共查询到19条相似文献,搜索用时 125 毫秒
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在遗传算法的应用研究中,总共做了两方面的工作。其一利用遗传算法对神经网络结构参数进行优化;其二对神经网络的初始权重进行优化。得到优化的遗传神经网络GA-BP-ANN。将此网络应用于解析流动注射-光度分析测得的铁(镍)-(5-Br-PADAP)络合物的重叠光谱,建立了不经分离同时测定铁和镍的新化学计量学方法。 相似文献
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<正> 磷矿中锰的测定,常用高锰酸法。该法选择性高,但灵敏度低。近年来,以非离子表面活性剂TritonⅩ—100增溶Mn(Ⅱ)—PAN络合物,光度法测定锰,方法的灵敏度高,ε为5.8×10~4。最近有用2(5-溴-吡啶偶氮)-5-=氨基酚(简称5-Br-PADAP)与锰生成红色络合物,亦为Triton增溶,可在水相中光度测定锰,ε为1.1×10~(5(3))。我们在磷 相似文献
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用载有2-(5-溴-吡啶偶氮)-5-二乙氨基苯酚(5-Br-PADAP)的改性硅胶(5-Br-PADAP-SG)可以分离、富集水样中的铜和镍。研究结果表明,5-Br-PADAP-SG 对铜、镍的最大吸附量分别是30.1μmol/g、16μmol/g。经5-Br-PADAP-SG 柱富集后,先用0.2mol/l 的硫脲(含0.01mol/l HCl)洗脱铜,再用0.2mol/l 的 HClO_4洗脱镍,以5-Br-PADAP 光度法可测定 ppb 级的铜、镍,富集倍数可达200倍以上,分离效果良好。 相似文献
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在pH为9.60的硼砂-氢氧化钠缓冲溶液、十六烷基三甲基溴化铵(CTMAB)存在下,铜(Ⅱ)、镍(Ⅱ)、钙(Ⅱ)和镁(Ⅱ)与二甲酚橙(XO)发生灵敏的显色反应,所形成的络合物吸收光谱严重重叠,各组分间相互干扰。采用人工神经网络结合分光光度法,设计不经分离同时测定铜(Ⅱ)、镍(Ⅱ)、钙(Ⅱ)和镁(Ⅱ)含量的方法。结果表明:该方法具有良好的准确性,四种金属离子同时测定结果的相对误差绝对值均≤2.74%。 相似文献
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研究了在pH 8.5的硼砂-硼酸缓冲溶液中,在表面活性剂辛基酚聚氧乙烯醚(曲拉通X-100)存在下,Cd(Ⅱ)与2-[5-溴-2-吡啶偶氮]-5-二乙氨基苯酚(5-Br-PADAP)形成有色络合物的条件.络合物的最大吸收波长为560 nm,其络合比为n[Cd(Ⅱ)]:n(5-Br-PADAP)=1:2,表观摩尔吸光系数为3.23×105L/(mol·cm).镉质量浓度在0~320μg/L符合比尔定律.通过巯基棉柱富集、分离,除去大量的干扰离子.该方法灵敏度高,有色络合物稳定时间长,显色温度范围宽,重现性好,应用于水中微量镉的测定,结果满意. 相似文献
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P Narayanan Remya M Lakshmipathy Reddy 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2004,79(7):734-741
The solvent extraction of magnesium(II), aluminium(III), titanium(IV), vanadium(V), chromium(III), manganese(II) and iron(III) from hydrochloric acid solutions has been investigated using the trialkylphosphine oxide Cyanex 923 (TRPO) in kerosene as extractant. The results demonstrate that titanium(IV), vanadium(V) and iron(III) are extracted into kerosene as TiOCl2·2TRPO, VO2Cl·TRPO and HFeCl4·2TRPO, respectively. On the other hand magnesium(II), aluminium(III), chromium(III) and manganese(II) are not extracted with TRPO from hydrochloric acid solutions (1.0–4.0 mol dm?3) under the experimental conditions. IR spectral studies of the extracted complexes were further used to clarify the nature of the extracted complexes. The effect of the diluent on the extraction of titanium(IV), vanadium(V) and iron(III) has been studied and correlated with the dielectric constant. The loading capacity of the TRPO system has been evaluated and the potential for the separation and recovery of titanium(IV), vanadium(V) and iron(III) from simulated waste chloride liquors of the titanium minerals processing industry has been assessed. Copyright © 2004 Society of Chemical Industry 相似文献
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Ozone used in preoxidation for water treatment processes allows the removal of inorganic compounds such as iron and manganese. The reactivity of ozone and manganese has been studied in a wide pH range. However, some difficulties appeared in the determination of the different species because of secondary reactions, the main difficulty being the interaction between indigo (used to determine ozone concentration) and manganese dioxide formed during ozonation. 相似文献
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《分离科学与技术》2012,47(5):943-959
Abstract The removal of iron and manganese from ground water is an important step for producing safe drinking water. A detailed investigation of the sorption of iron and manganese from ground water onto maize cobs is reported. This work deals with determination of adsorption equilibrium isotherms, kinetic, and fixed bed column studies. Results of Freundlich and Langmiur parameters revealed the favorability of maize cobs for adsorption of iron and manganese ions. Kinetic studies were carried out using from ground water samples (El‐Mina Governorate, Egypt). From the kinetic studies, a model is proposed to determine the external mass transfer (Ks) which can be correlated by the following equation Ks =A (mass)B. where A and B are constants. During the fixed bed column studies, the effect of process variables such as bed height, flow rate, initial concentration, and percentage breakthrough has been investigated. A simplified design method, namely, the bed depth service time (BDST) model has been applied to the experimental data and the results of this analysis are presented. The mechanism of the metal ion sorption on maize cobs was also investigated. Both the calorific values and differential thermal analysis (DTA) data proved that the loaded maize cobs can be used as solid fuel. Pretences of iron and manganese salts catalyze the thermal decomposition reaction toward more flammable gases, which increase their calorific values. The loaded maize cobs are considered a new potential source for energy conversion. 相似文献
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应用火焰原子吸收法测定液体肥料中的铜、锌、铁、锰,并对测定条件、干扰因素进行了综合考察。该方法简便、快速,适用于多元素液肥生产控制分析和样品系统分析 相似文献
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共振光散射法测定水中痕量总锰 总被引:1,自引:0,他引:1
建立一种环境水样中总锰的共振光散射分析新方法。在pH=6.0的Tris-HC l缓冲溶液中,锰(Ⅶ)氧化二甲基亚砜(DMSO)成为二甲基砜(DMSO2),生成的Mn2+与DMSO2结合形成离子缔合物,使体系的共振光散射急聚增强。在优化的实验条件下,在6.3×10-9~7.5×10-5mol/L浓度范围内,体系的△I值与锰(Ⅶ)浓度之间具有良好的线性关系,线性回归方程为△IRLS=-217.3+114.7 c(r=0.999 1);检出限为1.9×10-9mol/L;样品加标回收率为102.3%~106.5%。该法简便,特异,灵敏度高。用于环境水样中总锰的测定,结果满意。 相似文献