化反应的处理效率,当进水CODCr的浓度为150～641 mg/L,氨氮浓度为6～115 mg/L时,平均去除率分别达到84.28%、93.8%,出水COD浓度小于50mg/L,氨氮浓度小于5 mg/L,出水水质能够达到《城镇污水处理厂污染物排放标准》GB18918-2002中的一级A指标,该连续工艺深度处理此类废水具有可行性和稳定性。     

Increasing the capacity for treatment of chemical plant wastewater by replacing existing suspended carrier media with Kaldnes Moving Bed media at a plant in Singapore.

The Kaldnes biomedia K1, which is used in the patented Kaldnes Moving Bed biofilm process, has been tested along with other types of biofilm carriers for biological pretreatment of a complex chemical industry wastewater. The main objective of the test was to find a biofilm carrier that could replace the existing suspended carrier media and at the same time increase the capacity of the existing roughing filter-activated sludge plant by 20% or more. At volumetric organic loads of 7.1 kg COD/m3/d the Kaldnes Moving Bed process achieved much higher removal rates and much lower effluent concentrations than roughing filters using other carriers. The Kaldnes roughing stage achieved more than 85% removal of organic carbon and more than 90% removal of BOD5 at the tested organic load, which was equivalent to a specific biofilm surface area load of 24 g COD/m2/d. Even for the combined roughing filter-activated sludge process, the Kaldnes carriers outperformed the other carriers, with 98% removal of organic carbon and 99.6% removal of BOD5. The Kaldnes train final effluent concentrations were only 22 mg FOC/L and 7 mg BOD5/L. Based on the successful pilot testing, the full-scale plant was upgraded with Kaldnes Moving Bed roughing filters. During normal operation the upgraded plant has easily met the discharge limits of 100 mg COD/L and 50 mg SS/L. For the month of September 2002, with organic loads between 100 and 115% of the design load for the second half of the month, average effluent concentrations were as low as 9 mg FOC/L, 51 mg COD/L and 12 mg SS/L.     

Two-stage entrapped mixed microbial cell process for simultaneous removal of organics and nitrogen for rural domestic sewage application.

A two-stage entrapped mixed microbial cell ((2S)EMMC) process which separates nitrification and denitrification phases by the installation of the anoxic and oxic EMMC reactors packed with EMMC carriers was operated with 6, 4, 3, and 2 hours of hydraulic retention time (HRT) using simulated domestic wastewater. The activated sludge was immobilized using cellulose acetate for the EMMC carriers. Similar soluble chemical oxygen demand (SCOD) removal efficiencies of 90-97% were observed for all HRTs (SCOD loading rate of 0.84-2.30 g/L/d) applied. In order to achieve more than 80% of TN removal efficiency, the HRT should be maintained higher than 4 hours (less than 0.24 g/L/d of TN loading rate). Denitrification was a rate-limiting step which controlled overall TN removal efficiency at TN loading rate of 0.15-0.31 g/L/d although nitrification efficiencies achieved 97-99%. The effluent TSS of less than 25 mg/L in the (2S)EMMC process was maintained at the SCOD loading rate of less than 1.23 g/L/d with back-washing intervals of 5 and 10 days in the anoxic and oxic EMMC reactors, respectively. The minimum HRT of 4 hours is required for high removal efficiencies of organics (average 95.6%) and nitrogen (average 80.5%) in the (2S)EMMC process with 3 times of recirculation ratio.     

移动式污水处理系统应用于分散生活污水的试验研究

针对分散型生活污水量小面广的特点,开发出移动式污水处理系统,系统由生化预处理池和车载式移动污水处理设备组成.中试结果表明,采用该组合工艺,出水CODCr＜40 mg/L,BOD5＜10 mg/L,TP＜0.5 mg/L,TN＜10 mg/L,NH3-N＜1 mg/L,其平均去除率分别达到86.69%,94.89%,89.40%,74.35%和97.89%.出水指标均能达到＜城镇污水处理厂污染物排放标准＞(GB 18918-2002)一级A排放标准.     

Combined chemical biological treatment of bleached eucalypt kraft pulp mill effluent.

Effectiveness of ozonation before and after biological treatment for removal of recalcitrant organic matter in bleached kraft pulp effluents was compared. Two industrial ECF bleached eucalypt kraft pulp effluents (E1 and E2) were pretreated with 100 mg O3/L. Raw and pretreated effluents were treated biologically in bench-scale sequencing batch reactors, under constant conditions. Following biological treatment, effluents were post-treated with 100 and 200 mg O3/L. Effluent pretreatment increased effluent biodegradability by 10% in E1 and 24% in E2. Combined O3-biological treated led to small but significant increases in COD, BOD and lignin removal over biological treatment alone, but pretreatment had no significant effect on effluent colour and carbohydrate removal. Ozone pretreatment did not affect biological activity during treatment of effluent E1 but resulted in a 38% lower specific oxygen uptake rate in effluent E2. At an equivalent dose of 100 mg/L, pre-ozonation produced better quality effluent than post-ozonation, especially with regard to COD and colour. Likewise, when an equivalent dose of 200 mg/L was applied, splitting the dose equally between pre- and post-treatments was more efficient than applying the entire dose in the post-treatment. The potential for combined chemical-biological treatment to improve effluent quality has been confirmed in this study.