The role of buried bedrock valleys on the development of karstic aquifers in flat-lying carbonate bedrock: insights from Guelph, Ontario, Canada

A spatial relationship between high capacity municipal production wells (>5,000 m³/day), completed in a deep bedrock aquifer, and a buried bedrock valley was recognized in the city of Guelph, southwestern Ontario, Canada. Most production wells are completed in a discrete zone, ～60 m below ground surface, within flat-lying dolostones of the Silurian Amabel Formation. Thick overburden and limited subsurface data make characterization of the karstic aquifer difficult. This study integrates hydrogeologic data with models of karst formation, deriving a conceptual model of porosity development as it relates to valley incision. Bedrock valley incision likely occurred prior to the early Wisconsinan age (>60–75 ka). Incision created steep hydraulic gradients within the flat-lying bedrock, and provided the driving force required to integrate regional groundwater flow into karst conduits that drained at the base of the valley. Dissolution in production zone dolostones was favoured over dissolution in shallower bedrock due to abundant bedding plane partings and fossiliferous facies with high intercrystalline porosity. Burial of the valley during subsequent ice advances reduced the valley’s hydraulic influence and the efficacy of the flow system to cause dissolution. The high capacity municipal wells near the buried bedrock valley tap into the now dormant karst aquifer system.     

Platinum group element geochemistry of komatiites from the Alexo and Pyke Hill areas, Ontario, Canada

Thirty-three whole-rock drill core samples and thirteen olivine, chromite, and sulfide separates from three differentiated komatiite lava flows at Alexo and Pyke Hill, Canada, were analyzed for PGEs using the Carius tube digestion ID-ICP-MS technique. The emplaced lavas are Al-undepleted komatiites with ∼27% MgO derived by ∼50% partial melting of LILE-depleted Archean mantle. Major and minor element variations during and after emplacement were controlled by 30 to 50% fractionation of olivine Fo_93-94. The emplaced lavas are characterized by (Pd/Ir)_N = 4.0 to 4.6, (Os/Ir)_N = 1.07, and Os abundances of ∼2.3 ppb. Variations in PGE abundances within individual flows indicate that Os and Ir were compatible (bulk D_Os,Ir = 2.4-7.1) and that Pt and Pd were incompatible (bulk D_Pt,Pd < 0.2) during lava differentiation, whereas bulk D_Ru was close to unity. Analyses of cumulus olivine separates indicate that PGEs were incompatible in olivine (D_PGEs^Ol-Liq = 0.04-0.7). The bulk fractionation trends cannot be accounted for by fractionation of olivine alone, and require an unidentified Os-Ir-rich phase. The composition of the mantle source (Os = 3.9 ppb, Ir = 3.6 ppb, Ru = 5.4 ppb, Pt and Pd = 5.7 ppb) was constrained empirically for Ru, Pt, and Pd; the Os/Ir ratio was taken to be identical to that in the emplaced melt, and the Ru/Ir ratio was taken to be chondritic, so that the absolute IPGE abundances of the source were determined by Ru. This is the first estimate of the PGE composition of a mantle source derived from analyses of erupted lavas. The suprachondritic Pd/Ir and Os/Ir of the inferred Abitibi komatiite mantle source are similar to those in off-craton spinel lherzolites, orogenic massif lherzolites, and enstatite chondrites, and are considered to be an intrinsic mantle feature. Bulk partition coefficients for use in komatiite melting models derived from the source and emplaced melt compositions are: D_Os,Ir = 2.3, D_Ru = 1.0, D_Pt,Pd = 0.07. Ruthenium abundances are good indicators of absolute IPGE abundances in the mantle sources of komatiite melts with 26 to 29% MgO, as Ru fractionates very little during both high degrees of partial melting and lava differentiation.     

The transfer of organic signatures from bedrock to sediment

A case study in the Canadian Arctic demonstrates how an organic geochemical signature in the regional bedrock can be transferred by erosion and redeposition to younger geological formations and surface sediments. The hydrocarbon composition recorded in Laurentian (Lower Palaeozoic) carbonate bedrock was incorporated into overlying Miocene and Quaternary formations, and modern mass waste, alluvium, snow/ice, and proglacial deposits, and further distant in ice-rafted detritus. The retention of the original geological organic signature is reflected in consistent thermal maturities (hopane ratios) and environmental indicators (sterane distributions). In the modern sediments, the geological signature is variably mixed with a modern microbial organic signature reflected in high values of carbon preference index and diploptene. These data show that hydrocarbon occurrences in bedrock may be detected by the analysis of surface detritus, especially in carbonate terrains. However they also indicate that environmental signatures may be misleading if they are inherited from older geological units.     

Quaternary stratigraphy and geochemistry at the Owl Creek Gold Mine, Timmins, Ontario, Canada

The Owl Creek Gold Mine is located in Hoyle Township, approximately 18 km northeast of Timmins, Ontario, Canada. The open-pit mine exposes a sequence of altered and mineralized mafic tholeiitic volcanics bounded to the north and south by greywacke and argillite. Gold occurs in the free state in quartz veins, often with graphite, and as fine gold on surfaces of, and within fractures in, pyrite.The study was designed to determine the distribution and distance of transport of Au in overburden down-ice from subcropping Au mineralization. This required an understanding of the glacial history of the area.The Quaternary stratigraphy at Owl Creek was studied and sampled by means of 17 sonic and 15 reverse-circulation overburden drill holes near the open pit, and several overburden exposures in the open-pit walls. Nonmagnetic heavy-mineral concentrates (specific gravity >3.3) were made from the <2000 μm (−10 mesh) fraction of all overburden samples from the drill hole and section sampling. The heavy-mineral concentrates were analyzed for Au by neutron activation. A till pebble lithology study was done on the >2000 μm (−10 mesh) fraction of the sonic drill core.Our stratigraphic studies indicate that there were three major Wisconsinan (Weichselian) ice advances and one minor, late readvance in the Timmins area. The transport and deposition of sediments comprising the “Oldest”, “Older”, Matheson and Cochrane stratigraphic “packages” (oldest to youngest) are related to three ice advances and one readvance which moved towards 240° ± 10°, 150° ± 5°, 170° ± 5° and 130° ± 5°, respectively.Geochemically anomalous levels of Au in the overburden define two dispersal trains down-ice of the Owl Creek Gold Mine. One, in the “Older” lodgement till, is 400–500 m long. The other in Matheson ablation and waterlain tills, is approximately 700 m long.The till pebble lithology study showed that pebble counting can be used to approximate bedrock contacts, but may not necessarily identify the source rock type of the matrix.     

Mercury in lake sediments of the Precambrian Shield near Huntsville, Ontario, Canada

 Long sediment cores (>1 m) were collected from eight Precambrian Shield lakes in southern Ontario, Canada and analyzed for mercury (Hg), loss-on-ignition (LOI), and a suite of 36 other elements. Results indicated at least 100-fold variation in sediment Hg concentrations between lakes in close proximity (from 450 ppb), comparable to the variation reported for lakes across the whole of Canada. Strong areal correlations between Hg concentrations and LOI (r ² =0.77), between Hg and other trace element concentrations (Pb, Zn, Cd, Sb, As, Br), and similarities in the vertical concentration profiles of Hg and LOI, all point to the importance of organic matter in the release, transport and redistribution of metals in watershed systems. The spatial pattern of Hg concentrations in deep, precolonial sediments (>20 cm) was found to mirror the pattern of Hg concentrations in modern surface sediments, an observation that was confirmed in a follow-up survey (r ² =0.85;n=25 lakes), indicating that natural processes govern the unequal distribution of Hg among these lakes. Between-lake differences in surface sediment Hg concentrations normalized to organic carbon (Hg/C) were also reflected by Hg concentrations in smallmouth bass normalized to 35 cm length (R ² =0.63;n=15 lakes). The latter relationship suggests that smallmouth bass and lake sediment indicators provide mutually supportive information regarding Hg loading to the lacustrine environment from geological sources in the watershed system. Received: 31 October 1996 · Accepted: 27 May 1997     

Indicator mineralogy of kimberlite boulders from eskers in the Kirkland Lake and Lake Timiskaming areas, Ontario, Canada

Sixteen kimberlite boulders were collected from three sites on the Munro and Misema River Eskers in the Kirkland Lake kimberlite field and one site on the Sharp Lake esker in the Lake Timiskaming kimberlite field. The boulders were processed for heavy-mineral concentrates from which grains of Mg-ilmenite, chromite, garnet, clinopyroxene and olivine were picked, counted and analyzed by electron microprobe. Based on relative abundances and composition of these mineral phases, the boulders could be assigned to six mineralogically different groups, five for the Kirkland Lake area and one for the Lake Timiskaming area. Their indicator mineral composition and abundances are compared to existing data for known kimberlites in both the Kirkland Lake and Lake Timiskaming areas. Six boulders from the Munro Esker form a compositionally homogeneous group (I) in which the Mg-ilmenite population is very similar to that of the A1 kimberlite, located 7–12 km N (up-ice), directly adjacent to the Munro esker in the Kirkland Lake kimberlite field. U–Pb perovskite ages of three of the group I boulders overlap with that of the A1 kimberlite. Three other boulders recovered from the same localities in the Munro Esker also show some broad similarities in Mg-ilmenite composition and age to the A1 kimberlite. However, they are sufficiently different in mineral abundances and composition from each other and from the A1 kimberlite to assign them to different groups (II–IV). Their sources could be different phases of the same kimberlite or—more likely—three different, hitherto unknown kimberlites up-ice of the sample localities along the Munro Esker in the Kirkland Lake kimberlite field. A single boulder from the Misema River esker, Kirkland Lake, has mineral compositions that do not match any of the known kimberlites from the Kirkland Lake field. This suggests another unknown kimberlite exists in the area up-ice of the Larder Lake pit along the Misema River esker. Six boulders from the Sharp Lake esker, within the Lake Timiskaming field, form a homogeneous group with distinct mineral compositions unmatched by any of the known kimberlites in the Lake Timiskaming field. U–Pb perovskite age determinations on two of these boulders support this notion. These boulders are likely derived from an unknown kimberlite source up-ice from the Seed kimberlite, 4 km NW of the Sharp Lake pit, since indicator minerals with identical compositions to those of the Sharp Lake boulders have been found in till samples collected down-ice from Seed. Based on abundance and composition of indicator minerals, most importantly Mg-ilmenite, and supported by U–Pb age dating of perovskite, we conclude that the sources of 10 of the 16 boulders must be several hitherto unknown kimberlite bodies in the Kirkland Lake and Lake Timiskaming kimberlite fields.     

The contribution of rain-on-snow events to annual NO3-N export from a forested catchment in south-central Ontario,Canada

The contribution of rain-on-snow (ROS) events to NO₃-N levels in stream water has received relatively little research attention. However, individual ROS events during January and February contributed up to 40% of annual NO₃-N export from a forested catchment in south-central Ontario between 1980 and 2000, but comprised less than 10% of annual precipitation. Nitrate-N concentrations in stream water increased rapidly following ROS events, and were similar to the concentrations in incident rainfall and the accumulated snow pack, likely due to limited contact of runoff with mineral soil under snow cover and low winter biological activity. Increased NO₃-N associated with ROS events resulted in substantial depressions in stream pH and alkalinity, which may delay the biological recovery from acidification. The contribution of ROS events to annual or winter NO₃-N export has been generally greater in recent years, although there is a considerable year-to-year variation. As a result, ROS events contribute to inter-annual variability in stream NO₃-N concentrations and will have a strong effect on apparent temporal trends. The contribution of ROS events to annual NO₃-N export should be considered when assessing surface water recovery from acidification and the N-status of forests, particularly if climate change projections for winter warming result in a greater proportion of winter precipitation occurring as rain.     

Anthropogenic impact on sediment composition and geochemistry in vertical overbank profiles of river alluvium from Belgium and Luxembourg

The geochemical study of alluvial sediments allows to reconstruct pollution through time. Geochemical and sedimentological variations recorded in 40 vertical overbank sediment profiles from Belgium and Luxembourg can be classified in three dominant pattern types:• type 1 profiles with dominantly non-anthropogenically influenced geochemical distribution patterns. These profiles are devoid of anthropogenic particles such as charcoal, plastic, brick and slag fragments, with the exception, in some cases, of their uppermost parts. Background concentrations thus are displayed throughout the profile (subtype 1A). However, in this group, profiles displaying anomalous values caused by the presence of heavy minerals (subtype 1B) or by base metal mineralisations in the catchment (subtype 1C) also occur;• type 2 profiles displaying clear evidence of anthropogenic influences. Most of these profiles display a gradual increase in heavy metal content in their upper part, with values doubling or tripling (subtype 2A). However, other profiles display a dramatic increase in pollution-related elements caused by past or present-day heavy industrial activities in the catchment (subtype 2B). Here also the sedimentological patterns reflect the influence of the industrial activities;• type 3 profiles contain features related to pedogenetic translocations of mobile elements. Apart from classical pedogenetic features such as illuviation/eluviation, the mobility of As and Cd is of particular importance. From a sedimentological point of view, these profiles do not necessarily differ from type 1 or 2 profiles.It should be noted that in some profiles, pattern types can be superimposed. Type 2B profiles are of particular environmental concern, because the potential release of heavy metals may have consequences for agricultural activities or groundwater contamination in the catchment. Furthermore, reworking of polluted sediments temporarily stored in the alluvial plain can also have negative effects on the ecosystem.     

Natural and anthropogenic influences on the geochemistry of Quaternary lake sediments from Holzmaar, Germany

 The accumulation of heavy metals and trace elements has been investigated in a well laminated sequence of Holocene and late Pleistocene lake sediments composed of diatomaceous gyttja, tuff and silt and clay sediments. Varve chronology of the annually deposited gyttja yielded a continuous high-resolution time sequence and allowed the absolute age dating of the sediment. Fluxes of elements remained largely uniform from the late Pleistocene into the Holocene (12 867–2 364 VT years ago; VT: varve time, years before 1950). Higher trace element and heavy metal fluxes occur from 2 322 to 862 VT years ago and reached their maxima in the uppermost sediments (<845 VT years ago). These increasing element fluxes correlate with increasing inputs of clastic material. The changing accumulation rates are the result of elevated soil erosion in the lake catchment caused by human settlement, deforestation and agricultural activities. Thus disturbances of the natural geochemical cycles of the Holzmaar region have occurred since the beginning of the Iron Age and especially since the beginning of the Middle Ages. Received: 29 May 1996 · Accepted: 19 August 1996     

Late quaternary stratigraphy and geochemistry of the R47 section,Rouge River Basin,south-central Ontario,Canada: Correlation with Scarborough Bluffs

Quaternary glacial diamictons in section R47, overlying Ordovician shale in the Rouge River Basin of south-central Ontario, are considered to be representative of older and younger Wisconsinan glacial diamictons in the field area. Field characteristics, clast composition, mineralogy, particle size and geochemistry permit delineation of two units within the sequence and subdivision of deposits that correlate with Sunnybrook and Halton diamictons of Wisconsinan age. No Wisconsinan interstadial deposits are present in the section; however, outwash sandy gravel capping the Halton diamicton was probably emplaced by a high-energy stream draining into Lake Iroquois just prior to the incision of the Rouge Valley in the later Wisconsinan (ca. 11 000-12 000 yr BP). A buried palaeosol, which developed in this sandy gravel and in overlying aeolian sediment, shows partial leaching of carbonates and a slight increase of clay in the palaeosol solum. The main clay-mineral transformations in the buried palaeosol appear to involve the degradation of illite and illite-smectite accompanied by the production of vermiculite and minor amounts of chlorite. The ground soil capping the buried palaeosol is formed in colluvium emplaced 200 ± 80 yr BP following a local forest fire; the ground soil Ahk horizon gives an age of 4000 yr in the future, probably as a result of nuclear bomb testing effects on modern radiocarbon. The presence of an A/C profile in the ground soil system, although thin, indicates that surface soils may form rapidly. The geochemistry of the two Wisconsinan diamictons shows similar calcite and SiO₂-corrected mean element concentrations, with slightly elevated levels of Ca, Sr, Hf and Lu in the younger deposit. Both diamictons are geochemically quite different from the shale bedrock in the area, indicating that the bulk of transported sediment came from outside the area.     

Organic geochemistry of impactites from the Haughton impact structure, Devon Island, Nunavut, Canada

Organic matter in impactites from the 24 km wide and 39 Ma old Haughton impact structure, Canadian High Arctic, is a mixture of fossil and modern biological components. The fossil component represents a conventional oil that was generated from Lower Palaeozoic marine source material before impact and permeates bedrock dolomites. Biomarker maturity parameters record the thermal effect of the mid-Tertiary impact. Maturity-influenced sterane, rearranged hopanoid, and triaromatic steroid ratios all increase towards the centre of the impact structure, where thermal alteration was greatest. The heating was probably dominated by an impact-related hydrothermal system, as such systems last long enough for kinetically-based thermal alteration to occur. Kinetically-related biomarker data suggest that the hydrothermal heating lasted for c. 5000 years. Biomarkers are also preserved in dolomite clasts within impact melt breccia, and indicate strong thermal alteration. Modern biological contamination of the rocks is responsible for the superposition of two geochemical signatures (which could be cyanobacteria, non-marine algae, or higher plant matter) onto the fossil component, but they can be recognized and distinguished. The data show that the impact structure system holds a record of both the pre-impact organic signature and the thermal signature of the impact, and thereby indicates that organic geochemistry is a valuable tool in documenting the response of rocks to impacts.     

Correlation between the rainfall,sediment recharge,and triggering of torrential flows in the Rebaixader catchment (Pyrenees,Spain)

The debris flow (DF) and debris flood (DFD) activity in the Rebaixader catchment (Spanish Pyrenees) is analyzed in this study. The research is focused on how precipitation leads to the triggering of torrential floods and influences the sediment availability during the recharge period, in a supply-unlimited catchment. Two kinds of correlations are studied: (1) the correlation between the rainfall features (intensity and kinetic energy) and the DF/DFD triggering and (2) the correlation between the hyetograph and the DF/DFD volumes. The tested hypothesis was that a greater amount of rainfall during the recharge period would produce a greater DF/DFD volume. The period between two consecutive DF/DFD events is processed using a variable, the Erosion Index, originally developed for the Universal Soil Loss Equation. This analysis considered the rainfall time series and 22 DF/DFD events registered during the period 2009–2015. The results show that the precipitation of the recharge period does not seem to have a strong influence on the mobilized volumes. In many cases, a second DF/DFD event was triggered soon after the previous event, which highlighted the role of the first event in creating an unstable state of the catchment. Additionally, a threshold relationship between the kinetic energy of the rainfall event and the maximum rainfall intensity for a 30-min period seems to be a good criterion to discriminate between triggering and non-triggering rainfall events. The results show no clear trends with which to forecast the sediment volume from precipitation, weakening the role of rainfall characteristics in determining the return period of mobilized sediment volumes in catchments similar to the Rebaixader torrent.     

Trace element geochemistry in the waters of Pulicat lake,South India

The distribution of trace elements like Cu, Zn, Ni, Co and Mn in the waters of Pulicat lake has been studied in four aqueous environments — northern, central, southern and channel parts. It is observed that the concentration of the trace elements increase with increase of pH, chlorides and sodium in both monsoon and dry seasons. The concentration and the behaviour of the trace elements are controlled by adsorption, supplemented by organic reactions and by precipitation in sulphide-rich environments.     

On the origin and age of the Steep Rock buckshot, Ontario, Canada

The Steep Rock buckshot is a brecciated pisolithic ferruginous bauxite found in the Errington iron mine, Steep Rock Lake, Ontario, Canada. It occurs within the almost vertical ore zone included in the Archean Steep Rock Group, reaching a depth in excess of 1100 ft. (335 m). Successive authors considered its age as Precambrian. The biological observations now presented deny this supposed Precambrian age. Treatment of the concretions by HCI, followed by staining, put in evidence abundant microscopic figurate animal and vegetal remains, namely shreds of insect integument and varied fragments of vascular plant material. Comparable results were obtained by casting and by scanning electron miscroscopy (SEM) of the surface of the concretions and by thin sections. All these remains are Phanerozoic and one of them is probably not anterior to the Late Cretaceous. The macro- and micromorphology of the concretions obey models of termite constructions and the spectrum of organic remains is identical to the one found in tubulo-alveolar laterites and in termite constructions. The presence in the matrix of canaliculi attributable to thin roots gives force to the idea that the buckshot was originated near the soil surface.     

The relationship between length and width of plutons within the crustal-scale Cobequid Shear Zone, northern Appalachians, Canada

The lengths and widths have been measured for 69 component bodies of composite plutons along the Cobequid Shear Zone. Plutons on major fault strands, those with mylonite zones >0.1 km wide, exhibit evidence of multiple intrusion of magma batches. Small plutons along short faults in stepover zones appear related to rapid emplacement of magma in bodies 1.5–4 km long by 0.1–2 km wide. Such small plutons show low enrichment in incompatible elements in older component bodies, but increasing amounts in younger bodies as a result of progressive magma expulsion from crystal mush during crystallization and shear-enhanced compaction in fault zones. Wider plutons generally occur along longer fault strands accommodating more strain and penetrating deeper into the crust and show enrichment in incompatible elements. The width of the mylonitic fault zone is about 15% of the width of these plutons. The length-to-width ratio of component bodies and composite plutons varies between 2 and 11. The best-fit line describing these data has a slope of 1.056, which implies scaling behavior between plutonism and tectonic processes. Scalar properties of plutonic bodies are similar to those of faults, but scalar relationships observed in component bodies do not apply to composite plutons.     

Late Quaternary sediment, sediment mass flow processes and slope stability on the Scotian Slope, Canada

The study area, just to the west of the Verrill Canyon on the Scotian Slope, eastern Canada, exhibits both large and small scale sediment mass movement features. Study of high resolution seismic reflection and sidescan sonar data shows that a large portion (approximately 70%) of the near surface sediment (<20 m) in the area has undergone erosion, rotational slumping and internal deformation. Remoulded sediment observed in physical properties profiles of piston cores and sediment deformation structures are further evidence of slumping. Small scale mass flow events are recorded by abundant turbidites and debris flow deposits noted in piston cores. Sediment physical properties are highly dependent on sediment type (lithofacies). Frequent facies changes, both temporally and spatially, make correlation between cores difficult. Although the small scale mass movement events correlate with glacial recession on the continental shelf and lower relative sea levels, the triggering mechanisms for the large scale events are less obvious. Slope stability analyses indicate that, at present, the seabed is stable. The most plausible explanation for large scale slope failures in this region are ground accelerations related to earthquake shock. Our analyses demonstrate that it is unlikely that large magnitude, distant earthquakes, such as those previously proposed in the Laurentian Slope Seismic Zone (LSP) model, could initiate failure of sediment in the study region. Our data support the interpretation that more frequent, lower magnitude earthquakes, closer to the study region, as previously proposed in the Eastern Slope Experimental Source Zone (ESX) model, are the likely causes of large scale slope failures. Furthermore, excess pore pressures resulting from shallow gas and/or high sedimentation rates during deglaciation contribute to slope failure.     

The geochemistry of selenium associated with coal waste in the Elk River Valley,Canada

Selenium (Se) concentrations more than 12 times greater than the provincial freshwater quality guideline (2 µg/L) were detected in the Elk River downstream from the five open-pit coal mines in southeastern British Columbia's Elk River Valley. To identify possible sources of Se to the Elk River, samples from the coal-bearing Mist Mountain Formation were studied using X-ray diffraction, elemental and oxide analyses, sequential extractions and heavy liquid separation. Between 2.5 and 21.3% of the total Se in the five types of materials studied is water-soluble and 1.0 to 10.6% is associated with hydrous ferric and manganese oxides. Se associated with sulphides and organic material varies between 60 and 84% of the total Se and Se in the silicate structure varies from 5.9 to 24.7%. The ratio of sulphides to the total of organic carbon is well-correlated with the amount of Se in materials closely associated with coal seams containing less than 6 mg/kg of Se (r=0.916). This may suggest that the amount of organic matter present during deposition affects the amount of Se incorporated into sulphides.     

Light hydrocarbons geochemistry of surface sediment from petroliferous region of the Mehsana block,North Cambay Basin

A study was carried out to test the usefulness of surface geochemical methods as regional evaluation tools in petroliferous region of the Mehsana block, North Cambay Basin. A suite of 135 soil samples collected from the depth of 2.5 m, were analyzed for adsorbed light gaseous hydrocarbons and carbon isotopes (δ¹³C_methane and δ¹³C_ethane). The light gaseous hydrocarbon analysis show that the concentration ranges 402 ppb, 135 ppb, 70 ppb, 9 ppb and 18 ppb of C₁, C₂, C₃, iC₄ and nC₄, respectively. The value of carbon isotopic ranges of methane −29.5 to −43.0‰ (PDB) and ethane −19.1 to −20.9‰ (PDB). This data, when mapped, indicates patterns coinciding with major known oil and/or gas field of Sobhasan/Linch in this study area. The existence of un-altered petroliferous microseeps of catagenetic origin is observed in the study area. A regional study, such as the one described here, can provide important exploration facts concerning the regional hydrocarbon potential in a block. This method has been confirmed and can be applied successfully in frontier basins.