共查询到18条相似文献,搜索用时 62 毫秒
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锌精矿焙烧阶段产生的铁酸锌(ZnFe2O4)是一类具有尖晶石结构的复合氧化物,性质稳定,不溶于稀酸和碱,在常规浸出条件下,仍有20%的锌以铁酸锌的形式存在于锌浸渣中,导致锌精矿焙烧产物的锌浸出率不高,一般为80%左右。机械活化具有使矿物晶格产生缺陷,降低反应对温度、酸浓度等条件依赖程度的优点。因此,本文采用机械活化对锌焙砂进行预处理,以硫酸为浸出剂,研究了机械活化时间、球料比、硫酸浓度、液固比、温度对锌的浸出率及其他杂质离子的影响规律。结果表明:锌的浸出率随机械活化时间的延长呈现出先增大后降低的趋势。机械活化(H2C2O4·2H2O与锌焙砂的质量比为3.60%,球料比为2∶1,球磨时间10min)-酸浸(70g/L H2SO4,液固比为10∶1,温度为35℃)工艺结果表明,锌的浸出率为87.61%,与未机械活化时相比(82.59%),锌的浸出率提高5个百分点。机理分析表明,机械活化使锌焙砂颗粒粒径变小,产生晶格畸... 相似文献
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作为一种战略金属,镍广泛应用于不锈钢、特殊金属合金、二次电池等领域。近年来,随着新能源汽车产业的快速发展以及动力电池正极材料“无钴高镍”发展趋势,对镍的需求量持续攀升。然而,我国镍资源的对外依存度高达86%,供需矛盾日益突出。针对镍冶炼主要原料的硫化镍矿开采、富集较为困难,传统冶炼方法存在回收率低、环境风险高等瓶颈问题,本研究在分析硫化镍矿矿物学特性的基础上,系统综述了硫化镍矿中镍提取技术的研究进展及存在的问题,综合考虑镍的回收率、物质和能量消耗、环境影响等因素,提出了强化硫化镍矿中镍提取技术研发的建议,同时对硫化镍矿中镍提取技术发展趋势进行了展望。 相似文献
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对滚筒球磨、行星球磨和搅拌球磨不同设备机械活化攀枝花钛铁矿及其浸出反应进行了研究.结果表明,机械活化可以强化钛铁矿的浸出过程,搅拌磨强化浸出的效果最好,行星磨次之,滚筒磨最差.活化后的钛铁矿浸出活性与其晶胞在c轴方向的显微应变增大有关,而与a轴和b轴方向的显微应变关系不大.搅拌磨活化时能产生更细小的矿物颗粒,在c轴方向有更大的显微应变以及在颗粒表面有更高的表面活性,浸出活性更高.钛铁矿的浸出效果与有效的活化效果有关,而活化效果与机械力的强度和类型都有关. 相似文献
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机械活化对氧化锌矿碱法浸出及其物化性质的影响 总被引:1,自引:0,他引:1
研究了不同活化时间、活化方式对云南兰坪低品位氧化锌矿碱法浸出的影响. 结果表明,当浸出液NH4Cl浓度2.0 mol/L、NH3×H2O浓度1 mol/L、温度30℃、浸出液与浸出矿样液固比为10 L/g时,未活化矿样浸出90 min浸出率仅为60.08%,而活化90 min矿样浸出90 min的浸出率为69.36%,为可浸出含锌物相的103.97%;先磨后浸的强化效果优于边磨边浸. 不同活化时间、活化方式不仅造成矿物的形貌、粒度分布不同,而且使矿样在球磨过程中的物相转化存在差异:活化与浸出步骤分离时,球磨过程发生了机械化学反应,矿样中ZnS被氧化成利于浸出的物相,从而比两步骤合并的浸出效果好. 相似文献
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针对能产生自燃内因火灾的典型硫化矿石类型,介绍了其堆积、氧化自热、着火及燃烧各阶段的特征,分析了氧化自燃发生的原因和发展过程,并探讨了影响硫化矿石自燃的各种因素及其作用机理.在此基础上,澄清了对硫化矿山火灾防治有重要指导意义的自燃发火初期的概念及其征兆识别方法,可为现场硫化矿山自燃火灾的早期识别与防治提供指导. 相似文献
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The feasibility of oxidation leaching process of nickel from nickel sulfide ore and the form of different components in the lixivium has been studied at first. The method of leaching nickel sulfide concentration directly by oxidants with existence of ultrasonic has been advanced. The process of leaching nickel from nickel sulfide concentration by using the system of persulfate and silver has been determined. The influence of different factors on the leaching rates of nickel, such as with and without ultrasonic, the concentration of Na2S2O8, liquid-solid ratio and the concentration of AgNO3 have been explored. The results show that: (1) in the oxidative leaching system, nickel can be leached completely as Ni2+ or NiSO4(aq.)from nickel sulfide concentration in theory; (2) the nicopyrite can not exist steadily in the persulfate acid leaching system, but Ni2+can. Meanwhile, sulfur may be existed steadily in the leaching process; (3) nicopyrite with much lower electrostatic potential may be leached earlier than chalcopyrite and sideropyrite; and (4) the overall reaction rate of the leaching process can be enhanced with ultrasonic radiation, but it does not change the mecha-nism of leaching. The more oxidant concentration or higher liquid-solid ratio is, the higher leaching percentage of nickel. The leach-ing percentage of nickel can be increased significantly by adding a small amount of AgNO3 during the leaching processes. Under the same conditions, the higher concentration of AgNO3 is, the higher leaching yields of nickel will be obtained. 相似文献
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The process of activating coal spoil (CS) in order to recover aluminum as a high value product was investigated. The CS was first characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD) and thermogravimetric analysis-differential scanning calorimetry (TGA-DSC) in order to determine the chemical and mineral compositions of the CS. Then a mechanothermal activation method was adopted to increase the aluminum activity in the coal spoil. Over 95% of the aluminum in the CS could be extracted using this activation method. The mechanothermal activation process promoted the destruction of kaolinite structures and hindered the formation of amorphous γ-Al2O3. This resulted in a high aluminum leaching activity in the mechanothermally activated CS. 相似文献
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近年来,随着新能源产业规模的持续扩大,全球消费市场对锂产品的需求迫切度也日益增加。锂辉石作为优质的提锂原料,其最新的提取加工技术一直受到重点关注。采用澳大利亚马里恩矿区的锂辉石矿,通过机械活化法强化其在碱性水热体系中的浸出过程,并分析其浸出行为。结果表明,当锂辉石粒度小于75 μm、氢氧化钠质量分数为25%、碱矿质量比为1.5∶1、反应温度为523.15 K、反应时间为8 h、反应釜转速为100 r/min时,锂提取率可达90.18%。Avrami-Erofeev动力学经验模型能够较好地描述采用机械活化法强化锂辉石浸出的过程,其反应表观活化能为41.739 kJ/mol。 相似文献
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A new method is developed for obtaining powder nanocomposites consisting of a metallic or intermetallic matrix and ceramic
nanometer particles as a reinforcing phase. This method involves the following consecutive processes: short-time mechanical
activation of the mixture of powder reagents in a high-energy planetary ball mill, self-propagating high-temperature synthesis,
and additional mechanical activation of the synthesis products. Specific features of the reinforcing phase synthesis in matrices
are examined by an example of TiB2-Cu and TiB2-TiNi systems. Compaction conditions that allow obtaining volume nanostructural materials with high strength characteristics
are found.
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Translated from Fizika Goreniya i Vzryva, Vol. 43, No. 2, pp. 58–71, March–April, 2007. 相似文献
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研究了二氧化锰氧化法吸收硫化氢的新工艺,考查了酸度、时间、温度等条件对吸收硫化氢工艺的影响,确定了适合的工艺参数。较合适的条件为:一段,溶液体积0.3L、硫酸浓度0.4mol/L、温度为室温、二氧化锰用量10g;二段,溶液体积0.5L、硫酸浓度0.4mol/L、温度为室温、二氧化锰用量10g。氧化剂二氧化锰被还原为硫酸锰可用氧化水解的方法再生,循环使用。研究结果表明,采用氧化吸收新工艺可以使硫化氢气体的吸收率大于97%,而且二氧化锰可以通过氧化水解的方式再生,实现了氧化剂的再生和循环利用。 相似文献
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基于机械活化原理对铜尾矿性能进行了试验研究,结果表明粉磨10 min的铜尾矿掺入水泥后,水泥标准稠度需水量随着掺加量的增加而减小,继续延长粉磨时间水泥标准稠度需水量随着掺量增加而增加,而粉磨时间对掺有铜尾矿的水泥凝结时间几乎没有影响。在12%~16%范围内,延长粉磨时间对铜尾矿28 d活性指数较为有利,其余掺量并不明显,并且掺入铜尾矿的水泥流动性损失加剧。 相似文献