共查询到20条相似文献,搜索用时 109 毫秒
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《精细与专用化学品》2016,(5)
以间甲基苯甲酸、二乙胺为原料,采用高温常压条件一步反应合成了N,N-二乙基间甲基苯甲酰胺(DEET)。用红外光谱、核磁共振氢谱对产物进行了表征。分析和讨论了原料间甲基苯甲酸与乙二胺配比、催化剂种类、催化剂用量、反应温度对产物收率的影响,得出了最优条件。在该条件下,DEET的产品纯度可以达到99%以上,收率71.5%。 相似文献
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以氯苯和对氯苯甲酰氯为原料,经傅克酰基化、混酸硝化、混合溶剂碱性水解3步反应制备4,4’-二羟基-3,3’-二硝基二苯甲酮,总收率78.34%。通过红外光谱、质谱、氢谱以及高效液相色谱对产品进行表征。采用单因素实验法对水解反应工艺进行考察,确定了最佳工艺条件。在该条件下粗水解产物收率为96.71%,纯度为97.11%。用DMF和异丙醇对水解产物进行重结晶,重结晶后产品收率为81%,纯度为99.30%。 相似文献
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介绍了采用变压吸附─低温分离联合法从合成氨弛放气制取氢气的工艺流程及特点,制得氢气纯度>99.9%,回收率可提高到95%以上,纯氢产量约为313、8m3/h。 相似文献
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从纯化机制入手,介绍了氯碱厂的副产氢气经分离提纯到99.9%及99.9999%以上的方法:低温吸附法、变压吸附法和膜分离法等。 相似文献
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回收氢气装置是利用经过脱硫处理后的芳烃厂富氢干气,采用国内成熟的变压吸附专利技术回收干干气气中氢气。利用高压吸附,低压抽真空解吸的原理,从含粗氢的干气中提纯出99.9%(v)的产品氢,提供芳烃装置用氢。同时变压吸附的尾气通过尾气压缩机增压后供芳烃装置做加热炉燃料,从而达到厂内富氢干气综合利用的目的,提高装置综合经济效益。 相似文献
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变压吸附提氢工艺的优化 总被引:1,自引:0,他引:1
结合某甲醇厂甲醇尾气提氢技术指标,介绍了变压吸附装置的工艺原理;简述了8—1—6VPSA提氢装置工艺流程、工艺控制点以及自主开发的智能化PLC控制程序在提氢装置的应用情况;提出了提氢工艺的优化措施。结果表明,提氢装置可将氢气纯度提高到99.99%。 相似文献
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Ana M. Ribeiro 《Chemical engineering science》2008,63(21):5258-5273
The production of high purity hydrogen (99.99+%) at reduced cost is an important and sought target. This work is focused on the separation of hydrogen from a five component mixture (H2/CO2/CH4/CO/N2) by pressure swing adsorption. A complete mathematical model that describes the dynamic behaviour of a PSA unit is presented. This model is applied in the study of the behaviour of both single column and four columns PSA processes with layered activated carbon/zeolite beds and with an eight steps cycle. In the single column simulation, a 99.9994% purity hydrogen stream is attained at the end of the feed step for a process hydrogen recovery of 51.84% and a productivity of . The multicolumn simulation predicts a hydrogen recovery and purity, respectively, of 52.11% and 99.9958%. The influence of feed flow rate, purge to feed ratio and lengths of both adsorbent layers on the system performance is assessed. It is shown that the introduction of the zeolite layer improves both the purity and recovery of the process. Reduced models are formulated based on the sequential identification of controlling resistances in the complete model. The predictions of the reduced models are evaluated by comparing their results with those obtained from the complete model. It is shown that the model that merely takes into account the micropore resistance (described by the LDF model) and assumes thermal equilibrium only between the gas and solid phases satisfactorily predicts the behaviour of the pressure swing adsorption unit. 相似文献
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Hydrogen recovery from Tehran refinery off-gas was studied using simulation of PSA (pressure swing adsorption), gas absorption processes and modeling as well as simulation of polymeric membrane process. Simulation of PSA process resulted in a product with purity of 0.994 and recovery of 0.789. In this process, mole fraction profiles of all components along the adsorption bed were investigated. Furthermore, the effect of adsorption pressure on hydrogen recovery and purity was examined. By simulation of one-stage membrane process using co-current model, a hydrogen purity of 0.983 and recovery of 0.95 were obtained for stage cut of 0.7. Also, flow rates and mole fractions were investigated both in permeate and retentate. Then, effects of pressure ratio and membrane area on product purity and recovery were studied. In the simulation of the gas absorption process, gasoline was used as a solvent and product with hydrogen purity of 0.95 and recovery of 0.942 was obtained. Also, the effects of solvent flow rate, absorption temperature, and pressure on product purity and recovery were studied. Finally, these three processes were compared economically. The results showed that the PSA process with total cost of US$ 1.29 per 1 kg recovered H2 is more economical than the other two processes (feed flow rate of 115.99 kmol/h with H2 purity of 72.4 mol%). 相似文献
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Huiru Li Zuwei Liao Jingyuan Sun Binbo Jiang Jingdai Wang Yongrong Yang 《中国化学工程学报》2019,27(8):1870-1878
Methane steam reforming is the main hydrogen production method in the industry. The product of methane steam reforming contains H_2, CH_4, CO and CO_2 and is then purified by pressure swing adsorption(PSA) technology. In this study, a layered two-bed PSA process was designed theoretically to purify H_2 from methane steam reforming off gas. The effects of adsorption pressure, adsorption time and purgeto-feed ratio(P/F ratio) on process performance were investigated to design a PSA process with more than99.95% purity and 80% recovery. Since the feed composition of the PSA process changes with the upstream process, the effect of the feed composition on the process performance was discussed as well.The result showed that the increase of CH_4 concentration, which was the weakest adsorbate, would have a negative impact on product purity. 相似文献
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丙烷脱氢(PDH)是生产丙烯产品的重要方式之一,丙烷脱氢反应气组分复杂,为获得聚合级丙烯和纯度不小于99.90 mol/mol的氢气产品,在Aspen软件中对丙烷脱氢反应气分离和富氢尾气回收氢气的过程进行建模和模拟,分离过程包括醇胺脱碳、压缩深冷、脱乙烷、丙烯精馏和变压吸附单元。为了合理利用丙烯精馏塔的能量,对丙烯精馏塔进行能量集成,采用变压吸附工艺回收氢气并对分离过程工艺参数进行灵敏度分析及优化工艺参数,以提高经济性和能效。模拟结果可得到符合要求的丙烯和氢气产品,单位产品能耗分别为267.46 kg标准油/t丙烯产品,474.44 kg标准油/t氢气产品。 相似文献