Electron diffraction study of the structure the NbBr4 molecule

The structure of the NbBr₄ molecule is studied in synchronous electron diffraction and mass spectrometry experiments. Gaseous niobium tetrabromide is synthesized in the course of the experiment during the interaction of niobium chips with bromine at 496°C. Analysis of the geometrical models of the NbBr₄ molecules of C_2v, C_3v, D_2d, and T_d symmetries shows that the tetrahedral model is preferable. The thermally averaged parameters of the effective configuration of the NbBr₄ molecule are as follows: r_g(Nb?Br)=2.418(5) Å, l(Nb?Br)=0.074(2) Å, r_g(Br?Br)=3.921(16) Å, l(Br?Br)=0.271(12) Å, δ(Br?Br)=0.027(18) Å.     

Electron diffraction study of structure of iron trifluoride molecule

Ivanovo Chemical Technology Institute. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 4, pp. 62–67, July–August, 1991.     

Electron diffraction investigation of the structure of the 3,3-dimethyl-3-silathiophane molecule

Chemistry Faculty, M. V. Lomonosov Moscow State University. Irkutsk Institute of Organic Chemistry. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 2, pp. 148–151, March–April, 1991.     

Electron diffraction study of structure and internal rotation in molecule of β-chlorovinyldichloroarsine

Vol'sk Branch, State Union Scientific-Research Institute of Organic Chemistry and Technology. Translated from Zhurnal Strukturnoi Khimii, Vol. 33, No. 5, pp. 63–68, September–October, 1992.