疏水表面用于延缓热泵结霜及加快除霜的探讨

分析了水蒸气在不同表面冷凝形成冷凝水进而被冷却形成霜层的几种情况，以及冷凝水在不同表面的脱落现象，提出了疏水表面用于延缓结霜及加快除霜从而节能降耗的方法。     

Minimising frost growth on cold surfaces exposed to humid air by means of crosslinked hydrophilic polymeric coatings

Experiments have shown that frost growth on cold surfaces exposed to warm humid air streams can be reduced significantly by means of crosslinked hydrophilic polymeric coatings. This derives from the ability of these materials, under frosting conditions, to absorb available water, and hence retard the growth of frost when compared to an uncoated metallic surface. The extent of reduction of frost growth appeared to vary with the water absorbing potential of the polymer-coat, as well as its water content prior to frosting. In general, measurements in over two hours of testing, indicated that the reduction in frost growth rate and subsequently frost thickness lies in the range, 10–30%. The absorbed water improves the thermal conductivity of the polymeric coating. This, consequently, lowers the total thermal resistance between the air stream and the cold plate, and hence retards the frost surface temperature in its rise towards 0°C, an effect that would prolong the effective operation time of the thermal process before there is need for defrosting. Further observations made in this study tend to suggest that the nature of the frost formed with an air stream of low relative humidity (RH) differed from that resulting from a high RH air stream.     

Experimental investigations of frost release by hydrophilic surfaces

Frost formation occurs when water vapor in the surrounding air comes into contact with cold surfaces through heat and mass transfer. It is usually an undesirable phenomenon in most refrigeration and cryogenic systems. A few studies have shown that changing the surface energy, such as increasing the surface hydrophilicity or hydrophobicity, has significant effects on frost growth. In this paper, a kind of hydrophilic polymer paint is formulated to counteract frost deposition on cold surfaces. The coated surface can retard frost formation up to three hours under low plate temperatures (− 15.3°C) and high air humidity (72%). To test the antifrosting performance of the hydrophilic paint under more practical conditions, it is applied to a fin-and-tube heat exchanger and a domestic refrigerator at a coating thickness of 30 μm. Comparisons of frost deposition, pressure drops, and outlet temperatures are made between uncoated and coated heat exchangers. Under conditions of high air temperature (2.2°C) and relative high air humidity (90%), the paint prolongs the defrosting interval from 80 to 137 min. Experimental observations also show that the coated hydrophilic fins are free of frost deposition during the entire course of the test and that the coating has no significant additional thermal resistance.     

Modeling for predicting frosting behavior of a fin–tube heat exchanger

A mathematical model is proposed to evaluate the frosting behavior of a fin–tube heat exchanger under frosting conditions. Empirical correlations of the heat transfer coefficients for the plate and tube surfaces and a diffusion equation for the frost layer are used to establish the model. The correlations for the heat transfer coefficients, derived from various experimental data, were obtained as functions of the Reynolds number and Prandtl number. The proposed model is validated by comparing the numerical results with experimental data for the frost thickness, frost accumulation, and heat transfer rate. The numerical results agree well with the experimental data. It is also found that this model can be applied to evaluate the thermal performance of a common fin–tube heat exchanger under frosting conditions.     

Frost formation on a bionic super‐hydrophobic surface under natural convection conditions

A bionic super‐hydrophobic surface has a multiple micro‐nano‐binary structure (MNBS) similar to the lotus leaf surface microstructure. This kind of surface has a contact angle of water greater than 150^° and a roll angle smaller than 5^°. In this paper, the frost deposition phenomena on a bionic super‐hydrophobic surface were observed. The surface has many micro bumps and its contact angle is 162^°. The formation of water droplets, the droplet freezing process, the formation of initial frost crystals and the frost layer structure on a cold bionic super‐hydrophobic surface under natural convection conditions were closely observed. The frost layer structure formed on the super‐hydrophobic surface shows remarkable differences to that on a plain copper surface: the structure is weaker, looser, thin, and easily removed and most importantly, it is of a very special pattern, a pattern similar to a chrysanthemum, a frost layer structure that has not been reported before to the best of the present authors knowledge. The experimental results also show that a super‐hydrophobic surface has a strong ability to restrain frost growth. The frost deposition on this bionic surface was delayed 55 minutes when compared with a plain copper surface under the conditions of a cold plate temperature of ?10.1^°C, air temperature of 18.4^°C, and relative humidity of 40%. A theoretical analysis was also presented to explain the observed phenomena. © 2008 Wiley Periodicals, Inc. Heat Trans Asian Res, 37(7): 412–420, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20216     

Characteristics and performance evaluation of surface-treated louvered-fin heat exchangers under frosting and wet conditions

Hydrophilic, hydrophobic, and dual (hydrophilic and hydrophobic) coatings were applied to louvered-fins typically used for heat pump heat exchangers, and the characteristics and performance of the heat exchangers under both frosting and wet conditions were compared according to surface treatment. The hydrophilic heat exchanger had the highest air-side pressure drop under frosting conditions. The hydrophobic unit had a lower air-side pressure drop than the others (hydrophilic and dual), due to frost retardation, and the reduction of the heat transfer rate was also smaller. The dual-fin heat exchanger exhibited frost retardation only in the early stage of the experiment, and the heat transfer rate was slightly greater than that of the hydrophilic unit. In wet-condition experiments for evaluating the evaporating performance of surface-treated heat exchangers, the hydrophilic unit had a lower air-side pressure drop than the others, due to the thin film of water condensation on the fins. The differences in the heat transfer rates of the heat exchangers were not significant.     

Defrost improvement by heat pump refrigerant charge compensating

During winters, the air-source heat pump often operates with substantial frost formation on the outdoor heat exchanger, and the frost layer has to be melted away periodically to keep a high heat pump coefficient of performance (COP). Otherwise, the unmelted frost layer and water will become high density frost or ice layer in heating mode. However, it is difficult to melt the frost layer in the defrosting cycle, where the effective defrosting time plays an important role in improving the defrosting ability. Generally, the defrosting time can be decreased by the following ways: increasing the refrigerant flow rate effectively, and rapidly establishing the suction pressure, discharge pressure, and the compressor power. A new heat pump defrost system with a refrigerant charge compensator, instead of the accumulator which is a key component for the frosting cycle performance, is developed in this paper. Furthermore, test results showed that the improved frost system with the compensator worked as expected, and its suction and discharge pressures and the power of the compressor during the defrosting were much larger than before.     

Experimental Investigation of the Defrosting Process on Domestic Refrigerator Finned Tube Evaporators

Frost formation is an important problem for household refrigerator and air conditioning equipment manufacturers. When frost accumulates on the evaporator surface, it acts as a thermal insulator and reduces heat flow. Therefore, frost negatively affects evaporator performance. The purpose of this study is to decrease energy consumption and increase the efficiency of the defrosting process. In the first part of the experiment, frost formation on a no-frost refrigerator evaporator at real operating conditions was investigated. The ambient temperature was maintained at a constant 23°C. It was observed that when the evaporation temperature reaches –35°C, the frost formation on the evaporator exhibits a rather dense structure that is unlike the needle-type structure observed at higher temperatures. In the second part of the experiment, the defrosting process was observed with an endoscopic camera, and the initial melting points were investigated. The experiment revealed that although the heater density is higher on the lower rows, the frost on the higher rows of the evaporator melts faster. On the theoretical side, we prepared an analytical model that calculates the melting time of the frost on the fin. The experimental and theoretical results are within 5%.     

Surface wettability control by nanocoating: The effects on pool boiling heat transfer and nucleation mechanism

Experiments were performed to highlight the influence of surface wettability on nucleate boiling heat transfer. Nanocoating techniques were used to vary the water contact angle from 20° to 110° by modifying nanoscale surface topography and chemistry. The bubble growth was recorded by a high speed video camera to enable a better understanding of the surface wettability effects on nucleation mechanism. For hydrophilic (wetted) surfaces, it was found that a greater surface wettability increases the vapour bubble departure radius and reduces the bubble emission frequency. Moreover, lower superheat is required for the initial growth of bubbles on hydrophobic (unwetted) surfaces. However, the bubble in contact with the hydrophobic surface cannot detach from the wall and have a curvature radius increasing with time. At higher heat flux, the bubble spreads over the surface and coalesces with bubbles formed at other sites, causing a large area of the surface to become vapour blanketed. The best heat transfer coefficient is obtained with the surface which had a water contact angle close to either 0° or 90°. A new approach of nucleation mechanism is established to clarify the nexus between the surface wettability and the nucleate boiling heat transfer.     

An experimental investigation on frosting characteristics of a microchannel outdoor heat exchanger in an air conditioning heat pump system for electric vehicles

To increase the driving range of electric vehicles in cold climate, air conditioning heat pump (ACHP) system is supposed to be the most effective solution. Working near 0°C with high humidity, the microchannel outdoor heat exchanger (OHX) in system would experience badly frosting process, like traditional residential heat pump system. It would lead to a significant reduction of system performance without defrosting in time. In this article, experimental investigation has been implemented on the frosting process of ACHP system of electric vehicles which is with a microchannel OHX. The phenomenon of frosting distribution was observed, the frosted part on surface shows uneven with various flows paths. The typical frosting characteristics of an outdoor microchannel heat exchanger were also obtained. In a self-designed three-heat exchanger ACHP system, the inlet and outlet refrigerant temperature of OHX as well as the outlet air temperature of system decrease with increasing frosting coverage rate. The frosting phenomenon was analyzed with variation of ambient temperature and humidity. System influence by frosting was also studied with under different ambient conditions. When OHX begins to frost, the heating capacity reduction of system under different ambient conditions were both increased but the differences in the coefficient of performance (COP) variations under different ambient conditions were small as frosting progressed.     

Feasibility study of a vapor chamber with a hydrophobic evaporator substrate in high heat flux applications

A novel vapor chamber was fabricated to assess the feasibility of combining hydrophobic and hydrophilic wettabilities in the evaporator to optimize thermal performance. The proposed vapor chamber included a separate layer of hydrophilic sintered copper powder wick that was pressed in intimate contact with a hydrophobic evaporator substrate with a water contact angle around 140°. The contact between the wick layer and the evaporator was provided by sixteen posts implemented on the condenser, which pushed the wick layer toward the evaporator. The thermal performance was evaluated based on the thermal resistance, source temperature, and temperature uniformity across the condenser. Results were compared with those of a baseline vapor chamber that was fabricated by sintering hydrophilic copper particles on a hydrophilic copper evaporator substrate. The wick size and the copper powders used to fabricate the wick structure were the same in both vapor chambers. Overall, the performance of the proposed vapor chamber was lower than that of the baseline vapor chamber, possibly due to microscale gaps between the wick layer and the evaporator substrate. However, the concept of using a hydrophilic wick to force liquid in contact with a hydrophobic evaporating surface could enable a new family of vapor chambers with low thermal resistance, if more efficient techniques for improving the mechanical contact between the wick layer and the evaporator are introduced through further detailed research. If successful, the fabrication cost of vapor chambers would be reduced as well, by using prepared wick structures, which do not require high-temperature sintering processes on evaporators.     

Frost behavior on a fin considering the heat conduction of heat exchanger fins

A mathematical model is proposed for predicting frost behavior on a heat exchanger fin under frosting conditions, taking into account fin heat conduction. The change in the three-dimensional airside airflow caused by frost growth is reflected in this model. The numerical estimates of frost thickness are consistent with experimental data, with an error of less than 10%. Due to fin heat conduction, frost thickness decreases exponentially toward the fin tip, while considerable frost growth occurs near the fin base. When a constant fin surface temperature is assumed, the predicted frost thickness was larger by more than 200% at maximum, and the heat flux by more than 10% on average, compared to results obtained with fin heat conduction taken into account. Therefore, fin heat conduction could be an essential factor in accurately predicting frost behavior. To improve prediction accuracy under the assumption of constant fin surface temperature, the equivalent temperature (for predicting frost behavior) is defined to be the temperature at which the heat transfer rate neglecting fin heat conduction is the same as the heat transfer rate with fin heat conduction taken into consideration. Finally, a correlation for predicting the equivalent temperature is suggested.     

Experimental study of natural frost formation over a horizontal tube with annular compact fins under natural convection

This paper presents experimental measurements of natural convection heat transfer and frost deposition over a horizontal fin‐tube. Measurements are made for a fin‐tube of diameter 25.4 mm, fin thickness 0.4 mm, fin center diameter 56 mm, and fin spacing 2 mm. For measurements the ambient air temperature and relative humidity are changed from 18 to 25°C and from 35% to 55%, respectively. The tube surface temperature is changed from –5 to –9 °C, and super cooling degrees of 7.5 to 24.5 °C. Results include a visualization of frost deposition growth, frost accumulation rate, and heat transfer rate with respect to time for each experiment. The results show that cold air starts from the upper point and moves downward and frost deposition starts on the fin tips, and grows with time both radially and angularly. Frost growth thickness changes significantly from top to bottom, where the boundary layers of both thermal and concentration increase at the bottom of the fin‐tube section without considerable separation. Frost growth only takes place on the fin's tip and it blocks the heat and mass transfer from the fin surfaces and the tube base which reduces convection and frost growth considerably. © 2011 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.20397     

A study of thermal performance with frosting under forced convection on a flat plate: Prediction of frost growth using nonhomogeneous property

The purpose of this study is the evaluation of thermal performance of a heat exchanger with frosting and decision of optimal defrosting cycle. Because the increase of flow resistance is the principal factor of a drop of heat transfer performance with frosting, thermal performance characteristics were examined. Based on those experimental results, we proposed a one‐dimensional nonhomogeneous frost growth model, and compared it with the experimental data in time and space. In a nonhomogeneous model with the frost property distribution taken into account, density distribution similar to the experimental result can be predicted. It is possible to make prediction closer to the experimental result compared with the conventional homogeneous model with respect to the temporal variation of frost height. © 2003 Wiley Periodicals, Inc. Heat Trans Asian Res, 32(8): 674–689, 2003; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.10122     

Dimensionless correlations of frost properties on a cold cylinder surface

We propose dimensionless correlations for frost properties on a cold cylinder surface. Frosting experiments were performed while changing various frosting parameters such as the air temperature, cold cylinder surface temperature, air velocity, and absolute humidity. The experimental data showed that a uniform frost layer grew around the circumference of the cylinder at a high air velocity. Dimensionless correlations for the thickness, density, and surface temperature of the frost layer, and for the heat transfer coefficient were obtained as functions of the Reynolds number, Fourier number, absolute humidity, and dimensionless temperature. The applicable ranges of these correlations are Reynolds number of 700–3000 (air velocities of 0.5–2.0 m/s), Fourier number of 56.8–295.7 (operating time of 0–100 min), absolute humidity of 0.00280–0.00568 kg/kg_a, air temperatures of 3–9 °C, and cold cylinder surface temperatures of ?32 to ?20 °C. The proposed correlations agreed with the experimental data within an error of 15%.     

Interface resolving two-phase flow simulations in gas channels relevant for polymer electrolyte fuel cells using the volume of fluid approach

With the increased concern about energy security, air pollution and global warming, the possibility of using polymer electrolyte fuel cells (PEFCs) in future sustainable and renewable energy systems has achieved considerable momentum. A computational fluid dynamic model describing a straight channel, relevant for water removal inside a PEFC, is devised. A volume of fluid (VOF) approach is employed to investigate the interface resolved two-phase flow behavior inside the gas channel including the gas diffusion layer (GDL) surface. From this study, it is clear that the impact on the two-phase flow pattern for different hydrophobic/hydrophilic characteristics, i.e., contact angles, at the walls and at the GDL surface is significant, compared to a situation where the walls and the interface are neither hydrophobic nor hydrophilic (i.e., 90° contact angle at the walls and also at the GDL surface). A location of the GDL surface liquid inlet in the middle of the gas channel gives droplet formation, while a location at the side of the channel gives corner flow with a convex surface shape (having hydrophilic walls and a hydrophobic GDL interface). Droplet formation only observed when the GDL surface liquid inlet is located in the middle of the channel. The droplet detachment location (along the main flow direction) and the shape of the droplet until detachment are strongly dependent on the size of the liquid inlet at the GDL surface. A smaller liquid inlet at the GDL surface (keeping the mass flow rates constant) gives smaller droplets.     

Mass transfer on and within a frost layer

This paper investigates fundamental phenomena related to understanding of frost deposition and growth. The water vapor mass transfer rate from the air stream to a frost surface was tested and the results analyzed. The water vapor pressure at the frost surface was found to be supersaturated, and this phenomenon is explained using laminar concentration boundary layer analysis. A simple equation for calculating the supersaturated water vapor density at the frost surface was developed using boundary layer analysis, and it was compared to the experimental data. The comparison showed that the proposed equation for the water vapor supersaturation degree at the frost surface agrees well with the experimental data. The physical meaning of the tortuosity factor, which is related to mass diffusion within the frost layer, is mathematically explained, and published correlations were reviewed. It was found that some existing correlations are basically empirical curve fits that force agreement of the frost growth rate with the measured values. Further, these empirical curve fits do not satisfy the known physical bounds on the tortuosity factor. This deficiency further supports the existence of supersaturation at the frost surface. The effect of uncertainty in tortuosity factor on the heat transfer rate through a frost layer was quantitatively analyzed, and it was found that its uncertainty does not significantly affect the heat transfer rate through the frost layer in typical frosting conditions.     

Self-healing of super hydrophobic and hierarchical surfaces for gas diffusion layer

Surface wettability of gas diffusion media (GDM) is one of the key issues related to the water management in fuel cells. In this study, a facile coating approach of combining carbon black and polydimethylsiloxane (PDMS) is developed to fabricate the gas diffusion layer (GDL) with super hydrophobic and hierarchical surfaces. Due to the Wenzel and Cassie's effect, the fabricated GDL shows the average contact angle as high as 158° and the roll angle less than 5°. Its super durability could be identified by the constant potential oxidation with the oxidization peak current approaching to 0.1 mA cm⁻², an order of magnitude smaller than that of conventional GDL coated with polytetrafluoroethylene (PTFE) and carbon black (10/90 wt/wt). Furthermore, these hierarchical hydrophobic surfaces exhibit a recovery of hydrophobicity from 107° to 133° by heat treatment. The mechanism of the exceptional self-healing capability is investigated by microscopic and spectroscopic analysis. It is indicated that ring siloxanes with lower surface tension formed on GDL surface during heat treatment process. This paper provides a fundamental research on the hierarchical superhydrophobic surfaces of GDL and a promising solution to develop long-live super hydrophobic GDL.     

A comparison of the airside performance of the fin-and-tube heat exchangers in wet conditions; with and without hydrophilic coating

An experimental study was performed on compact fin-and-tube heat exchangers in wet conditions. Airside performance for both hydrophilic coated and un-coated surface is examined. It is found that the effect of inlet relative humidity on the heat transfer performance is small. For un-coated surfaces, the effect of inlet relative humidity has a pronounced effect on pressure drops. It is likely that this phenomenon is related to the condensate flow pattern along the fin surface. The heat transfer performance for the hydrophilic coating surface is lower than the corresponding un-coated surface tested at the same wet condition. Further, the degradation of heat transfer performance may be up to 20% for fin pitches of 1.2 mm. The pressure drops for the hydrophilic coated surface are also lower than the corresponding un-coated surfaces. A maximum 40% reduction is observed for plain fin geometry. The effect of inlet condition on frictional performance is more pronounced in the enhanced slit geometry.     

Frost formation on a plate with different surface hydrophilicity

The objectives of this study are to develop frost maps for two different surfaces having two different hydrophilic characteristics and to find ambient conditions associated with the formation of frost structures. Test samples with two different surfaces having dynamic contact angle (DCA) of 23° and 88° were installed in a wind tunnel and exposed to a humid airflow. Frost structure is observed with a visualization system in the operating conditions of household refrigerator: airflow temperature in the range of +10-20 °C, humidity in the range of 2.64-9.36 g/kg^′, Reynolds number in the range of 7000-17,000 and cold plate temperature in the range of −11.6 to −28.4 °C. As results of this study, frost structures are classified and frost maps are proposed for two different surface hydrophilicities. Surface with low DCA (23°) shows lower frost thickness and higher frost density than that with high DCA (88°). It was found that frost structures on surfaces with different DCA are similar. However, low DCA surface at low humidity provides 20-30% denser frost formation due to the shift of areas with different structures.