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甲酸甲酯-甲醇-水是化工生产过程中最常见的三元混合物之一。目前,间歇精馏工艺分离该三元混合物的研究较少,在动态控制方面也少有报道。本文研究了分离甲酸甲酯-甲醇-水的带有中间储罐的间歇精馏工艺动态控制模拟优化。利用Aspen Plus和Aspen Plus Dynamics软件,在稳态模拟的基础上,分别考察了液位控制结构和组分控制结构两种控制方案。结果表明,液位控制结构控制性能较差,达到稳定后甲醇和水的纯度较低。组分控制结构虽能提高产品纯度,但出现了较为严重的振荡现象。根据对组分控制结构的动态响应分析,本文提出了一种改进的组分控制结构,该控制结构能实现带有中间储罐的间歇精馏工艺的稳健控制,使各产品纯度得到提高。 相似文献
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Vacuum distillation techniques are widely used in food, biological, pharmaceutical, and wastewater treatment industries. Because of its operation at low temperatures, vacuum distillation prevents the thermal decomposition of materials and alleviates corrosion processes; however, condenser size can be dramatically increased because of reductions in mean temperature differences under the vacuum operation. In batch vacuum distillation processes, vapor generation rate and mean temperature differences are changed with time. In view of these characteristics of batch operation, this paper suggests a novel methodology to minimize the condenser size in batch vacuum distillation processes. The target process is a sulfuric acid recycling system in semiconductor manufacturing plants. In this paper, an equation-oriented dynamic model is established and optimization problem is formulated. By solving the nonlinear programming problem, the condenser size is dramatically reduced when operation time is fixed. In contrast, operation time is greatly shortened when the installed condenser surface area is fixed. 相似文献
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以Aspen Batch Distillation(ABD)中的间歇精馏仿真系统为过程原型,提出了利用过程的模拟测试数据来建立间歇精馏过程的样条插值简化模型(spline interpolation model, SIM)。结合变回流比下的动态修正函数,构造出了一种简单实用的动态模型。该模型可有效模拟不同组分浓度下回流比发生变化时馏出液浓度和流量的动态变化情况。以该模型作为预测模型,进一步提出了一种变回流比的预测控制(model predictive control, MPC)算法来使馏出液浓度按照期望的设定值变化。控制仿真结果表明该控制方案计算简单,同时具有较好的控制效果。 相似文献
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In this article, a combination of the wavelet neural network framework and the line-up competition algorithm is used to solve the economic optimization algorithm for an industrial-scale atmospheric distillation column (ADC) process. Compared to the relevant measuring data from Sinopec Wuhan Petroleum Group Company, China, the first optimal operating conditions show that the increments of the duties of furnace and pump-arounds of the ADC can effectively improve oil production. In our approach, the preflash column (PFC) coupled with ADC is denoted as an industrial-scale crude distillation unit (CDU) process. Since the PFC can produce light naphtha and reduce the furnace duty and steam consumption of ADC, it is verified that the CDU process provides the higher economic potential than ADC. Based on the second optimal operating conditions, the plantwide control strategy is employed to operate the system safely as well as regulate the outputs of the plant in the presence of inlet perturbations. Within the plantwide control framework, the inventory control aims to keep the controlled variables close to the desired operating condition and the quality control loops use a combination of inferential predictions and feedforward ratios to effectively suppress the temperature spikes of trays and furnaces. Finally, the simulations show that the product quality is guaranteed due to no offset ASTM D86 distillation temperature responses. 相似文献
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In this paper, the mixture of dimethyl carbonate, ethyl methyl carbonate and diethyl carbonate was separated by middle-vessel batch distillation with feeding in middle-vessel and process control characteristics were researched. The steady state simulation results in Aspen Plus were exported to Aspen Dynamics. Then control effect of liquid level control with HighSelector, composition control (structure1, structure2) and temperature control (proportional action, proportional integration action) were proposed. Composition control structure 2 and temperature control with PI action were investigated to achieve a good control effect. 相似文献
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Gundale Mangesh Murlidhar 《Chemical engineering science》2007,62(4):1111-1124
In this article, a nonlinear adaptive control strategy is proposed for a multicomponent batch distillation column. The hybrid control scheme consists of a generic model controller (GMC) and a nonlinear adaptive state estimator (ASE). In the first part of the study, an adaptive observer is designed aiming to estimate the partially known parameters based on the measured compositions in the presence of process/predictor mismatch. The open-loop dynamic behavior of the developed ASE estimator is investigated under initialization error, disturbance, and uncertain parameters. In the subsequent part, the adaptive GMC-ASE controller (GMC control structure in conjunction with ASE estimator) has been synthesized for the example distillation column. A simulation-based comparative study has been conducted between the derived nonlinear GMC-ASE control algorithm and a gain-scheduled proportional integral (GSPI) law in terms of constant composition control. The proposed adaptive control scheme is shown to be quite promising due to the exponential error convergence capability of the ASE estimator in addition to the high-quality performance of the GMC controller. 相似文献
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E. Sørensen S. Macchietto G. Stuart S. Skogestad 《Computers & Chemical Engineering》1996,20(12):1491-1498
While both the dynamic modelling, and to a lesser extent, the optimisation of reactive batch distillation have been studied in the past, issues related to control and on-line operation of such a process have not been properly addressed. In this study, a priori optimal profiles of the operating variables are established for an industrial reactive distillation process. The optimal profiles are found either by maximising the profitability or by minimising the operating time subject to constraints on the reactor temperature and the loss of volatile reactant in the distillate. The control properties at optimal and non-optimal conditions are assessed. A one-point column control scheme with a PI-controller is designed to implement the optimal profiles. The controller performance is tested using a simulation model including disturbances in the reaction model and in the reboiler heat duty. The fully automatic operation of the process according to the optimal policies is demonstrated in conjunction with both a continuous controller and a real time control system. Good performance is achieved in both cases. 相似文献
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理想操作条件下二元提馏式间歇精馏优化操作的汽化总量与最小汽化总量的计算是约束函数优化问题。本文采用罚函数法,将此约束函数优化转变为无约束函数优化,并采用固定双步长因子梯度法数值求解该函数的极值。计算表明:固定双步长因子梯度法具有良好的收敛性,同时,降低分段数较多时,数值截断误差积累对计算结果的影响。二元提馏式间歇精馏优化操作较恒残液组成操作的能耗低的原因如下:在理论板数相对较少(接近二元提馏式间歇精馏恒残液组成操作所需的最少理论板)时,优化操作通过控制再沸比提高了能耗效率;在理论板数相对较多时,优化操作通过控制再沸比,在保证过程的能耗效率较高的同时,可尽可能快地将物料移出系统,减少了精馏过程中塔顶贮槽内液体的混合熵产。通过对计算结果的归纳与外推,得到了理想操作条件下理论板数为无穷多时二元提馏式间歇精馏优化操作再沸比的变化方式以及最小汽化总量的计算公式。 相似文献
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根据严格逐板计算的结果,运用差分法求出灵敏度系数,对TCS-S热偶精馏进行灵敏度分析,确定灵敏板的位置即确定最优控制点,在此基础上选择最优控制方案,实现TCS-S热偶精馏塔的最优设计。 相似文献
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Batch extractive distillation (BED) is a special method used in the distillation process by adding a solvent into the batch distillation column to alter the relative volatility of the components and improve the separation. A comprehensive design and simulation method is required due to the complexity of BED. In this study, a quasi-steady-state model for BED is proposed, the derivation and solution of the model are presented. This shortcut model can be used to simulate the composition and temperature of the reboiler, the top and other plates of the column in a batch extractive distillation operation. The calculated values are in good agreement with the experi-mental data. The results show that the quasi-steady-state model is a practical method because of some advantages such as high precision and fast calculation. 相似文献
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提出了通过塔顶、塔中上以及塔中3个温度控制进行操作状态转换的无累积罐循环全回流间歇精馏控制方法,并以理想物系--乙醇-正丙醇混合物为分离物系进行了实验研究。通过实验确定了温度控制条件为当塔顶温度稳定后且塔顶和塔中上温差为0.3 ℃时变全回流为全采出操作,当塔中温度升高1.0 ℃时停止全采出转为全回流操作。同时还考察了在不同乙醇投料浓度条件下这种操作的运行情况,发现不同投料浓度对塔顶产品平均纯度的影响并不显著,基本能保持在0.99。最后在相同的投料浓度和操作条件下,对比了这种新型控制方式和双温度控制方式,结果表明三温度控制方式比双温度控制方式操作时间减少了23.3 min,分离效率提高了23.95%,产品浓度提高了1.06%,产品收率提高了1.08%。 相似文献
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Process automation involves both steady-state optimization and feedback control. In this paper, the economic optimum steady-state operating conditions for a petroleum crude distillation process are determined using a tray-to-tray model. This model is used to evaluate the steady-state operation achieved with several multivariable process control designs. Only one controller design was found to result in essentially optimum steady-state operation; others deviated significantly. The method applied in this paper relies on a knowledge of the key disturbances occurring in the process; good economic performance may not be obtained should other disturbance types occur. The results demonstrate the importance of implementing the operations optimization through a control strategy which will respond properly to disturbances. 相似文献
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Dehydration of isopropanol applying batch heteroazeotropic distillation with toluene as entrainer (E) is investigated. The composition of the feed is near to that of the isopropanol (A)-water (B) azeotrope. The effects of recycling the entrainer and the off-cut are studied by dynamic simulation with a professional flow-sheet simulator. Three consecutive batches (one production cycle) is studied. Both operational modes (Mode I: decantation after distillation and Mode II: decantation during distillation) are simulated. For Mode II, calculations are performed both for Strategy A (distillate from the aqueous (E-lean) phase only) and Strategy B (partial withdrawal of the organic (Erich phase), as well). The E-rich phase, the final column hold-up and the off-cut (Mode II only) are recycled to the next batch. The influence of the following parameters are determined: quantity of entrainer, reflux ratios of the steps. The variations caused by the recycling in the 2nd and 3rd batches are also shown. The best results (lowest specific energy demand and highest recovery of A) are obtained by Mode II, Strategy A. Recycling increases the recovery, and drastically diminishes the entrainer consumption. However, it makes the production slower and decreases the quantity of fresh feed that can be processed. 相似文献