共查询到16条相似文献,搜索用时 93 毫秒
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研究煤的吸附和放散特性,对于查明煤与瓦斯突出中甲烷的作用,提高煤层气采收率或矿井抽采率具有重要作用。通过自行研制的实验装置,对河南新安矿和平煤一矿软煤和硬煤甲烷吸附和扩散的性质、相同吸附压力下的吸附量和Langmuir吸附常数的差异进行分析,阐明煤表面能的控制因素,查明煤在初始解吸时刻的扩散系数。结果表明,同一煤层中软煤比共生的硬煤具有更大的Langmuir吸附体积,在同一吸附压力下同阶煤的吸附量与煤的软硬和吸附压力有关,软煤和硬煤的表面能与煤阶有关,短时间解吸时软煤扩散系数大于硬煤,长时间解吸后硬煤的扩散系数大于软煤,且软硬煤的扩散系数均随解吸时间延长和吸附平衡压力的增加而减小。 相似文献
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为了研究甲烷在颗粒煤中扩散、吸附至平衡过程的扩散特性,基于颗粒煤吸附甲烷幂函数扩散模型,利用磁悬浮天平高压等温吸附仪,测定不同压力下颗粒煤甲烷吸附过程中扩散量随时间变化值,研究颗粒煤甲烷吸附达到平衡前的扩散特征。实验结果表明:平衡压力对颗粒煤甲烷吸附和扩散特性影响显著;吸附量和平均扩散系数随着压力增大而增大;颗粒煤甲烷吸附过程扩散系数随时间呈幂函数衰减,前500 s衰减幅度较大,平均扩散系数与时间呈负相关关系。研究认为颗粒煤吸附甲烷幂函数扩散模型对于描述颗粒煤甲烷吸附扩散过程具有较高准确性,有助于分析煤层气排采过程煤层气吸附量的动态变化,提高煤层气采收率。 相似文献
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扩散是煤层甲烷运移的关键环节之一,而目前有关煤层中甲烷扩散特征的认识并不充分.以沁水盆地南部高煤阶煤层气藏为例,应用微纳渗流力学理论分析了煤基质中气体扩散模式及定量表征参数;应用Simed软件开展了扩散性能对不同煤体结构煤层气排采规律的影响数值研究.结果表明:煤层甲烷的扩散受化学势梯度的驱动,产气过程中体相扩散、努森扩散和构型扩散模式并存且呈动态变化;甲烷扩散性能受气体温度、压力、气体种类、水分以及基质孔隙结构共同影响,基质孔隙吸附甲烷会改变微孔孔径并影响扩散路径的空间形态;煤基质中甲烷的扩散是非热力平衡过程,扩散系数是吸附量的函数.基于拟稳态扩散的数值研究表明,扩散性能强弱对于长期累计产气量几乎没有影响,而对短期产气速率具有较大的影响;扩散性能弱的,产气速率峰值较低,但峰值之后的一段时间内产气速率相对较高;与高渗煤层相比,低渗构造煤层的产气速率对吸附时间常数更敏感. 相似文献
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甲烷在煤基质中的扩散性能是影响煤层气产出的重要储层参数。采用云南东南部地区新近系中新统小龙潭组褐煤样品,开展了低煤阶煤中甲烷等温吸附实验。基于等温吸附实验获得的吸附量与时间的关系数据,应用一元孔隙结构气体非稳态扩散模型,计算了煤中甲烷气体扩散系数,揭示了煤中甲烷扩散规律和控制机理。研究结果表明,低煤阶煤中气体扩散规律服从Langmuir方程,煤中甲烷有效扩散系数和扩散系数随着压力的增高而增大;吸附时间常数随着压力的增高而减小,服从负指数函数规律。4个实验煤样Langmuir有效扩散系数和扩散系数分别是(1.71~5.46)×10-4 s-1和(2.17~6.91)×10-12 m2/s,Langmuir压力为0.63~1.97 MPa。在相同温度和压力条件下,干燥煤样的有效扩散系数和扩散系数大于平衡水分煤样,随着温度的增高,其有效扩散系数和扩散系数增加,煤中气体扩散性能增强。 相似文献
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无烟煤对甲烷等温吸附解吸特性实验研究 总被引:10,自引:0,他引:10
研究空气干燥基无烟煤对甲烷(CH4)的等温吸附/解吸特性,发现其对甲烷的解吸残余率达56%。为了对其进行深入探讨,特设计了原煤样的炭化和活化实验,扩大了原料的比表面积,进而在等温条件下研究了两个改性样品对甲烷的吸附/解吸特性。对比发现,比表面积的增大能显著增加样品对甲烷的吸附总量,但对解吸残余率没有明显的影响。考虑到影响甲烷吸附/解吸的因素,又在等温条件下对主控因素——水分作了平行实验,结果显示,水分对活化样解吸残余率有明显影响。 相似文献
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煤层气产出一般要经过解吸、扩散和渗流三个阶段,而煤层气在变形较强的构造煤中的扩散过程不同于在原生结构煤或变形较弱的煤体中的扩散。外界压力的变化只是构造煤吸附与解吸整个过程的一种外在因素,构造煤的变形和结构变化以及吸附势场的转换才是构造煤吸附与解吸的内在因素,是导致解吸过程不可逆性的根本原因。当构造煤体与CH4等多元气体间的吸附平衡状态遭到破坏时,变形较强的构造煤在降压后会产生解吸滞后现象;而变形较弱的煤,分子结构中的气体会很快解吸,第一阶段是气体解吸作用,第二阶段是游离气体从微孔向较大孔隙扩散的过程,气体扩散速率主要由第二阶段决定。构造煤气体扩散机理主要是由孔隙形状、大小、连通性和多元气体性质和状态所决定的。韧性变形煤的微孔隙比较发达,所以韧性变形煤以Knudsen扩散为主,脆性变形煤的中、大孔隙所占比例较大,而且脆性变形煤的孔隙之间具有很好的连通性,所以脆性变形煤以Fick型扩散为主,脆-韧性变形煤以及接近脆-韧性变形煤的脆性变形煤和韧性变形煤均以过渡型扩散为主。在试井渗透率比较中,一定变形程度的脆性变形煤>韧性变形煤,脆性变形煤中以过渡孔为主,其余为微孔,测不出亚微孔和极微孔,脆性变形还增加了各孔隙之间的相互连通性。韧性变形煤中过渡孔比表面积所占比例下降,微孔和亚微孔增高,扩散主要发生在微孔和过渡孔中,所以韧性变形煤的试井渗透率低于脆性变形煤的试井渗透率。 相似文献
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Role of coal type and rank on methane sorption characteristics of Bowen Basin, Australia coals 总被引:5,自引:0,他引:5
The effect of coal composition, particularly the organic fraction, upon gas sorption has been investigated for Bowen Basin and Sydney Basin, Australia coals. Maceral composition influences on gas retention and release were investigated using isorank pairs of hand-picked bright and dull coal in the rank range of high volatile bituminous (0.78% Ro max) to anthracite (3.01% Ro max). Adsorption isotherm results of dry coals indicated that Langmuir volume (VL) for bright and dull coal types followed discrete, second-order polynomial trends with increasing rank. Bright coals had a minimum VL at 1.72% Ro max and dull coals had a minimum VL at 1.17% Ro max. At low rank, VL was greater in bright coal by about 10 cm3/g, but as rank increased, the bright and dull trends converged and crossed at 1.65% Ro max. At ranks higher than 1.65% Ro max, both bright and dull coals followed similar trends. These competing trends mean that the importance of maceral composition on VL varies according to rank. In high volatile bituminous coals, increases in vitrinite content are associated with increases in adsorption capacity. At ranks higher than medium to low volatile bituminous, changes in maceral composition may exert relatively little influence on adsorption capacity. The Langmuir pressure (PL) showed a strong relationship of decreasing PL with increasing rank, which was not related to coal type. It is suggested that the observed trend is related to a decrease in the heterogeneity of the pore surfaces, and subsequent increased coverage by the adsorbate, as coal rank increases. Desorption rate studies on crushed samples show that dull coals desorb more rapidly than bright coals and that desorption rate is also a function of rank. Coals of lower rank have higher effective diffusivities. Mineral matter was found to have no influence on desorption rate of these finely crushed samples. The evolution of the coal pore structure with changing rank is implicated in diffusion rate differences. 相似文献
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Summary During an investigation to study the gas flow characteristics of coal, adsorption and desorption rates of methane from powdered coal samples were measured. From adsorption tests, it was found that the capacity of coal to hold methane varies significantly with gas pressure. For pressures up to 4.14 MPa (600 psi) the amount of gas adsorbed was still rising and monomolecular saturation was not reached. Results of desorption tests were used to test three equations suggested by previous investigators to measure the quantity of desorbed gas. It was confirmed that no single equation would define adequately the complete desorption process. Changes of regime appeared to exist at desorption times of 100 s and, to a lesser extent, 1000 s following the initial release of ambient gas pressure. A hypothesis was advanced that initial flow was inhibited or choked by an efflux of desorbing gas molecules. This was followed by a short transitional period and a longer term regime of free flow with reduced resistance offered by the flow paths. 相似文献
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为研究不同煤阶煤体润湿性对煤层气吸附/解吸的影响,采集寺河煤矿3号煤与大佛寺煤矿4号煤样品进行接触角测量及吸附/解吸实验,通过热力学计算分析等量吸附热特征。结果表明,大佛寺4号煤水润湿性远好于寺河3号煤,原因在于大佛寺4号煤为低变质长焰煤,其所含羧基、羟基等含氧官能团数量较多,同时具有物质组分亲水性好及孔裂隙较发育的优势。煤体润湿性影响煤自身含水率大小,间接影响煤层气吸附/解吸特征。大佛寺4号煤与寺河3号煤润湿性、含水率、解吸率及采收率间关系复杂,受临界含水量制约,存在温度临界点。等量吸附热对比发现煤体亲水性不利于煤层气的吸附。煤层气吸附放热远小于解吸吸热,存在解吸滞后,且解吸滞后程度随着吸附/解吸量增加而逐渐减弱,低阶煤的减弱趋势更加明显。 相似文献
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构造煤甲烷吸附表面能研究 总被引:1,自引:0,他引:1
煤的表面能是致使煤具有吸附性差异的根本原因。通过分析动力变质作用对构造煤结构和组分的影响,借助甲烷等温吸附实验,计算了不同温度下随着压力增大,原生结构煤和构造煤吸附甲烷的煤表面能的变化情况,并从构造煤动力变质角度分析了其表面能变化的原因。结果表明:动力变质作用对构造煤结构和组分改造作用明显,构造煤比共生的原生结构煤微孔隙更发育,吸附能力更强;计算结果也表明,随着温度的升高和压力的增大,构造煤吸附甲烷的表面能降低值均大于共生的原生结构煤,构造煤吸附甲烷的能力更强。 相似文献
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