突发污染应急调控处置启动判别技术:以南水北调中线工程为例

针对突发水污染灾害的特点,把应急处置工程决策纳入应急预警范畴,构建了拓展后的应急预警新框架,为应急处置小组等利益相关者提供系统化的信息支持。综合考虑污染物水溶性、挥发性、持久性和污染性等污染物自身属性及污染发生季节、发生位置和迁移特征等水环境属性,进行污染威胁度评估;进一步结合事故现场及河道沿岸等工况条件生成应急调控处置工程的启动准则。在南水北调中线工程"放水河节制闸-蒲阳河节制闸"典型渠段,以甲苯运输泄漏为事故情景,依托调水工程实际参数和实地调控处置设施,进行案例分析。该预警模式(突发污染应急调控启动判别模型)链接了污染输移、水力调控措施与应急调控处置措施,在传统以水质预测为主的污染预警基础上向减灾过程推进了一步,提供了更为完整的预警信息和决策建议。     

环境污染应急处置技术的CBR-MADM两步筛选法模型

突发环境污染事件进行应急处置时,需要在历史案例库和处置技术库的基础上通过筛选模型筛选出最适宜的应急处置技术.其中筛选的效率和准确性是构建技术筛选模型的首要因素,目前尚无较为满意的解决方案.本文结合案例推理技术(CBR)和模糊多属性群决策模型(MADM)的优势,建立了环境污染应急处置技术的CBR-MADM两步筛选法模型:第1步,先利用基于熵权G1法的CBR推理从案例库中匹配案例,再从相似度最高的几个案例中提取应急处置技术作为备选技术;第2步,利用MADM对备选技术进行筛选和决策.CBR-MADM两步筛选法既充分利用了历史处置经验,又极大地提高了应急处置技术的筛选速度和效率.将该方法应用于2012年底山西长治浊漳河苯胺泄漏污染事件中,成功筛选出“投加混凝剂-活性炭坝拦截”技术,同实际情况吻合,验证了其适用性和可行性.     

水污染预警DSS系统框架下的白河水质预警模型研究

为了应对频发的水环境污染事故,在污染事故发生后快速有效地制定应急响应措施,保护水环境,有必要在水源保护区建立水污染预警DSS系统,重点对系统建立的核心与难点——水质预警模型进行研究.密云水库是北京市最重要的地表水源地,以密云水库上游的白河为研究区域建立水污染预警DSS系统,设计水污染预警DSS系统的三层结构框架,将控制端、核心预警模型、GIS空间数据库紧密联合起来;在此基础上对核心预警模型的建模过程、参数取值等进行研究;最后以典型污染物氰化钠为例,设置水污染事故情景以及应急措施预案情景,进行了情景模拟分析.实例研究表明,此水质预警模型能够较准确地对污染发展趋势进行分析预测,并对不同的应急处理方案的实施效果进行模拟分析,模拟结果能够支持应急方案的制定与优选决策,达到了DSS系统的功能需求.     

我国突发水污染事件应急处置技术与对策研究

当前,我国突发水污染事件仍处于高发态势,对应急处置的要求高、挑战大,主要表现为事件成因多样、污染物类型复杂、情景差异明显,而与之相应的是应急处置技术体系尚不健全。本文针对我国突发水污染事件应急处置技术面临的突出问题,提出了提升我国突发水污染事件应急处置技术水平的基本思路,以解决制约我国环境应急处置的突出问题为出发点,统筹全面布局与重点突破,针对重点污染物、重点环节、重点区域,按照"夯实基础、突出重点、加强融合、优化决策"的应急处置技术研发与应用各项任务,构建健全高效的突发水污染事件应急处置技术体系,全面提高我国水环境安全保障水平。     

如何做好突发环境事件应急监测的快速响应

应急监测是突发性环境污染事故处置中的首要环节,是对污染事故及时、正确地进行应急处理、减轻事故危害和制定恢复措施的根本依据。文章从制定应急监测预案、加强应急监测能力建设、摸清污染源状况、加强应急培训和应急演练等方面对做好突发环境事件应急监测的快速响应作了简要的阐述,供大家探讨。     

有毒气体重大突发泄漏情景设计及仿真分析

某石化企业生产过程中会产生大量有毒气体硫化氢,而且厂区内人员较多,距周边社区较近,如果突发重大泄漏事故,应急响应不及时或处置不当,后果将不堪设想。通过对厂区内可能发生的硫化氢重大突发泄漏情景进行设计及仿真分析,呈现重大突发事件发生、发展过程,分析事故影响区域及规律,可为企业应对有毒气体泄漏的重大突发事件应急准备及应急响应提供依据,同时可用于检验现有应急预案存在的不足并进行针对性完善。     

基于IAHP-DS的流域突发化学品污染事故应急处理技术动态优选体系研究

因化学品造成的突发性水污染事故时有发生,为了在最短时间内降低污染物对水环境的影响,如何结合事故现场情况科学高效地选择最适宜的应急处理技术方案是当前应急响应的关键问题。基于改进层次分析法(IAHP)和Dempster-Shafer(D-S)证据理论构建了流域突发化学品污染事故应急处理技术动态优选体系。首先在利用IAHP确定指标权重的过程中,结合D-S证据理论引入专家权重,可客观地综合不同专家的意见,解决专家意见间的冲突性;然后采用加权秩和比(WRSR)法对应急处理技术进行综合评估,最终确定出最佳的应急处理技术方案;最后以浙江建德苯酚水污染事故为案例进行了验证分析,成功筛选出活性炭筑坝拦截技术,与本案例实际采用的应急处理技术方案一致,表明该优选体系具有较强的适用性和可行性,能够快速实现应急处理技术的优选。     

两阶段评估体系筛选水源突发污染应急最优技术方案

为预判突发污染对水源的威胁程度,进而筛选适宜污染情景的最优应急处置技术,本研究构建了包含10个评价指标的水源突发污染威胁度判别指标体系,依据威胁度等级判定,确定与不同威胁度对应的应急处置技术评估指标体系的指标权重.同时,为合理体现群决策过程中专家差异对权重的影响,提出了基于循环修正的群组G1指标赋权法.以Spearman等级相关系数作为检验标准,应用平均值法、Board法、Copeland法3种组合评价方法对单一专家评价结果进行循环迭代修正,最终得到评价指标的一致性排序和各位专家的权重,使各项指标的权重赋值更为准确.将综合评估模型应用于2012年广西龙江镉污染事故中,成功筛选出“调水稀释—絮凝沉降—水厂强化混凝”的组合应急技术方案,同实际情况吻合,验证了评估模型的可行性.     

突发性水体重金属污染应急处理处置技术研究进展

近年来突发性水体重金属污染事件频发,严重威胁流域水资源安全,制约国民经济和社会的可持续发展。尽管突发性水体重金属污染应急处理处置技术备受关注,但现有的技术储备仍十分薄弱。本文基于文献调研和已有的案例总结,系统评述了现有的应急处理处置技术的优缺点,并简要介绍了这些应急技术在已报道的国内历次突发性重金属水污染事件中的实践应用,指出了突发性重金属水污染应急处理处置技术的发展趋势,对于未来应对突发性重金属水污染事件快速选择经济、有效、绿色的应急处理处置技术和应对策略具有重要的参考价值。     

上海世博会突发环境事故应急预案系统研究探讨

针对中国2010年上海世博会可能发生的各类突发环境事故,提出应集成运用数据库、GIS、数学模型、专家系统等多种技术手段,特别是提出采用CBR技术,开发世博会突发环境事故应急预案系统。以提高世博会运行管理时期对各类突发环境事故的预防和处理处置能力;指出环境事故应急预案的主要研究工作应包括应急预案的种类、内容、支撑技术体系,以及应急预案系统的规划、建设与运行管理等;给出了需要解决的关键技术问题和系统开发方案。     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.     

Removal of heavy metals from sewage sludge by low costing chemical method and recycling in agriculture

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