Assessment of UV-permeability in nano-ZnO filled coatings via high throughput experimentation

The degree of UV protection afforded by nano-ZnO in a polyurethane/acrylic clear topcoat was investigated. The influence of nano-ZnO concentration and dry film thickness on the optical properties (e.g., UV permeability and visible transmittance) of the coating was probed using a library of 28 samples that were prepared by high throughput techniques. A model for predicting the UV permeability of nano-ZnO filled coatings was developed and the nano-ZnO loading condition required to block >99% UV radiation was determined to be 2.0 g/m². This model can be used to assist in the development of coatings and other polymeric systems embedded with nano-ZnO to protect the coating and underlying materials (i.e., substrate) from UV degradation.

板翅式换热器封头结构物流分配的PIV实验研究

在数值模拟的基础上,利用粒子图像测速仪(PIV)对板翅式换热器原始封头A和3种改进的顺排孔板型封头结构(B、C、D)的流场进行了可视化的实验,获得了封头内部不同截面处流场的速度流线分布图.比较了Re＝6.22×10⁴时原始封头A和一种改进型封头B的出口物流分配以及3种不同中孔面积比率的改进型封头对出口物流分配的影响.结果表明：改进型封头结构能有效地改善物流分配的均匀性;C型封头的不均匀参数S_U和最大流速与最小流速之比θ_U最低;流量分布和中孔面积比率之间存在着一个最佳值.     

涡轮桨搅拌槽内湍流特性的V3V实验及大涡模拟

分别用体三维速度测量技术（volumetric three-component velocimetry measurements,V3V）和大涡模拟（large eddy simulation,LES）方法对涡轮桨搅拌槽内流场进行研究,发现在完全湍流状态下,涡轮桨搅拌槽内流场的量纲1相平均速度及湍动能分布同Reynolds数无关。用V3V方法实现了Rushton桨叶附近三维流场的重构;探讨尾涡的三维结构及运动规律;分析了叶片后方30°截面轴向、径向和环向速度沿径向分布规律。用V3V实验结果对比了2D-PIV（particle image velocimetry）数据中的尾涡涡对位置和涡量,涡对位置吻合度较好,但2D-PIV中涡量较V3V小37.5%;通过大涡模拟得到完整的尾涡结构,发现在叶片上边缘后侧存在一个和尾涡形成方式相同但不成对出现的涡结构;将大涡模拟结果和2D-PIV及V3V实验结果对比发现,大涡模拟在速度分布及尾涡运动轨迹方面均同实验结果吻合较好,表明大涡模拟能较好地预测涡轮桨搅拌槽内流场。     

Use of PIV to measure turbulence modulation in a high throughput stirred vessel with the addition of high Stokes number particles for both up- and down-pumping configurations

A refractive index matching technique combined with particle image velocimetry (PIV) was used to measure turbulent properties of solid–liquid suspensions in a small high throughput scale cylindrical vessel of 45 mm diameter agitated with a 45° pitched blade turbine (PBT) for up-pumping (U) and down-pumping (D) configurations. This study analyses the effect of large 1.5 mm diameter particles (Stokes number>1), on liquid mean velocities, turbulent kinetic energy (TKE) and energy dissipation (ε) at particle concentrations of 0%, 1.5% and 5% by volume. Only small changes in the time-averaged liquid velocities were observed with increasing particle concentration. However, maximum TKE near the impeller decreased up to 40% with increasing particle concentration for both configurations. The Smagorinsky SGS method was used to estimate local energy dissipation rate near the impeller and the maximum value was found to decrease by 50% between 0% and 5% concentration for the (U) configuration. A lesser but still significant drop of 30% was observed for the (D) configuration. These data confirm that large Stokes number particles can suppress turbulence, in agreement with some previous experimental studies, but in contradiction with existing theories.     

The confined impeller stirred tank (CIST): A bench scale testing device for specification of local mixing conditions required in large scale vessels

A new stirred tank geometry, the confined impeller stirred tank (CIST), was designed to provide repeatable testing of the effect of mixing on the performance of chemical additives at the bench scale. The CIST (T = 0.076 m, H = 3T) is filled with five or six impellers. Three impeller geometries were tested: A310, Rushton and Intermig. This paper presents the following hydrodynamic characteristics of the CIST: power number, flow number, momentum number, velocity profiles at different locations in the tank and the transition point from fully turbulent to transitional flow. Based on the scaled velocity profiles, the CIST was able to keep the flow turbulent at Re < 2000 for Rushton turbines and 3200 for Intermigs. The ratio ?_max/?_average was lower for the CIST than for a conventional stirred tank, indicating that the energy dissipation is more uniformly distributed in the CIST. The CIST consistently maintains turbulent flow down to a Reynolds number 10× smaller than that needed in a conventional stirred tank.     

A novel fabrication method of temperature-responsive poly(acrylamide) composite hydrogel with high mechanical strength

High strength, stimuli-responsive poly(acrylamide) composite hydrogels (PAAm CH gels) were prepared by grafting polymerization of acrylamide (AAm) onto temperature-sensitive core–shell microgels. These microgels, composing of poly(N-isopropylacrylamide) as core and polyvinylamine (PVAm) as shell, were used as both initiator and crosslinker to form a robust three-dimensional network via bonding the poly(acrylamide) (PAAm) backbone. The CH gels exhibited a remarkably rapid shrinking rate and transmittance switch in response to the environmental temperature change, which the conventional chemically cross-linking PAAm hydrogels (PAAm OR) were short of. Even compared to the bulk PNIPAAm hydrogels (PNIPAAm OR) crosslinked with N,N′-methylenebisacrylamide (MBA), the CH gels were featured with faster responsive rate, which could be attributed to the formation of interconnected water transportation channels between the microspheres and PAAm gel matrix due to the fast shrinking of microgels. Moreover, the effects of microgel species and content on swelling and mechanical properties of CH gels were also systematically investigated. The results elaborated that the CH gels could be compressed almost 99% without breaking and completely recovered their original shape when the stress was removed. And the optimized compressive strength of CH gels could be up to 21.94 MPa. Based on the analysis of CH gel mechanical properties, the influence of microsphere content on effective network chains density of CH gels was discussed through rheology measurements. Finally, the essential reinforcement on mechanical properties was mainly contributed to the homogeneous microstructure of hydrogel network and the energy dissipation mechanism of microgels in gel matrix.     

Synergetic optimization of p-type Ba2+ substitution and carbon nanotubes enwrapping in Na3V2(PO4)3: A superior cathode with high electrochemical and safety performance for half and full cells

Na₃V₂(PO₄)₃ (NVP) has been deemed as a promising cathode because of high capacity and good stability. Nevertheless, poor intrinsic conductivity seriously limits its further application. Herein, partial Ba²⁺ substitution on V³⁺ site is introduced to modify NVP in terms of increasing cell volume due to larger ionic radius of Ba²⁺ and generating beneficial hole carriers derived from p-type doping. The expanded crystal channels efficiently facilitate the Na ⁺ migration and the hole carriers are beneficial for transfer charge to improve electronic conductivity. Ba²⁺ doping further enhances the structural stability due to the pillar effect, which has been proved by DSC measurement. The increase of exothermic peak temperature and decrease of heat release rate demonstrates the excellent thermal stability of NVBa0.07P@CNTs. Moreover, disordered carbon layer and enwrapped CNTs construct an effective network to provide abundant routes for electronic transportation. Notably, the optimized NVBa0.07P@CNTs delivers superior electrochemical performance in both half and full cells. It releases a capacity of 117.23 mA h g⁻¹ at 0.1C and submits a capacity of 101.99 mA h g⁻¹ with retention of 80% at 15 C over 2000 cycles. Even at 50 C, it still delivers a high value of 78.33 mA h g⁻¹.     

Alkali decomposition of poly(ethylene terephthalate) with sodium hydroxide in nonaqueous ethylene glycol: A study on recycling of terephthalic acid and ethylene glycol

Pellets of poly(ethylene terephthalate) (PET; 0.48–1.92 g) were heated in anhydrous ethylene glycol (EG; 5 mL) with 2-equivs of NaOH at 150°C for 80 min or 180°C for 15 min to convert them quantitatively to disodium terephthalate (Na₂-TPA) and EG. The disodium salt was precipitated quantitatively in pure state from the EG solution and separated readily. The other product EG, being the same component to the solvent, remains in the solution and can be obtained after distillation as a part of the solvent. The rate of decomposition was significantly accelerated by the addition of ethereal solvents to EG, such as dioxane, tetrahydrofuran, and dimethoxyethane. The reaction system is simple; no water and no extra reagent other than NaOH and EG are used. A few recycling systems of PET can be designed on the basis of the present alkali decomposition reaction. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 63: 595–601, 1997     

Fluorescence study of the dynamics of a star-shaped poly(?-caprolactone)s in THF: A comparison with a star-shaped poly(l-lactide)s

Molecular dynamics of 2-, 4- and 6-arm star-shaped poly(?-caprolactone)s (PCLs) functionalized with pyrene at all chain ends followed by excimer formation were investigated in THF as a solvent. Dilute solutions (10⁻⁸ to 10⁻⁶ mol L⁻¹) of these polymers revealed excimer emission due to the intramolecular cyclization, proceeding via chain end interaction. Time-resolved fluorescence measurements of star-shaped PCLs showed complex decay profiles of monomer and excimer fluorescence. An intensity rise component of decay profiles monitored in excimer region (500 nm) was observed for star-shaped polymers due to dynamic formation of excimers. Dipyrene-PCL (2-arm) also showed partial formation of static pyrene excimers as followed from measurement of excitation spectra at ambient temperature in THF. Excimer intensity of di- and four pyrene-telechelic PCLs was found to be comparable with that of di- and four pyrene-telechelic polylactide (PLA) polyesters having similar molar masses. 6-Arm PCL showed depressed excimer formation with regard to 6-arm PLA under the otherwise identical conditions contrary to the conclusion expected from the higher flexibility of the PCL chain. Eventually, molecular dynamic simulations showed that possible explanation can be related to different conformations of 6-arm PLA versus PCL stars.     

Extracting Cu(II) from aqueous solutions with hydrophobic room-temperature ionic liquid in the presence of a pyridine-based ionophore to attempt Cu recovery: A laboratory study

Extraction of Cu(II) from neutral aqueous solutions with the hydrophobic room-temperature ionic liquid (IL) N-butyl-N-methylpyrrolidinium bis((trifluoromethyl)sulfonyl)imide (BMP-TFSI) in the presence of the pyridine-based ionophore N¹,N¹,N⁴,N⁴-tetrakis(2-(pyridin-2-yl)ethyl)butane-1,4-diamine (C₄N₂Py₄) is demonstrated in this study. Although the distribution coefficients, D_M, of Cu(II) extraction depend on the concentration of Cu(II) in aqueous solutions, all values were higher than 200, indicating extremely high extraction efficiency. Based on spectrophotometric, electrochemical, and X-ray crystallography studies, the coordination number of the C₄N₂Py₄-coordinated Cu(II) ions was determined as 2. The voltammetric behavior of Cu(I), Cu(II), and their C₄N₂Py₄ complex ions were also studied. The recovery of Cu from the IL was conducted by washing the IL phase containing the extracted Cu(II) complex with an acidic aqueous phase or by controlled-potential electrolysis. The IL containing C₄N₂Py₄ was employed for two complete rounds and a decrease in extraction efficiency was only observed when higher concentration of Cu(II) was used.     

Comparative study of lithium ion conductors in the system Li1+xAlxA2−x (PO4)3 with A=Ti or Ge and 0≤x≤0·7 for use as Li sensitive membranes

Preparations and physico-chemical characterizations of NASICON-type compounds in the system Li_1+xAl_xA_2−x^IV(PO₄)₃ (A^IV=Ti or Ge) are described. Ceramics have been fabricated by sol-gel and co-grinding processes for use as ionosensitive membrane for Li⁺ selective electrodes. The structural and electrical characteristics of the pellets have been examined. Solid solutions are obtained with Al/Ti and Al/Ge substitutions in the range 0≤x≤0·6. A minimum of the rhombohedral c parameter appears for x about 0·1 for both solutions. The grain ionic conductivity has been characterized only in the case of Ge-based compounds. It is related to the carrier concentration and the structural properties of the NASICON covalent skeleton. The results confirm that the Ti-based framework is more calibrated to Li⁺ migration than the Ge-based one. A grain conductivity of 10⁻³ S cm⁻¹ is obtained at 25°C in the case of Li_1·3Al_0·3Ti_1·7(PO₄)₃. A total conductivity of about 6×10⁻⁵ S cm⁻¹ is measured on sintered pellets because of grain boundary effects. The use of such ceramics in ISE devices has shown that the most confined unit cell (i.e. in Ge-based materials) is more appropriate for selectivity effect, although it is less conductive.©