For increasing the compatibility of polystyrene (PS) and polyolefin elastomer (POE) blends, a Lewis acid catalyst, aluminium chloride (AlCl3), was adopted to initiate the Friedel-Crafts alkylation reaction and induce the formation of PS-graft-POE copolymer. The dynamic mechanical and rheological tests were used to study the effects of catalyst content on the miscibility and rheological behaviors. The results showed that the viscosity increased and the MFI decreased with the increase of the catalyst content. However, when the catalyst content was overmuch, the viscosity decreased and the MFI increased. The variety of miscibility and rheological behaviors of PS/POE blends was the results of the competition between in situ graft reaction and decomposition of blending compounds. 相似文献
Immiscible blends of high density polyethylene (HDPE) and an amorphous glassy phase consisting of either pure polystyrene (PS) or a miscible blend of PS and a polyether copolymer (PEC) were compatibilized with various amounts of a styrene-hydrogenated butadiene block copolymer (SEBS). PEC is structurally similar to poly(2,6-dimethyl-1,4-phenylene oxide) (PPO). Using a liquid displacement stress dilatometer, the volume change of samples during uniaxial mechanical straining was determined and related to the various modes of deformation. Blends were fabricated by both injection and compression molding. Miscible PEC and PS blends were found to undergo a craze to shear yielding transition between 40 and 60% PS, which occurred at higher PS concentrations as SEBS was added. Blends with a HDPE matrix and a dispersed glassy phase showed reduced volume dilatation on adding SEBS, indicating better interfacial adhesion between the incompatible blend components. Increases in the sample volume were substantially less in blends with a PEC/PS glassy phase instead of pure PS, suggesting more effective compatibilization by the SEBS copolymer in blends with PEC. This trend is presumed to stem from an exothermic heat of mixing between the PS endblocks of SEBS and the PEC-rich phases in the blend. Microscopic evidence of the improved adhesion and modes of deformation agrees with the results obtained by dilatometry. The volume dilatation of compression-molded materials do not seem to be similarly affected by the composition of the glassy phase which may reflect morphological differences between injection-and compression-molded blends. 相似文献
Various amounts of a styrene-butadiene-based triblock copolymer (SEBS) was used to compatibilize immiscible blends of high density polyethylene (HDPE) and an amorphous glassy phase consisting of either pure polystyrene (PS) or a miscible blend of PS and a polyether copolymer (PEC). PEC is structurally similar to poly(2,6-dimethyl-1,4-phenylene oxide) (PPO). Mechanical properties were determined for blends fabricated by injection and compression molding. The inherently brittle two-phase HDPE/(PEC/PS) blends show significant increases in ductility and impact strength resulting from addition of SEBS. These improvements coincide with a slight loss in modulus and yield strength. If the amount of HDPE and SEBS is held constant, impact strength and ductility increase with the amount of PEC in the glassy phase. These trends evidently result from the added ductility of glassy phases containing PEC and perhaps from better interfacial adhesion in blends after adding SEBS. The latter stems from the thermodynamic miscibility between PEC and PS endblocks of SEBS which provide an enthalpic driving force for compatibilization. Differences between the properties of compression and injection-molded blends can be attributed to the degree of crystallinity and orientation induced during molding. 相似文献
The effects of dissolved supercritical carbon dioxide on the viscosity and morphological properties were investigated for polyethylene/polystyrene blends in a twin-screw extruder. The viscosities of the blend/CO2 solutions were measured using a wedge die mounted on the extruder. A considerable reduction of viscosity was found when CO2 was dissolved in the blend. It was observed that the dissolution of CO2 into PE/PS blends, regardless of the CO2 content used, led to decreased shear thinning behavior resulting in an increase of the power law index from 0.29 to 0.34. The cell structures of foamed PE/PS blends showed a typical dependence of pressure and CO2 concentration, with higher operating pressures and CO2 content leading to a smaller cell size. Also, it was noted that the size of the dispersed PS phase in the PE/PS phase blends decreased by increasing the CO2 concentration, and that the dispersed PS phase domains were highly elongated in the direction normal to the cell radius. 相似文献
AbstractThe effect of SBS and nano-CaCO3 on the mechanical properties of PS blends was studied, and their morphologies were characterised by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The Izod impact strengths of notched samples of PS/SBS/CaCO3 blends with nanometre particles of nano-CaCO3 and SBS are higher than those of PS and PS/SBS blends with the same content of SBS, and the tensile strengths are higher than those of PS/SBS blends. The inclusion of nano-CaCO3 within the dispersed phase of SBS enlarges the volume of the domains of SBS, which increases the toughness of the ternary blends (PS/SBS/CaCO3). The mass ratio of SBS/CaCO 3 plays an important role in the properties of the ternary blends because it affects the concentration of SBS in these blends, the dispersion of nano-CaCO3 and the morphology of the ternary blends. 相似文献
Summary: In the previous study, we observed compatibilizing effects of low density polyethylene (LDPE)/polystyrene (PS) with polystyrene‐block‐poly(ethylene‐co‐butylene)‐block‐polystyrene (SEBS), a triblock copolymer. Blends consisting of 70 wt.‐% LDPE and 30 wt.‐% PS were prepared with a SEBS concentration of up to 10 wt.‐%. This study examined the electrical properties such as the electrical breakdown, water tree length, permittivity and tan δ in the blends. The possibility of using these blends as insulating material substitutes for LDPE was investigated. The electrical breakdown strength reached a maximum of 66.67 kV/mm, which is superior to 50.27 kV/mm of the LDPE used as electrical insulators for cables. In addition, the water tree length decreased with increasing SEBS concentration. The water tree lengths of the blends containing SEBS were shorter than that of the LDPE. The permittivity of the blends was 2.28–2.48 F/m, and decreased with increasing SEBS concentration with the exception of S‐0. Tan δ of the blends increased smoothly with increasing SEBS content.
Breakdown strength , water tree length, permittivity and tan δ of the LDPE/PS/SEBS blends and raw materials. 相似文献