共查询到20条相似文献,搜索用时 15 毫秒
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Takayuki Suehiro Naoto Hirosaki Ryo Terao Junichi Tatami Takeshi Meguro Katsutoshi Komeya 《Journal of the American Ceramic Society》2003,86(6):1046-1048
Aluminum nitride (AlN) nanopowder was successfully synthesized from transition alumina nanopowder using an NH3 –C3 H8 gas mixture as a reduction–nitridation agent. Phase-pure, nanocrystalline AlN powder with a specific surface area of 36.4 m2 /g and a mean particle size of 51 nm was prepared under typical reaction conditions. The resulting AlN nanopowders possessed excellent sinterability, allowing full densification in conventional processing, even without the addition of sintering aids. 相似文献
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YU Renhong FU Yadong ZHANG Mengmeng WANG Lizhi HONG Quanquan ZHANG Ruohua High Temperature Materials Institute Henan University of Science Technology Luoyang China 《中国耐火材料》2011,(1)
Carbothermal reduction and nitridation(CRN)of zircon(ZrSiO4)permits obtaining different composites of oxides and nitrides such as ZrO2-Si2N2O and ZrN-Si3N4.The effects of technological parameters(carbon source,reaction temperature,and carbon content)on the reaction rate and product phase composition of CRN of zircon were investigated by TGA and XRD.The results show that:(1)carbon source is an important factor for a rapid reaction,and activated carbon is chosen as the carbon source considering the expect pro... 相似文献
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Edwin Kroke Lars Loeffler Fred F. Lange Ralf Riedel 《Journal of the American Ceramic Society》2002,85(12):3117-3119
Aluminum nitride (AlN) powders were prepared from the oxide precursors aluminum nitrate, aluminum hydroxide, aluminum 2-ethyl-hexanoate, and aluminum isopropoxide (i.e., Al(NO3 )3 , Al(OH)3 , Al(OH)(O2 CCH(C2 H5 )(C4 H9 ))2 , and Al(OCH(CH3 )2 )3 ). Pyrolyses were performed in flowing dry NH3 and N2 at 1000°–1500°C. For comparison, the nitride precursors aluminum dimethylamide (Al(N(CH3 )2 )3 ) and aluminum trimethylamino alane (AlH3 ·N(CH3 )3 ) were exposed to the same nitridation conditions. Products were investigated using XRD, TEM, EDX, SEM, and elemental analysis. The results showed that nitridation was primarily controlled by the water:ammonia ratio in the atmosphere. Single-phase AlN powders were obtained from all oxide precursors. Complete nitridation was not obtained using pure N2 , even for the non-oxide precursors. 相似文献
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The ZrN–SiAlON composite refractory powder was successfully synthesised from zircon and bauxite minerals by the carbothermal reduction nitridation or the aluminothermic reduction nitridation method with three typical reducers, including carbon coke, carbon black and aluminium powder. The effect of reaction temperatures on phase composition and microstructure was investigated using X-ray diffraction and a scanning electron microscopy (SEM), respectively. The thermodynamics equilibrium relationships of the condensed phases were analysed as well. The results showed that carbon coke was the most optimum reducer and when it was used as the reducer, the main final products were granular ZrN with a little β-SiAlON. Nevertheless, ZrO2 was produced during reduction at 1600°C when the reducer was carbon black, because the activity of carbon black was the poorest. Additionally, more byproducts were produced in the case of Al powder used as reducer at 1600°C, such as AlN polytype and Al2O3. 相似文献
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Adam J. Parkison Stephen S. Parker Andrew T. Nelson 《Journal of the American Ceramic Society》2016,99(12):3909-3914
A carbothermic reduction to nitridation process was developed which is capable of producing high‐purity thorium mononitride (ThN) in bulk quantities. This was accomplished through study of three distinct processing routes using thermogravimetric analysis. The information gathered was then used to guide development of a draft process, which was tested within a tungsten production furnace. Scaling issues were identified and corrected following the draft process. Finally, a partitioned process was developed in response to the draft process which separates the reduction from the nitridation and carbon cleanup steps. This partitioned process was demonstrated to be capable of producing phase‐pure ThN, with oxygen and carbon impurities of 990 ± 130 wppm and 240 ± 30 wppm, respectively. 相似文献
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首先,以四氯化钛为原料,异丙醚为氧供体,二氯甲烷为溶剂,采用非水解溶胶凝胶法合成高活性的TiO2凝胶;其次以其为钛源,选用分子量为1300000的聚乙烯吡咯烷酮为碳源,采用碳热还原氮化法合成TiN粉体。X射线衍射仪、场发射扫描电镜和激光粒度仪测试结果表明,与水解法相比,采用非水解法合成的TiO2凝胶经800℃煅烧0.5h仍为活性较高的锐钛矿相,以该凝胶为钛源,经1200℃碳热还原氮化2h可合成纯度相对较高的TiN粉体,将合成温度升至1300℃还原氮化5h可合成更高纯度的TiN粉体。TiN粉体颗粒呈近似球形,发育较好,粒径在1μm以下,激光粒度测定粒径主要集中在10μm左右,d50为8μm。 相似文献
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ZHANGHaijun LIUZhanjie ZHONGXiangchong 《中国耐火材料》2004,13(4):8-12
The phase composition and microstructure of Sialon prepared from Chinese bauxite have been studied. The use of Si powder is more effective than that of activated carbon for reduction-nitridation. For bauxite specimens with 40~50% Si addition, more than 90% of Sialon may be obtained when nitrided at 1450~1500℃ ; the main crystalline phase is O‘-Sialon ( Z =0.2). 相似文献
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Guo-Jun Zhang Jian-Feng Yang Motohide Ando Tatsuki Ohji 《Journal of the American Ceramic Society》2002,85(12):2938-2944
Aluminum nitride–boron nitride (AlN–BN) composites were prepared based on the nitridation of aluminum boride (AlB2 ). AlN powder was added to change the BN volume fraction in the obtained composites. Thermogravimetry–differential thermal analysis (TG-DTA), X-ray diffractometry, and the nitridation ratio were used to investigate the nitridation process of AlB2 . At ∼1000°C, a sharp exothermic peak occurred in the DTA curve, corresponding to the rapid nitridation of aluminum in AlB2 . On the other hand, the nitridation of the transient phase, Al1.67 B22 , was very slow when the temperature was <1400°C. However, the nitridation speed obviously accelerated at temperatures >1600°C. The pressure of the nitrogen atmosphere was also an important factor; high nitrogen pressure remarkably promoted nitridation. Treatment at 2000°C was disadvantageous for nitridation, because of the rapid formation of a dense surface layer that inhibited nitrogen diffusion into the specimen interior. Three specimens, with 5 wt% Y2 O3 additive and different BN contents, were prepared by pressureless reactive sintering, according to the determined sintering schedule. Electron microscopy (scanning and transmission) observations revealed that the in-situ -formed BN flakes were homogeneously and isotropically distributed in the AlN matrix. A schematic mechanism for microstructural formation was developed, based on the results of nitridation and the microstructural features of the obtained composites. The obtained composites, with a low BN content, exhibited a high bending strength, comparable to that of reported hot-pressed AlN–BN composites. 相似文献
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Takayuki Suehiro Junichi Tatami Takeshi Meguro Katsutoshi Komeya Shuitsu Matsuo 《Journal of the American Ceramic Society》2002,85(3):715-717
Aluminum nitride fibers were successfully synthesized from alumina fibers using an NH3 –C3 H8 gas mixture as a reduction–nitridation agent. Observation using SEM clearly demonstrated that the morphology of the nitrided fibers was exactly the same as that of the raw alumina fibers, retaining the original regular shape and smooth surface. Up to 95% of the starting alumina was converted to aluminum nitride at 1400°C within 0.5 h via a single-step synthesis process. 相似文献
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A thermodynamic analysis for the vapor synthesis of AlN is presented. A thermodynamic equilibrium computer code and recent thermochemical tables are used to evaluate various reactant gases for their potential to produce high-purity AlN at high yields. The Al/N/H/X/Y systems are examined, where X is any halide atom and Y is an inert gas. The effects of reactant ratio, temperature, and pressure on reactant conversion and product purity are estimated. Results from two systems are presented in the form of design diagrams, which represent the phases formed and the conversion achieved at various process conditions. 相似文献
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叶蜡石在碳热还原氮化过程中的相变 总被引:5,自引:1,他引:4
研究了叶蜡石在不同温度下碳热还原氮化合成SiAlON过程中的相变。SEM、XRD以及EDS分析结果表明 :130 0℃开始氮化形成O’ SiAlON ,14 0 0℃时O’ SiAlON的XRD峰已经很明显 ,14 5 0℃时O’ SiAlON大量生成并在 15 0 0℃时达到最大值 ;14 5 0℃时开始形成β SiAlON(z=2 )和少量SiC ;15 5 0℃时 ,β SiAlON成为主要的氮化产物 ,与少量的O’ SiAlON并存 ;莫来石和方石英直到 15 0 0℃仍然存在 ,15 5 0℃消失。 相似文献
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本文用无机铝盐借助溶胶-凝胶工艺和表面活性剂的作用制得了一种铝碳良好结合、均匀、无(或弱)团聚的混合凝胶细粉(文中简称“均质混料”),以此为原料氮化合成了纯度达98%的超细AIN粉末,文中着重分析了使用这种均质混料能降低合成条件、提高粉末性能的热力学机制,探讨了影响合成过程的诸因素,最后得出结论认为:铝凝胶均质混料的制备和使用是改进成热还原氮化工艺的最有效途径。 相似文献
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Katsutoshi Komeya Cheng Zhang Mikinori Hotta Junichi Tatami Takeshi Meguro Yi-Bing Cheng 《Journal of the American Ceramic Society》2000,83(4):995-997
Carbothermal reduction—nitridation (CRN) of SiO2 is an attractive method to manufacture Si3 N4 powders with controlled grain morphology. Moreover, β-SiAlON powders could also be synthesized from either pure powder mixture or some inexpensive raw minerals by CRN and the resulting powders favored the sintering of SiAlON product. However, there have been few works on preparing α-SiAlON powders so far. In this work, Ca α-SiAlON powder was synthesized by CRN of a SiO2 —Al2 O3 —CaCO3 mixture. An unusual morphology of hollow beads 200 to 500 nm in diameter with a great deal of nanosize α-SiAlON particles around 10 to 30 nm in diameter was observed from the resultant Ca α-SiAlON powders, which has not been reported for SiAlON ceramics before. 相似文献
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低品位铝土矿合成β-SiAlON的相变过程研究 总被引:4,自引:4,他引:4
采用XRD、SEM和EDS等手段 ,研究了低品位铝土矿碳热还原氮化合成SiAlON过程的相变。结果表明 :130 0℃开始氮化 ,形成Si2 N2 O和X SiAlON ;14 0 0℃开始形成 β SiAlON (z =3) ,X相明显增加 ;14 5 0℃时 ,β SiAlON (z =3)成为主要的氮化产物 ,并与少量的Si3 N4和刚玉并存 ;15 0 0℃开始形成 15R ,同时 ,β SiAlON的z值开始由 3变为 4 ;15 5 0℃时 ,15R和 β SiAlON成为主要物相 ,同时含有部分刚玉相和Si3 N4相。 14 5 0℃时 ,由低品位铝土矿合成纯净的 β SiAlON复合少量刚玉相粉体材料的最佳保温时间是 6~ 9h ,时间过短则含有较多的X相 ;时间过长则发生过量氮化 ,形成部分 15R和少量Si3 N4。 相似文献