共查询到20条相似文献,搜索用时 93 毫秒
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研究了水和无水乙醇对萘磺酸掺杂的纳米管结构聚苯胺的电阻率-温度依赖关系的影响(测量温区为80—300K).实验结果表明,水分子和乙醇分子的进入均使样品的电导率升高.利用电荷能量限制隧道模型结合纳米管粉末压片的结构特点,认为样品电阻主要来源于纳米管间接触电阻.水或乙醇分子在纳米管聚苯胺中通过与分子链的相互作用,增加了链间与链上非局域化载流子的数量,增大管间接触界面,降低了载流子的隧穿势垒,进而提高了导电能力.但水和乙醇对样品导电性质影响程度是不同的,主要是因为水分子和乙醇分子在结构和物理化学性质上的不同.
关键词:
聚苯胺
纳米管
电阻率 相似文献
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通过研究用自组装法制备的萘磺酸掺杂的纳米管结构聚苯胺(苯胺与萘磺酸的摩尔比分别为1∶025,1∶05,1∶1,1∶2,1∶3)的电阻率温度依赖关系(测量温区为80—300K),仔细分析聚苯胺的结构形貌特征,提出了变程跳跃隧道穿透混合模型:认为在萘磺酸掺杂的纳米管结构聚苯胺样品中,跳跃和隧穿两种机制同时起作用,载流子沿纳米管传导是变程跳跃过程起主要作用,而载流子在纳米管之间的传导是隧穿过程起主要作用.实验结果表明,不同浓度的萘磺酸掺杂对样品的低温电阻率的影响很大,随着掺杂浓度增加,载流子传导所需克服的能垒C0迅速减小,当掺杂接近饱和时,C0不再减小.实验中还研究了不同形貌对电阻率的影响,结果表明样品中纳米管所占比例的增大有利于载流子传导
关键词:
聚苯胺
纳米管
低温电阻率 相似文献
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The powder diffractometer and Hi-Q diffractometer at Dhruva reactor make use of five identical 1-D position sensitive detectors (PSDs) to scan scattering angles in the range 3° to 140°. In order to improve the overall throughput of these spectrometers, it is planned to install a bank of 15 high-efficiency and high-resolution PSDs arranged in three layers with five PSDs in each layer. With each high pressure PSD (3He 10 bar + Kr 2 bar) showing the efficiency gain of 1.8 at 1.2 Å, detector bank is expected to show overall gain of 5.5 times the present detection efficiency and reduction in data collection time by equivalent factor. The 1-D PSDs are developed in batches of five, and are characterized so that all PSDs operate at uniform parameters such as position resolution, uniformity of efficiency and linearity of response. Position spectrum indicates the differential position resolution to be ~1 mm and integral position resolution to be 3–4 mm. Broadening of position spectrum at the extreme end of sensitive length of PSD is analysed using fine shift of the beam. Dependence of position resolution and dynamic range of output pulse on the input impedance of pre-amplifier is also presented. 相似文献
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A. Mahesh Kumar M. Chaitanya Varma G.S.V.R.K. ChoudaryP. Prameela K.H. Rao 《Journal of magnetism and magnetic materials》2012,324(1):68-71
The study of gadolinium substitution in small amounts on the saturation magnetization and DC resistivity of nickel-zinc nanoferrite has led to the understanding of the degree of formation of a secondary orthoferrite GdFeO3 phase, the generation of cationic and oxygen vacancies and the dilution of gadolinium in the lattice. The role of secondary phase in modifying the electromagnetic properties has been stressed by making further investigations on the Curie temperature and the activation energies. 相似文献
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A. V. Belushkin 《Pramana》2008,71(4):639-651
Different types of neutron scattering experiment for the study of condensed matter properties pose specific and often contradictory
requirements for detector characteristics. There is no single type of detector which satisfies all the criteria. Therefore,
compromise is inevitable and some of the characteristics are trade off in favour of others.
Present report gives an overview of detector systems presently operating at the leading neutron scattering facilities as well
as some development work around the globe.
相似文献
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基于CFETR工程设计,使用TOKSYS建立了CFETR极向场线圈、真空室壁和包层结构的等效二维模型.在三种平衡的等离子体位形下,分析了包层结构整体等效电阻率和极向不同位置的等效电阻率对等离子体垂直位移增长率的影响.结果表明,垂直位移增长率随着包层整体等效电阻率的增加近似线性增大;降低极向±60°附近的等效电阻率,能减... 相似文献
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Daniel Mattis 《Journal of statistical physics》1994,77(1-2):383-396
A first-principles calculation of the initial decay of a current-carrying state is used to infer the electrical resistivity ofinteracting fermions (electrons or holes). This approach is useful when it is impractical to apply the Kubo formalism. 相似文献
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T. S. Orlova A. M. Mavlyutov A. S. Bondarenko I. A. Kasatkin M. Yu. Murashkin R. Z. Valiev 《哲学杂志》2016,96(23):2429-2444
An ultrafine grained (UFG) structure has been obtained in commercial purity Al by high-pressure torsion (HPT). Changes in microhardness and electrical resistivity of the UFG material after annealing at various temperatures within a range of 363–673 K have been investigated in correlation with the microstructure evolution. It has been shown that annealing at 363 K leads to substantial decrease in the electrical resistivity while keeping high microhardness level and approximately the same average grain size. The contributions from the various microstructural units (vacancies, dislocations, grain boundaries (GBs)) to the electrical resistivity were analysed. It was shown for the first time that a non-equilibrium state associated with strain-distorted grain boundary (GB) structure strongly affects electrical resistivity of UFG Al. The resistivity of non-equilibrium GBs in UFG structure formed by HPT was evaluated to be at least 50% higher than the resistivity of the thermally equilibrium GBs in a coarse-grained structure. 相似文献
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The far-infrared spectra of six mixed ferrites (CdxCo1−x+tTitFe2−2tO4; x=0.2, 0.00?t?0.25) in the range 200-1000 cm−1 are reported. Two strong high-frequency bands ν1 and ν2 are observed. The first one ν1 is assigned to the tetrahedral and the second ν2 is assigned to the octahedral site. A small kink ν3 around near ν2 is observed and its intensity increases with divalent octahedral metal ion concentration. Seebeck coefficient measurements showed that the substitution of tetravalent ion Ti4+ does not change the polarity of the Seebeck coefficient from p- to n-type. The activation energy and the carrier mobility μ were also calculated. The effect of mechanical pressure on the dc resistivity was investigated. 相似文献
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To probe the effect of the protein environment on the retinal chromophore of rhodopsin, we performed molecular dynamics simulations using combined quantum mechanics/molecular mechanics (QM/MM). The starting geometry of the protein is based on the 2.6Å X-ray structure of bovine rhodopsin of Okada et al. [T. Okada, et al. Proc. Natl. Acad. Sci. USA 99 5982 (2002)]. The wild-type chromophore of rhodopsin according to our calculations shows a highly twisted conformation around the central region, from C10 to C13, due to non-bonded interaction with the protein pocket. The absolute sense of twist of the C11–C12 and C12–C13 bonds is negative (?19 ± 9°) and positive (170 ± 8°), respectively. The 13-demethyl retinal chromophore, in which the methyl group at the C13 position is removed, is less distorted in this region. The C11–C12 bond is less twisted (?15 ± 10°) and the C12–C13 bond is planar (179 ± 9°) . The flattened geometry of this artificial chromophore is supported by spectroscopic evidence. 相似文献
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《Waves in Random and Complex Media》2013,23(4):650-670
A mathematical model is developed in which the effect of imperfect bonding between the constituents of layer and half-space on the phase velocity and damped velocity of SH-wave is discussed. The model consists of a micropolar elastic half-space bonded imperfectly with a heterogeneous viscoelastic layer. The dispersion equation and damping equation of SH-wave propagation in the said model is obtained in the closed form analytically. The effects of imperfect bonding, internal friction, heterogeneity, micropolarity, and complex interface stiffness parameters highlighted through numerical computation and graphical demonstrations. Standard Love-wave equation and dispersion equation as well as damping equation for perfectly bonded micropolar half-space with heterogeneous viscoelastic layer is obtained as a special case of the problem. Through comparative study of homogeneity with heterogeneity in the layer; imperfect bonding of layer and half-space with their welded (perfect) contact; and presence of micropolarity in half-space with its absence in half-space are compared meticulously. 相似文献