滇西北兰坪盆地金顶超大型矿床有机岩相学和地球化学

云南兰坪金顶矿床是世界上形成时代最新且唯一陆相沉积岩容矿的超大型铅锌矿床,也是中国目前最大的铅锌矿床,有机物质在金属成矿中可能发挥重要作用,受人关注.矿石及矿化岩石中产有包括干酪根、轻油、烃类气、重油、沥青及方解石中石油、甲烷包裹体等多种形式、产状和成熟度的有机物质,油气显示突出,古油气藏遗迹明显,是金顶古油气藏在铅锌成矿过程中热成熟、裂解和被改造、破坏不同阶段的产物.有机物质的氯仿沥青\"A\"变化大(72×106～395415.42×106).\"A\"的族组分中,总烃(58.47%)大于\"非烃 沥青烯\"(41.53%),饱和烃/芳香烃比值大于1,具Ⅰ型有机母质特征.有机转化率(A/C=0.5%～7.2%)较矿床外围岩石低,有机热成熟度高.矿石及矿化岩石中有机质的饱和烃包括正构烷烃、Pr、Ph和iC18等化合物,碳数分布介于C10～C34之间,C21 22/C28 29=0.78～3.582,Pr/C17=0.25～0.646,Ph/C18=0.39～1.57,有机母质为海相菌藻类.有机质中检测出萘、菲、三芳甾烷、联苯、荧蒽等芳香烃类化合物,菲系列化合物最为明显,MPI1=0.215～0.434,MPI2=0.252～0.588,菌藻等有机母质发育在高盐度还原沉积环境,烃源岩主要是三叠系残留海相碳质泥岩和泥灰岩.伴随金顶局部穹隆过程,很可能在金顶穹隆中形成油气藏,它是矿区铅锌快速大规模集中成矿的重要还原剂之一.     

Use of laser ablation ICP-MS to determine trace element distributions in coals, with special reference to V, Ge and Al

Laser ablation ICP-MS has been used to produce element profiles from polished coal samples. The elements analysed (V, Ge, Ni, Cu, Zn, Sr and Ba) were those known to have an organic association, with the addition of Al and Fe as controls on the clay and pyrite abundances. The element profiles were compared with the petrography and a statistical analysis was also carried out. Sporinite was found to have low trace element concentrations, inertinite higher concentrations of detrital elements and vitrinite higher concentrations of V, Ge and Al. The relationships between these elements are explored and all are thought to be present in the organic matter and not as minerals. It is thought that these elements became concentrated during diagenesis, with the possibility that some of the Al could be residual. The Cu/Ni ratio in the pyrite is relatively constant, suggesting constant ionic proportions during diagenesis, and possibly a seawater source.     

Middle to Late Devonian basin evolution in the Rügen area,NE Germany

The Middle to lower Upper Devonian succession of the Rügen Depression in NE Germany consists of largely clastic sediments, whereas the Upper Devonian deposits are mixed carbonate and clastic. Petrographic and geochemical data suggest that the sediments were deposited in a cratonic or recycled setting. Deposition was largely confined to a fault-bounded basin, located between two structural highs. During the Devonian, the Rügen area underwent evolution from a continental and marginal marine area during the Eifelian-early Frasnian to a deeper marine environment during the late Frasnian-early Famennian. By the latest Famennian, an open-shelf carbonate-facies environment was established.     

新疆图拉尔根基性-超基性岩体中基性包体岩石地球化学特征及其成岩过程

新疆哈密图拉尔根铜镍硫化物矿床是东天山黄山-镜儿泉韧性剪切带上的一个典型岩浆熔离-贯入型矿床。在图拉尔根岩体中的角闪辉橄岩相中发育了一些基性包体,这些包体尺寸在几到几十厘米之间,岩性主要为辉长岩、斜长岩,辉长岩包体含矿性好,而斜长岩包体不含矿。通过岩相学观察发现,包体与寄主岩在矿物种类、含量、蚀变类型及程度以及矿物接触交代关系和生成顺序上存在较大的差异,并且,两者存在截然的接触边,该接触边以鳞片状绿泥石为主。哈克图解和SiO₂与不相容元素La、Nd、Zr、Yb的相关性图解都显示图拉尔根基性-超基性岩体样品具有很好的相关性,而包体样品则不具有明显的相关性,指示了岩浆混染作用在包体成岩中的重要作用。微量元素地球化学特征显示包体和图拉尔根岩体均具Nb、Ta亏损,这可能是陆壳混染作用的结果,或源区存在俯冲的洋壳物质。此外,包体中K、Pb、Sr、P含量非常高,暗示后期流体作用较强;包体的Nb/U、Ce/Pb值都更接近大陆地壳的值,这些都说明陆壳混染的可能性较高,或存在较强的流体迁移作用。     

Microfacies and depositional environment of Tertiary Tanjung Enim low rank coal, South Sumatra Basin, Indonesia

The South Sumatra basin is among the most important coal producing basins in Indonesia. Results of an organic petrography study on coals from Tanjung Enim, South Sumatra Basin are reported. The studied low rank coals have a mean random huminite reflectance between 0.35% and 0.46% and are dominated by huminite (34.6–94.6 vol.%). Less abundant are liptinite (4.0–61.4 vol.%) and inertinite (0.2–43.9 vol.%). Minerals are found only in small amounts (0–2 vol.%); mostly as iron sulfide.Based on maceral assemblages, the coals can be grouped into five classes: (1) humotelinite-rich group, (2) humodetrinite-rich group, (3) humocollinite-rich group, (4) inertinite-rich group and (5) humodetrinite–liptinite-rich group. Comparing the distribution of maceral assemblages to the maceral or pre-maceral assemblages in modern tropical domed peat in Indonesia reveals many similarities. The basal section of the studied coal seams is represented typically by the humodetrinite–liptinite-rich group. This section might be derived from sapric or fine hemic peat often occurring at the base of modern peats. The middle section of the seams is characterized by humotelinite-rich and humocollinite-rich groups. The precursors of these groups were hemic and fine hemic peats. The top section of the coal seams is typically represented by the humodetrinite-rich or inertinite-rich group. These groups are the counterparts of fibric peat at the top of the modern peats. The sequence of maceral assemblages thus represents the change of topogenous to ombrogenous peat and the development of a raised peat bog.A comparison between the result of detailed maceral assemblage analysis and the paleodepositional environment as established from coal maceral ratio calculation indicates that the use of coal maceral ratio diagrams developed for other coal deposits fails to deduce paleo-peat development for these young tropical coals. In particular, mineral distribution and composition should not be neglected in coal facies interpretations.     

Characterisation of dispersed organic matter from lower Palaeozoic metasedimentary rocks by organic petrography, X-ray diffraction and micro-Raman spectroscopy analyses

Dispersed organic matter (DOM) concentrates of C-rich rocks from areas with different metamorphic characteristics were studied by organic petrography, X-ray diffraction (XRD) and micro-Raman spectroscopy analysis. The concentrates contain several types of DOM with different morphologies, reflectance, X-ray diffraction and micro-Raman characteristics.Four different morphological types were identified in the two studied areas. The different types have different distributions and their reflectance is quite variable in the four types, with a dominance of the highest reflectance values in the DOM from the area with the highest metamorphic grade.XRD analyses of samples from the areas reveal the presence of fine graphite together with non-graphitised carbons.The Raman spectral profiles show the usual bands G (1582 cm⁻¹) and D1 (1350 cm⁻¹), on the first-order Raman spectrum, and S1 (2700 cm⁻¹) on the second-order spectrum. Additional weaker bands, D2 (1620 cm⁻¹), and more rarely D3 (1500 cm⁻¹) and S2 (2900 cm⁻¹), are present. These are characteristic for disordered carbons in the different types of DOM and in both studied areas. However, the Raman parameters (D1/G intensity area ratio and the frequency and width of G band) indicate variable degrees of organisation in all DOM types.The existence of different types of DOM with different degrees of ordering in the same lithologies and metamorphic grade seems to be related to different organic precursors, as they are graphitised to different extents under the same metamorphic conditions. However, in the same lithologies and metamorphic grade, the existence of various stages of graphitisation within the same type of DOM can only be explained though the interaction of DOM with the metamorphic fluids present in the rocks. The ordering graphitisation process may be due to the existence of metamorphic fluid circulation events with a variety of compositions.     

云南播卡金矿区钠长岩地球化学特征及其地质意义

播卡金矿床位于滇中元古代铜金多金属成矿带之东川矿集区。重点报道了区内与成矿密切相关的钠长岩的岩相学、岩石地球化学及同位素特征。研究表明,播卡钠长岩的主要造岩矿物有钠长石、辉石、黑云母,主量元素特征显示其为富碱、高钠、偏铝质的碱性-过碱性岩石。岩石的稀土元素总量低,相对富集轻稀土元素,明显富集大离子亲石元素K、Rb、Nd及轻稀土元素La、Ce、Sm,相对亏损高场强元素Nb、Ta、U、Th等。岩石的I_(sr)值、ε_(Nd)(t)值显示,其可能为中元古代晚期会理—东川一带大陆裂谷岩浆作用的产物,来源于深部地幔,可能有部分陆壳物质的参与。     

新疆哈密图拉尔根Ni-Cu硫化物矿床成矿模式研究

新疆图拉尔根Ni-Cu硫化物矿床产于康古儿塔格—黄山韧性剪切带的北东段,属于岩浆熔离贯入型矿床。1号岩体以全岩矿化为特征,各岩相环带状产出,岩性具有单期岩浆多次脉动上涌成矿特征。由大地电磁测深剖面图、稀土元素配分曲线和微量元素可知1号和2号岩体具有同源性,并具有互补性,在深部具有同一个岩浆通道。较低的La/Sm(2)和Th/Ta值(4.6)表明成矿岩浆为地幔来源,岩体就位时很少受到地壳的混染。PGE特征表明,图拉尔根岩浆源于地幔低程度的部分熔融。Pd-Ni图显示在岩浆演化早期没有发生过硫化物的熔离作用。根据岩石学、岩相学、地球化学等资料综合分析,对图拉尔根Ni-Cu硫化物矿床的成矿模式进行了探讨,认为其成矿模式为深部熔离反相复式贯入成矿。构造在图拉尔根矿床就位过程中起了重要影响,决定了矿体的产出状态。     

The origin and distribution of HAPs elements in relation to maceral composition of the A1 lignite bed (Paleocene, Calvert Bluff Formation, Wilcox Group), Calvert mine area, east-central Texas

The origin and distribution of twelve potentially Hazardous Air Pollutants (HAPs; As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, and U) identified in the 1990 Clean Air Act Amendments were examined in relation to the maceral composition of the A1 bed (Paleocene, Calvert Bluff Formation, Wilcox Group) of the Calvert mine in east-central Texas. The 3.2 m-thick A1 bed was divided into nine incremental channel samples (7 lignite samples and 2 shaley coal samples) on the basis of megascopic characteristics. Results indicate that As, Cd, Cr, Ni, Pb, Sb, and U are strongly correlated with ash yield and are enriched in the shaley coal samples. We infer that these elements are associated with inorganic constituents in the coal bed and may be derived from a penecontemporaneous stream channel located several kilometers southeast of the mining block. Of the HAPs elements studied, Mn and Hg are the most poorly correlated to ash yield. We infer an organic association for Mn; Hg may be associated with pyrite. The rest of the trace elements (Be, Co, and Se) are weakly correlated with ash yield. Further analytical work is necessary to determine the mode of occurrence for these elements. Overall, concentrations of the HAPs elements are generally similar to or less than those reported in previous studies of lignites of the Wilcox Group, east-central region, Texas. Petrographic analysis indicates the following ranges in composition for the seven lignite samples: liptinites (5–8%), huminites (88–95%), and inertinites (trace amounts to 7%). Samples from the middle portion of the A1 bed contain abundant crypto-eugelinite compared to the rest of the samples; this relationship suggests that the degradation of plant material was an important process during the development of the peat mire. With the exception of Hg and Mn, relatively low levels of the HAPs elements studied are found in the samples containing abundant crypto-eugelinite. We infer that the peat-forming environment for this portion of the coal bed was very wet with minimal detrital input. Relatively high concentrations of crypto-humotelinite were found in samples from the top and base of the coal bed. The presence of abundant crypto-humotefinite in this part of the coal bed suggests the accumulation of wood-rich peat under conditions conducive to a high degree of tissue preservation in the peat mire. Although several of the trace elements (Be, Co, Ni, and Sb) exhibit enrichment in these samples, they are not necessarily chemically associated with humotelinite. We infer that these elements, with the exception of Be, are possibly associated with deposition of the roof and floor rock of the coal bed; however, further analytical work would be necessary to confirm this hypothesis. Beryllium may have an organic origin.     

纳米比亚欢乐谷地区白岗岩岩石学及地球化学特征

对纳米比亚欢乐谷地区的白岗岩进行了详细的岩石学和地球化学特征研究,初步讨论了白岗岩成因。研究结果表明,欢乐谷地区白岗岩的矿物组成和化学成分显示了较大的变化范围,白岗岩岩性主要为正长花岗岩和二长花岗岩,部分为碱长花岗岩、英云闪长岩和花岗闪长岩等。根据岩石和矿物的颜色、结构、矿物学特征、矿化特点等,可将其划分为A、B、C、D、E、F 6种类型,并且从A类至F类,白岗岩的形成时间顺序为由早到晚。白岗岩具有高硅、高碱和低锰、镁、钠、磷、钙的特点,为高钾钙碱性系列钾玄岩系列的准铝质过铝质岩石。不同类型的白岗岩主量元素特征未显示出它们是同源岩浆演化的产物,而可能是达马拉造山运动晚期构造演化不同阶段的产物。     

Petrological, organic geochemical and geochemical characteristics of coal from the Soko mine, Serbia

A petrological, organic geochemical and geochemical study was performed on coal samples from the Soko Mine, Soko Banja basin, Serbia. Ten coal and two carbonaceous clay samples were collected from fresh, working faces in the underground brown coal mine from different parts of the main coal seam. The Lower Miocene, low-rank coal of the Soko Mine is a typical humic coal with huminite concentrations of up to 76.2 vol.%, liptinite less than 14 vol.% and inertinite less than 11 vol.%. Ulminite is the most abundant maceral with variable amounts of densinite and clay minerals. Sporinite and resinite are the most common macerals of the liptinite group. Inertodetrinite is the most abundant maceral of the inertinite group. The mineral-bituminous groundmass identified in some coal samples, and carbonaceous marly clay, indicate sub-aquatic origin and strong bacterial decomposition. The mean random huminite reflectance (ulminite B) for the main coal seam is 0.40 ± 0.05% Rr, which is typical for an immature to early mature stage of organic matter.The extract yields from the coal of the Soko Banja basin ranges from 9413 to 14,096 ppm, in which alkanes constituted 1.0–20.1%, aromatics 1.3–14.7%, asphaltenes 28.1–76.2% and resins 20.2–43.5%. The saturated hydrocarbon fractions included n-C₁₅ to n-C₃₂, with an odd carbon number that predominate in almost all the samples. The contents of n-C₂₇ and n-C₂₉ alkanes are extremely high in some samples, as a contribution of epicuticular waxes from higher plants. Acyclic isoprenoid hydrocarbons are minor constituents in the aliphatic fraction, and the pristane/phytane (Pr/Ph) ratio varies between 0.56 and 3.13, which implies anaerobic to oxic conditions during sedimentation. The most abundant diterpanes were abietane, dehydroabietane and 16α(H)-phyllocladane. In samples from the upper part of the coal seam, diterpanes are the dominant constituents of the alkane fraction. Polycyclic alkanes of the triterpane type are important constituents of alkane fractions. The occurrence of ββ- and αβ-type hopanes from C₂₇ to C₃₁, but without C₂₈, is typical for the Soko Banja coals.The major and trace elements in the coal were analysed using X-ray fluorescence (XRF), and inductively coupled plasma-mass spectrometry (ICP-MS). In comparison with world lignites, using the geometric mean value, the coal from the Soko Banja Basin has a high content of strontium (306.953 mg/kg). Higher values than the world lignites were obtained for Mo (3.614 mg/kg), Ni (8.119 mg/kg), Se (0.884 mg/kg), U (2.642 mg/kg) and W (0.148 mg/kg). Correlation analysis shows inorganic affinity for almost all the major and trace elements, except for S, which has an organic affinity.