A review of the recent developments in biocomposites based on natural fibres and their application perspectives

The growing ecological and environmental consciousness has driven efforts for development of new innovative materials for various end-use applications. Polymers synthesized from natural resources, have gained considerable research interest in the recent years. This review paper is intended to provide a brief outline of work that covers in the area of biocomposites, major class of biodegradable polymers, natural fibres, as well as their manufacturing techniques and properties has been highlighted. Various surface modification methods were incorporated to improve the fibre–matrix adhesion resulting in the enhancement of mechanical properties of the biocomposites. Moreover, an economical impact and future direction of these materials has been critically reviewed. This review concludes that the biocomposites form one of the emerging areas in polymer science that gain attention for use in various applications ranging from automobile to the building industries.     

Effects of environmental ageing on the static and cyclic bending properties of braided carbon fibre/PEEK bone plates

The use of titanium and steel bone plates to fix fractured limbs can create problems due to stress shielding, bone resorption and subsequent refracture. Here, braided carbon fibre reinforced poly-ether-ether-ketone (CF/PEEK) was evaluated as a possible implant material that could reduce these problems. CF/PEEK bone plates were aged in a simulated body environment for up to 12 weeks and then mechanically tested in 3 and 4-point bending tests. Sample mass increased by around 0.3 wt.%, yet bending stiffness and strength remained unchanged. Scanning Electron Microscopy (SEM) showed no changes in failure modes with age. Braided CF/PEEK shows an excellent resistance to fatigue failure even after prolonged ageing, easily surpassing the fatigue life of commonly used stainless steel alloys such as 316L. In addition, CF/PEEK had half the stiffness of steel for the same static strength, which would reduce stress shielding. Together, the results suggest that CF/PEEK is a highly suitable material for bone plates and should be further investigated for this application.     

Nanocomposites based on polystyrene-b-poly(ethylene-r-butylene)-b-polystyrene and exfoliated graphite nanoplates: Effect of nanoplatelet loading on morphology and mechanical properties

Exfoliated graphite nanoplates (xGnPs)/polystyrene-b-poly(ethylene-r-butylene)-b-polystyrene (SEBS) nanocomposites have been prepared by the simple melt-compounding approach. The structural, mechanical and viscoelastic properties of these composites were studied and compared. Wide-angle X-ray diffraction (WAXD) studies indicated that the processing of nanocomposites did not change the original d-spacing of xGnPs. Scanning electron microscopy observation on the fracture surfaces of the composites shows a uniform dispersion of xGnPs throughout SEBS matrix and strong interfacial adhesion between oxidized xGnPs and the matrix, which are responsible for the considerable enhancement of mechanical properties of the composites. It is found that the addition of xGnPs particles improved both the elastic modulus and storage modulus of pure SEBS significantly and the higher the xGnPs content, the higher the modulus of the nanocomposite. Moreover, the effects of dispersed xGnPs on the microphase separation of SEBS have also been investigated using small angle X-ray scattering (SAXS).     

Effect of interface debonding on the thermal conductivity of microencapsulated-paraffin filled epoxy matrix composites

Microcapsules containing phase change materials (microPCMs) can be filled in polymeric matrix forming smart temperature-controlling composites. The aim of this study was to investigate the effect of interface debonding on the thermal conductivity of microPCMs containing paraffin/epoxy composites. The shell thickness and average size of microPCMs were controlled by regulating the core/shell ratios and emulsion stirring rates. Test results indicated that the thermal conductivity (K_e) of all composites decreased after a thermal shock treatment. SEM and thermography measurements were applied to observe the interface behaviors of composites after a violent thermal treatment process. It was proved that the interface debonding was generated because of the mismatch of expansion coefficient between shell and epoxy. A modeling analysis of the relative thermal conductivity (K_r) indicated that the effective approach to decrease the debonding is to enhance the molecule tangling degree between shell and matrix.     

Development of a biocomposite based on green epoxy polymer and natural cellulose fabric (bark cloth) for automotive instrument panel applications

Natural fiber reinforced composites have attracted interest due to their numerous advantages such as biodegradability, dermal non-toxicity and with promising mechanical strength. The desire to mitigate climate change due to greenhouse gas emissions, biodegradable resins are explored as the best forms of polymers for composites apart from their synthetic counterparts which are non-renewable. In this study biodegradable bark cloth reinforced green epoxy composites are developed with view of application to automotive instrument panels. The optimum curing temperature of green epoxy was shown to be 120 °C. The static properties showed a tensile strength of 33 MPa and flexural strength of 207 MPa. The dynamic mechanical properties, frequency sweep showed excellent fiber-matrix bonding of the alkali treated fabric with the green epoxy polymer with glass transition temperature in the range of 160 °C–180 °C. Treatment of the fabric with alkali positively influenced the mechanical properties of the fabric reinforced biocomposites.     

Effect of ZnO nanoparticles doped graphene on static and dynamic mechanical properties of natural rubber composites

In this work, effect of ZnO nanoparticles doped graphene (Nano-ZnO–GE) on static and dynamic mechanical properties of natural rubber composites were studied. Nano-ZnO–GE was synthesized by sol–gel method and thermal treatment. With the incorporation of nano-ZnO–GE into the matrix, the mechanical properties of NR nanocomposite significantly improved over that of NR composite containing with 5 phr of conventional-ZnO. The results demonstrated that the presence of nano-ZnO on the surface of graphene sheets not only conduces to suppressing aggregation of graphene sheets but also acts as a more efficient cure-activator in vulcanization process, with the formation of excellent crosslinked network at low nano-ZnO–GE content. This work also showed that NR/Nano-ZnO–GE nanocomposites exhibited higher wet grip property and lower rolling resistance compared with NR/Conventional-ZnO composite, which makes nano-ZnO–GE very competitive for the green tire application as a substitute of conventional-ZnO, enlarging versatile practical application to prepare high-performance rubber nanocomposites.     

Mechanical,flow and electrical properties of thermoplastic polyurethane/fullerene composites: Effect of surface modification of fullerene

Thermoplastic polyurethane (TPU) composites with fullerene loadings varying from 0.5 to 2 weight% were prepared by melt-mixing method. Nitric acid oxidation and silanization were applied to fullerene surface to improve interfacial interactions with TPU matrix. The influence of surface modifications of fullerene on mechanical, melt flow and electrical properties of TPU based composites were investigated. Incorporation of fullerene leads to nearly twofold increase in tensile strength and Young's modulus of the composites in addition to enhancing the flexibility. The best results are obtained in nitric acid and silane modified fullerene containing composites at the lowest concentration (0.5%). Higher MFI values were observed for composites loaded with surface treated fullerenes compared to pristine fullerene because of their better dispersion in TPU. Electrical properties of TPU also improved by the addition of surface modified fullerene particles. Surface oxidation and silanization gave rise to dispersion homogeneity which may be the reason of both tensile strength and strain improvements at the same time.     

Effect of shearing on the orientation, crystallization and mechanical properties of HDPE/attapulgite nanocomposites

High density polyethylene (HDPE)/attapulgite (AT) nanocomposites, prepared by conventional injection molding (CIM) and dynamic packing injection molding (DPIM), were investigated with focus on AT-induced crystallization and orientation under shear. Infrared spectroscopy (FTIR) analysis showed there is no special chemical interaction between HDPE and AT, but shear induced significant changes on the material structure and properties. Differential scanning calorimetry (DSC) analysis showed strong nucleation effect by AT especially under shear. And more, shear will induce much better dispersion of AT in the DPIM sample vs. CIM. AT nanorods and lamellae of HDPE are more organized in the DPIM sample while there is only random distribution in the CIM sample. Most AT nanorods embed in the HDPE lamellae and form a brush-like hybrid structure due to shear. The shear-induced orientation will be enhanced with higher AT loading. The mechanical performance of the composites was significantly improved via DPIM.     

Effect of coupling agent on natural fibre in natural fibre/polypropylene composites on mechanical and thermal behaviour

To enhance the adhesion between the natural fibre and the thermoplastic matrix, a coupling agent of maleic anhydride grafted polypropylene MAPP is applied. In literature, there are different guidelines of the optimum percentage required of MAPP. Therefore, a systematic work is carried out to optimise the MAPP percent with respect to the type of the natural fibre. Different parameters are investigated namely; Coupling agent ratio to the fibre (0%, 6.67%, 10%, 13.3%, 16.67%), coupling agent source, fibre type (flax, hemp, sisal), and fibre content (30%, 50%). Composite is produced using a kneader and the resulting material is assessed mechanically, thermally, microscopically and for water absorption. For different MAPP source and the natural fibre type, optimum MAPP to fibre ratio is found in average to range between 10% and 13.3% according to the investigated property (stiffness, strength and impact). Increase of MAPP is found to decrease the melting temperature. The thermal behaviour is also linked to the copolymer molecular weight.     

Free-volume correlation with mechanical and dielectric properties of natural rubber/multi walled carbon nanotubes composites

The microstructure, mechanical strength, dielectric properties, Doppler broadening measurements and positron life time studies of the composites containing multi walled carbon nanotubes (MWCNTs) and natural rubber (NR) are investigated. The uniform distribution of MWCNTs in the elastomer medium is studied by Raman spectroscopy and the electron microscopy images show the composite’s internal microstructure. Free volume sizes and interstitial mesopore sizes of the nanocomposites are determined by positron annihilation lifetime spectroscopy (PALS). PALS investigates the influence of the nanotubes in regulating the interphase nanoscale character. Strong interfacial interaction causes an apparent reduction of the free-volume fraction of NR probably by depressing the formation of free-volume holes in the interfacial region. The mechanical percolation and percolation observed from the dielectric measurements are correlated with the life time values. It is established that the sub-nano level free volumes and nano level structure of the composites have significant roles in regulating the mechanical properties.     

Mode-I,mode-II and mixed-mode I+II fracture behavior of composite bonded joints: Experimental characterization and numerical simulation

The fracture behavior of composite bonded joints subjected to mode-I, mode-II and mixed-mode I + II loading conditions was characterized by mechanical testing and numerical simulation. The composite adherents were bonded using two different epoxy adhesives; namely, the EA 9695 film adhesive and the mixed EA 9395-EA 9396 paste adhesive. The fracture toughness of the joints was evaluated in terms of the critical energy release rate. Mode-I tests were conducted using the double-cantilever beam specimen, mode-II tests using the end-notch flexure specimen and mixed-mode tests (three mixity ratios) using a combination of the two aforementioned specimens. The fracture behavior of the bonded joints was also simulated using the cohesive zone modeling method aiming to evaluate the method and point out its strengths and weaknesses. The simulations were performed using the explicit FE code LS-DYNA. The experimental results show a considerable scatter which is common for fracture toughness tests. The joints attained with the film adhesive have much larger fracture toughness (by 30–60%) than the joints with the paste adhesive, which exhibited a rather brittle behavior. The simulation results revealed that the cohesive zone modeling method performs well for mode-I load-cases while for mode-II and mixed-mode load-cases, modifications of the input parameters and the traction-separation law are needed in order for the method to effectively simulate the fracture behavior of the joints.     

Procedural influences on compression and injection moulded cellulose fibre-reinforced polylactide (PLA) composites: Influence of fibre loading,fibre length,fibre orientation and voids

The influence of fibre loading (20, 30, 40 mass%), fibre fineness, and the processing procedure (compression moulding – CM and injection moulding – IM) on the tensile and impact strength of lyocell/PLA composites was examined. The results revealed a significantly higher tensile and impact strength for CM composites compared to IM composites. An increase in strength up to a fibre loading of 40% was determined for CM composites, while for IM composites the highest values were measured at a fibre loading of 30%. Composites were investigated for their void content, fibre orientation, fibre length and process-induced fibre damage. A better fibre/matrix adhesion and compaction of IM composites was found while fibre orientation as well as mechanical properties of extracted fibres show no significant differences between CM and IM composites. The different mechanical characteristics of CM and IM samples are attributed predominantly to the fibre aspect ratio and the distribution of voids.     

Influence of process induced defects on the failure of composite T-joint specimens

An experimental investigation of the failure load of T-joint structures has been undertaken, with a focus on the influence of process induced defects within the deltoid area. Static pull-off tension tests have been conducted for a comparative assessment. An extensive literature review on the subject to place is also presented. The role of the deltoid area in stabilizing the primary load bearing plies and minimising the volume fraction reduction in the off-axis plies is critical to maximise the failure load and minimise the performance variability of the T-joint structures. A deltoid area reduction of 25%, with no change in the external geometry, yielded a similar mechanical performance to the nominal baseline specimen but with increased variability. However, a reduction of 50% in the deltoid area yielded a strength reduction of 33%. The findings of this study suggest that the reduction in the deltoid area can be tolerated within certain limits.     

Fire behaviour of thermally insulated RC beams strengthened with NSM-CFRP strips: Experimental study

This paper presents the results of fire resistance tests on reinforced concrete (RC) beams flexurally strengthened with carbon fibre reinforced polymer (CFRP) strips installed according to the near surface mounted (NSM) technique using two different adhesives. The beams were simultaneously subjected to a service load and the ISO 834 standard fire. Different fire protection schemes were studied, comprising a thinner insulation layer along the bottom soffit of the beams and a thicker one at the CFRP anchorage zones. The main objectives of this paper were (i) to understand in further depth the fire behaviour of NSM-strengthened RC beams, in particular the structural effectiveness of the strengthening system during fire, (ii) to evaluate the efficiency of the above-mentioned fire protection strategy in extending the CFRP mechanical contribution during fire, and (iii) to compare the fire performance of the NSM-strengthening system with that of the alternative externally bonded reinforcement (EBR) technique, recently investigated under similar test conditions. The results obtained showed that using the adopted insulation schemes (i.e., thicker insulation at the anchorage zone and thinner insulation in the current zone), even after the CFRP-concrete bond is highly damaged in the central zone of the beams, the strengthening system is able to retain its structural effectiveness through a cable mechanism: for insulation thicknesses of 25 mm (current zone) and 50 mm (anchorage zones), the fire resistance of the strengthening system was extended up to 114 min. The loss of effectiveness of the CFRP system occurred when the average temperature in the adhesive at the CFRP anchorage zones attained values ranging from 2.2 to 5.6 times its glass transition temperature (T_g). The comparison with the EBR-strengthened beams confirmed the much better performance of the NSM strengthening.     

Multi-technique approach for non destructive diagnostic of structural composite materials using bulk ultrasonic waves,guided waves,acoustic emission and infrared thermography

The damage phenomenon occurring in glass fiber reinforced polymer (GFRP) laminate is very complex; it is inherently an anisotropic, multi-source and multi-scale process. In the present work, a new non destructive testing (NDT) approach is suggested using, simultaneously, multiple techniques. These are bulk and guided ultrasonic waves, acoustic emission, passive and active infrared thermography, for evaluating mechanical damage occurring in GFRP laminate under uniaxial tensile tests. The principal result of this work, other than the success of each applied technique to evaluate the created damage in the material, is the possibility to effectively combine multiple NDT techniques in order to validate or to complete the diagnosis of the structural health of the materials.     

Wet thermo-mechanical behavior of steel–CFRP joints – An experimental study

The long term durability of CFRP strengthened steel structures is a key parameter for their safe use and effective design. Strengthened members can be subjected to different environmental conditions and loading scenarios during their service life, the effect of which on the failure mechanism of the strengthened member requires fundamental investigations. This paper presents an experimental investigation into the effects of wet thermo-mechanical loading on the bond strength and the failure mode of steel–CFRP single lap joints. A total of thirty four steel–CFRP single lap shear specimens were prepared and exposed to different combinations of wet thermal cycle ranges and sustained loads. The results show that these conditions (wet thermal cycles and sustained loads) have little impact on the bond strength of steel–CFRP lap joint when applied separately. However, when applied simultaneously, the bond strength of the joint is significantly reduced with failure observed at less than 30% of the static strength under temperatures that are well below the glass transition temperature of the adhesive.     

Destructive and nondestructive evaluations of the effect of moisture absorption on the mechanical properties of polyester-based composites

In this study the effect of moisture absorption on the mechanical properties of glass-reinforced polyester composites is evaluated using both destructive and nondestructive tests. The composite resins were produced with two different production processes, while the mechanical properties of the composite materials were measured using DMA destruction tests. According to the DMA tests, the dependency in terms of temperature for the real component of the complex elastic modulus (E′), the imaginary component of the complex elastic modulus (E″), as well as tan(δ) can be traced. For a more efficient use of the composite materials, the compliance tensor was obtained with nondestructive tests based on ultrasound. A method for the generation and reception of Lamb waves in plates of composite materials is described, based on using air-coupling, low-frequency, ultrasound transducers in a pitch–catch configuration. The results of the nondestructive measurements made in this study are in good agreement with those obtained when using the DMA destructive tests.     

Indentation of polyethylene laminates by a flat-bottomed cylindrical punch

Cross-ply polymer laminates reinforced by ultra-high molecular weight polyethylene (UHWMPE) fibers and tapes have been subjected to quasi-static indentation by a flat-bottomed, circular cross section punch and their penetration resistance and failure mechanisms investigated. Three fiber- and two tape-reinforced grades progressively failed during indentation via a series of unstable failure events accompanied by substantial load drops. This resulted in a ‘saw-tooth’ load versus indentation depth profile as the load increased with indentation depth after each failure event. The penetration behavior scaled with the ratio of the thickness of the remaining laminate to the diameter of the punch, and the indentation pressure scaled with the through thickness compressive strength. Failure occurred by ply rupture. The results are consistent with penetration governed by an indirect tension failure mechanism, and with experimental reports that tape-reinforced materials have a similar ballistic resistance to the higher tensile strength fiber-reinforced grades in rear-supported test conditions.     

Experimental investigation of composite lockbolt fastened joints under in-plane low velocity impact

Two different composite fastened configurations, i.e. the filled hole and the single-lap double-fastener joint, are experimentally investigated in tensile mode through different loading rates. The composite material system is the UD carbon/epoxy AS4/8552 and the coupons are fastened with titanium countersunk lockbolts. The experiments are performed in a range from quasi-static to 2.8 m/s impact velocity, using an innovative testing device developed and adapted in a drop tower machine. The main experimental observations are the limited loading rate sensitivity in terms of strength for both tested configurations, the elevated absorbed energy values in the dynamic tests of the lap joint samples, as well as the differences in their failure evolution and modes between quasi-static and impact loading.     

Highly thermally conductive POSS-g-SiCp/UHMWPE composites with excellent dielectric properties and thermal stabilities

Polyhedral oligomeric silsesquioxane grafting thermally conductive silicon carbide particle (POSS-g-SiCp) fillers, are performed to fabricate highly thermally conductive ultra high molecular weight polyethylene (UHMWPE) composites combining with optimal dielectric properties and excellent thermal stabilities, via mechanical ball milling followed by hot-pressing method. The POSS-g-SiCp/UHMWPE composite with 40 wt% POSS-g-SiCp exhibits relative higher thermal conductivity, lower dielectric constant and more excellent thermal stability, the corresponding thermally conductive coefficient of 1.135 W/mK, the dielectric constant of 3.22, and the 5 wt% thermal weight loss temperature of 423 °C, which holds potential for packaging and thermal management in microelectronic devices. Agari’s semi-empirical model fitting reveals POSS-g-SiCp fillers have strong ability to form continuous thermally conductive networks.