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敏化TiO2纳米晶太阳能电池 总被引:28,自引:3,他引:25
介绍了敏化TiO2纳米晶太阳能电池的工作原理和表征方法,并对常用的制备工艺,敏化剂的选择,目前达到的水平进行了综述,在此基础上提出了一些值得深入研究的问题。 相似文献
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敏化TiO2纳米晶多孔膜电极的制备与表征 总被引:9,自引:1,他引:9
研究了染料敏化TiO2纳米晶多孔薄膜电极的制备、表征及其光电转换性质,采用溶胶-凝胶法液压涂层制备了TiO2纳米晶多孔薄膜,在无水乙醇中利用薄膜吸附染料2,2′-联吡啶-4,4′-二甲酸合硫氰酸钌进行敏化处理,并利用XPS、AFM、XRD、SEM杉可见-紫外分光光度仪对敏化TiO2纳米晶多孔薄膜进行了表征分析。研究结果表明:薄膜中纳米粒子晶型主要为锐钛矿,粒径在20-30nm,多孔薄膜的孔径在50-200nm;染料敏化多孔薄膜表面吸附了一个单分子层的染料分子,敏化薄膜对可见光有很强的吸收作用,用此薄膜制作的太阳能电池具有较高的光电转化效率,电池效率达到2%,这种薄膜电极改进后可用于制作敏化太阳能电池的光阳极。 相似文献
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采用水相共沉积法制备Ag2Se量子点(QDs), 并与染料共敏化制备固态染料敏化太阳能电池(DSSCs)。考察了Ag2Se量子点不同敏化方式(TiO2/N719/QDs, TiO2/QDs/N719)及敏化时间(0~5 h)对DSSCs性能的影响。通过透射电子显微镜(TEM)和紫外-可见光谱图(UV-Vis)对Ag2Se量子点结构及光学性质进行了表征; 采用光调制光电流/电压谱(IMPS/VS)以及交流阻抗谱(EIS)对器件中载流子传输过程进行了研究。TiO2/QDs/N719的电池器件比TiO2/ N719/QDs具有更高的单色光量子转化效率(IPCE)及光电转化效率, 这是由于TiO2/QDs/N719可以吸附更多的量子点和染料。随着Ag2Se量子点敏化时间的延长, 光电转化效率先提高后降低, 最高达到3.97%。Ag2Se量子点在器件中起到了阻挡层作用, 可以促进电子传输, 抑制电子-空穴复合。而随着量子点敏化时间超过2 h, 电子陷入陷阱的几率增加, 导致器件的光伏性能下降。 相似文献
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以商业TiO2纳米粉(P25)为原料,将其充分研磨得到胶体,用刮涂和热处理的方法在氟掺杂氧化锡导电玻璃基底上制备TiO2纳米多孔薄膜阳极,并组装成染料敏化太阳能电池(DSSC).对TiO2膜进行X射线衍射、扫描电镜表征分析,并对所制备的DSSC进行光电性能测试.采用正交实验设计优化制备TiO2胶体时乙酰丙酮、OP乳化剂、蒸馏水的量和研磨时间,并讨论其对DSSC性能的影响.用在最优参数下所得胶体制备的DSSC的光电转换效率最高,约为4.51%. 相似文献
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采用连续离子层吸附反应法(SILAR)在TiO2/FTO电极上沉积SnS, 组装结构为FTO/TiO2/SnS/ P3HT:PCBM/Ag的多层异质结太阳能电池, 结果显示: SnS掺杂能显著提高P3HT/PCBM体系太阳能电池的光电转化性能。通过SEM观察、UV-Vis光谱、J-V曲线、Raman光谱以及射频辉光放电光谱仪(GD-OES)等手段, 系统研究了不同前驱体液浓度制备的SnS对电池的影响, 发现当n(Sn2+):n(S2-)为1:1.5时, 电池的光电转化效率最高, 达到0.369%, 其开路电压、短路电流和填充因子分别达到0.373 V、1.92 mA/cm2和51.2%。另外, GD-OES谱图显示前驱体溶液中Sn2+/S2-比例对于SnSx层的化学组成及沉淀量具有重要影响, 从而导致复合太阳能电池光电性能的显著变化。 相似文献
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为有效解决染料敏化太阳能电池(DSSC)的固态电解质与光阳极界面接触差的问题,文中采用化学原位聚合法在染料敏化TiO2光阳极表面制备聚苯胺(PANI)导电膜,研究了PANI成膜的最佳工艺参数。通过微观形貌观察及电导率测试说明,低温条件用樟脑磺酸(CSA)掺杂PANI薄膜颗粒细小均匀,电导率高达6.297S/cm。红外光谱分析表明,用CSA掺杂PANI较盐酸掺杂的电荷离域更充分,掺杂效果更好。PANI/Dye-TiO2复合膜在可见光区的吸收峰增多,吸收频带增宽;最后通过DSSC电池性能测试得到以PANI为电解质的DSSC较液态DSSC开路电压高,短路电流低的结果。 相似文献
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Performance and Stability of Lead Perovskite/TiO2, Polymer/PCBM,and Dye Sensitized Solar Cells at Light Intensities up to 70 Suns 下载免费PDF全文
Chunhung Law Lukas Miseikis Stiochko Dimitrov Pabitra Shakya‐Tuladhar Xiaoe Li Piers R. F. Barnes James Durrant Brian C. O'Regan 《Advanced materials (Deerfield Beach, Fla.)》2014,26(36):6268-6273
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采用较高粘度的有机溶液作为阳极氧化电解质溶剂制备了TiO2纳米管阵列. 通过探讨阳极氧化工艺参数对纳米管形貌的影响, 研究出高长径比TiO2纳米管阵列的制备工艺, 同时对TiO2纳米管作为染料敏化太阳能电池光阳极的光电性能进行了测试, 并讨论了TiO2纳米管的形貌对电池性能的影响. 结果表明:提高氧化电压和延长时间有利于获得高长径比纳米管, 在含0.5wt%NH4F乙二醇电解质中50V氧化17h可制备出长径比为313.6的TiO2纳米管阵列. TiO2纳米管(在含0.5wt%NH4F乙二醇电解质中40V氧化13h)作为染料敏化太阳能电池光阳极可得到开路电压为0.723V、短路电流为2.15mA/cm2的光电性能. 相似文献
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分别以气煤、焦煤、瘦煤为原料制备了低成本、高性能煤基炭对电极(counter electrodes, CEs), 并使用煤基炭CE同时代替导电玻璃基底和催化层, 分别考察了浸渍和表面修饰对煤基炭CE结构和光电性能的影响。采用X射线衍射、扫描电镜和电化学阻抗谱等表征手段, 对煤基炭CE的结构和性能进行了表征。结果表明: 浸渍后煤基炭CE形成了底层致密表层多孔的一体化结构; 经过表面修饰的煤基炭CE表现出良好的光电性能, 其开路电压(Voc)、短路电流密度(Jsc)和填充因子(FF)分别为0.79 V、13.48 mA/cm2和0.67, 光电转化效率(η)达到了7.16%, 与传统Pt电极的效率相当, 比石墨电极效率提高30%。煤基炭CE是传统Pt/FTO电极的良好替代材料。 相似文献
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In this communication,the synthesis and structural,morphological,optical,and photo-electrochemical properties of TiO_2 and CaCO_3/TiO_2 nanoparticles as well as their applications in dye sensitized solar cells(DSSCs),have been reported.In an X-ray diffraction pattern of CaCO_3/TiO_2 nanoparticles,the peak at 29.41°of CaCO_3 has been detected,demonstrating its coating on the surface of TiO_2,which is further verified using high resolution-transmission electron microscopy,energy dispersive X-ray spectroscopy and Fourier transform infrared spectroscopy.The strong quenching in photoluminescence emission,in the case of CaCO_3/TiO_2nanoparticles,has been attributed to the decrease in recombination rate of photo-generated electron—hole pairs.In the case of UV—visible reflectance spectra,the absorption edge for CaCO_3/TiO_2 nanoparticles has slightly been found to be blue-shifted as compared to bare TiO_2 nanoparticles,which corresponds to an increase in energy band gap of the former.The dye desorption studies reveal that CaCO_3/TiO_2 electrodes adsorbed more dye than the bare TiO_2 electrode.CaCO_3/TiO_2 based DSSC show improved photoelectrochemical properties compared to the bare TiO_2 based DSSC as CaCO_3 coating on TiO_2 forms an energy barrier,and,consequently suppressing the charge recombination,and,thus,improving the overall energy conversion efficiency(η) from 0.46%to 1.44%under the illumination of simulated light of 100 mW/cm~2. 相似文献
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Sanjivani V. Umale Sneha N. Tambat Vediappan Sudhakar Sharad M. Sontakke Kothandam Krishnamoorthy 《Advanced Powder Technology》2017,28(11):2859-2864
In this study, anatase TiO2 nanoparticles were synthesized by three techniques, namely, sol–gel, acid-base co-catalyst and room temperature colloidal methods. The synthesized materials were characterized by X-ray diffraction, scanning electron microscopy, pore diameter, pore volume and surface area. The dye-sensitized solar cells were fabricated using the synthesized materials and characterized for incident photon to current conversion efficiency, photocurrent density to photo voltage measurement and electrochemical impedance analysis. Among the studied materials, TiO2 synthesized by sol–gel method displayed highest photon to current conversion of 76.8% and a maximum solar cell efficiency of 7.85% with Jsc of 14.75 mA/cm2, Voc of 0.76 V and FF of 0.7. This is the first study to report a high power conversion efficiency of DSSC using a sol–gel synthesized titania and its comparison with other two synthesized materials. The high power conversion efficiency of the solar cell using TiO2 synthesized by sol–gel method is attributed to its characteristic properties such high surface area, larger pore diameter and larger pore volume and highest dye loading capacity. 相似文献