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采用原位插层聚合法,制备了蒙脱土含量较高的共聚酯/蒙脱土纳米复合材料,意在做母料使用,含有该母料的聚合物复合材料的染色性能、吸湿浸润性能、抗静电性能及抗紫外性能等都有所改善。阐述了合适的共聚酯/蒙脱土纳米复合材料的制备工艺,讨论了制备过程中的影响因素,结果发现:在采用酯交换-缩聚反应釜进行原位插层聚合制备共聚酯/蒙脱土纳米复合材料的过程中,蒙脱土在缩聚釜中加入更符合生产实际;缩聚反应的实际过程证明了蒙脱土中含有的金属离子对缩聚反应有催化作用;另外,控制聚合的最终温度不超过278℃。最后,对共聚酯/蒙脱土纳米复合材料的结构进行了表征。 相似文献
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聚乙烯/蒙脱土纳米复合材料的制备及性能研究 总被引:16,自引:2,他引:16
以蒙脱土/十六烷基三甲基溴化铵作为前驱物负载Ziegler-Natta催化剂,通过插层原位聚合的方法制备了聚乙烯/蒙脱土纳米复合材料。对聚乙烯/蒙脱土纳米复合材料的制备规律进行了研究。用透射电镜、扫描电镜、XRD,DSC等手段研究了结构和性能的相互关系,以及蒙脱土的含量对复合材料熔点与结晶行为的影响。研究表明:蒙脱土的片层结构被破坏,并以纳米级均匀分散在聚合物基体中。蒙脱土的质量分数为3%左右时,聚乙烯/蒙脱土纳米复合材料具有优良的综合性能。 相似文献
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采用原位接枝插层法制备了聚丙烯/蒙脱土纳米复合材料.借助长链有机胺有机化的蒙脱土在溶液中与马来酸酐和少量辅助溶胀剂进行溶胀;溶胀后的有机蒙脱土再与聚丙烯、适量引发剂在Haake混炼机中进行熔融反应,得到一种聚丙烯/蒙脱土接枝插层共混物;再将接枝插层共混物按一定比例与聚丙烯在Haake混炼机中进行混炼得到聚丙烯/蒙脱土纳米复合材料.用X射线衍射仪(XRD)、透射电镜(TEM)和热失重分析仪(TGA)分别对各步骤的产物进行表征.产物的XRD和TEM分析结果表明蒙脱土完全剥离并均匀分散在聚丙烯基体中,形成了真正的聚丙烯/蒙脱土纳米复合材料.TGA分析结果显示出该纳米复合材料具有相当好的热稳定性. 相似文献
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聚乳酸/有机蒙脱土纳米插层复合材料的原位插层聚合工艺及结构表征研究 总被引:2,自引:0,他引:2
采用新疆夏子街钠基蒙脱土为原矿制备的有机蒙脱土和丙交酯,通过原位插层聚合方法,合成聚乳酸/有机蒙脱土纳米复合材料.通过对反应体系真空度、催化剂用量、反应温度、反应时间和OMMT 加入量等对工艺条件的研究,确定了最佳合成条件.结果为:反应体系真空度为0.085 MPa,催化剂用量为丙交酯质量的0.5%,聚合反应的温度控制在170 ℃,聚合反应时间7 h,OMMT加入量3%(质量含量).采用傅立叶红外光谱仪、X射线衍射仪、扫描电子显微镜、透射电子显微镜对聚乳酸/有机蒙脱土纳米插层复合材料的微观结构、相态等进行了表征和分析. 相似文献
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插层法制备聚合物/蒙脱土纳米复合材料的研究进展 总被引:15,自引:0,他引:15
对插层法制备聚合物/蒙脱土纳米复合材料的国内外研究现状作了简要的回顾,并对聚合物/蒙脱土纳米复合材料的力学性能、结晶性能、阻隔性能、热稳定性、各向异性及阻燃性能进行了综述。 相似文献
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In situ polymerization of styrene was conducted in the presence of expanded graphite obtained by rapid heating of a graphite intercalation compound (GIC), to form a polystyrene–expanded graphite conducting composite. The composite showed excellent electrically conducting properties even though the graphite content was much lower than in normal composites. The transition of the composite from an electrical insulator to an electrical semiconductor occurred when the graphite content was 1.8 wt%, which is much lower than that of conventional conducting polymer composites. TEM, SEM and other studies suggest that the graphite was dispersed in the form of nanosheets in a polymer matrix with a thickness of 10–30 nm, without modification of the space between carbon layers and the structure of the graphite crystallites. The composite exhibited high electrical conductivity of 10?2 S cm?1 when the graphite content was 2.8–3.0 wt%. This great improvement of conductivity could be attributed to the high aspect ratio (width‐to‐thickness) of the graphite nanosheets. The rolling process strongly affected the conductivity and the mechanical properties of the composite. © 2001 Society of Chemical Industry 相似文献
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Hu Haiyan Pan Mingwang Li Xiucuo Shi Xudong Zhang Liucheng 《Polymer International》2004,53(2):225-231
In this article, poly(vinyl chloride) (PVC)–organoclay nanocomposites were prepared via in situ polymerization intercalation and melt blending intercalation, respectively. Their nanostructures were characterized by X‐ray diffraction (XRD) and transmission electron microscopy (TEM). Differences in the morphologies of the PVC hybrids prepared by in situ intercalation and melt intercalation were investigated. In addition, three kinds of organoclay were used, in order to consider the effect of the interlayer environment on intercalation. The results show that ammonium cations have a great influence on the hybrids prepared by melt intercalation, while they have no obvious effect on the nanostructures of the composites produced via in situ intercalation due to its distinctive process and its mechanism. Copyright © 2004 Society of Chemical Industry 相似文献
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Tobias S. Halbach 《Polymer》2008,49(4):867-876
Polyethylene (PE)-boehmite nanocomposites were prepared by means of metallocene/MAO-catalyzed in-situ polymerization of ethylene in the presence of boehmites, which were rendered organophilic by modification with carboxylic acids such as stearic acid and undecylenic acid. Such organoboehmites are readily dispersed in the polymerization media such as toluene. Polymerization activity, filler dispersion and mechanical properties of the nanocomposites were investigated as a function of type and concentration of the organoboehmites. The catalyst activity of different metallocenes (Cp2ZrCl2 and rac-Me2Si(2-Me-benz[e]-Ind)2ZrCl2) was increased up to 100% in the presence of organoboehmite fillers. The dispersion of nanoboehmites, as evidenced by TEM studies, was dependent upon the content of the carboxylate modifier. At 20 wt.% carboxylate content uniform dispersions of organoboehmite particles with average particle sizes smaller than 100 nm were obtained. According to stress-strain measurements, the Young's modulus increased with increasing boehmite content without sacrificing high elongation at break. 相似文献
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An in situ polymerization was conducted in the presence of expanded graphite obtained by rapid heating of the graphite intercalation compound (GIC) to form a polymer/expanded graphite conducting composite. Study showed that the graphite was dispersed in the form of nanosheets in the polymer matrix. The transition from an electrical insulator to an electrical semiconductor for the composite occurred when the expanded graphite content was 1.8 wt %, which was much lower than that of conventional conducting polymer composite. The composite exhibited high electrical conductivity of 10−2 S/cm when the graphite content was 3.0 wt %. This great improvement of conductivity could be attributed to the high aspect ratio (width-to-thickness) of the graphite nanosheets. Study suggested that extensive rolling of the blend greatly affected the conductivity of the composite. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 2506–2513, 2001 相似文献
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A stable aqueous nanocomposite dispersion containing cellulose whiskers and a poly(styrene‐co‐hexylacrylate) matrix was prepared via miniemulsion polymerization. We were able to prepare a stable dispersion with a 20 wt % solid content and a cellulose whiskers content ranging from 1 up to 5 wt % based on polymer content. To avoid particle agglomeration leading to coagulum formation, the addition of a low amount of reactive silane, i.e., methacryloxypropyl triethoxysilane revealed to efficiently stabilize the dispersion. The nanocomposite dispersion was characterized using dynamic light scattering, transmission electron microscopy, and atomic force microscopy. Films obtained by casting followed by water evaporation and particle coalescence were analyzed by differential scanning calorimetry, dynamic mechanical analysis, and tensile testing. At 5 wt % whiskers loading, an enhancement by 500% of the storage modulus above the glass transition was determined. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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This study describes the preparation of polystyrene–clay nanocomposite (PS‐nanocomposite) colloidal particles via free‐radical polymerization in dispersion. Montmorillonite clay (MMT) was pre‐modified using different concentrations of cationic styrene oligomeric (‘PS‐cationic’), and the subsequent modified PS‐MMT was used as stabilizer in the dispersion polymerization of styrene. The main objective of this study was to use the clay platelets as fillers to improve the thermal and mechanical properties of the final PS‐nanocomposites and as steric stabilizers in dispersion polymerization after modification with PS‐cationic. The correlation between the degree of clay modification and the morphology of the colloidal PS particles was investigated. The clay platelets were found to be encapsulated inside PS latex only when the clay surface was rendered highly hydrophobic, and stable polymer latex was obtained. The morphology of PS‐nanocomposite material (after film formation) was found to range from partially exfoliated to intercalated structure depending on the percentage of PS‐MMT loading. The impact of the modified clay loading on the monomer conversion, the polymer molecular weight, the thermal stability and the thermomechanical properties of the final PS‐nanocomposites was determined. Copyright © 2012 Society of Chemical Industry 相似文献
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