复合合金化对AZ91镁合金铸态组织的影响

利用光学显微镜、扫描电镜和X射线衍射仪研究了0.5?、0.2?、0.2%Sr(质量分数,下同)复合合金化对AZ91合金铸态组织影响。结果表明,0.5?、0.2?、0.2%Sr复合加入可以显著细化合金的铸态组织,0.5?、0.2?、0.2%Sr同时加入,其细化效果优于0.5?和0.2?或0.5?和0.2%Sr的复合加入,并且在组织中出现针状或杆状的Al4Ce新相。     

复合添加Ce、Sr和La对AZ91镁合金显微组织和力学性能的影响

研究了Ce、Sr和La对AZ91镁合金显微组织和力学性能的影响。结果表明,复合添加Ce、Sr、La可显著细化镁合金铸态组织,使呈网状分布的β-Mg17Al12相断裂成块状或粒状,均匀分布在基体中,并在合金组织中生成杆状或者针状的Al4Ce和Al4La相。复合添加0.5%Ce-0.3%La-0.2%Sr的镁合金显微组织最佳,并且抗拉强度达到了270 MPa,伸长率达到了7.75%。     

Ce、Sr合金化对铸态及均匀化态Mg-Sn-Ca合金第二相的影响

采用扫描电子显微镜及能谱仪系统研究了Ce、Sr合金化对铸态以及均匀化态Mg-Sn-Ca合金第二相的影响。结果表明,与铸态合金相比,0.2%~0.5%Ce元素的添加并未改变Mg-2Sn-2Ca均匀化态合金第二相Mg Sn Ca和Mg_2Ca的种类,且随着Ce含量的增多,会有少量的Mg_(12)Ce相伴生出现,均匀化态合金的Mg Sn Ca和Mg_2Ca相的形貌由最初大块的条状变为相对更加细小且弥散的点条状。添加0.5%~1.5%Sr元素后,Mg-2Sn-2Ca合金表现出类似的变化规律,且随着Sr含量的增加,均匀化态合金中出现了大量颗粒状的Mg_(17)Sr_2相。     

Sr、Mn对含铁AZ91合金力学及耐蚀性能的影响

利用万能材料试验机和失重法分别研究了Sr、Mn复合添加对含0.2%Fe的AZ91镁合金力学性能和耐蚀性的影响。结果表明:合金组织的主要相为α-Mg、β-Mg17Al12、Al4Sr和Al6Mn。Mn的加入可提高合金的力学性能,当添加0.5%Sr和0.5%Mn时,合金的铸态和T6热处理的抗拉强度达到最大值,分别为128、174 MPa。在0.5%Sr时,Mn的加入能显著提高合金耐腐蚀性。本试验中,复合加入0.5%Sr和0.8%Mn,经T6热处理后的合金腐蚀速率最小,为1.4 mg.cm-2.d-l。     

Ca和Sr对AZ91D镁合金低周疲劳性能的影响

研究了合金元素Ca、Sr复合添加对金属型铸造镁合金AZ91D的低周疲劳性能的影响。通过运用控制总应变幅0.05 mm～0.25 mm范围内,在应力比R=-1条件下施加拉-压载荷,测试不同状态下合金的低周疲劳性能,并利用光学电子显微镜观察了材料在不同状态下的显微组织及低周疲劳断口特征。结果表明:Ca、Sr元素的添加能细化铸态AZ91D镁合金的晶粒,复合加入0.4%Ca和0.3%Sr,可以提高镁合金的低周疲劳性能。     

微量Sr干预下Ce含量对ZL101合金组织及性能的影响

研究了单一Ce变质剂和Ce+Sr复合变质剂对ZL101合金组织及性能的影响。结果表明,与Ce变质相比,复合变质效果更理想。在微量元素0.05wt%Sr干预下,复合变质显著改善了铸态合金中共晶硅形态,从而提升了合金力学性能。变质效果在0.45%Ce+0.05%Sr时最佳,此时ZL101合金的抗拉强度为319 MPa,伸长率为11.03%。     

碱土元素对AZ91D镁合金组织和性能的影响

通过向AZ91D合金中添加Ca、Ba、Sr3种碱土元素,熔炼制备了铸态镁合金,利用OM、SEM、EDS和XRD等手段研究了合金的铸态组织和物相组成,测试了其力学性能.结果表明, Ca、Ba、Sr的综合作用可以显著细化镁合金的铸态组织,并使网络状β-Mg17Al12相以球块状弥散分布,室温抗拉强度从AZ91D合金的156.3 MPa提高到AZ91D-0.5Ca-0.2Ba-0.1Sr合金的187.6 MPa.     

Ce、Ca、Sr合金化对AZ91合金腐蚀性能的影响

利用静态失重法研究了Ce、Ca、Sr复合合金化对AZ91镁合金在3.5%NaCl水溶液中的腐蚀性能。结果表明,Ce、Ca、Sr复合加入显著降低合金的腐蚀速率,其耐蚀性明显高于基体合金,也优于单独添加Ce的合金。腐蚀性能提高的原因主要归结为：复合合金化导致α-Mg晶粒明显细化,Al元素的偏析减轻,块状的β-Mg17Al12相变为非连续网状分布。     

Mg、Ce、Sr复合微合金化对A356铝合金组织和性能的影响

通过金相显微镜、扫描电镜、透射电镜、拉伸试样机等分析手段研究了Mg、Ce、Sr等元素复合添加对A356合金微观组织和力学性能的影响。结果表明，多元素复合添加对A356铝合金的细化和变质效果较好，α-Al相尺寸减小，共晶硅也由针片状转变为颗粒状或短杆状。添加0.25%Mg、0.2%Ce、0.015%Sr后合金的抗拉强度、屈服强度、伸长率分别为345 MPa、289 MPa、7%。变质后合金的断裂以韧性断裂为主。     

Ca含量对Mg-5Zn-2Al合金铸态组织和性能的影响

采用光学显微镜、XRD和SEM等手段,研究了Ca对Mg-5Zn-2Al合金铸态显微组织和力学性能的影响.结果表明:Ca的加入对Mg-5Zn-2Al合金铸态的晶粒能够显著地细化.合金的抗拉强度和伸长率均呈现先上升后下降的变化趋势.该合金中加入0.2wt％Ca细化效果最明显,其合金铸态时的抗拉强度和伸长率分别为为233MPa和13.33％.     

Refinement effect of cerium,calcium and strontium in AZ91 magnesium alloy

Refinement effects of cerium (Ce), calcium (Ca) and strontium (Sr) additions to AZ91 magnesium alloy have been investigated. Results show that an addition of 0.8 wt.%Ce combined with either 0.2 wt.%Ca or 0.2 wt.%Sr has a significant refining effect, and a higher degree of refinement using Ce–Ca combination rather than Ce–Sr. EDS microanalysis and water-quenched microstructure observation were used to reveal the grain refinement mechanism. It is assumed that grain refinement is mainly due to the impeding effect on grain growth during solidification of Ce, Ca and Sr segregation on grain boundaries.     

Ca和Sr对AZ91D合金组织的细化作用

研究了Ca ,Sr对AZ91D合金晶粒细化的影响。试验结果表明 ,往AZ91D合金中添加少量的Ca[w(Ca) <1.0 %] ,虽然可以起到细化晶粒、提高屈服强度的作用 ,但是由于Al2 Ca相在晶界的偏聚 ,使得合金的基体脆化 ,导致了合金的抗拉强度和伸长率均下降。往AZ91D合金中添加少量的Sr[w(Sr) <0 .2 %] ,晶粒尺寸基本不发生变化。往AZ91D合金中复合添加Ca ,Sr ,不仅可以减小AZ91D合金的晶粒尺寸 ,而且还可以提高Mg合金的综合力学性能。     

Pt-25Rh-0.2La-0.2Ce合金的组织结构及性能研究

采用真空电弧熔炼预合金化-高频熔炼方法制备Pt-25Rh-0.2La-0.2Ce合金。利用金相显微镜、扫描电子显微镜、透射电镜及电子拉伸试验机等,研究Pt-25Rh-0.2La-0.2Ce合金的显微组织结构、力学性能及高温抗氧化性能。结果表明,稀土的添加可有效细化合金的晶粒尺寸,提高合金的室温及高温力学性能,同时对合金的高温抗氧化性能无明显负面影响。     

Effect of ageing treatment on microstructures,mechanical properties and corrosion behavior of Mg-Zn-RE-Zr alloy micro-alloyed with Ca and Sr

Effects of ageing treatment on the microstructures, mechanical properties and corrosion behavior of the Mg-4.2Zn-1.7RE-0.8Zr-xCa-ySr [x=0, 0.2 (wt.%), y=0, 0.1, 0.2, 0.4 (wt.%)] alloys were investigated. Results showed that Ca or/and Sr additions promoted the precipitation hardening behavior of Mg-4.2Zn-1.7RE-0.8Zr alloy and shortened the time to reaching peak hardness from 13 h to 12 h. The maximum hardness of 77.1±0.6 HV for the peak-aged Mg-4.2Zn-1.7RE-0.8Zr-0.2Ca-0.2Sr alloy was obtained. The microstructures of peak-aged alloys mainly consist of α-Mg phase, Mg₅₁Zn₂₀ phase and ternary T-phase. The Zn-Zr phase is formed within the α-Mg matrix, and the Mg₂Ca phase is formed near T-phase due to the enrichment of Ca in front of the solid-liquid interface. Furthermore, fine short rod-shaped β′₁ phase is precipitated within the α-Mg matrix in the peak-aged condition. The peak-aged Mg-4.2Zn-1.7RE-0.8Zr-0.2Ca-0.2Sr alloy exhibits optimal mechanical properties with an ultimate tensile strength of 208 MPa, yield strength of 150 MPa and elongation of 3.5%, which is mainly attributed to precipitation strengthening. In addition, corrosion properties of experimental alloys in the 3.5wt.% NaCl solution were studied by the electrochemical tests, weight loss, hydrogen evolution measurement and corrosion morphology observation. The results suggest that peak-aged alloys show reduced corrosion rates compared with the as-cast alloys, and minor additions of Ca and/or Sr improve the corrosion resistance of the Mg-4.2Zn-1.7RE-0.8Zr alloy. The peak-aged Mg-4.2Zn-1.7RE-0.8Zr-0.2Ca-0.2Sr alloy possesses the best corrosion resistance, which is mainly due to the continuous and compact barrier wall constructed by the homogeneous and continuous second phases.

     

Comparison about effects of Sr,Zr and Ce additions on as cast microstructure and mechanical properties of Mg–3·8Zn–2·2Ca (wt-%) magnesium alloy

Abstract

The effects of Sr, Zr and Ce additions on the as cast microstructure and mechanical properties of Mg–3·8Zn–2·2Ca (wt-%) magnesium alloy are investigated and compared. The results indicate that adding 0·1 wt-%Sr, 0·6 wt-%Zr or 1·0 wt-%Ce can effectively refine the grains of the alloy, and the refinement efficiency of Zr addition is relatively high, followed by the additions of Ce and Sr respectively. In addition, adding 0·1 wt-%Sr, 0·6 wt-%Zr or 1·0 wt-%Ce can improve the tensile properties of the alloy, and the improvement of Zr addition is relatively high, followed by the additions of Ce and Sr respectively. However, the effects of adding 0·1 wt-%Sr, 0·6 wt-%Zr and 1·0 wt-%Ce on the creep properties of the alloy are different. Adding 0·1 wt-%Sr or 0·6 wt-%Zr result in a decrease of creep properties. Oppositely, a significant improvement of creep properties can be obtained by adding 1·0 wt-%Ce.     

Ce、Y和Gd对Mg-3Sn-2Sr镁合金铸态组织和力学性能的影响(英文)

通过扫描电镜、X射线衍射、差热分析以及抗拉和蠕变性能测试等手段,调查和比较了Ce、Y和Gd对Mg-3Sn-2Sr镁合金铸态组织和力学性能的影响。结果表明:Mg-3Sn-2Sr三元合金主要由?-Mg、初生和共晶SrMgSn以及Mg2Sn相组成。当添加1.0%Ce、1.0%Y和1.0%Gd到Mg-3Sn-2Sr合金后,合金中分别形成了Mg12Ce、YMgSn、GdMgSn和/或Mg17Sr2相。同时,合金中初生SrMgSn相的形成被抑制,且呈针状的粗大初生SrMgSn相也被变质和细化。此外,添加1.0%Ce、1.0%Y和1.0%Gd均能同时改善Mg-3Sn-2Sr合金的抗拉性能和蠕变性能。在含Ce、Y和Gd合金中,含Ce合金的抗拉性能相对较含Y和含Gd合金的高。     

添加Ce与P+Sr复合变质对高硅耐热铝合金组织与性能的影响

研究了添加Ce与P+Sr复合变质对Al-21Si-1．5Cu-0．5Mg-2．5Fe合金显微组织与性能的影响。结果表明:添加1．5％Ce使粗大针状铁相消失,形成富Ce富Fe的鱼骨状相;P+Sr复合变质可使初晶硅平均尺寸由70 mm细化到20mm,共晶硅平均截线长降到2．1 mm,合金室温抗拉强度比未变质前提高21．5％,与P+Sr+Ce复合变质的Al-21Si-1．5 Cu-1．5Ni-2．5Fe-0．5Mg合金相当。     

Ce对高铁A356合金铸态显微组织的影响

采用光学显微镜、X射线衍射仪和电子探针,研究了Ce对高Fe含量的A356合金铸态显微组织的影响。结果表明,添加Ce能将粗大针状Fe相转变成细小短棒状Fe相,但过量的Ce会导致针状Fe相长度的增加。当Ce的加入量为0.4%时,针状Fe相的长度最短;Ce可以细化α-Al晶粒,当Ce的加入量为0.4%～0.7%时,可以对共晶硅起到较好的变质效果,但当Ce的加入量>0.7%,变质效果减弱。     

Sr对Mg-Al-Ca铸造合金微观组织的影响

研究Sr对Mg-Al-Ca铸造合金微观组织演变的影响。研究发现,微量Sr会导致镁基体组织轻微粗化。当Sr含量从0.1%增加至0.5%时,镁基体的晶粒尺寸由83.9μm减小到65.8μm。添加0.1%-0.3%Sr对Al2Ca相有显著的变质细化作用,同时,使其形貌从条状转化为球状。Al2Ca的含量随着Sr元素的添加而有所增加。镁基体晶粒细化主要是由于Sr的添加增加了熔体的有效过冷度以及合金固/液界面前沿区域形成很强的成分过冷效应引起的。Sr对Al2Ca的变质作用主要归因于Sr在Al2Ca晶体上的吸附。当Sr含量增加至0.5%时,合金会出现过变质现象。