Oxidationsverhalten von HVOF–gespritzten MCrAlY–Schichten

Oxidation Behavior of HVOF–sprayed MCrAlY–Coatings The influence of two spraying parameters (kerosene flow rate and pressure of the combusting chamber) on the high temperature oxidation behavior of HVOF‐sprayed MCrAlY‐coatings was studied on CoNiCrAlY‐coatings containing 15wt.% aluminum. After thermal spraying, different test‐specimens were heat treated for structure improvement (homogenization, reducing of the porosity and internal stresses as well as for new phase precipitation) and afterwards oxidized at 950 °C for 3000 minutes in synthetic air. In order to point out the effects of the different spraying parameters on the oxidation behavior of the coatings, the thermo gravimetrical analysis (TG) was used. The morphology and structure of the coatings were characterized before and after oxidation experiments by scanning electron microscopy (SEM) and X‐ray diffraction (XRD). The results revealed indubitable, that an increase of the kerosene flow rate and of the pressure in the combusting chamber during the spraying process leads to a better oxidation behavior of the MCrAlY‐coatings.     

CdS@SiO2 Core–Shell Electroluminescent Nanorod Arrays Based on a Metal–Insulator–Semiconductor Structure

Enormous advancement has been achieved in the field of one‐dimensional (1D) semiconductor light‐emitting devices (LEDs), however, LEDs based on 1D CdS nanostructures have been rarely reported. The fabrication of CdS@SiO₂ core–shell nanorod array LEDs based on a Au–SiO₂–CdS metal–insulator–semiconductor (MIS) structure is presented. The MIS LEDs exhibit strong yellow emission with a low threshold voltage of 2.7 V. Electroluminescence with a broad emission ranging from 450 nm to 800 nm and a shoulder peak at 700 nm is observed, which is related to the defects and surface states of the CdS nanorods. The influence of the SiO₂ shell thickness on the electroluminescence intensity is systematically investigated. The devices have a high light‐emitting spatial resolution of 1.5 μm and maintain an excellent emission property even after shelving at room temperature for at least three months. Moreover, the fabrication process is simple and cost effective and the MIS device could be fabricated on a flexible substrate, which holds great potential for application as a flexible light source. This prototype is expected to open up a new route towards the development of large‐scale light‐emitting devices with excellent attributes, such as high resolution, low cost, and good stability.     

Phase diagram calculation and experimental research on Fe–12Cr–B–Al–alloys

The vertical sections of Fe–12%Cr–B–xAl–C system with different aluminum contents have been calculated by use of Thermo‐Calc software and the influence of aluminum content on the phase regions and the parameters of eutectic point have been analyzed. Fe–12.0%Cr–1.0%B–2.0%Al–0.3%C and Fe–12.0%Cr–1.0%B–4.0%Al–0.3%C alloy were chosen to be studied by experiment. The phase transition temperatures were measured by differential scanning calorimetry and the microstructure and the phase type was detected by scanning electrone microscope‐energy dispersive X‐ray spectroscopy and X‐ray diffraction. The results indicate that calculated phase diagrams agree well with the experimental results and further prove the thermodynamics database of Thermo‐Calc software is reliable and it can be used to help design the alloy composition and heat treatment process.     

Superplastic Property of the Ti–6Al–4V Alloy with Ultrafine‐Grained Heterogeneous Microstructure

Ti–6Al–4V alloy having a heterogeneous microstructure composed of ultrafine‐equiaxed‐α‐grains and fine‐lamellar‐α‐grains is investigated for microstructural changes during superplastic deformation at temperature of 700 °C. The Ti–6Al–4V alloy having an optimum fraction of fine‐lamellar‐α‐grains exhibits an excellent superplastic property and the highest elongation of 583% (tested at 700 °C 10^?3 s^?1). This is mainly due to the optimized activation of grain‐boundary‐sliding and additional accommodation mechanism associated with frequent occurrences of dynamic recrystallization and β precipitation at boundaries during deformation of the heterogeneous starting microstructure. The present result suggests the possibility that optimizing the starting microstructure so as to have an optimum heterogeneous‐microstructure serves as an additional stress accommodation mechanism and leads to a large superplastic elongation.

     

Robust and provably second‐order explicit–explicit and implicit–explicit staggered time‐integrators for highly non‐linear compressible fluid–structure interaction problems

An explicit–explicit staggered time‐integration algorithm and an implicit–explicit counterpart are presented for the solution of non‐linear transient fluid–structure interaction problems in the Arbitrary Lagrangian–Eulerian (ALE) setting. In the explicit–explicit case where the usually desirable simultaneous updating of the fluid and structural states is both natural and trivial, staggering is shown to improve numerical stability. Using rigorous ALE extensions of the two‐stage explicit Runge–Kutta and three‐point backward difference methods for the fluid, and in both cases the explicit central difference scheme for the structure, second‐order time‐accuracy is achieved for the coupled explicit–explicit and implicit–explicit fluid–structure time‐integration methods, respectively, via suitable predictors and careful stagings of the computational steps. The robustness of both methods and their proven second‐order time‐accuracy are verified for sample application problems. Their potential for the solution of highly non‐linear fluid–structure interaction problems is demonstrated and validated with the simulation of the dynamic collapse of a cylindrical shell submerged in water. The obtained numerical results demonstrate that, even for fluid–structure applications with strong added mass effects, a carefully designed staggered and subiteration‐free time‐integrator can achieve numerical stability and robustness with respect to the slenderness of the structure, as long as the fluid is justifiably modeled as a compressible medium. Copyright © 2010 John Wiley & Sons, Ltd.     

Reaktives Diffusionslöten von Keramik an Stahl mittels Zr–Cu–Zr‐ und Zr–Ni–Cu–Zr‐Schichten für Anwendungen im Hochtemperaturbereich

Joints manufactured by transient liquid phase bonding feature comparable properties as diffusion weldements, but considerably lower process temperatures and pressures have to be applied. The liquid phase, which is hereby used, occurs due to interdiffusion between the base and/or the filler materials at a constant temperature, which lies below the melting temperature of the substrates. An essential requirement for this diffusion‐based melting is that the involved materials have low melting alloy‐constitution areas, such as eutectics. The aim of the study, presented in this contribution, is to evaluate an approach, in which an active transient liquid is created by suitable interlayers, in order to facilitate the wetting of ceramics. The potential of this attempt will be illustrated on zirconia/stainless‐steel‐joints for high temperature applications, such as solid oxide fuel cells. In such applications, the used materials have to withstand harsh conditions, e.g. high operating temperatures, oxidizing or reducing environments, which represent a demanding challenge for joining technologies, even at the latest state of research. In this study interlayers, consisting of Zirconium, as the active element, in combination with Copper and/or Nickel, have been investigated. These systems exhibit a wide range of alloy‐constitutions with low melting temperatures, which can be used for the formation of the transient liquid phase. For the application of the interlayers, physical vapor deposition as well as 75 µm‐thick Nickel‐foils have been used. The joining was carried out in high vacuum with changing holding times and temperatures. Additionally, the ratio of the thickness of the used interlayers was changed. Results of microstructural investigations, nano‐hardness measurements of the joining area as well as shear strength and fractography are presented.     

Efficient Vacuum‐Processed Light‐Emitting Diodes Based on Carbene–Metal–Amides

Efficient vacuum‐processed organic light‐emitting diodes are fabricated using a carbene–metal–amide material, CMA1. An electroluminescence (EL) external quantum efficiency of 23% is achieved in a host‐free emissive layer comprising pure CMA1. Furthermore external quantum efficiencies of up to 26.9% are achieved in host–guest emissive layers. EL spectra are found to depend on both the emissive‐layer doping concentration and the choice of host material, enabling tuning of emission color from mid‐green (Commission Internationale de l'Éclairage co‐ordinates [0.24, 0.46]) to sky blue ([0.22 0.35]) without changing dopant. This tuning is achieved without compromising luminescence efficiency (>80%) while maintaining a short radiative lifetime of triplets (<1 μs).     

Single‐Atom Nanozyme Based on Nanoengineered Fe–N–C Catalyst with Superior Peroxidase‐Like Activity for Ultrasensitive Bioassays

Single‐atom catalysts are becoming a hot research topic owing to their unique characteristics of maximum specific activity and atomic utilization. Herein, a new single‐atom nanozyme (SAN) based on single Fe atoms anchored on N‐doped carbons supported on carbon nanotube (CNT/FeNC) is proposed. The CNT/FeNC with robust atomic Fe–N_x moieties is synthesised, showing superior peroxidase‐like activity. Furthermore, the CNT/FeNC is used as the signal element in a series of paper‐based bioassays for ultrasensitive detection of H₂O₂, glucose, and ascorbic acid. The SAN provides a new type of signal element for developing various biosensing techniques.     

Luminescence Lifetime–Based In Vivo Detection with Responsive Rare Earth–Dye Nanocomposite

For years, luminescence lifetime imaging has served as a quantitative tool in indicating intracellular components and activities. However, very few studies involve the in vivo study of animals, especially in vivo stimuli‐responsive activities of animals, as both excitation and emission wavelengths should fall into the near‐infrared (NIR) optical transparent window (660–950 and 1000–1500 nm). Herein, this work reports a lifetime‐responsive nanocomposite with both excitation and emission in the NIR I window (800 nm) and lifetime in the microsecond region. The incorporation of Tm³⁺‐doped rare‐earth nanocrystals and NIR dye builds an efficient energy transfer pathway that enables a tunable luminescence lifetime range. The NaYF₄:Tm nanocrystal, which absorbs and emits photons at the same energy level, is found to be 33 times brighter than optimized core–shell upconversion nanocrystals, and proved to be an effective donor for NIR luminescence resonance energy transfer (LRET). The anti‐interference capability of luminescence lifetime signals is further confirmed by luminescence and lifetime imaging. In vivo studies also verify the lifetime response upon stimulation generated in an arthritis mouse model. This work introduces an intriguing tool for luminescence lifetime–based sensing in the microsecond region.