Comparison of magnetic parameters with vehicular Br levels in urban roadside soils

Chemical methods are generally chosen to monitor soil pollution but magnetic measurements proved to yield additional information at low cost and less time consumption. In this investigation, the novel use of rapid and non-destructive magnetic measurements to characterize Br levels in Xuzhou (China) urban roadside soils was reported. X-ray fluorescence spectrometry (XRF) was used to quantify Br in the soil samples. Data from 21 roadside soil samples confirm Br contamination, with a mean level of 4.36 mg kg⁻¹ and a range of 2.4–8.7 mg kg⁻¹. These values are higher than that of unpolluted soils in Xuzhou that averages 1.1 mg kg⁻¹. Hierarchical clustering analysis shows Br in Xuzhou roadside soils is mainly from road traffic. Clear correlations between Br levels and simple magnetic parameters [mass specific susceptibility (χ _LF), susceptibility of anhysteretic remanent magnetization (χ _ARM), saturation isothermal remanence (SIRM)] are observed. The present study shows that these three magnetic parameters can be used as a proxy for Br levels in Xuzhou urban roadside soils.     

Environmental magnetic and geochemical characteristics of Chennai coastal sediments,Bay of Bengal,India

In this study, environmental magnetic, heavy metal and statistical analyses were conducted on 21 surface sediments collected from Chennai coast, India, to examine the feasibility of heavy metal pollution using magnetic susceptibility. The Chennai coastal sediment samples are dominated by ferrimagnetic minerals corresponding to magnetite-like minerals. The percentage of frequency dependent magnetic susceptibility reflects the presence of super-paramagnetic/single domain magnetic minerals in Chennai harbour, Cooum and Adayar rivers sediments. High pollution load index in sample E1, E2, CH7, C11, C12 and A16 is mainly due to anthropogenic activities such as, harbour activities, Cooum and Adayar rivers input and industrial effluent. Factor analysis shows that the magnetic concentration dependent parameters (χ, χ _ARM and SIRM) covary with the heavy metal concentrations, suggesting that the input of magnetic minerals and heavy metals in Chennai coastal sediments are derived from the same anthropogenic sources. Strong correlation obtained between pollution load index (PLI) and concentration dependent parameters (χ, χ _ARM and SIRM) for the polluted samples with magnetic susceptibility excess of 50×10^− 8 m³kg^− 1. Significant correlations between heavy metals and magnetic susceptibility point out the potential of magnetic screening/monitoring for simple and rapid proxy indicator of heavy metal pollution in marine sediments.     

Magnetic characteristics of topsoil from Xinjiang, Northwestern China, and their implications

In this study, a set of environmental magnetic parameters (_{χlf, χfd}%, _χARM , SIRM, HIRM, SOFT and SIRM/_{χlf, χARM} /SIRM and _χARM /_χlf) of 331 top-soil samples from Xinjiang Uygur Autonomous Region of China were systematically measured and the magnetic characteristics and its environmental significance were discussed. Our results indicate that the main magnetic minerals of these top-soils are single-domain magnetite. The content of magnetic minerals in top-soils from north Xinjiang is higher than that from south Xinjiang; however, the content of hard magnetic minerals is higher in the topsoils from south Xinjiang. The top-soils from Yili region contain similar magnetic minerals as that from south Xinjiang, but with much stronger magnetic SP content due to higher pedogenic processes. The differences in magnetic characteristics among top-soils from different regions of Xinjiang might reflect the differences of regional climatic factors, especially the precipitation.     

Inter-profile correlation of the Chinese loess/paleosol sequences during Marine Oxygen Isotope Stage 5 and indications of pedogenesis

Low-field magnetic susceptibility has been widely used to determine the pedostratigraphy of the Chinese loess/paleosol sequences. However, uncertainties remain in correlating between the loess magnetic susceptibility and the marine oxygen isotope records because susceptibility variations are affected by both global and local paleoclimatic changes. To provide a more sound paleoclimatic interpretation of magnetic susceptibility variations, age models across Marine Oxygen Isotope Stage (MIS) 5 for the Jiuzhoutai (JZT) and Yuanbao (YB) sections, western Chinese Loess Plateau, were constructed through an integrated approach by linking the major pedostratigraphic boundaries of the loess profiles to the SPECMAP oxygen isotope curve, and by correlating relative magnetic paleointensity records with both the SINT800 global paleointensity stack from marine sediments and ³⁶Cl records from the GRIP ice core. Results indicate good correlation of SIRM_60 mT (a residual remanence of saturation isothermal remanent magnetization after a 60 mT alternating field demagnetization) variations between these two sites, which agree well with fluctuations in subtropical Atlantic sea surface temperatures. All cooling events recorded by ice-core and Atlantic marine sediments within MIS5 have counterparts in SIRM_60 mT. SIRM_60 mT is partially controlled by the degree of low-temperature oxidation, which is strongly temperature dependent. However, strong pedogenesis can decrease SIRM_60 mT due to further oxidation of partially oxidized magnetites above some critical points. Therefore, we propose that SIRM_60 mT is best suited to record paleotemperature changes in loess profiles from the western Chinese Loess Plateau, where pedogenesis is the weakest. Furthermore, by inter-profile correlation between the YB and JZT sections, we note that the seemingly uniform sub-paleosol unit with a broad susceptibility peak (previously assigned to MIS5c) between ∼34.4 and ∼37.4 m in the YB profile actually consists of two independent units (lower part of S1L1/MIS5b and S1S2/MIS5c). This indicates that susceptibility values can be strongly affected by local factors (e.g., mainly precipitation). Therefore, beside the simplistic traditional paleoclimatic interpretation of variations in loess susceptibility involving only cold/dry and warm/humid scenarios, cold/humid and warm/dry scenarios should also be considered.     

Magnetic signature of heavy metals pollution of sediments: case study from the East Lake in Wuhan,China

Detailed magnetic measurements and geochemical analyses were performed on 114 sediment samples collected from the East Lake, Wuhan city, China, to establish a possible link between the enhanced concentration of anthropogenic magnetic particles and heavy metals with known sources. Relatively higher magnetic susceptibility values (mass-specific, χ, >150 × 10⁻⁸ m³ kg⁻¹) were observed for samples near the pollution sources: e.g. the Wuhan Iron and Steel Company (WISC), the Qingshan Thermal Power Plant (QTPP), the banks (driveways) of the lake and near the sightseeing route of yachts on the lake. Moreover, χ is positively correlated to the concentration of Pb (correlation coefficient r = 0.682), but negatively or weakly correlated with both Zn and Cu. In contrast, anhysteretic remanent magnetization (ARM) is significantly correlated with these major heavy metals (r = 0.645 for Zn–ARM, 0.699 for Pb–ARM and 0.841 for Cu–ARM, respectively), which indicate that ARM serves a better indicator for the pollution of heavy metals in this lake. Thermomagnetic analysis combined with magnetic hysteresis measurements revealed that magnetites in the pseudo-single-domain/multidomain grain-size regions are dominant. Scanning electron microscopy and energy dispersive X-ray examinations of the magnetic extracts showed that these Fe-rich particles have different morphologies: orange-peel structure, hollow structure with adhered smaller particles, Zr-rich melted-like irregular particles, pear-shaped spherules and spherules with slick surfaces. These features are typical for particles produced by anthropogenic activities. Because of the genetic relationship between the environmental setting of the East Lake and the nearby pollution sources, this study suggests that in situ magnetic surveys are sensitive to evaluate the environmental pollution on the lake bottom.     

A preliminary study on the magnetic signatures of modern soil in Central Asia

In this study, magnetic techniques were used to characterize the surface soil from different geomorphologies (i.e., sand desert, oasis, Gobi, and dry lake) in Central Asia. Results demonstrate that the main magnetic minerals in the surface soil are magnetite, maghaemite and haematite with some paramagnetic materials. Cross plots of M _rs/M _s versus B _cr/B _c and χ_fd% versus χ_arm/saturation isothermal remanent magnetization (SIRM) indicate that the main magnetic grain sizes in surface soil are pseudo single domain (PSD) and multidomain (MD). The samples from West China (i.e., Tarim basin and Junggar basin) are dominated by magnetic minerals with larger grain size, while those from North China (i.e., Alxa plateau, Erdos plateau, and Mongolia plateau) are dominated by fine magnetic minerals. The similarity in magnetic mineral constitutions between the Chinese loess and the surface soils from Central Asia implies that the loess originated from a vast area of arid, semi-arid regions of Central Asia. The low value of concentration-dependent magnetic parameters indicates that the low concentration of magnetic minerals in the surface soils from Central Asia and the magnetic enhancement from the pedogenic take place in both the loess and the paleosols, although the progress is stronger in the latter. Translated from Quaternary Sciences, 2006, 26(6): 937–946 [译自: 第四纪研究]     

Heavy metal geochemistry and mineral magnetic characterization of urban soil in Xuzhou,China

In the present study, the enrichment, availability, speciation of heavy metals including Pb, Zn, Cu, Cd, Ni and Sb and magnetic properties of urban soils of Xuzhou (China) were investigated. All analyzed metals showed elevated concentrations compared to local background concentrations. Cadmium and Sb are the metals most enriched in the analyzed area, presenting enrichment factor, on average, of 16.5 and 8.3, respectively. By self-organizing map in combination with diagnostic ratios, the source of Sb, Cd, Cu and Pb in soils might be mainly from traffic emissions. Sequential extractions indicate that metals were primarily associated with the reducible fraction with the exception of Ni. The order of extraction efficiency of various metals was SBET (simplified physiologically based extraction test) > DTPA (diethylenetriaminepentaacetic acid) > CaCl₂. The magnetic results show that soil samples were dominated by a strong ferrimagnetic mineral component with multi- and single-domain magnetic grains. Only CaCl₂ extractable Sb was found to show significant correlations with χlf and SIRM. For both DTPA and SBET extractions, all metals investigated showed significant associations with both χlf and SIRM (saturation isothermal remanent magnetization).     

Rock magnetic response to climatic changes in west Philippine Sea for the last 780 ka: Discussion based on relative paleointensity assisted chronology

We conducted rock magnetic and paleomagnetic research on two deep-sea sediment cores from the west Philippine Sea, located to the east of Benham Rise with the length of 4 m and water depth of over 5000 m. At the bottom of core 146 occurs a reversal of inclination and deflection of relative declination, which is recognized as Brunhes-Matuyama Polarity Boundary (MBPB). No reversal occurs in core 89, which implies a younger bottom age than that of core 146. Rock magnetic results reveal magnetic uniformities in mineralogy, concentration and grain size along the two cores, thus relative paleointensity variations are acquired. The three normalizers-anhysteresis remanent magnetization (ARM), magnetic susceptibility (k) and saturation isothermal remanent magnetization (SIRM) are used for normalization to obtain relative paleointensities. The three normalization results are averaged to indicate the paleoitensity of the cores and are further stacked together to get a synthetic curve for west Philippine Sea (named asWPS800 in this paper). Based on the magnetic correlation between cores and paleointensity to Sint800, we transfer the changes of rock magnetic parameters from depth to time. Furthermore, the astronomically tuned oxygen isotope from ODP site 1143 in the south China Sea is used for the glacial and interglacial indicator. Three concentration proxies (ARM, k and SIRM) and grain size indicators (k _ARM/SIRM, k _ARM/k) are examined according to the paleointensity-assisted chronology. The grain size changes in the two cores display a consistent pattern with the climatic changes embodied by oxygen isotope. The magnetic sizes are usually coarser in glacial periods and finer in interglacial times, which may reflect the influence of chemical erosion rather than fining from sea level rising on the source sediment. Furthermore, the sub-peaks and sub-troughs in interglaciations almost correspond with that of oxygen isotope records, which means sedimentation can reflect the subtle changes in interglaciations. This kind of revelation of climatic fluctuation by magnetic size is also found in the South China Sea, which shows a common pattern of magnetic signals to climate at least within East Asia. The concentration of ARM (representing more about fine grain) also shows similar response to glacial and interglacial cycles, that is, high in interglacial cycle and low in glacial cycle; but k and SIRM (reflecting more about coarse grain) lack the response to the climatic cycles. At the same time, S-ratio lacks the correlation with aeolian dust record and rhythmic changes, indicating the dominant source of main magnetic carrier (low coercivity magnetite) is the suspended matter instead of dust. The decreasing trend of sedimentation rate from west to east also reveals that the sediments are mainly from west Luzon and adjacent land. Grain sizes first became coarse and then stable around 400 ka B.P., and at the same time all the magnetic contents lowered and amplitude of magnetic mineral changes increased. The magnetic transition around 400 ka B.P. is simultaneous with the decreases of carbonate content, reflecting a global carbonate dissolution event, i.e. mid Brunhes event. The synchronization of magnetic content and grain size with climatic cycles of glacials and interglacials imply the validity of paleointesnityassisted chronology. Also, the response of rock magnetic signals to stable oxygen isotope changes and carbonate variation reveals that rock magnetismmethod can be an effective tool for paleoclimatic and paleoceanographic research. __________ Translated from Quaternary Sciences, 2007, 27(6): 1040–1052 [译自 : 第四纪研究]     

Relationship between magnetic properties and heavy metals of urban soils with different soil types and environmental settings: implications for magnetic mapping

Two types of soil (fluvisols and anthrosols) were collected from different environmental settings (suburb and industrial area) in Wuhan, central China, aiming to examine the applicability of magnetic mapping for heavy metal pollution of urban soil in a large region. Magnetic measurements and chemical analysis indicated elevated magnetization and heavy metal concentrations of topsoils in the industrial area. Magnetic susceptibility (χ), anhysteretic remanent magnetization (ARM) and saturation isothermal remanent magnetization (SIRM) of fluvisols are much higher than those of anthrosols, but contrary for frequency-dependent susceptibility, indicating that soil magnetism strongly depends on the soil type/condition. Predominant magnetic carrier in topsoils in industrial area is pseudo-single-domain/multi-domain magnetite. Environmental scanning electron microscope/energy dispersive X-ray examination of the magnetic extracts from these topsoils revealed abundant spherical particles with diameters of 10–50 μm that are rich in iron-oxides, and could be attributed to the nearby industrial activities (e.g., steel work and power generation). Significant correlations were observed between magnetic concentration-related parameters (e.g., χ, ARM and SIRM) and concentrations of Cu, Pb, Zn, Hg and Tomlinson pollution load index. These results proposed that magnetic proxy mapping of soil pollution is an effective, fast and inexpensive tool for delineation of heavy metal pollution. However, interpretation of magnetic properties for such a purpose must be done on a site-specific basis, taking into account the possibilities of pedogenic enhancement/depletion under the specific soil conditions.     

Magnetic rock properties of the gabbros from the ODP Drill Hole 1105 A of the Atlantis Bank, Southwest Indian Ridge

Laboratory studies of 30 samples from 158 m long drill core of the Hole 1105 A (ODP Leg 179) of the Atlantis Bank, Southwest Indian Ridge have revealed magnetic properties of the gabbros, olivine gabbros, oxide gabbros and olivine oxide gabbros down the core. Comparison of modal proportions of the oxides, grain sizes and magnetization parameters of the rocks has confirmed that most coarse-grained oxide mineral bearing rocks record low Koenigsberger ratio (2 to 5) and median destructive fields (5 to 7 mT). Average natural remanent magnetization (J_nrm) and stable remanent magnetization (J_st) of the core samples are 5.8 A/m and 1.9 A/m, respectively. Their mean stable magnetic inclination is 66‡ ± 4‡, about 14‡ steeper than the expected dipole inclination of the area similar to the one reported at Hole 735 B. The excess inclination perhaps marks a tectonic block rotation of the reversely magnetized rocks of the bank. We interpret that gabbros and serpentinites devoid of basaltic carapace significantly contribute to seafloor spreading anomalies of the bank.     

Ferrimagnetic minerals in red paleosols of Pleistocene Epoch, eastern China

The type,grain size and origin of ferimagnetic minerals separated from red paleosols of pleistocene Epoch(Q2)in eastern China ,were studied by using mineral magnetic measurement,X-ray powder diffraction and electron microscopy.Results showed that the iron oxider in red paleosols were composed of hematite(α-Fe2O3),maghemite(γ-Fe2O3) and goethite(α-FeOOH),Mineral magnetic parameters and X-ray diffraction patterns indicated that maghemite was the dominant remanence carrier in red paleosols,which is characterized by superparamagnetic(SP) and stable single domain(SSD) grains,The variations of magnetic susceptibility(χ） ,anhysteretic magnetic susceptibility(χRAM）and saturation isothermal remanent magnetization(SIRM) for red paleosols following heating to various temperatures showed two peak values at 700℃ and 900℃.The spherulitic magnetic particles measuring 250-1000μm in diameter in red paleosols were separated by the magnetic separation method,indicating that these magnetic particles were an assemblage of superparamagnetic and stable single domain ferrimagnetic grains,It is suggested that the ferrimagnetic minerals of red paleosols be a pedogenic ferrimagnetic component under high temperature and high humid conditions in the Pleistocene Fpoch(Q2).It is concluded that the magnetism characteristics of red paleosols can be used to evaluate the environmental changes of Quaternary in eastern China.     

Fluid flow in the Duperow and Winnepegosis Formations, Williston Basin, Canada: Evidence from preliminary magnetic measurements

The Devonian Winnepegosis and Duperow Formations were examined in well 4-27-11-22W1, located in at the eastern edge of the Williston Basin in Manitoba. The variation in characteristic remanent magnetization (ChRM) direction and magnetic mineral carrier is obvious: the older Winnepegosis Formation has a primary or early post-depositional magnetization held in magnetite or pyrrhotite (n = 15; D = 324.1°, I = − 27.3°, α₉₅ = 10.4°, k = 15.7), whereas the younger Duperow Formation magnetizations are carried by hematite and could be as late as Early Jurassic. The variability may be attributable to the intervening Prairie Evaporite acting as an aquitard to fluid migration.     

Reconnaissance paleomagnetism of Late Triassic blocks, Kuyul region, Northern Kamchatka Peninsula, Russia

The northernmost Kamchatka Peninsula is located along the northwestern margin of the Bering Sea and consists of complexly deformed accreted terranes. Progressing inland from the northwestern Bering Sea, the Olyutorskiy, Ukelayat and Koryak superterranes (OLY, UKL and KOR) are crossed. These terranes were accreted to the backstop Okhotsk-Chukotsk volcanic-plutonic belt (OChVB) in northernmost Kamchatka. A sedimentary sequence of Albian to Maastrichtian age overlaps the terranes and units of the Koryak superterrane, and constrains their accretion time. A paleomagnetic study of blocks within the Kuyul (KUY) terrane of the Koryak superterrane was completed at two localities (Camp 2: λ=61.83°N, φ=165.83°E and Camp 3: λ=61.67°N, φ=164.75°E). At both localities, paleomagnetic samples were collected from Late Triassic (225–208 Ma) limestone blocks (2–10 m in outcrop height) within a melange zone. Although weak in remanent magnetization, two components of remanent magnetization were observed during stepwise thermal demagnetization at 32 sites. The A component of magnetization was observed between room temperature and approximately 250 °C. This magnetic component is always of downward directed inclination and shows the best grouping at relatively low degrees of unfolding. Using McFadden–Reid inclination-only statistics and averaging all site means, the resulting A component mean is I_opt=60.3°, I₉₅=5.0° and n=36 (sites). The B magnetic component is observed up to 565 °C, at which temperature, most samples have no measurable remanent magnetization, or growth of magnetic minerals has disrupted the thermal demagnetization process. Combining sites with Fisher estimates of kappa (k-value)≥13 and n (sites)≥3, where bedding orientation differs within a block, most of these sites show the best grouping of B component directions at 100% unfolding, and two of the blocks display remanent magnetizations of both upward and downward directed magnetic inclination. Combining sites with Fisher estimates of kappa (k-value)≥13 and n (sites)≥3, the resulting overall B component paleolatitude and associated uncertainty are λ_obs=30.4°N or S, λ₉₅=8.9° and n=19 (sites). When compared with the expected North America paleolatitude of λ_{APWP expected}=57.9°N, our data support a model in which blocks within the Koryak superterrane are allochthonous and far travelled.     

Magnetic enhancement of urban roadside soils as a proxy of degree of pollution by traffic-related activities

Detailed magnetic and geochemical measurements were performed on urban roadside soils collected from Lishui city, China, to establish a possible link between the enhanced concentration of traffic-related magnetic particles and heavy metals. Relatively higher magnetic susceptibility (mean: 124.1 × 10⁻⁸ m³ kg⁻¹) and concentrations of metals (Cd, Cu, Pb and Zn) were observed for roadside soils. Concentration-dependent magnetic parameters (χ and SIRM) are highly significantly positively correlated to the concentration of metals (Ca, Cr, Ni, Cu, Zn, Cd, Pb, Fe, and V), but not significantly correlated with As, Mn, Co, Mg, and K. The principal component analysis showed that χ and SIRM significantly correspond to elements Ca, Cd, Cu, Pb, and Zn. The χ and SIRM also have significant linear correlation with integrated pollution index, indicating that χ and SIRM can be used as effective proxy indicators for the pollution of heavy metals. Magnetite in the pseudo-single-domain/multidomain (PSD/MD) grain size was identified as the dominant magnetic carrier by temperature-dependent measurements of saturation magnetization (Ms–T curve), XRD and hysteresis loops. Field emission scanning electron microscopy and energy dispersive X-ray spectroscopy (EDS) analysis of the magnetic particles revealed the presence of large traffic-related angular-subangular, blocky, and spherical iron oxide particles. These iron oxide particles are typical for particles produced by traffic-related anthropogenic activities. It is concluded that vehicle emissions may be the major source of elevated heavy metals and magnetic particles in roadside soils. The results proved the applicability of magnetic method in detecting roadside pollution derived from vehicle emissions.     

Magnetic properties of urban topsoils and correlation with heavy metals: a case study from the city of Xuzhou, China

Heavy metals in urban topsoils have been shown to be very useful tracers of environmental pollution. Thus, their detailed studies are of great importance. Apart from expensive and time-consuming chemical methods, several simple, rapid and cheap proxy methods have been developed recently, one of them being based on rock-magnetic parameters. This examines the use of rock-magnetic methods designed to assess the degree of heavy-metal pollution of urban topsoils from the city of Xuzhou (China). The aim was to identify the magnetic properties and to link the “magnetic pollution” to the concentrations of the heavy metals. Since a strong correlation has been found between saturation isothermal remanent magnetization (SIRM) and the heavy metals, namely, Fe, Se, Ti, Sc, Ba, Bi, Pb, Cu, Zn, Cr and Mo, an anthropogenic contamination origin is thought to be the cause. The present study shows that SIRM is a fast, inexpensive and non-destructive method for the detection and mapping of heavy-metal-contaminated urban topsoils.     

Paleogeographic evidence on the Jurassic tectonic history of the Pontides: new paleomagnetic data from the Sakarya continent and Eastern Pontides

The Jurassic paleogeographic position of the Pontides is not well studied because of insufficient paleomagnetic data. For this reason, a paleomagnetic study was carried out in order to constrain the paleolatitudinal drift of the Turkish blocks during the Jurassic period. A total of 32 sites were sampled from volcanic and volcanoclastic rocks of the Lower/Middle Jurassic Kelkit formation (Eastern Pontides), Mudurnu formation (Sakarya continent) and Upper Jurassic–Lower Cretaceous Ferhatkaya formation exposed around Amasya region (Eastern Pontides). Rock magnetic experiments demonstrate that the main ferromagnetic mineral is pseudo-single-domain titanomagnetite in these rocks. Paleomagnetic analysis revealed two main components of the natural remanent magnetization during stepwise thermal and alternating field demagnetization. The first component is a low-coercivity (unblocking temperature) component with a direction sometimes similar to that of the earth’s present field or a viscous component. The second component, which is interpreted as the characteristic remanent magnetization (ChRM) direction, has low to high coercivity properties between 20 and 100 mT or unblocking temperatures between 300 and 580°C. A positive fold test at the 95% level of confidence proved that the ChRM of the sites is primary. Paleomagnetic directions calculated for the Kelkit formation in the Eastern Pontides have a mean direction of D = 334.8°, I = 49.7°, α ₉₅ = 7.1° after tilt-correction. A mean direction of D = 332.2°, I = 48.5°, α ₉₅ = 14.6° was obtained from the volcanoclastic rocks of the Mudurnu formation, and D = 324.3°, I = 43.3°, α ₉₅ = 9.5° was calculated for the Upper Jurassic–Lower Cretaceous limestones/Ferhatkaya formation of the Amasya region. The Jurassic rocks in the Eastern Pontides and Mudurnu region are considered to represent products of the rifted Neo-Tethys ocean, while the Upper Jurassic–Lower Cretaceous sediments in Amasya are related to basin-filling materials. The data suggest that the Kelkit formation was formed at 30.5°N paleolatitude and the equivalent Mudurnu formation at 29.5°N paleolatitude. The paleolatitude of the Eastern Pontides indicates that this rifting block was separated from Eurasia by a marginal basin instead of being a part of Eurasia. The lower paleolatitude of the Amasya region at 24.8°N in the Upper Jurassic to Lower Cretaceous clearly indicates southward drift of the Turkish blocks during the Jurassic to Lower Cretaceous period together with the motion of Eurasia.     

Correlation between magnetic susceptibility and heavy metals in urban topsoil: a case study from the city of Xuzhou, China

Anthropogenic influence, mainly due to urban and industrial activities and traffic exhaust, may affect urban topsoil via atmospheric contamination and solid waste. Magnetic susceptibility measurements were conducted on 21 urban topsoil samples from the city of Xuzhou, China. High intensities of magnetic susceptibility were detected in the majority of the samples. SEM analysis shows that magnetic minerals are in the form of spherules and mainly due to anthropogenic inputs. The heavy metals Pb, Cu, Zn, Se, Sc, Mo, Fe, and Bi show strong correlations with magnetic susceptibility, and Ag, Ba, Cd, Ni, Cr, Sb, and Sn, on the other hand, show a weak correlation with magnetic susceptibility. Whereas, of these metals studied, only Hg has no significant correlation with the susceptibility. The Tomlinson pollution load index (PLI) also shows significant correlation with the susceptibility (χ). The present study shows that magnetic susceptibility is a fast, inexpensive, and non-destructive method for the detection and mapping of contaminated soils.     

Paleomagnetism of the Society Cliffs dolostone and the age of the Nanisivik zinc deposits, Baffin Island, Canada

Dolostones of the ∼1200 Ma Society Cliffs Formation within the hydrothermal zone surrounding the Nanisivik zinc deposits retain a stable characteristic remanent magnetization (ChRM) on alternating field and thermal step demagnetization. Based on the thermal data and saturation isothermal remanence analyses, the ChRM resides in pseudosingle domain magnetite and hematite. A paleomagnetic fold test favours a post-folding ChRM, and a paleomagnetic contact test, using a Franklin gabbro dike, indicates that the ChRM predates ∼720 Ma. The pole position calculated from the ChRM direction is at 168.2°E, 42.8°N (δ_p=4.9°, δ_m=6.8°), giving an age of 1095 ± 10 Ma on the well-defined “Logan Loop” portion of the North American apparent polar wander path. This age is considered to date recrystallization of the dolostone host rocks in the halo around the hydrothermal sulfide deposits. No evidence is found for a postulated Cretaceous remagnetization event in the region. Received: 9 January 1999 / Accepted: 3 March 2000     

Über die Umkehr der remanenten Magnetisierung von Titanomagnetiten in Basaiten

Selfreversal of the remanent magnetization of titanomagnetites from basalts has been investigated as a matter of special magnetic properties of ferrites. The spontaneous and the remanent magnetization has been measured in the range between 77° K and 700° K. The spontaneous magnetization plotted vs temperature turns out to be similar toNéelsQ-,P-,L- orN-type curves. The occurence of different curves is interpreted as a function of differences in the chemical composition of the titanomagnetites. The N-type of the spontaneous magnetization shows selfreversal of the remanence, which only was observed below room temperature.     

Extraction and distribution of soil organic and inorganic selenium in coal mine environments of Wyoming, USA

 Selenium (Se), an animal toxicant and aquifer contaminant, occurs in coal mine environments of Wyoming. There is a paucity of information on solution-phase Se speciation in mine soils. The objectives of this study were to compare Se extraction efficiencies of various reagents and to characterize SeO^2– ₃ (selenite), SeO^2– ₄ (selenate) and organic Se components in these extracts. Forty coal mine soils were extracted using DI (deionized) water, hot water (0.1% CaCl₂), AB-DTPA, NaOH, and KH₂PO₄. Each solution was analyzed for total dissolved Se, and inorganic and organic Se fractions. Both inorganic and organic Se fractions were detected in the soil extracts. The order of Se (total, inorganic, and organic) extraction efficiency for different reagents was DI water < hot water < AB-DTPA < NaOH < KH₂PO₄. The inorganic–organic Se ratios in DI water, hot water, AB-DTPA, NaOH, and KH₂PO₄ extracts were 60 : 40, 26 : 74, 61 : 39, 87 : 13, and 52 : 48, respectively, indicating predominance of inorganic Se in all but the hot water extract. Selenite was the dominant inorganic species in AB-DTPA and KH₂PO₄ extracts, while SeO^2– ₄ was the major Se species in the DI water, hot water, and NaOH extracts. Significant correlations (P<0.01) were observed among extractable inorganic Se [NaOH and KH₂PO₄ (r=0.95); hot water and AB-DTPA (r=0.89)], total soluble Se [DI water with hot water (r=0.98) and AB-DTPA (r=0.95)], and Se species [SeO^2– ₃ in AB-DTPA with SeO^2– ₄ in NaOH (r=0.94) and SeO^2– ₃ in KH₂PO₄ (r=0.88)]. These correlations are indicative of Se extraction efficiency, thermodynamically predicted chemical transformations (such as oxidation of SeO^2– ₃ to SeO^2– ₄), and probable interconversions between the organic and inorganic Se fractions (r=0.70 in KH₂PO₄ extracts); as a whole the correlations can be used as statistical validations of possible geochemical processes. Received: 21 August 1995 · Accepted: 16 October 1995