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采用365 nm光助高铁酸钾法对4-氯酚水溶液进行氧化降解,考察了高铁酸钾投加量、溶液pH以及反应时间等因素对4-氯酚的降解效果的影响。结果表明:365 nm光助高铁酸钾对4-氯酚的CODCr降解明显优于单纯的高铁酸盐氧化法,但对脱氯具有抑制作用,在50 mg/L的4-氯酚溶液,在pH为3,高铁酸钾与对氯苯酚的摩尔比为8︰1,反应时间为60 min时,365 nm光助高铁酸钾协同作用下的4-氯酚的CODCr去除率与脱氯率分为90%与55%,比单纯高铁酸钾作用CODCr去除率提高了约10%,脱氯率降低了约7%。 相似文献
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探讨了次氯酸盐氧化法制备的高纯度高铁酸钾对微污染水中双酚A(BPA)的降解效果以其影响因素。结果表明,采用次氯酸盐氧化法自制的高铁酸钾的质量分数可以稳定在90%以上;在pH为5、7.1和9时,高铁酸钾降解BPA效果较好,降解率分别为95.4%、99.0%和98.5%;BPA降解率与高铁酸钾投加量之间的关系符合Slogistic模型,高铁酸钾的投加量越大,BPA去除率越高,但m(K2FeO4):m(BPA)大于5时,去除率增长缓慢。高铁酸钾去除微污染水中BPA的优化pH在5~9,K2FeO4与BPA的质量浓度比应当控制在5~6,优化反应时间为10 min。 相似文献
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新型多功能材料高铁酸钾的合成与性能研究 总被引:3,自引:0,他引:3
高铁酸钾是一种新型的强氧化剂,在水处理中不仅可用于杀灭藻类和细菌,氧化降解水中的无机物和有机物,去除水中一些重金属离子,同时可以起到脱色、除臭、絮凝沉降的作用,且具有见效快、无残留毒性和不对水体造成二次污染等突出优点.作者使用次氯酸盐氧化法(湿法)进行高铁酸钾的合成.并利用高铁酸钾的强氧化性对劣质柴油进行脱色和脱臭实验,讨论了酸度、浓度、温度等对高铁酸钾在水溶液中稳定性的影响,得到当ω(HNO3)=4.5%,高铁酸钾质量浓度在100 g/L时处理效果最好,而温度则对处理效果影响不显著. 相似文献
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新兴有机污染物在传统的污水处理厂处理过程中难以完全去除,如果进入到水环境中,不仅影响水质,而且对水生态系统和人类健康具有潜在的风险。高铁酸钾在水处理领域被称为环境友好型的多功能水处理剂,其氧化降解新兴有机污染物的研究备受关注。本文采用高铁酸钾(K2FeO4)氧化降解甲萘酚水溶液,研究表明,甲萘酚水溶液浓度为10 mg/L时,初始pH=12~13,高铁酸钾与甲萘酚的质量比8∶1,反应时间10 min,温度25℃为最优反应条件,甲萘酚去除率达到89.6%左右。通过对反应产物的分析,推测甲萘酚首先被高铁酸钾氧化为1,2-萘二酚,再进一步被氧化开环生成终产物。 相似文献
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一年一届的中国国际塑料橡胶工业展览会(国际橡塑展),是全球多个行业寻找橡塑工业世界性商贸伙伴的机遇,也是企业开拓中国以至亚洲市场商机之"金钥匙"。在25届国 相似文献
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Jasna Djonlagic Anica Lancuski Marija S. Nikolic Jelena Rogan Sanja Ostojic Zoran Petrovic 《应用聚合物科学杂志》2017,134(9)
Two series of semiinterpenetrating networks (SIPN) based on linear hydrophilic poly(vinyl alcohol) (PVA) and thermo‐responsive poly(N‐isopropylacrylamide) (PNIPA), physically crosslinked with inorganic clay, are presented. The hydrogels with different crosslinking densities were prepared by varying the content of clay from 1 to 6 wt % and contained linear interpenetrant, PVA in the range of 0.5–1.5 wt %. The effect of clay content on swelling/deswelling behavior and phase transition in PNIPA gels, as well as the feasibility of reinforcing the gels with high molecular weight PVA, were analyzed. The thermal response of hydrogels, followed by DSC, confirmed that the insertion of hydrophilic PVA did not have a significant effect on the onset of the volume phase transition temperature, while the response was faster. The equilibrium degree of swelling of SIPNs and PNIPA hydrogels was in the range of 9–79 and decreased with increasing content of clay. The internal morphology and surface wettability of the hydrogels were investigated by scanning electron microscope analysis and contact angle measurements, respectively. The network structural parameters of the PNIPA and SIPN nanocomposites hydrogels, such as the average molecular weight between crosslinks, Mc, and effective crosslinking density, Ne, were determined by dynamic mechanical analysis. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44535. 相似文献
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Electrodialysis (ED) was applied to concentrate brine solutions of various concentrations — similar to effluentsfrom the desalination of brackish and industrial water — to about 20%. The consequent reduction in effluent volumes would facilitate a reduction in disposal costs. The energy requirement for concentrating solutions from 70 to 300 mN (0.4-1.8%) to 3.9 N (20%) was in the range 1.5-7.1 kWh/m3, in contrast to approximately 25 kWh/m3 by thermal evaporation. With the aim of preventing precipitation of CaSO4 on the membranes, laboratory-scale ED experiments were carried out on solutions of different compositions to determine the conditions that would lead to the precipitation of excess gypsum on gypsum seeds in a separate precipitator. The results were then applied in a pilot-scale ED unit in which the brine that circulated through the ED brine cells passed through a separate CaSO, precipitator containing gypsum seeds. 相似文献
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D. T. Hopkins R. R. Dahlgren D. Davis A. W. Munson H. P. Dupuy 《Journal of the American Oil Chemists' Society》1973,50(9):381-384
Cyclopropenoids inactivated by reactingSterculia foetida oil with cottonseed oil fatty acids were fed at three dietary levels to growing rats and laying hens for 4 weeks. At the
termination of the experiments, all animals were autopsied and examined microscopically for pathological lesions, but no pathology
that could be related to dietary treatment was observed. Hemoglobin, packed cell volume and plasma cholesterol were similar
in animals fed all of the diets. Growth rate of rats and egg production of hens fed the experimental diets were similar to
those of animals fed the control diet. After 3 and 6 months of storage, eggs from hens fed the inactivated cyclopropenoids
were normal and showed no evidence of the unusual characteristics of cyclopropenoid feeding. Lipids of heart, liver and adipose
tissues of all the rats and hens varied little from the normal fatty acid composition. Small amounts of three unidentified
fatty acids were found in the adipose tissues of rats fed the higher levels of inactivated cyclopropenoids. The results of
these feeding studies suggest that inactivation of cyclopropenoids with fatty acids eliminates the unusual biological effects
attributable to cyclopropenoids.
Presented at the AOCS Meeting, New Orleans, April 1970. 相似文献
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介绍厦门正新橡胶工业有限公司在观念、产品、管理和技术方面开展创新活动的经验。观念创新是名牌战略的灵魂,相互理解与支持、创建伙伴关系是公司对外往来的原则,坚决实施名牌战略,坚持以人为本、适才适用的原则;产品创新是占领市场的法宝,根据市场需求不断适时开发新产品;管理创新是维护品牌形象的前提,各项试验均执行企业内控标准,严把产品质量关;技术创新是实施名牌战略的源泉,以自有技术开发各种轮胎。通过开展创新活动,公司利税指标一直位居国内前列。 相似文献
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Summary A polyurethane prepared from 1,9-nonanediol and toluene-2,4-diisocyanate with Mn=11,840, was capped on both ends in a reaction with 4-(benzocyclobutenyl) methanol. The polyurethane was used to crosslink styrene-butadiene rubber through Diels-Alder reactions on the benzocyclobutene functionality. The synthesis and characterization of 4-(benzocyclobutenyl) methanol, a molecule not reported previously, is presented. The crosslinking reaction was carried out on intimate mixtures of the telechelic polyurethane and SBR at elevated temperature and pressure. Various physical properties of the crosslinked material were studied.Work done at the Department of Chemistry, University of Akron, Akron, OH 44325, USA 相似文献
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É. P. Volchkov V. V. Terekhov V. I. Terekhov 《Combustion, Explosion, and Shock Waves》2002,38(3):269-277
Results of numerical simulation of the influence of intensity of hydrogen injection through a porous surface in the case of hydrogen burning in the boundary layer are presented. Turbulent characteristics of the flow were simulated using the k–epsiv; turbulence model with Chien's modification for low Reynolds numbers. The diffusion model (infinitely large burning rate) was used to describe the chemical reaction process, but the difference in diffusion coefficients of different substances was taken into account. A comparison of injection with and without combustion shows that the presence of a heat-release front delays the laminar–turbulent transition and significantly deforms the profiles of density and viscosity of the gas mixture. As the injection velocity increases, the flame front is shifted from the porous surface toward the outer edge of the boundary layer. The contributions of injection itself and combustion to reduction of skin friction are analyzed. Key wrds: boundary layer, combustion, porous injection, heat and mass transfer, friction. 相似文献