共查询到19条相似文献,搜索用时 62 毫秒
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建立了固液相自动测汞仪对土壤样品中总汞含量的测定方法。无需将土壤样品进行消解,直接采用将热处理装置和原子吸收光谱集于一身的DMA80固液相自动测定仪测试。总汞在0~200 ng范围内,线性相关系数为0.999 9,在土壤样品中进行4个水平(0.5、1、10、20μg/kg)的加标回收实验,回收率在95.8%~100.7%,相对标准偏差RSD值为3.2%~18.5%,方法的检出限为0.05μg/kg。使用固液相自动测汞法与原子荧光法测试结果进行比对,结果表明固液相自动测汞法测定土壤样品汞含量,结果准确、简便、快速、安全,可用于土壤中总汞含量的快速检测。 相似文献
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《化学工业与工程技术》2018,(1):87-90
结合我国固体生物质燃料中碳氢测定的检验标准和仪器使用现状,利用固体生物质燃料与煤炭的特性有较多相似之处,研究制定了运用电量-重量法测定固体生物质燃料中碳氢含量的标准方法。研究了固体生物质燃料中碳、氢的组成及其特点,按照GB/T 28734—2012《固体生物质燃料碳氢测定方法》的要求,结合GB/T 476—2008《煤中碳和氢的测定方法》,对8种固体生物质燃料中碳和氢的测定进行了正交试验,考察了氧气流量、进样时间方案、试样质量、催化剂等因素对测定结果的影响,得到电量-重量法的最佳测定条件为:试样质量0.065~0.070 g、覆盖足量的三氧化钨催化剂、氧气流量80 m L/min、进样时间方案2-4 min。试验结果为进一步制定固体生物质燃料中碳氢含量测定的标准方法奠定了基础。 相似文献
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建立了DMA-80型汞分析仪直接固体进样测定粗制氧化锌中汞的方法。试样经干燥和高温分解处理,采用催化分解和吸附净化使分解产物转变为氧化汞蒸气,通过金质汞齐化器还原并以金汞齐形式被捕集,最后在波长253.65 nm处进行原子吸收测量,依据朗伯-比尔定律定量。优化了干燥时间和温度、分解时间和温度等实验条件,同时做了方法检出限、精密度、回收率等实验。结果表明:方法检出限为0.015 ng,线性范围为0.02~100 ng,相关性系数≥0.999,回收率为93.2%~102.7%,精密度(RSD,n=7)≤5.0%,可用于进口粗制氧化锌的快速检验。 相似文献
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Johan Werkelin Bengt-Johan Skrifvars Maria Zevenhoven Bjarne Holmbom Mikko Hupa 《Fuel》2010,89(2):481-9766
Advanced fuel characterization helps to predict ash fouling and slagging. Chemical fractionation analysis, i.e. sequential leaching in H2O, NH4Ac(aq), and HCl(aq), was applied to the biomass of spruce, pine, birch, and aspen. All of the Cl in the samples and most of the K, Na, and P were water-soluble; most of the Mg and Mn, and some of the Ca were leached in NH4Ac; most of the Ca was leached in HCl; and most of the Si and S remained insoluble in the biomass. Ion Chromatography found the water-soluble Cl, P, and S present as Cl−, , and , respectively, and equimolar concentrations of as leached Ca in the acid fraction. The biomass solids were determined for anionic groups by methylene blue sorption. The contents were lowest in the wood samples (22-118 mmol/kgD.S.) and highest in the bark samples (130-453 mmol/kgD.S.). The closing of the ion charge balance led to a quantitative model for the ash-forming matter: water-soluble salts (KCl, K2HPO4, and K2SO4), acid-soluble minerals (CaC2O4), non-soluble minerals (SiO2), and organically associated ash-forming elements (ionically bonded Ca2+, Mg2+, Mn2+, and K+, and covalently bonded P and S). 相似文献
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《煤炭加工与综合利用》2017,(1)
试验研究了全自动原子荧光法测定煤中Hg含量的影响因素;煤样量的多少对测定结果没有影响,受Hg污染的王水以及受到污染的煤样对测定结果有影响;建议在干净清洁的环境中进行实验,以防止含Hg物质的污染,从而提高测定结果的准确度。 相似文献
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Sun Uk Lee Kwonsu Jung Gwon Woo Park Charles Seo Yeon Ki Hong Won Hi Hong Ho Nam Chang 《Korean Journal of Chemical Engineering》2012,29(7):831-850
This review deals with a recent development of biofuels and chemicals from biomass. Some of the grainbased biofuels and chemicals have already been in commercial operation, including fuel ethanol, biodiesel, 1.3-propanediol, polylactic acid (PLA) and polyhydroxy butyric acid/alkanoates (PHB/PHA). The next generation bioproducts will be based on lignocellulosics due to their abundance and to stabilize rising food prices. However, the technologies of handling biomass are yet in their infancy and suffer from low yield, low product titer, and low productivity. This review focuses on bioprocessing technologies for biofuels production: organic raw biomaterials available in Korea; volatile fatty acids platform, multi-stage continuous high cell density culture (MSC-HCDC), enrichment of fermentation broth by forward osmosis; various purification methods of pervaporation of ethanol, solvent extraction on succinic, lactic acids and reactive separation methods. 相似文献
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In this study, the combustion properties of three of the UK’s commonly imported biomass fuels for co-firing, which are palm kernel expellers, shea residue, and waste from olive oil production are examined. The fuels were characterised and their thermal decomposition properties were studied by thermogravimetric analysis (TGA). Additionally the products from their devolatilisation were identified by gas chromatography-mass spectrometry (py-GC-MS) analysis of the evolved vapours and tars from high heating rate pyrolysis tests. Finally, chars from the fuels were prepared, analysed, and combustion studies were conducted by TGA-MS to determine the conversion of char-nitrogen to different nitrogen-containing species. In general, the main constituents of their ash fractions were K, Si, Ca and Mg, resulting in high alkali indices, which predict a large tendency to fouling. The pyrolysis and combustion kinetic parameters, estimated from TGA studies of these fuels and their chars, are much lower than those reported in the literature for lignocellulosic biomass. It is suspected that there is oil/fat evaporation processes overlapping with the decomposition of their lignocellulosic fractions, which significantly affects the apparent kinetics. The pyrolysis conditions used promoted depletion of nitrogen in the char, resulting in approximately 79-91% of the fuel-N being released with the volatiles. In combustion of the char, NOx and N2 are the major nitrogen compounds detected. Another primary product, HCN, was detected from the combustion of some of the fuel chars, as well as C2N2. 相似文献
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Biodegradability of biomass pyrolysis oils: Comparison to conventional petroleum fuels and alternatives fuels in current use 总被引:1,自引:0,他引:1
Joël Blin Ghislaine Volle Philippe Girard Tony Bridgwater Dietrich Meier 《Fuel》2007,86(17-18):2679-2686
Concern with environmental issues such as global climate change has stimulated research into the development of more environmentally friendly technologies and energy sources. One critical area of our economy is liquid fuels. Fast pyrolysis of lignocellulosic biomass for liquids production is of particular concern, as it is one of the most interesting ways to produce renewable liquid fuel for transport and heat and power production.The aerobic biodegradability of various pyrolysis oils from different origins and of a EN 590 diesel sample was examined using the Modified Sturm (OECD 301B). The results demonstrate that all fast pyrolysis oils assessed are biodegradable with similar shaped curves with 41–50% biodegradation after 28 days, whereas the diesel sample reached only 24% biodegradation. Since pyrolysis oils achieved biodegradability over 20% these are classified as inherently biodegradable. Modelling of biodegradation processes was successfully performed with a first-order chemical reaction.The biodegradability results obtained for biomass pyrolysis oils are compared to those of conventional and alternative fuels. 相似文献
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The design of a furnace, crucible stand, and ancillary equipment is described to enable eight simultaneous determinations to be made of volatile matter in coal or coke. Equipment operation to achieve the recovery time and uniform heat zone specifications in standard methods is discussed. Rapid processing of large sample batches is possible, with accuracy and precision statistics acceptable to international standards. Design changes to existing equipment are described to accommodate eight samples. 相似文献
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C. M. Tseng H. Garraud D. Amouroux O. F. X. Donard A. de Diego 《Journal of Automated Methods and Management in Chemistry》1998,20(4):99-108
This paper describes rapid, simple microwave-assisted leaching/ digestion procedures for total and mercury species determination in sediment samples and biomaterials. An open focused microwave
system allowed the sample preparation time to be dramatically reduced to only 24 min when a power of 40-80 W was applied. Quantitative leaching of methylmercury from sediments by HNO3 solution and complete dissolution of biomaterials by an alkaline solution, such as 25% TMAH solution, were obtained. Methylmercury compounds were kept intact without decomposition or losses by evaporation. Quantitative recoveries of total mercury were achieved with a two-step microwave attack using a combination of HNO3 and H202 solutions as extractant. The whole pretreatment procedure only takes 15 min, which can be further shortened by an automated robust operation with an open focused system. These analytical procedures were validated by the analysis of environmental certified reference materials. The results confirm that the open focused microwave technique is a promising tool for solid sample preparation in analytical and environmental chemistry. 相似文献