Dilution of North Pacific Intermediate Water studied with chlorofluorocarbons

Assessment was made of residual ratio of North Pacific Intermediate Water (NPIW) produced in subpolar region of the North Pacific using chlorofluorocarbons, CFC-11 and CFC-12 (CCl₃F and CCl₂F₂), along 175°E. NPIW on density horizons less than 26.80 remained more than 80% north of 30°N. It was suggested that new NPIW laterally spreads over the northern North Pacific without hardly being diluted by the surroundings. For density horizons greater than 26.80 north of 30°N, NPIW remained less than 60%. The difference in the residual ratio between <26.80 and >26.80 north of 30°N suggests that NPIW is produced on density horizons less than 26.80, which contacts the atmosphere in the subpolar region, and that NPIW is diluted by upwelling deep water on density horizons greater than 26.80 in high latitude of the North Pacific. NPIW on a density horizon of 26.80 remained about 50% south of 30°N. The decrease in the horizontal distribution of the residual ratio of NPIW suggests that half the new NPIW produced in the subpolar region is laterally spread over the North Pacific with the southward movement of NPIW.     

Chlorofluorocarbons in the western North Pacific in 1993 and formation of North Pacific intermediate water

Chlorofluorocarbons (CFC-11 and CFC-12) in the intermediate water having between 26.4 and 27.2 were determined at 75 stations in the western North Pacific north of 20°N and west of 175.5°E in 1993. The intermediate water of 26.4–26.6 was almost saturated with respect to the present atmospheric CFC-11 in the zone between 35 and 45°N around the subarctic front. Furthermore, the ratios of CFC-11/CFC-12 of the water were also of those formed after 1975. These suggest that the upper intermediate water (26.4–26.6) was recently formed by cooling and sinking of the surface water not by mixing with old waters. The water below the isopycnal surface of 26.8 contained less CFCs and the area containing higher CFCs around the subarctic front was greatly reduced. However, the CFC age of the lower intermediate water (26.8–27.2) in the zone around the subarctic front was not old, suggesting that the water was formed by diapycnal mixing of the water ventilated with the atmosphere with old waters not containing appreciable CFCs, probably the Pacific Deep Water. The southward spreading rate decreased with depth and it was one sixth of its eastward spreading rate of the North Pacific Intermediate Water (NPIW).     

Distribution of particulate organic carbon and nitrogen in the Bering Sea and northern North Pacific Ocean

Particulate matter was collected in the Bering Sea and the northern North Pacific Ocean during the cruise of R. V. Hakuho-maru, Ocean Research Institute of Tokyo University in summer of 1975. The particulate matter was analyzed for organic carbon and nitrogen, chlorophylla and amino acids.The concentrations of particulate organic carbon and nitrogen were measured with the range of 16–422gC l^–1 and 1–85gN l^–1, 19–186gC l^–1 and 1–26gN l^–1, 46–1,038gC l^–1 and 6–79gN l^–1 and 19–246gC l^–1 and 2–25gN l^–1 in the Oyashio, the Deep Bering Sea, the continental shelf of Bering Sea and the northern North Pacific, respectively. Particulate organic carbon and nitrogen decreased with depth throughout the areas. The average concentrations of organic carbon and nitrogen in the entire water column tended to decrease in the following order; the continental shelf > Oyashio > northern North Pacific > Deep Bering Sea.C/N of particulate matter varied in the range of 3–15 (7 on average) in surface waters throughout the areas and these values tended to increase with depth to 5–20 (11 on average) in deep waters without significant regional variability.Linear regressions between chlorophylla and particulate organic carbon in the euphotic layers indicate that detrital organic carbon accounted for 34.2, 44.9, 49.1 and 25.2 % of particulate organic carbon in the Oyashio, the Deep Bering Sea, the continental shelf and the northern North Pacific, respectively.Particulate amino acid was determined in the range of 10.3–78.0g l^–1, 104–156g l^–1 and 10.4–96.4g l^–1 in the Deep Bering Sea, the continental shelf and the northern North Pacific, respectively. Aspartic acid, glutamic acid, serine, glycine and alanine were found as dominant species of amino acid of particulate matter.     

Topographic Effect of Izu Ridge on the Distribution of the North Pacific Intermediate Water South of Japan

The topographic effect of the Izu Ridge on the horizontal distribution of the North Pacific Intermediate Water (NPIW) south of Japan has been studied using observational data obtained by the Seisui-Maru of Mie University (Mie Univ. data) and those compiled by Japan Oceanographic Data Center (JODC data). Both data sets show that water of salinity less than 34.1 psu on potential density () surface of 26.8 is confined to the eastern side of the Izu Ridge, while water of salinity less than 34.2 psu is confined to the southern area over the Izu Ridge at a depth greater than 2000 m and to the southeastern area in the Shikoku Basin. It is also shown by T-S analysis of Mie Univ. data over the Izu Ridge that water of salinity less than 34.2 psu dominates south of 30°N, where the depth of the Izu Ridge is deeper than 2000 m and NPIW can intrude westward over the Izu Ridge. JODC data reveal that relatively large standard deviations of the salinity on surface of 26.7, 26.8 and 26.9 are detected along the mean current path of the Kuroshio and the Kuroshio Extension. Almost all of the standard deviations are less than 0.05 psu in other area with the NPIW, which shows that the time variation in the salinity can be neglected. This observational evidence shows that the topographic effect of the Izu Ridge on the horizontal distribution of the NPIW, which is formed east of 145°E by the mixing of the Kuroshio water and the Oyashio water, is prominent north of 30°N with a depth shallower than 2000 m.     

Chlorinated hydrocarbons in the North Pacific and Indian Oceans

PCBs, DDT compounds and HCH isomers were detected in the air and surface waters of the North Pacific and Indian Oceans, including the Bering Sea, East China Sea, South China Sea, Bay of Bengal and the Arabian Sea. The general concentrations of each chlorinated hydrocarbon were as follows: water PCBs 0.1 to 1.0, DDT 0.01 to 1.0, HCH 1.0 to 10 ngl ^–1; air DDT 0.01 to 1.0, HCH 0.1 to 10 ng m^–3. PCB concentrations in surface waters were slightly lower than those of the North Atlantic and North Sea previously reported, while DDT concentrations in the air and water were higher. Remarkably high concentrations of DDT and HCH were found in the air off the western coast of India. Also in the Pacific site off Central America, a fairly high concentration of DDT was observed in an air sample. These data suggest that large amounts of DDT and HCH are being used in the tropical zone, especially in southern Asia. Furthermore, high concentrations were observed both in the air and water of the Northwest Pacific between 30°N and 40°N latitude. There is a possibility that both pesticides are not only still being used in lower latitude countries but also in the mid-latitude ones of the Asian continent excluding Japan. In addition to this atmospheric circulation may also contribute to the concentration of these pesticides in the mid-latitudinal zone.     

Inferring dynamic height variations from acoustic travel time in the Pacific Ocean

Using climatological atlas data and historical hydrographic data, the relationship between dynamic height anomaly D and acoustic round-trip travel time in the Pacific Ocean is investigated. A tight, linear relation is found in a region centered on the Kuroshio and Kuroshio Extension. In this region, the slopem of the relation is approximately –50 dyn m s^–1, about equal to the value expected for first-baroclinicmode response and twice as large as the value form in the Gulf Stream region of the Atlantic Ocean. The value ofm in the Pacific generally increases in magnitude towards the south and with increasing depth to which the integrals for D and are carried. It is changed only slightly by correcting for the temperature and salinity march of the seasons in the surface layer. The Kuroshio region is established as one in which the record of from an inverted echo sounder can be interpreted reliably in terms of D. An inverted echo sounder can also be used in this way in a number of other regions of the Pacific, although the available hydrographic data sets are too sparse to establish their boundaries clearly.     

Calcium-alkalinity relationship in the North Pacific

The dissolution of calcium carbonate in deep ocean water causes variation in calcium concentration (Ca) and alkalinity (TA) in the ratio of one to two. The decomposition of organic matter generates nitric acid, phosphoric acid and sulfuric acid. A proton flux which is derived from this process also changes alkalinity. Using the variation in nitrate concentration (NO₃) as an index of the proton flux, the relationship betweenCa,TA andNO₃ is expressed asCa=0.5TA+0.63NO₃ The values of Ca obtained from direct measurements in the North Pacific are in good agreement with the values estimated from this equation.     

δ15N of PON and Nitrate as a Clue to the Origin and Transformation of Nitrogen in the Subarctic North Pacific and Its Marginal Sea

Nitrogen isotope compositions of particulate organic matter and nitrate were analyzed for seawater sampled at five stations at the Alaskan Gyre, Western Subarctic Gyre and East China Sea, focusing on the samples from the surface to 5000 m water to characterize the nitrogen cycling in the subarctic North Pacific Ocean and its marginal sea. The ¹⁵N of particulate organic matter showed little agreement with a conceptual closed model that interprets isotopic variation as being caused by isotope discrimination on nitrate utilization. The ¹⁵N and ¹³C of particulate organic matter varied with the water depth. A correlation between isotope compositions and C/N elemental ratio was found generally at all stations, although some irregular data were also found in deep layers. We developed a hypothetical nitrogen balance model based on N₂ fixation and denitrification in seawater and attempted to apply it to distinguish nutrient cycling using both ¹⁵N-NO₃ ^– and N* variation in seawater. This model was applied to the observed data set of ¹⁵N-NO₃ ^– and N* in the North Pacific water and estimated the ¹⁵N-NO₃ ^– of primordial nitrate in the North Pacific deep water as 4.8. The North Pacific intermediate water for all stations showed similar ¹⁵N-NO₃ ^– and N* values of 6 and –3 µmol/kg, respectively, suggesting a similar nitrogen biogeochemistry. In the East China Sea, analysis showed evidence of water exchange with the North Pacific intermediate water but a significant influence of nitrogen from the river runoff was found in depths shallower than 400 m.     

Analysis of the global relationship of biennial variation of sea surface temperature and air-sea heat flux using satellite data

We investigated the phase difference and the cross correlation coefficient between the band-pass filtered biennial variations of sea surface temperature (SST) and air-sea heat flux estimated by the monthly mean 2°×2° satellite data of Advanced Very High Resolution Radiometer (AVHRR) and Special Sensor Microwave/Imager (SSM/I) from July 1987 to June 1991. Judging from the phase difference, it can be determined whether the biennial variation of SST is controlled by local thermal air-sea interaction or oceanic processes of horizontal transport. When the local air-sea heat flux controls the biennial variation of SST, the phase of SST advances /2 (6 months) against that of the air-sea heat flux. In contrast, when the biennial variation of SST is controlled by the oceanic process, the phase difference between the SST and the air-sea heat flux becomes 0 or (12 months). In this case, two types of the phase differences are determined, depending on which variability of SST and air-sea heat flux is larger. The close thermal air-sea interaction is noticeable in the tropics and in the western boundary current region. The phase difference of /2 appears mainly in the north Pacific, the southeast Indian Ocean, and the western tropical Pacific; zero in the eastern tropical Pacific and the northeast and equatorial Atlantic; and that of in the central equatorial Pacific and north of the intertropical convergence zone (ITCZ) of the Atlantic. Phase differences of 0, , or /2 are possible in the western boundary current regions. This fact indicates that each current plays a different role to the biennial variation of SST. It is inferred that SST anomalies in the tropics are mutually correlated, and the process in which marked SST anomalies in the tropics are transferred to the remote area was probed. In the equatorial Pacific, the SST anomaly is transferred by the long planetary wave. On the other hand, it is found from the phase relationship and the horizontal correlation of SST that the SST anomaly in the central and western equatorial Pacific is connected through atmospheric mediation. It is suggested that the biennial variation of SST in the eastern Indian Ocean is affected by heat transport due to the Indonesian throughflow from the western tropical Pacific. It is found that the mentioned pattern of the interannual variation of SST in the tropical Atlantic as a dipole is not tenable.     

Volume transport of the western boundary current penetrating into a marginal sea

The amount of penetration of a western boundary current into a marginal sea which is connected to an open ocean by two narrow straits is estimated from a linear, steady and barotropic theoretical model. In this model the western boundary current in the open ocean is driven by a wind stress imposed at the sea surface. The inflow of the water of the open ocean into the marginal sea is caused by the pressure difference between two straits produced by the wind-driven circulation in the open ocean.Main external parameters are combined into two non-dimensional parameters; and (the ratio of the depth of the marginal sea to that of the open ocean), whereb is the distance between north and south boundaries of the ocean,D ₀ is the depth of the open ocean, is the latitudinal variation of the Coriolis parameter andR is the coefficient of friction. The friction is assumed to be proportional to the flow velocity.In the limit of infinite the volume transport into the marginal sea is not affected by the width of two straits and . It is mainly controlled by the wind stress and the positions of two straits. For finite values of , however, the volume transport depends considerably on and the width of the straits.Guided by both this model and physical considerations, we obtained a relation between the volume transport into the marginal sea and the external parameters. This relation predicts that about 2 % of the volume transport of the Kuroshio penetrates into the Japan Sea.     

Parameterization of the dispersion relation of internal waves using the data of hydrological soundings in the Tropical Atlantic

Dependences have been determined which connect the parameters of the dispersion relation of the lowest mode of internal waves with the integral characteristics of the seasonal thermocline when 10 min30 min, 20 mh150 m, and 0·4 m²/s² Q5·2 m²/s².Translated by Mikhail M. Trufanov.     

A Box Model of Glacial-Interglacial Variability in the Japan Sea

The Japan Sea has experienced drastic changes in the last 60 ka: the surface water was colder than the present value by five degrees and extremely freshened (24 ppt) in the last glacial maximum (15 ka), and then it contained Oyashio water for a few thousand years. It is an open question whether the inflow-outflow pattern was entirely reversed, opposite to the present exchange with an inflow through Tsushima Strait and an outflow through Tsugaru Strait. A box model is employed with two boxes representing the northern and the southern half domains in the upper (300-m-thick) layer. The model is driven by atmospheric forcing and inflow through Tsushima Strait and/or Tsugaru Strait. Here, the net transport through Tsushima to Tsugaru is given in the model. A baroclinic component is added to the net transport through each strait. It is the baroclinic components that allow the upper and the lower portions to flow to the opposite directions in the straits, and hence a reversal flow becomes possible against the net transport, under the condition of an extremely freshened Japan Sea. The fresh surface layer in 1814 ka is attributable to a near-shutoff of the inflow due to the low sea level. Shortly after the near-shutoff, the baroclinic transport through Tsugaru Strait yields intrusion of the Oyashio water into the Japan Sea. Thus, it is implied that Oyashio water existed in the Japan Sea a few thousand years after the reopening of Tsugaru Strait, even though the net transport was one-way, similar to the present state.     

Radiation balance and heat budget at the ocean/atmosphere interface in the western North Pacific

The downward short- and long-wave radiation fluxes at the sea surface (S, L) were measured aboard the R/VHakuho Maru, University of Tokyo, for the period of 117 days on six cruises from 1981 to 1985 in the western North Pacific near Japan. The upward fluxes of short- and long-wave radiation (S, L) were calculated by Payne's (1972) table and the Stefan-Boltzmann's law, respectively. The sensible and laten heat fluxes (Q _h ,Q _e ) were also estimated from an aerodynamic bulk method.From April to August, the daily mean value ofS varied with the amplitude of 100200 Wm^–2. The value ofS was estimated approximately 6% ofS in all seasons. The difference betweenL andL was so small that the net radiation flux (Q _n ) was dominated byS. In addition, the net heat flux at the sea surface was also dominated byS due to small values ofQ _h andQ _e , and then the ocean was warmed at the rate of 111 Wm^–2 in April and 63 Wm^–2 in August in the Oyashio Area, and 132 Wm^–2 in May and 164 Wm^–2 in June in the Kuroshio Area, respectively.From September to March, a remarkable negative correlation between the day to day variation ofS and that ofL was observed except when an intense cold air outbreak occurred. It was found that the correlation was caused by the cloud climatological feature of the western North Pacific in this period.S was not a dominant factor in the net heat flux. The value ofQ _h +Q _e in the Kuroshio Area ranged from 260 Wm^–2 to 630 Wm^–2, much larger thanQ _n which ranged from –8 Wm^–2 to 92 Wm^–2 in the leg mean values (each leg period was about 10 days). Then the ocean was cooled at the rate of –160–620 Wm^–2 during this period. The net heat flux in the Kuroshio Area averaged over five legs from late November to February was –473 Wm^–2. This value is 50100% larger than the climatological values reported so far.The temporal and spatial variability of radiation fluxes and heat fluxes during each leg was also discussed.     

A Preliminary Study of Oceanic Bomb Radiocarbon Inventory in the North Pacific during the Last Two Decades

Radiocarbon and total carbonate data were obtained near the 1973 GEOSECS stations in the North Pacific along 30°N and along 175°E between 1993 and 1994. In these stations, we estimated radiocarbon originating from atomic bomb tests using tritium, trichlorofluoromethane and silicate contents. The average penetration depth of bomb radiocarbon during the two decades has deepened from 900 m to 1300 m. Bomb radiocarbon inventories above the average value for the whole North Pacific were found widely in the western subtropical region around 30°N both in the 1970s and 1990s, and its area in the 1990s was broader than that in the 1970s. In most of the North Pacific, while the bomb radiocarbon has decreased above 25.4, the bomb radiocarbon flux below 25.4 was over 1 × 10¹² atom m^-2yr^-1 in the subtropical region around 30°N. In the tropical area south of 20°N, the bomb radiocarbon inventory below 25.4 increased from zero to over 10 × 10¹² atom m^-2 during the last three decades. These distributions suggest that the bomb radiocarbon removed from the surface is currently accumulated with bomb ¹⁴C flux of over 1 × 10¹² atom m^-2yr^-1 below 25.4 in the subtropical region, mainly by advection from the higher latitude, and that part of the accumulated bomb ¹⁴C gradually spread southward with about 30 years.     

Tritium in the northwestern North Pacific

Vertical profiles of tritium in seawater were determined for samples collected during the period from 1988 to 1990 at fourteen stations in the northwestern North Pacific (the Oyashio region) including the Okhotsk Sea and the Bering Sea. The profiles usually had a maximum in the surface layer and decreased gradually with depth down to 1,000 m. The water column inventory of tritium averaged 63% of the total atmospheric input in this region.The horizontal distribution of tritium showed a maximum in the region facing the Okhotsk Sea near 45°N for every isopycnal surface of ₀ ranging from 26.60 to 27.40. The ages of the intermediate water were calculated for the respective isopycnal surfaces in the maximum region. This calculation assumed that the intermediate water was formed by the isopycnal mixing of two water masses—the Okhotsk Sea and the Bering Sea Component Waters, which had been produced in wintertime by the diapycnal mixing of the surface and the deep waters in the respective marginal seas. The results show that the intermediate water in this region was formed in the late 1980's for the water which has ₀ of 26.60 to 26.80 and about 1970 for the water which has ₀ of 27.00 to 27.40. Although we have estimated the mean ages of the intermediate water, the horizontal profile of dissolved oxygen suggests that the Okhotsk Sea Component Water is younger than the mean age.     

Analysis of photographic images of the structure of the surface of the sea near a speck of light

Values of root mean square slope ₀ and its variations -₀ are estimated using the brightness field of an image of the surface of the sea near a speck of light. When ₀ and -₀ are defined it is highly important to take into account direct as well as dissipated solar radiation.The space-time analysis of the structure of the image brightness field is performed. This gives an opportunity to estimate dispersion relationship and the running effect of a brightness contrast packet. Comparison of the parameters obtained with the theoretical dispersion ratio of internal waves (IW) allows one to make a conclusion that IW surface manifestations are recorded in a frame.UDK 551.463.5     

Organic geochemistry of the Japan Sea sediments-1: Bulk organic matter and hydrocarbon analyses of Core KH-79-3, C-3 from the Oki Ridge for paleoenvironment assessments

Organic geochemical study of bulk organic matter (OM), hopanoid hydrocarbon and normal hydrocarbon (C₂₃C₃₅) was conducted for a 936-cm-long sediment core sample from the Oki Ridge of the Japan Sea (Core KH-79-3, C-3; 37°03.5 N, 134°42.6E, water depth 935 m). Stable carbon isotopic ratios were also measured for both bulk OM and individual hydrocarbons. The following results were obtained: (1) The weight ratios of total organic carbon to total nitrogen range from 6.2 to 9.4 in the core. The ¹³C values of bulk OM range from –25.1–20.7%.. The ¹³C values of OM in the sections of 140190 cm are lower (–25–24) than those in the other sections (–23–21). This result indicates that OM in the core except for the 140190 cm sections is essentially of marine origin. (2) The ¹³C value of diploptene (a hopanoid hydrocarbon) in the last glacial maximum (LGM), is –66.3 (vs. PDB), which indicates it originating in methanotrophic bacteria. This result provides evidence to support for the previous ideas (Oba et al., 1980, 1984; Masuzawa and Kitano, 1984) that the bottom waters in the Japan Sea were anoxic in LGM. (3) Long chain (C₂₃C₃₅) n-alkanes of higher-plant wax origin were found throughout the core. Their concentration is high in 140190 cm in depth, suggesting that eolian dust load was high in LGM. (4) The n-alkane/TOC ratio increases with decreasing ¹³C values of bulk OM. This result indicates that the load of terrestrial (probably eolian dust-derived) OM to the Japan Sea became higher in colder climates. (5) The CPI values of long-chain n-alkanes are different in different ¹³O stages of paleoclimate, probably reflecting variations in species of terrestrial higher plants as a result of climatological adaptations.     

Regeneration of silicate in the ocean

Regeneration of silicate in the Japan Sea, an example of semi-closed sea, was studied. In the Japan Sea Proper Water the apparent regenerative ratio of the nutrients was determined to be:O C N P Si=–289 (116)14.3181.It was assumed that the dissolved silicate present in sea water is grouped into three fractions; 1)preformed silicate of conservative nature, 2)oxidative silicate which dissolves in oxidation process of organisms with consumption of oxygen, and 3)non-oxidative silicate which dissolves without oxygen consumption. The dissolution rate ofnon-oxidative silicate in the Japan Sea Proper Water was estimated to be 0.07g-at. Si/l/yr from the data ofAOU values and assumed rates of oxygen consumption. This dissolution rate ofnon-oxidative silicate agreed with that obtained in the deep Pacific by the vertical advection diffusion model byKido andNishimura (1972).     

Southward intrusion of the intermediate Oyashio water along the east coast of the Boso Peninsula I. Coastal salinity-minimum-layer water off the Boso Peninsula

Index species of zooplankton of the Oyashio water are found in and beneath the salinity minimum layer in Sagami Bay. In order to clarify the intrusion path of the intermediate Oyashio Water (or the water of the Mixed Water Region), the oceanographic conditions off the Boso Peninsula are studied by using available hydrographic data obtained mainly by Japan Meteorological Agency. The cross-sectional salinity distribution along KJ line which extends southeastward from off the tip of the peninsula always indicates the existence of a low salinity patch just off the coast in the salinity minimum layer. This water is well separated from the offshore low salinity water which is considered as the water in the western margin of the so-called North Pacific Intermediate Water. We refer to the former water as the coastal salinity-minimum-layer (SML) water and to the latter as the offshore SML water. The coastal SML water is usually bounded by the current zone of the Kuroshio. The existence of the coastal SML water seems to indicate the possible pathway of the intermediate Oyashio water along the Boso Peninsula into Sagami Bay. The detailed water type analysis is made in T-S plane, S-_st plane, and O₂-_st plane. There is no significant difference in distribution ranges of the water types between the coastal SML water and the offshore SML water. However, the water types of the coastal SML water is not uniformly distributed, and the water can be classified into two groups: group A with relatively high oxygen content and relatively low salinity value and group B with relatively low oxygen content and relatively high salinity value. Group A is thought to be associated with strong event-like intrusions, the details of which will be discussed in Part II.     

Differential sorption of organic matter by various sized sediment particles in recent sediment from the bering sea

A recent unconsolidated marine sediment collected from the Aleutian basin of the Bering Sea (5702.9N, 17657.4W) was separated into eight size fractions by sieving. Each of the fractions was analyzed for density, organic carbon, total nitrogen and various organic materials. A detailed analysis of the correlation of organic carbon and total nitrogen to the mean diameter of the particles separated, indicated that the surface sorption processes of organic matter were the determinative factor controlling the concentration of organic carbon and total nitrogen on silt and clay particles of the sediments.Selective sorption of amino acids was found to occur in the 8–20 and 5–8m. fractions of the sediment. This is assumed to be due to their surface active property.