Chemical and isotopic signatures of the basement rocks from the Campi Flegrei geothermal field (Naples, southern Italy): inferences about the origin and evolution of its hydrothermal fluids

The Campi Flegrei (Naples, Campanian Plain, southern Italy) geothermal system is hosted by Quaternary volcanic rocks erupted before, during and after the formation of the caldera that represents one of the major structural features in the Neapolitan area. The volcanic products rest on a Mesozoic carbonate basement, cropping out north, east and south of the area. Chemical (major, minor and trace elements) and stable isotope (C, H, O) analyses were conducted on drill-core samples recovered from geothermal wells MF-1, MF-5, SV-1 and SV-3, at depths of ˜ 1100 to 2900 m. The study was complemented by petrographic and SEM examination of thin sections. The water which feeds the system is both marine and meteoric in origin. Mineral zonation typical of a high-temperature geothermal system exists in all the geothermal wells; measured temperatures in wells are as high as ˜ 400 °C. The chemical composition of the waters suggests the existence of two reservoirs: a shallow reservoir (depth < 2000 m) fed by seawater that boiled at 320 °C and became progressively diluted by steam-heated local meteoric water during its ascent; and a deeper reservoir (depth > 2000 m) of hypersaline water. The drill-cores are mainly hydrothermally altered volcanics of trachy-latitic affinity, but some altered pelites and limestones are also present. Published Na, Mg and K concentrations of selected geothermal waters indicate that the hydrothermal fluids are in equilibrium with their host rocks, with respect to K-feldspar, albite, sericite and chlorite. The measured δ¹⁸O_(SMOW) values of rocks range from +4.3 to + 16.5%. The measured δD_(SMOW) values range from − 79 to − 46%. The calculated isotopic composition of the fluids at equilibrium with the samples vary from + 1 to + 8.3%. δ¹⁸O and from − 52 to + 1%. δD. The estimated isotopic composition of the waters at equilibrium with the studied samples confirmed the existence of two distinct fluid types circulating in the geothermal system. The shallower has a marine water signature, while the deeper water has a signature consistent both with magmatic and meteoric origins. In the latter case, the recharge of this aquifer likely occurs at the outcrop of the Mesozoic Limestones surrounding the Campanian Plain; after infiltration, the water percolates through evaporitic layers, becoming hypersaline and D-depleted.     

Determination of characteristics of steam reservoirs by Radon-222 measurements in geothermal fluids

The authors conducted a Rn²²² survey in wells of the Larderello geothermal field (Italy) and observed considerable variations in concentrations. Simple models show that flow-rate plays an important part in the Rn²²² content of each well, as it directly affects the fluid transit time in the reservoirs. Rn²²² has been sampled from two wells of the Serrazzano area during flow-rate drawdown tests. The apparent volume of the steam reservoir of each of these two wells has been estimated from the Rn²²² concentration versus flow-rate curves.List of symbols Q Flow-rate (kg h^–1) - Decay constant of Rn²²² (=7.553×10^–3 h^–1) - Porosity of the reservoir (volume of fluid/volume of rock) - ₁ Density of the fluid in the reservoir (kg m^–3) - ₂ Density of the rock in the reservoir (kg m^–3) - M Stationary mass of fluid filling the reservoir (kg). - E Emanating power of the rock in the reservoir (nCi kg _rock ^–1 h^–1). - P Production rate of Rn²²² in the reservoir: number of atoms of Rn²²² (divided by 1.764×10⁷) transferred by the rock to the mass unit of fluid per unit time (nCi kg _fluid ^–1 h^–1). - N Specific concentration of Rn²²² in the fluid (nCi kg^–1) - Characteristic time of the steam reservoir at maximum flow-rate (=M/Q)     

Possible geothermal resources in the Coast Plutonic Complex of southern British Columbia,Canada

In southern British Columbia the terrestrial heat flow is low (44 mW m^–2) to the west of the Coast Plutonic Complex (CPC), average in CPC (50–60 mW m^–2),and high to the east(80–90 mW m^–2). The average heat flow in CPC and the low heat generation (less than 1 W m^–3) indicate that a relatively large amount of heat flows upwards into the crust which is generally quite cool. Until two million years ago the Explorer plate underthrust this part of the American plate, carrying crustal material into the mantle. Melted crustal rocks have produced the inland Pemberton and Garibaldi volcanic belts in the CPC.Meager Mountain, a volcanic complex in the CPC 150 km north of Vancouver, is a possible geothermal energy resource. It is the product of intermittent activity over a period of 4 My, the most recent eruption being the Bridge River Ash 2440 y B.P. The original explosive eruption produced extensive fracturing in the granitic basement, and a basal explosion breccia from the surface of a cold brittle crust. This breccia may be a geothermal reservoir. Other volcanic complexes in the CPC have a similar potential for geothermal energy.Earth Physics Contribution No. 704.     

Gas geochemistry of the Valles caldera region, New Mexico and comparisons with gases at Yellowstone, Long Valley and other geothermal systems

Noncondensible gases from hot springs, fumaroles, and deep wells within the Valles caldera geothermal system (210–300°C) consist of roughly 98.5 mol% CO₂, 0.5 mol% H₂S, and 1 mol% other components. ³He/⁴He ratios indicate a deep magmatic source (R/R_a up to 6) whereas δ¹³C–CO₂ values (−3 to −5‰) do not discriminate between a mantle/magmatic source and a source from subjacent, hydrothermally altered Paleozoic carbonate rocks. Regional gases from sites within a 50-km radius beyond Valles caldera are relatively enriched in CO₂ and He, but depleted in H₂S compared to Valles gases. Regional gases have R/R_a values ≤1.2 due to more interaction with the crust and/or less contribution from the mantle. Carbon sources for regional CO₂ are varied. During 1982–1998, repeat analyses of gases from intracaldera sites at Sulphur Springs showed relatively constant CH₄, H₂, and H₂S contents. The only exception was gas from Footbath Spring (1987–1993), which experienced increases in these three components during drilling and testing of scientific wells VC-2a and VC-2b. Present-day Valles gases contain substantially less N₂ than fluid inclusion gases trapped in deep, early-stage, post-caldera vein minerals. This suggests that the long-lived Valles hydrothermal system (ca. 1 Myr) has depleted subsurface Paleozoic sedimentary rocks of nitrogen. When compared with gases from many other geothermal systems, Valles caldera gases are relatively enriched in He but depleted in CH₄, N₂ and Ar. In this respect, Valles gases resemble end-member hydrothermal and magmatic gases discharged at hot spots (Galapagos, Kilauea, and Yellowstone).     

Terrestrial heat flow in Hungary

Summary The geothermal gradient in the Carpathian Basin lies between 40–70 C/km. According to careful measurements in shafts the value of terrestrial heat flow in the southern part of Hungary is (2.055–3.066)·10^–6 cal/cm² sec. These measurements are believed the first ever attempted in continental Europe. Systematic heat flow measurement are being extended to other part of this country.     

Fracture surface energy of olivine

A relatively simple indentation technique for the rapid measurement of fracture surface energy, , of small samples is described. The reliability of this technique is assessed by testing soda-lime glass for which there are good independent fracture mechanics determinations of fracture surface energy. The indentation technique gives a value for of 4.33 J m^–2 which compares favourably with the accepted value of 3.8 J m^–2. Fracture surface energies of the {010} and {001} cleavage planes of single crystal olivine (modal composition Fo₈₈Fa₁₂) are then determined and compared with theoretical estimates of the thermodynamic surface energy, , calculated from atomistic parameters ( is equal to in the absence of dissipative processes during crack extension). The experimental values for _{010} and _{001} are respectively 0.98 J m^–2 and 1.26 J m^–2. The calculated values of _{010} and _{001} are respectively in the range from 0.37 J m^–2 to 8.63 J m^–2 and 12.06 J m^–2. The particular advantages of the indentation technique for the study of the fracture surface energies of geological materials are outlined.     

Geoelectromagnetic and geothermic investigations in the Ihlara Valley geothermal field

The Ihlara Valley is situated within a volcanic arc that is formed by the collision of the eastern Mediterranean plate system with the Anatolian plate. In this study we will present data from a reservoir monitoring project over the Ihlara-Ziga geothermal field, located 22 km east of Aksaray, in central Anatolia.Although identified geothermal resources in the Ihlara Valley are modest, substantial undiscovered fields have been inferred primarily from the volcanic and tectonic setting but also from the high regional heat flow (150–200 mWm⁻²) on the Kir ehir Massif.In 1988 and 1990, geoelectromagnetic surveys were undertaken by MTA-Ankara to confirm the presence of a relatively shallow (≈ 0.5–1 km), hydrothermally caused conductive layer or zone. CSAMT and Schlumberger resistivity data show good correspondence with each other, and 2-D geoelectric models are also in harmony with geologic data and gravity anomalies.The depth of the resistive basement, which is interpreted as Paleozoic limestone, is 200–250 m in the western part and increases eastward (≈ 600–750 m). This may imply N-S-oriented normal faulting within the survey area. The parameters of the top layer are a resistivity of 25 to 95 ohm m and a thickness of between 100 and 250 m. The thickness of the conductive tuffs between the top layer and the basement, whose resistivity is about 4–5 o hmm, also increases eastward (from 100 to 450 m). The apparent resistivity maps for the frequencies between 32 and 2 Hz reveal a localized low resistivity anomaly to the east of Belisirma.     

Progressive cooling of the hyaloclastite ridge at Gjálp, Iceland, 1996–2005

In the subglacial eruption at Gjálp in October 1996 a 6 km long and 500 m high subglacial hyaloclastite ridge was formed while large volumes of ice were melted by extremely fast heat transfer from magma to ice. Repeated surveying of ice surface geometry, measurement of inflow of ice, and a full Stokes 2-D ice flow model have been combined to estimate the heat output from Gjálp for the period 1996–2005. The very high heat output of order 10⁶ MW during the eruption was followed by rapid decline, dropping to  2500 MW by mid 1997. It remained similar until mid 1999 but declined to 700 MW in 1999–2001. Since 2001 heat output has been insignificant, probably of order 10 MW. The total heat carried with the 1.2 × 10¹² kg of basaltic andesite erupted (0.45 km³ DRE) is estimated to have been 1.5 × 10¹⁸ J. About two thirds of the thermal energy released from the 0.7 km³ edifice in Gjálp occurred during the 13-day long eruption, 20% was released from end of eruption until mid 1997, a further 10% in 1997–2001, and from mid 2001 to present, only a small fraction remained. The post-eruption heat output history can be reconciled with the gradual release of 5 × 10¹⁷ J thermal energy remaining in the Gjálp ridge after the eruption, assuming single phase liquid convection in the cooling edifice. The average temperature of the edifice is found to have been approximately 240 °C at the end of the eruption, dropping to  110 °C after 9 months and reaching  40 °C in 2001. Although an initial period of several months of very high permeability is possible, the most probable value of the permeability from 1997 onwards is of order 10^− 12 m². This is consistent with consolidated/palagonitized hyaloclastite but incompatible with unconsolidated tephra. This may indicate that palagonitization had advanced sufficiently in the first 1–2 years to form a consolidated hyaloclastite ridge, resistant to erosion. No ice flow traversing the Gjálp ridge has been observed, suggesting that it has effectively been shielded from glacial erosion in its first 10 years of existence.     

Infrared absorption spectra of atmospheric dust over an interior desert basin

Summary Based on the qualitative microspectrophotometric analysis of 287 atmospheric dust samples taken within the surface boundary layer over south central New Mexico, U.S.A. from May 1966 through October 1967, a representative infrared absorption spectrum from 4000 to 250 cm^–1 (2.5 to 40 m) is presented. The strongest absorption band is centered at 1027 cm^–1 (9,7 m), within the 1250 to 770 cm^–1 (8 to 13 m) atmospheric window, and is silicate induced. Two other strong broad absorption bands are the carbonate band at 1425 cm^–1 (7.0 m) and the silicate band at 468 cm^–1 (21.4 m). Temporal variations in the absorption spectra of the dust are observed primarily in the varying relative intensities of the 1027 and 1425 cm^–1 (9.7 and 7.0 m) absorption bands and in the occasional enhancement of the 1027 cm^–1 (9.7 m) band caused by sulfates in the dust. This study indicates that there is a close similarity between the absorption spectra of the atmospheric dust and the spectra of the small particle fraction of area soils, and between the representative dust spectrum and a spectrum of a synthetic mixture (by weight) of 80% silicates, 16% carbonates, and 4% nitrates.     

Exploration drilling and reservoir model of the Platanares geothermal system, Honduras, Central America

Results of drilling, logging, and testing of three exploration core holes, combined with results of geologic and hydrogeochemical investigations, have been used to present a reservoir model of the Platanares geothermal system, Honduras. Geothermal fluids circulate at depths ≥ 1.5 km in a region of active tectonism devoid of Quaternary volcanism. Large, artesian water entries of 160 to 165°C geothermal fluid in two core holes at 625 to 644 m and 460 to 635 m depth have maximum flow rates of roughly 355 and 560 l/min, respectively, which are equivalent to power outputs of about 3.1 and 5.1 MW(thermal). Dilute, alkali-chloride reservoir fluids (TDS ≤ 1200 mg/kg) are produced from fractured Miocene andesite and Cretaceous to Eocene redbeds that are hydrothermally altered. Fracture permeabillity in producing horizons is locally greater than 1500 and bulk porosity is ≤ 6%. A simple, fracture-dominated, volume-impedance model assuming turbulent flow indicates that the calculated reservoir storage capacity of each flowing hole is approximately 9.7 × 10⁶ l/(kg cm⁻²), Tritium data indicate a mean residence time of 450 yr for water in the reservoir. Multiplying the natural fluid discharge rate by the mean residence time gives an estimated water volume of the Platanares system of ≥ 0.78 km³. Downward continuation of a 139°C/km “conductive” gradient at a depth of 400 m in a third core hole implies that the depth to a 225°C source reservoir (predicted from chemical geothermometers) is at least 1.5 km. Uranium-thorium disequilibrium ages on calcite veins at the surface and in the core holes indicate that the present Platanares hydrothermal system has been active for the last 0.25 m.y.     

Importance of ciliated protozoa in relation to the bacterial and phytoplanktonic biomass in an oligo-mesotrophic lake,during the spring diatom bloom

The abundance and the biomass of bacterial, phytoplanktonic, and ciliate communities were estimated at different depths during the spring planktonic development in an oligo-mesotrophic lake (the Pavin lake).The bacterial population, which consists mainly of free bacteria (94% of the total bacterial abundance), displays only low cell densities (0.6 to 7 × 10⁵ cells · ml^–1) and represents low biomass values (0.9 to 11.5 µgC·l^–1) The bacteria represent from 0.9 to 23.8% (M = 9.7%) of the microplanktonic biomass (with the exclusion of heterotrophic nanoflagellates, i.e. bacteria + phytoplankton + ciliates, size range 0.2–160 µm). The abundance of the phytoplankton varies between 0.5 and 1.8 × 10⁶ cells·l^–1, and the biomass values between 12 and 118 µC·l^–1. The phytoplankton population constitutes the largest part of the microplanktonic biomass (51.9 to 96.6%, M = 80.6%), and the diatomMelosira italica subsp.subarctica is the largely dominant species of this community. The population of ciliates, essentiallyOligotrichida andScuticociliatida, displays densities between 1.3 and 38.3 × 10³ cells·l^–1 (M = 6.7 × 10³ cells·l^–1), and biomass values vary from 0.10 to 16.30 µgC·l^–1 (M = 6.01 µgC·l^–1). The ciliates constitute thus from 0.1 to 26.4% (M = 9.8%) of the microplanktonic biomass. Whereas the oligotrichs are best represented in the euphotic zone, the small-sized scuticociliates dominate in the hypolimnion. Besides, species having symbionts and considered to be mixotrophic (Strobilidium gyrans, Strombidium viride, Stokesia vernalis) develop preferentially in the epilimnion and constitute more than 50% of the total ciliate biomass.     

Earthquake-induced variations in the composition of the water in the geothermal reservoir at Vulcano Island, Italy

During 1979–1989, variations were observed in the oxygen composition of the water contained in the geothermal reservoir at Vulcano Island, Italy.The reservoir water, that has a magmatic origin, showed an oxygen composition of +1.0±0.5‰ δ¹⁸O during periods without local tectonic earthquakes, and an oxygen composition of +3.4±0.5‰ δ¹⁸O after the highest-energy seismic activity that occurred recently near the island. A slight increase of the δ¹⁸O value in the reservoir water was also observed after a low-energy sequence of tectonic earthquakes that occurred at very shallow depth just beneath Vulcano Island. These ¹⁸O variations in the reservoir water are consistent with earthquake-induced increases in the contribution from high-temperature δ¹⁸O-rich magmatic condensate to the geothermal reservoir, and with subsequent decreases in the δ¹⁸O value due to ¹⁸O exchanges at the temporarily increased reservoir temperature during reactions between the highly reactive magmatic condensate and the local rocks.Only minor changes in the deuterium composition of the reservoir water occurred with time, as the δD value in the magmatic condensate released from the magma after major local earthquakes quickly approached the δD value of the water contained in the geothermal reservoir.Also the chloride concentration in the reservoir water appears to be linked to the contribution from the magmatic fluid. This chloride content seems not to have undergone major changes with time, as it may be buffered by temporary increases in the reservoir temperature up to values >300°C induced by major local earthquakes. This mechanism may possibly occur also in other magmatic–hydrothermal systems.     

New terrestrial heat flow values from Hungary

Summary Temperature and conductivity measurements show, that in the Southern part of Transdanubia (the part of Hungary which lies Westwards from Danube) the heat flow is about 2–2.4·10^–6 cal/cm² sec. Eastward from the Danube, in the Hungarian Plain estimates are even higher, and vary between 2.3·10^–6 and 2.8·10^–6 cgs. The gradient of temperature is everywhere quite high, 5.0 resp. 5.8·10^–4 deg. C/cm on the average. Thus, at a depth of 1000 m, the virgin rock temperature is about 60–70 deg. C, at 2000 m about 110–130 deg. C.     

Drifter observations of the Hebrides slope current and nearby circulation patterns

The mean flow at and around the Hebrides and Shetland Shelf slope is measured with ARGOS tracked drifters. Forty-two drifters drogued at 50 m were deployed in three circles over the Hebrides slope at 56.15°N in two releases, one on 5th December, 1995 and the second on 5–9th May, 1996. The circles span a distance of some 20 km from water depths of 200 m to 1200 m. Drifters are initially advected poleward along-slope by the Hebrides slope current at between 0.05 and 0.70 m s^–1 in a laterally constrained (25–50 km wide) jet-like flow. Drifters released in winter remained in the slope current for over 2000 km whilst summer drifters were lost from the slope current beyond the Wyville-Thomson Ridge, a major topographic feature at 60°N. Dispersion from the slope region into deeper waters occurs at bathymetric irregularities, particularly at the Anton Dohrn Seamount close to which the slope current is found to bifurcate, both in summer and winter, and at the Wyville-Thomson Ridge where drifters move into the Faeroe Shetland Channel. Dispersion onto the continental shelf occurs sporadically along the Hebrides slope. The initial dispersion around the Hebrides slope is remarkably sensitive to initial position, most of the drifters released in shallower water moving onto the shelf, whilst those in 1000 m or more are mostly carried away from the slope into deeper water near the Anton Dohrn Seamount. The dispersion coefficients estimated in directions parallel and normal to the local direction of the 500 m contour, approximately the position of the slope current core, are approximately 8.8 × 10³ m² s^–1 and 0.36 × 10³ m² s^–1, respectively, during winter, and 11.4 × 10³ m² s^–1 and 0.36 x 10³ m² s^–1, respectively, during summer. At the slope there is a minimum in across-slope mean velocity, Reynolds stress, and across-slope eddy correlations. The mean across-slope velocity associated with mass flux is about 4 × 10^–3 m s^–1 shelfward across the shelf break during winter and 2 × 10^–3 m s^–1 during summer. The drifters also sampled local patterns of circulation, and indicate that the source of water for the seasonal Fair Isle and East Shetland currents are the same, and drawn from Atlantic overflows at the Hebrides shelf.     

Water/rock interaction in the Kızılcahamam Geothermal Field, Galatian Volcanic Province (Turkey): a modelling study of a geothermal system for reinjection well locations

The Kızılcahamam geothermal field is emplaced in Tertiary-aged volcanic units 70 km NW of Ankara (Turkey). Data for this low-temperature (74–86°C) geothermal field regarding the fracture zone system were obtained from surface manifestations (hot springs, alteration zones), five exploration wells (MTA-2, -3, -4, -5, -6) and two production wells (KHD-1, MTA-1). The Kızılcahamam reservoir developed along the Kızılcahamam fault zone and so the production wells (180–1556 m) effect each other due to their limited separation. Meteoric water enters from a recharge area NE of Kızılcahamam, circulates and gains heat through the fault zone, and discharges to the surface.Detailed petrographical studies have been carried out with samples taken from surface rocks, cores, and cuttings from three wells (KHD-1, MTA-2, -3). X-ray diffraction techniques were also used in the present study. Kaolinite and montmorillonite zones were identified at outcrop samples. Chloritization, clay mineralization, sericitization and carbonization were determined in the ground mass of samples from wells. The observed alteration mineral assemblages indicate that Kızılcahamam geothermal system has been cooling since the alteration minerals formed.The exploration well MTA-3 seems to be more suitable for a reinjection well than the other wells (MTA-2, -6), even if the cost of surface piping to transport the waste water to MTA-3 is higher than to another well (MTA-6).     

Two-dimensional kinematic and rheological modeling of the 1912 pyroclastic flow,Katmai, Alaska

Pyroclastic flow emplacement is strongly influenced by eruption column height. A surface along which kinetic energy is zero theoretically connects the loci of eruption column collapse with all coeval ignimbrite termini. This surface is reconstructed as a two-dimensional energy line for the 1912 Katmai pyroclastic flow in the Valley of Ten Thousand Smokes from mapped flow termini and the runup of the ignimbrite onto obstructions and through passes. Extrapolation of the energy line to the vicinity of the source vent at Novarupta suggests the eruption column which generated the ignimbrite eruption was approximately 425 m high. The 1912 pyroclastic flow travelled about 25 km downvalley. Empirical velocity data calculated from runup elevations and surveyed centrifugal superelevations indicate initial velocities near Novarupta were greater than 79–88 m s^–1. The flow progressively decelerated and was travelling only 2–8 m s^–1 when it crossed a moraine 16 km downvalley. The constant slope of the energy line away from Novarupta suggests the flow was systematically slowed by internal and basal friction. Using a simple physical model to calculate flow velocities and a constant kinetic friction coefficient (Heim coefficient) of 0.04 derived from the reconstructed energy line, the flow is estimated to have decelerated at an average rate of –0.16 m s^–2 and to have taken approximately 9.5 minutes to travel 25 km down the Valley of Ten Thousand Smokes. The shear strength of the flowing ignimbrite at the moraine was approximately 0.5 kPa, and its Bingham viscosity when it crossed the moraine was 3.5 × 10³ P. If the flow was Newtonian, its viscosity was 4.2 × 10³ P. Reynolds and Froude numbers at the moraine were only 41–62 and 0.84–1.04, respectively, indicating laminar, subcritical flow.     

Temperature paleogradient estimations in the central Bohemian basin

Summary The coalification data of 12 boreholes in the Central Bohemian Basin are used to evaluate the paleotemperature gradients for the Upper Carboniferous period of the basin's development. Two versions of the burial history considered are supposed to yield an upper and a lower estimate. According to the more probable lower version, the average values of the paleogradient suggest an increasing tendency from west to east in the interval of 45–53K/km. The current geothermal gradients vary in the range of 28–35K/km. By combining the present thermal conductivity and the paleogradients, we have tried to estimate the Upper Carboniferous heat flow. Its values range from 96mW/m ² to 117mW/m ² .The results obtained can be compared with the paleogradient estimates in the Saar-Nahe Basin (F. R. of Germany). This region, which is similar with respect to the time of origin and tectonic pattern to the Central Bohemian Basin, displays on the average a slightly higher Permo-Carboniferous geothermal gradient of 60K/km.     

Petrology of ultramafic and mafic xenoliths in picrite of Kahoolawe Island,Hawaii

A picrite lava (22 wt% MgO; 35 vol.% ol) along the western shore of the1.3–1.4 Ma Kahoolawe tholeiitic shield, Hawaii, contains small xenoliths of harzburgite, lherzolite, norite, and wehrlite. The various rock types have textures where either orthopyroxene, clinopyroxene, or plagioclase is in a poikilitic relationship with olivine. The Mg#s of the olivine, orthopyroxene, and clinopyroxene in this xenolith suite range between 86 and 82; spinel Mg#s range from 60 to 49, and plagioclase is An_75–80. A ⁸⁷Sr/⁸⁶Sr ratio for one ol-norite xenolith is 0.70444. In comparison, the host picrite has olivine phenocrysts with an average Mg# of 86.2 (range 87.5–84.5), and a whole-rock ⁸⁷Sr/⁸⁶Sr ratio of 0.70426. Textural and isotopic information together with mineral compositions indicate that the xenoliths are related to Kahoolawe tholeiitic magmatism, but are not crystallization products of the magma represented by their host picrite. Rather, the xenoliths are crystalline products of earlier primitive liquids (FeO/MgO ranging 1 to 1.3) at 5–9 kbar in the cumulate environment of a magma reservoir or conduit system. The presence of ultramafic xenoliths in picrite but not in typical Kahoolawe tholeiitic lava (6–9 wt% MgO) is consistent with replenishment of reservoirs by dense Mg-rich magma emplaced beneath resident, less dense tholeiitic magma. Mg-rich magmas have proximity to reservoir cumulate zones and are therefore more likely than fractionated residual liquids to entrain fragments of cumulate rock.     

Geodynamic implications of deep mantle upwelling in the source of Tertiary volcanics from the Veneto region (South-Eastern Alps)

Major and trace element and Sr–Nd–Hf–Pb isotopic data for the most primitive Tertiary lavas from the Veneto region (South-Eastern Alps, Italy) show the typical features of HIMU hotspot volcanism, variably diluted by a depleted asthenospheric mantle component (⁸⁷Sr/⁸⁶Sr_i=0.70306–0.70378; _Ndi=+3.9 to +6.8; _Hfi=+6.4 to +8.1, ²⁰⁶Pb/²⁰⁴Pb_i=18.786–19.574). P-wave seismic tomography of the mantle below the Veneto region shows the presence of low-velocity anomalies at depth, which is consistent with possible upwellings of plume material. Between the depths of 100–250 km the velocity anomalies are approximately 2–2.5% slower than average, implying a temperature excess of about 220–280 K, in agreement with estimates for other mantle plumes in the world. In this context, the Veneto volcanics may represent the shallow expression of a mantle upflow. The presence of a HIMU-DM component in a collision environment has significant geodynamic implications. Slab detachment and ensuing rise of deep mantle material into the lithospheric gap is proposed to be a viable mechanism of hotspot magmatism in a subduction zone setting.