BIOGEOCHEMICAL PROCESSES OF PHOSPHORUS AND SILICON IN SOUTHERN BOHAI SEA SURFACE SEDIMENTS

Based on the author’s previously obtained results on P and Si forms in southern Bohai Sea surface sediments,this study maindy foucusing on the controlling factors,existence forms,and biogeo-chemical processes of P and Si showed that the transferable forms of phosphorus in sediments were mainly controlled by the mineralization of organic matters and the reduction of high-valence iron;whereas the transferable forms of silicon were possibly controlled by the dissolution and precipitation as well as bio-chemical processes of living organisms.     

NUTRIENTS IN SEAWATER AND INTERSTITIAL WATER OF THE SEDIMENTS IN THE HUANGHE RIVER ESTUARINE AREA (NOVEMBER)

The investigation shows that the concentrations of nutrients are high in estuarine and coastal waters and low in offshore waters. The concentration of nitrate in estuaries is controlled through a physical mixing process and is also affected by hiotic activity. The annual transport of total inorganic nitrogen and dissolved phosphate-phosphorus from the Huanghe River water to the sea is about 8.45×104 and 1.45×103 tons respectively. The distributions of inorganic nitrogen and silicate in interstitial water of surface sediments are similar to those in surface and bottom sea water. Their contents in interstitial water are227 552μmol/l (average 375) for ammonia, 0.31 -9.0μmol/l (average 1.6) for nitrite, 0 41μmol/1 (average 6.0) for nitrate, and 41 139μmol/l (average 77) for silicate. The average concentrations of phosphate in the surveyed area are 0.64μmol/l for seawater and 1.2μmol/l for interstitial water. A cycle of phosphate in the estuary is also suggested in this paper.     

Densities of Huanghe River estuary and Bohai Bay waters

The densities of 36 water samples from the Huanghe River estuary and Bohai Bay were determinedby a magnetic float densimcter under three temperatures from 15℃ to 25℃.All the measured densities ofsamples were greater than that of the values calculated from the International Equation of State of Seawater.The differences between the measured and calculated densities increased with the decrease of salinities.The dif-ferences appeared exponentially correlated with[Ca~(2+)]/s,[Mg~(2+)]/s and[SO_4~(2-)]/s,and had"s"type curverelationship with the alkalinity in all salinity range.But in the salinity ranging from 25.72 to 31.57,therelationships were all linear.The density difference can be estimated from the equation △ρ（10~3kg·m~(-3)）=（-2.79+236.5([Ca~(2+)]/s)/(-9.7464×10~（-3）+[Ca~(2+)]/s).It was the high alkalinity and[Ca~(2+)]/s that resulted in the measured densi-ties of seawaters being higher than the calculated densities in the Huanghe estuary and Bohai Bay.     

Forms of phosphorus and silicon in the natural grain size surface sediments of the southern Bohai Sea

The forms of phosphorus and silicon in the natural grain sizes surface sediments of the southern Bohai Sea were studied. In sediments, the organic matter bound form of phosphorus was the main form of transferable phosphorus and ranged from 0.37μmol/g to 1.57μmol/g, accountingfor 10.7% of the total phosphorus, others were the carbonate bound form, iron-manganeso oxide bound form and ion-exchange able form; the transferable form of phosphorus accounted for 19.2% of the total phosphorus. Silicon‘ s carbonate bound form was predominant over others among its transferable forms, and content ranged from 1.55μmol/g to 8.94μmol/g, accounting for 0.05% of the total silicon; the total amount of transferable silicon forms accounted for only 0.12% of the total silicon. Therefore, 19.2% of the total phosphorus and 0.12 % of the total silicon contained in the surface sediments of the southern Bohai Sea could participate in the biogeochemical cycling.     

A contrast analysis on the load character of the Changjiang River and the Huanghe River

According to the analysis of grain size, mineral composition and inclusion in quartz grain of the suspended and bed load sampled from the Changjiang (Yangtze) River and the Huanghe (Yellow) River, the authors reveal the differentiation of loads between the two rivers. In the Huanghe River the size of suspended load is coarser than that in the Changjiang River, while the bed load is on the contrary. Through heavy mineral analysis, the biotite content of the Huanghe River loads is much higher than that of the Changjiang River, and the monomorillonite content of the former is about two times higher than the latter. All those may be attributed to the effects of different material sources and hydraulic conditions on load. The analysis of inclusion in quartz grain definitely illustrates the environmental difference of material sources between the two rivers. In the meantime, it provides a new method in seeking source of river load. Subsidized by the National Natural Science Foundation. This paper is attributed to careful guidance from Prof. Wang Ying & Prof. Shi Yunliang.     

CHARACTERISTICS OF PERIGLACIAL GEOMORPHOLOGY IN THE SOURCE AREA OF THE HUANGHE RIVER

There widely occur stretches of permafrost at more than 3,800-4,200 meters above sea level in the source area of the Huanghe (Yellow) River. The periglacial geomorphology develops quite well, including frozen disintegration geomorphology, freezing and thawing geomorphology in cold environments, periglacial dune, buried ices and fossil periglacial phenomena. In light of the relation between stratigraphy and periglacial phenomena, three periglacial periods can be divided, which are the Middle Pleistocene periglacial period, the Late Pleistocene periglacial period and modern periglacial period.     

Several problems about the eco-environmental research on the source regions of the Changjiang River and the Huanghe River

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BACKGROUND STUDY ON NON-RESIDUAL PHASE OF ELEMENTS IN CHANGJIANG AND HUANGHE ESTUARINE SEDIMENTS

Analysis of Zn, Cu, Pb, Co, Cr, Li, Ni, K, Al, Fe extracted by 1 mol/L HCl or 0.5 mol/LHCl/H_2O_2, showed concentrations of Zn, Cu, Pb, Co, Cr, Fe, Ni were significantly correlated with Li, Al,K, and clay. Two methods are used to indicate the background value of the non-residual phase of elementsin sediments, and are the same as the methods used to indicate the background value of totalconcentrations in sediments. The first method uses correlograms and regression equations,the second usesthe mean element concentrations normalized with grain size. Li, Al, K can be used as reference elements to determine the background value of Zn, Cu, Pb, Co,Cr, Ni, Fe, while the clay concentration's correlation with some extractable concentrations can be used tocalculate the background value of the non-residual phase of elements as a percentage of clay concentrationin the sediments. Based on this study, the concept of using the background value of the non-residualphase of elements to compare the pollution level in differ     

An approach to the age of Huanghe River in shelf regions of Yellow Sea and Bohai Sea

There are two different opinions on the formation history of Huanghe （Yellow） River. One postulates that Huanghe River might have come into existence before Tertiary. The other supposes that it joined up into a long river only in the last stage of Late Pleistocene. The appearance of Huanghe River is believed to have close relation to the uplifting of Tibetan Plateau. It is not likely that it could have come into being before its high elevation riverhead was formed. Today Huanghe River occurred probably during the recession of the sea in glacial periods. In the last glacial age, the climate was very harsh in the area north of the modern estuary of Changjiang （Yangtse） River; some areas were permafrost and the others barren deserts. At that time, eolation was the major exogenic force on exposed shelf. Beginning from 12 Ka BP, the global climate warmed up, resulting in gradual disappearance of continental mountain glaciers retreated, and sea level rose. Consequently, Huanghe River was replenished with water to become modern river system. With continued rising of sea level, Huanghe River delta moved continuously eastward.     

Impacts of Climatic Factors on Runoff Coefficients in Source Regions of the Huanghe River

Runoff coefficients of the source regions of the Huanghe River in 1956–2000 were analyzed in this paper. In the 1990s runoff of Tangnaihai Hydrologic Station of the Huanghe River experienced a serious decrease, which had at- tracted considerable attention. Climate changes have important impact on the water resources availability. From the view of water cycling, runoff coefficients are important indexes of water resources in a particular catchment. Kalinin baseflow separation technique was improved based on the characteristics of precipitation and streamflow. After the separation of runoff coefficient (R/P), baseflow coefficient (Br/P) and direct runoff coefficient (Dr/P) were estimated. Statistic analyses were applied to assessing the impact of precipitation and temperature on runoff coefficients (including Dr/P, Br/P and R/P). The results show that in the source regions of the Huanghe River, mean annual baseflow coefficient was higher than mean annual direct runoff coefficient. Annual runoff coefficients were in direct proportion to annual pre- cipitation and in inverse proportion to annual mean temperature. The decrease of runoff coefficients in the 1990s was closely related to the decrease in precipitation and increase in temperature in the same period. Over different sub-basins of the source regions of the Huanghe River, runoff coefficients responded differently to precipitation and temperature. In the area above Jimai Hydrologic Station where annual mean temperature is –3.9oC, temperature is the main factor in- fluencing the runoff coefficients. Runoff coefficients were in inverse relation to temperature, and precipitation had nearly no impact on runoff coefficients. In subbasin between Jimai and Maqu Hydrologic Station Dr/P was mainly affected by precipitation while R/P and Br/P were both significantly influenced by precipitation and temperature. In the area be-tween Maqu and Tangnaihai hydrologic stations all the three runoff coefficients increased with the rising of annual precipitation, while direct runoff coefficient was inversely proportional to temperature. In the source regions of the Huanghe River with the increase of average annual temperature, the impacts of temperature on runoff coefficients be-come insignificant.     

Types and distribution patterns of modern tidal channels along the Huanghe River Delta coast

INTRODUCTIONTidalchannelsareimportantgeomorphologicunitsalongsiltcoasts.Theyhaveanevidentfunc tionfortidalflatbecausetheyareassociatedwithitsrapidbayheadwarderosionandlateralswing ing.Thetidalchannelsdevelopalongthecoastandplayanimportantroleinseaandlandinterac tion .Manyscientistsresearchedthetidalchannels (Bayliss Smith ,1 978;Shao ,1 988;Zhang ,1 995) .TheScientificandTechnicalCommitteeofShandongProvince (1 991 )investigatedthecoastoftheHuanghe (Yellow)RiverDeltaandresearchedtheti…     

Changes in Huanghe （Yellow） River estuary since artificial re-routing in 1996

With the combination of historical data, field observations and satellite remotely sensed images(Landsat TM/ETM and CBERS), changes in Huanghe (Yellow) River estuary since 1996 when artificial Chahe distributary was built up were studied, mainly including water and sediment discharge from the river, tides, tidal currents, suspended sediment diffusion, coastline changes and seabed development. During following six and half years (up to the end of 2002), runoff and sediment loads into the river mouth declined dramatically. At the beginning of the re-routing, abundant sediment loads from the river filled up nearshore shallow water areas so that the newborn delta prograded quickly. With rapid decrease of sediment loads transported to the estuary, the delta retrograded. In 1997, subaerial tip of the abandoned delta receded 1.5km; its annual mean recession rate was about 150 m in following years. In addition, marine dynamic condition near the artificial outlet had also changed. Under the interaction of ocean and river flow, most of incoming sediment loads deposited in the vicinity of the outlet. Seabed erosion occurred at the subaqueous delta front. Between 1999 and 2002, erosion thickness averaged at 0.3 m in the subaqueous delta of 585.5 km2.