共查询到18条相似文献,搜索用时 93 毫秒
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以四氯化铪(HfCl4)和硝酸锌为原料,通过水热法制得Hf掺杂氧化锌纳米材料(Hf-ZnO),并将Hf-ZnO、酪氨酸酶(Tyr)和壳聚糖(CS)修饰在玻碳电极(GCE)上,制得Tyr/Hf-ZnO/CS/GCE生物电极。利用FESEM、DLS、XRD和XPS对Hf-ZnO的结构和性能进行表征。采用循环伏安伏安法(CV)和计时电流法(IT)对Tyr/Hf-ZnO/CS/GCE电极进行电化学测试。结果表明,Tyr/Hf-ZnO/CS/GCE电极在pH 5和-50 mV的低电势下对邻苯二酚有最佳检测能力,对邻苯二酚检测的线性范围是0.5~47 μmol/L,灵敏度为195 μA/(mmol/L),检测限是0.1215 μmol/L(S/N=3)。此外,该生物电极的稳定性和重复性好,可有效避免尿素、多巴胺、抗坏血酸等与邻苯二酚电活性相近物质的干扰。 相似文献
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以四氯化铪(HfCl_4)和六水合硝酸锌为原料,通过水热法制得Hf掺杂氧化锌纳米材料(Hf-ZnO),并将Hf-ZnO、酪氨酸酶(Tyr)和壳聚糖(CS)修饰在玻碳电极(GCE)上,制得Tyr/Hf-ZnO/CS/GCE生物传感器。利用FESEM、DLS、XRD和XPS对Hf-ZnO的结构和性能进行表征。采用循环伏安法(CV)和计时电流法(IT)对Tyr/Hf-ZnO/CS/GCE电极进行电化学测试。结果表明,Tyr/Hf-ZnO/CS/GCE电极在pH=5和–50 mV的低电势下对邻苯二酚有最佳检测能力,对邻苯二酚检测的线性范围是0.5~47.0μmol/L,灵敏度为195 mA/(mol/L),检测限是0.1215μmol/L (S/N=3)。此外,该生物电极的稳定性和重复性较好,可有效避免尿素、多巴胺、抗坏血酸等与邻苯二酚电化学活性相近物质的干扰。 相似文献
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用静电纺丝法,研究了制备氮化镓纳米管的影响因素,并利用扫描电镜(SEM),透射电镜(TEM),X射线衍射(XRD)进行表征。结果表明,PVP浓度为14%,纺丝电压为12 kV,固化距离为12 cm时得到外径约600 nm内径约400 nm的纳米管前躯体;通过焙烧得到外径约300 nm内径约200 nm的纳米管氧化物;最后测试了其介电性能。 相似文献
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介绍了静电纺丝的原理以及静电纺丝纤维膜作为医用敷料的优点;综述了国内外静电纺丝制备医用敷料的研究进展,包括用于体外创伤护理、皮肤再生和具有定向药物释放功能的静电纺丝医用敷料。指出静电纺丝纳米纤维医用敷料作为一种高科技的功能性敷料,具有良好的发展前景。 相似文献
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用电纺法制备了聚丙烯腈(PAN)纳米纤维,用场发射扫描电镜(FESEM)对其形态进行了研究,讨论了不同工艺参数对纤维直径和分散形态的影响。结果发现,纤维直径随着浓度的增加而增大,随着电压升高而减小,接收距离和溶剂类型对纤维直径的影响不大。将形态最好的纤维在240℃下进行活化处理,然后将活化处理过的纤维在氮气氛中煅烧,用FESEM观察了煅烧的纤维直径及形态的变化,红外(IR)分析了纤维化学结构的变化,证实了经900℃煅烧后的纤维为碳纳米纤维。 相似文献
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Lukas Zeininger Martin Klaumünzer Wolfgang Peukert Andreas Hirsch 《International journal of molecular sciences》2015,16(4):8186-8200
A new prototype of a Hamilton receptor suitable for the functionalization of inorganic nanoparticles was synthesized and characterized. The hydrogen bonding receptor was coupled to a catechol moiety, which served as anchor group for the functionalization of metal oxides, in particular zinc oxide. Synthesized zinc oxide nanorods [ZnO] were used for surface functionalization. The wet-chemical functionalization procedure towards monolayer-grafted particles [ZnO-HR] is described and a detailed characterization study is presented. In addition, the detection of specific cyanurate molecules is demonstrated. The hybrid structures [ZnO-HR-CA] were stable towards agglomeration and exhibited enhanced dispersability in apolar solvents. This observation, in combination with several spectroscopic experiments gave evidence of the highly directional supramolecular recognition at the surface of nanoparticles. 相似文献
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Shuyao Wu Chengquan Sui Chong Wang Yulu Wang Dongqing He Ying Sun Yu Zhang Qingbo Meng Tianyi Ma Xi-Ming Song 《Frontiers of Chemical Science and Engineering》2021,15(6):1572
High density and uniform distribution of the gold nanoparticles functionalized single-stranded DNA modified reduced graphene oxide nanocomposites were obtained by non-covalent interaction. The positive gold nanoparticles prepared by phase inversion method exhibited good dimensional homogeneity and dispersibility, which could readily combine with single-stranded DNA modified reduced graphene oxide nanocomposites by electrostatic interactions. The modification of single-stranded DNA endowed the reduced graphene oxide with favorable biocompatibility and provided the preferable surface with negative charge for further assembling of gold nanoparticles to obtain gold nanoparticles/single-stranded DNA modified reduced graphene oxide nanocomposites with better conductivity, larger specific surface area, biocompatibility and electrocatalytic characteristics. The as-prepared nanocomposites were applied as substrates for the construction of cholesterol oxidase modified electrode and well realized the direct electron transfer between the enzyme and electrode. The modified gold nanoparticles could further catalyze the products of cholesterol oxidation catalyzed by cholesterol oxidase, which was beneficial to the enzyme-catalyzed reaction. The as-fabricated bioelectrode exhibited excellent electrocatalytic performance for the cholesterol with a linear range of 7.5−280.5 μmol·L−1, a low detection limit of 2.1 μmol·L−1, good stability and reproducibility. Moreover, the electrochemical biosensor showed good selectivity and acceptable accuracy for the detection of cholesterol in human serum samples. 相似文献
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Cyanide is a highly poisonous and hazardous substance which may release into the environment from natural sources or industrial effluent; therefore, cyanide detection is a fundamental step to prevent environmental pollution and secure health and safety. In this study, we prepared a sensitive amperometric inhibition biosensor for cyanide detection by immobilization of horseradish peroxidase (HRP) enzyme and reduced graphene oxide (rGO) on the surface of glassy carbon electrode (GCE). To do so, we performed the amperometric measurement by modified GCE to test its efficiency in detecting cyanide. The optimum conditions of pH equal to 7.5, −100 mV applied potential, 0.7 μM mediator concentration, and 0.5 mM substrate concentration were found. Then, experiments were performed at different boundary conditions in a range of 0.1 to 10 μM cyanide concentration at optimal conditions and a low detection limit of 0.01 μM was obtained. Also, the possible mechanism of inhibition was analyzed based on the Michalis–Menten equation and non-competitive inhibition was observed. Due to high sensitivity, low detection limit, and low cost, this biosensor is proposed as a useful method for cyanide determination in real samples. 相似文献
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分别通过光还原和电还原在以氧化铟锡玻璃为基体的ZnO上沉积Cu和Cu2O,后经400℃空气中热处理,制备了两种CuO/ZnO叠层复合薄膜。用X射线衍射、扫描电子显微镜和X射线能量散射谱分别对复合薄膜的晶相、形貌和化学组成进行表征。以橙黄II在模拟自然光照射下的光催化降解作为探针反应评价其光催化活性。结果表明:由Cu/ZnO经400℃下焙烧1h转化的CuO/ZnO叠层复合薄膜具有更高的光催化活性,反应1h后,橙黄II的降解率比由Cu2O/ZnO经400℃下焙烧1h转化的CuO/ZnO提高了14%。对CuO/ZnO叠层复合薄膜光催化活性提高的原因也进行了讨论。 相似文献
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Chan-Geun Song Jonghan Won Inhoon Jang Hyeunseok Choi 《Journal of the American Ceramic Society》2021,104(9):4398-4407
In metal oxide nanofiber fabrication using the electrospinning method, heat treatment is performed at temperatures of 500°C or higher for crystallization and polymer desorption. Therefore, it is difficult to fabricate low-temperature phase metal oxides that crystallize at low temperatures. TiO2, a representative metal oxide often used as photocatalysts, is known to have higher photocatalytic activity in the low-temperature phase (anatase structure) than in the high-temperature phase (rutile structure). Studies on the fabrication of TiO2 anatase nanofibers using conventional electrospinning have reported disadvantages such as the partial expression of rutile structures and low crystallinity. This study developed an anatase TiO2 nanofiber as a high-efficiency catalyst based on the electrospinning method and a residual organic matter cleaning method that employs ultra-violet (UV) light. We fabricated nanofibers using the electrospinning method and implemented TiO2 nanofibers with the anatase structure through heat treatment at 260°C. Residual organics remaining after heat treatment of the fabricated crystalized TiO2 nanofibers were removed by exposing them to UV light, thereby improving photocatalytic efficiency. The photocatalytic efficiency of the fabricated TiO2 nanofibers was confirmed through a methylene blue (MB) decomposition experiment under visible light irradiation. The photocatalytic efficiency (time taken for the concentration of the MB solution to reach 50%) of the UV-treated TiO2 nanofibers was approximately six times higher than of P25 and the heat-treated nanofibers. 相似文献
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Sampathkumar Chrisolite Vanithakumari Vijayan Athulya Rani Pongachira George John Philip 《应用聚合物科学杂志》2021,138(13):50118
In this work superhydrophobic coating with self cleaning property is fabricated on 304L SS samples directly using a simple one step electrospinning process followed by silane treatment by using polyvinyl alcohol (PVA) and tetraethyl orthosilicate solution. A maximum water contact angle of 169.2° ± 2.1° is obtained at an electrospinning potential of 15 kV for 2 h, with a distance of 18 cm between the collector and needle. The hierarchical nanostructures thus formed on 304L SS composed of poly(vinyl alcohol)-silica microbeads and nanofibers. The surface morphologies are optimized by varying the electrospinning voltage, time, distance between needle and the collector and aging duration of the precursors. Attenuated total reflectance-infrared spectroscopy studies at different stages of preparation confirmed the presence of PVA/SiO2 composite nanofibers deposited on the 304L SS surface. The reaction of SiO2 nanofibers with hexamethyl disilazane resulted in the formation of Si O Si bonds that provided water repellent property. The developed SHP surface coating on 304L SS sample showed dynamic bouncing of water droplets and excellent self cleaning performance. The sample retained the SHP behavior in chloride solutions with different ionic strengths and pH. 相似文献